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    • 1. 发明授权
    • Extraction of pre-reduced lateritic ores with aqueous sulphuric acid in
the presence of peroxidant
    • 在过氧化物存在下用硫酸水溶液萃取预还原的红土矿石
    • US4301125A
    • 1981-11-17
    • US60762
    • 1979-07-26
    • Alfred R. BurkinAndrew J. Monhemius
    • Alfred R. BurkinAndrew J. Monhemius
    • B01D11/02C22B3/00C22B23/00E21C20060101C22B23/04
    • C22B23/043C22B23/0461
    • In a process according to the present invention pre-reduced lateritic ores containing iron and nickel are leached with an aqueous sulphuric acid leach liquor containing or into which is introduced in the presence of the ore a peroxidant selected from hydrogen peroxide and peroxymonosulphuric acid. By so doing, the liquor is obtained with a lower concentration of iron than if the peroxidant had not been employed.In preferred embodiments the leaching is carried out at from 40.degree. to 70.degree. C. for a period of 1 to 5 hours; when hydrogen peroxide is used, it is preferably introduced continuously or progressively throughout the reaction period and when peroxymonosulphuric acid is used it is preferably introduced initially. The acidity of the liquor can be reduced at the end of the reaction to pH3 to 4 to further lower the content of iron in solution.
    • 在根据本发明的方法中,含有铁和镍的预还原红土矿用含有硫酸浸出液浸出,所述硫酸浸出液在矿石存在下引入选自过氧化氢和过氧单硫酸的过氧化物。 通过这样做,与未使用过氧化物相比,获得的铁浓度较低。 在优选的实施方案中,浸出在40℃至70℃下进行1至5小时; 当使用过氧化氢时,优选在整个反应期间连续地或逐渐引入,并且当使用过氧单硫酸时,优选最初引入。 在反应结束时,液体的酸度可以降低至pH3至4,以进一步降低溶液中铁的含量。