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1. 发明授权

US09321037B2 Hydroprocessing co-catalyst compositions and methods of introduction thereof into hydroprocessing units 有权
标题翻译：加氢处理助催化剂组合物及其引入加氢处理装置的方法
公开(公告)号：US09321037B2
公开(公告)日：2016-04-26
申请号：US13715918
申请日：2012-12-14
申请人： Julie Chabot , Bo Kou , Alexander Kuperman
发明人： Julie Chabot , Bo Kou , Alexander Kuperman
IPC分类号： B01J8/20 , B01J23/78 , B01J23/28 , B01J23/30 , B01J23/75 , B01J23/755 , B01J35/00 , B01J23/85 , B01J31/02 , B01J35/02 , B01J37/00 , B01J31/04 , B01J31/06 , C10G45/08 , C10G45/16 , B01J37/04 , B01J21/02 , B01J21/06 , B01J21/10 , B01J21/12
CPC分类号： B01J23/78 , B01J21/02 , B01J21/06 , B01J21/10 , B01J21/12 , B01J23/28 , B01J23/30 , B01J23/75 , B01J23/755 , B01J23/85 , B01J31/0247 , B01J31/04 , B01J31/06 , B01J35/0006 , B01J35/023 , B01J37/0036 , B01J37/04 , C10G45/08 , C10G45/16 , C10G2300/1033 , C10G2300/202
摘要： A hydroprocessing co-catalyst composition may comprise in an embodiment a first component comprising co-catalyst particles and a liquid carrier, and a second component comprising a dispersant and a dispersant diluent. The co-catalyst particles may be in the micron size range, and the dispersant may promote dispersion of the co-catalyst particles in materials such as the liquid carrier, the dispersant diluent, and combinations thereof. Methods of introducing a hydroprocessing co-catalyst composition into a hydroprocessing system are also disclosed.
摘要翻译：加氢处理助催化剂组合物可以在一个实施方案中包括包含助催化剂颗粒和液体载体的第一组分，和包含分散剂和分散剂稀释剂的第二组分。助催化剂颗粒可以在微米尺寸范围内，并且分散剂可以促进助催化剂颗粒在诸如液体载体，分散剂稀释剂及其组合的材料中的分散。还公开了将加氢助催化剂组合物引入加氢处理系统的方法。

2. 发明授权

US09243016B2 Synthesis and characterization of open metal clusters 有权
标题翻译：开放金属簇的合成与表征
公开(公告)号：US09243016B2
公开(公告)日：2016-01-26
申请号：US14034406
申请日：2013-09-23
申请人： Alexander S. Katz , Alexander Kuperman , Alexander Okrut , Ron C. Runnebaum , Xiaoying Ouyang
发明人： Alexander S. Katz , Alexander Kuperman , Alexander Okrut , Ron C. Runnebaum , Xiaoying Ouyang
IPC分类号： C07F15/00 , B01J31/24 , C01G55/00 , B01J31/06 , B01J31/16 , B01J31/20
CPC分类号： C07F15/0033 , B01J31/066 , B01J31/1616 , B01J31/1683 , B01J31/20 , B01J31/24 , B01J31/2404 , B01J31/2457 , B01J37/08 , B01J37/12 , B01J2231/645 , B01J2531/0211 , B01J2531/0288 , B01J2531/827 , C01G55/008 , C07C5/03 , C07C2531/24 , C07F15/004
摘要： The present invention is directed to the synthesis of novel stable open metal clusters by selective oxidation of bound ligands. The synthesis comprises, for example, using an amine based oxidant for decarbonylation of specific carbonyl ligands. The synthesis can also comprise further removal of a bound amine group by an acid. The resulting metal cluster contains a coordinatively unsaturated site comprising a carbonyl vacancy. The resulting metal cluster can be used as a catalyst in a variety of chemical transformations.
摘要翻译：本发明涉及通过选择性氧化结合的配体合成新的稳定的开放金属簇。合成包括例如使用胺基氧化剂来脱羰特定的羰基配体。合成还可以包括通过酸进一步除去结合的胺基。所得金属簇含有包含羰基空位的配位不饱和位点。所得到的金属簇可以用作各种化学转化中的催化剂。

3. 发明申请

US20150266796A1 PARAFFINIC JET AND DIESEL FUELS AND BASE OILS FROM VEGETABLE OILS VIA A COMBINATION OF HYDROTREATING, PARAFFIN DISPROPORTIONATION AND HYDROISOMERIZATION 审中-公开
标题翻译：通过加氢，分离分解和水解的组合，来自植物油的PARAFFINIC喷射和柴油燃料和基础油
公开(公告)号：US20150266796A1
公开(公告)日：2015-09-24
申请号：US14729831
申请日：2015-06-03
申请人： Cong-Yan CHEN , Dennis John O'REAR , Thomas Francis FINGER , Stephen Joseph MILLER , Alexander KUPERMAN
发明人： Cong-Yan CHEN , Dennis John O'REAR , Thomas Francis FINGER , Stephen Joseph MILLER , Alexander KUPERMAN
IPC分类号： C07C6/04 , C07C5/27 , C10L1/08 , C07C5/03 , C10L1/04 , C10G3/00 , C07C5/333
CPC分类号： C07C6/04 , B01J23/30 , B01J23/58 , B01J23/6527 , B01J35/0006 , B01J37/0201 , C07C5/03 , C07C5/2775 , C07C5/333 , C07C6/00 , C07C6/02 , C07C6/08 , C07C2523/652 , C07C2529/85 , C10G3/42 , C10G3/44 , C10G3/47 , C10G3/48 , C10G3/50 , C10G2300/1011 , C10G2300/1014 , C10G2300/1018 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/10 , C10L1/04 , C10L1/08 , C10L2200/0469 , C10L2270/026 , C10L2270/04 , Y02P30/20
摘要： The present invention relates to a new process which comprises the steps of hydrotreating, paraffin disproportionation and hydroisomerization to convert biological hydrocarbonaceous oxygenated oils comprising triglycerides into biologically-derived paraffinic jet/diesel fuels, solvents and base oils. A combination of conventional hydrogenation/dehydrogenation catalysts, such as Pt/Al2O3, and conventional olefin metathesis catalysts, such as WO3/SiO2, or inexpensive variations thereof, is generally employed in the paraffin disproportionation step.
摘要翻译：本发明涉及一种新方法，其包括加氢处理，石蜡歧化和加氢异构化以将包含甘油三酯的生物烃类含氧油转化为生物衍生的链烷烃喷射/柴油燃料，溶剂和基础油的步骤。常规的氢化/脱氢催化剂如Pt / Al 2 O 3和常规的烯烃复分解催化剂如WO 3 / SiO 2或其便宜的变体的组合通常用于石蜡歧化步骤。

4. 发明申请

US20140171299A1 HYDROPROCESSING CO-CATALYST COMPOSITIONS AND METHODS OF INTRODUCTION THEREOF INTO HYDROPROCESSING UNITS 有权
标题翻译：氢化催化剂组合物及其引入方法进入水解单位
公开(公告)号：US20140171299A1
公开(公告)日：2014-06-19
申请号：US13715943
申请日：2012-12-14
申请人： Julie Chabot , Bo Kou , Alexander Kuperman
发明人： Julie Chabot , Bo Kou , Alexander Kuperman
IPC分类号： B01J23/78 , B01J23/75 , B01J23/755 , B01J23/28 , B01J23/30
CPC分类号： B01J23/78 , B01J21/02 , B01J21/06 , B01J21/10 , B01J21/12 , B01J23/28 , B01J23/30 , B01J23/75 , B01J23/755 , B01J23/85 , B01J31/0205 , B01J31/0247 , B01J35/0006 , B01J35/023 , B01J37/0036 , B01J37/04 , C10G47/26 , C10G49/02 , C10G49/12
摘要： A hydroprocessing co-catalyst composition may comprise in an embodiment a first component comprising co-catalyst particles and a liquid carrier, and a second component comprising a dispersant and a dispersant diluent. The co-catalyst particles may be in the micron size range, and the dispersant may promote dispersion of the co-catalyst particles in materials such as the liquid carrier, the dispersant diluent, and combinations thereof. Methods of introducing a hydroprocessing co-catalyst composition into a hydroprocessing system are also disclosed.
摘要翻译：加氢处理助催化剂组合物可以在一个实施方案中包括包含助催化剂颗粒和液体载体的第一组分，和包含分散剂和分散剂稀释剂的第二组分。助催化剂颗粒可以在微米尺寸范围内，并且分散剂可以促进助催化剂颗粒在诸如液体载体，分散剂稀释剂及其组合的材料中的分散。还公开了将加氢助催化剂组合物引入加氢处理系统的方法。

5. 发明申请

US20140166541A1 HYDROPROCESSING CO-CATALYST COMPOSITIONS AND METHODS OF INTRODUCTION THEREOF INTO HYDROPROCESSING UNITS 审中-公开
公开(公告)号：US20140166541A1
公开(公告)日：2014-06-19
申请号：US13715959
申请日：2012-12-14
申请人： Julie Chabot , Bo Kou , Alexander Kuperman
发明人： Julie Chabot , Bo Kou , Alexander Kuperman
IPC分类号： C10G45/04
CPC分类号： C10G45/04 , C10G45/16
摘要： A hydroprocessing co-catalyst composition may comprise in an embodiment a first component comprising co-catalyst particles and a liquid carrier, and a second component comprising a dispersant and a dispersant diluent. The co-catalyst particles may be in the micron size range, and the dispersant may promote dispersion of the co-catalyst particles in materials such as the liquid carrier, the dispersant diluent, and combinations thereof. Methods of introducing a hydroprocessing co-catalyst composition into a hydroprocessing system are also disclosed.

6. 发明申请

US20070128100A1 METHOD FOR MAKING HYDROGEN USING A GOLD CONTAINING WATER-GAS SHIFT CATALYST 有权
标题翻译：使用含金属含水气体转移催化剂的氢气制备方法
公开(公告)号：US20070128100A1
公开(公告)日：2007-06-07
申请号：US11567893
申请日：2006-12-07
申请人： Alexander Kuperman , Michael Moir
发明人： Alexander Kuperman , Michael Moir
IPC分类号： B01J23/00
CPC分类号： B01J35/10 , B01J21/066 , B01J23/48 , B01J23/72 , B01J27/053 , B01J27/055 , B01J35/002 , B01J35/0066 , B01J35/1014 , B01J35/1019 , B01J37/0201 , B01J37/0207 , B01J37/0236 , B01J37/031 , C01B3/16 , C01B3/583 , C01B2203/0283 , C01B2203/0288 , C01B2203/044 , C01B2203/047 , C01B2203/1041 , C01B2203/1082 , C01B2203/1609 , H01M8/0612 , Y02P20/52 , Y02P70/56
摘要： The present invention relates to a method for making hydrogen comprising contacting in a water-gas shift reaction zone a feed comprising carbon monoxide and water under water-gas shift conditions with an effective catalytic amount of a catalyst comprising highly dispersed gold on a sulfated zirconia, and collecting from the water-gas shift reaction zone an effluent comprising hydrogen and carbon dioxide. The invention also provides a catalyst composition and a method of making the catalyst. A method of CO oxidation using the catalyst is also disclosed. In a specific embodiment the invention provides a method for carrying out the water-gas shift reaction in the fuel processor associated with a fuel cell.
摘要翻译：本发明涉及一种制造氢气的方法，包括在水煤气变换反应区中在水煤气变换条件下使含有一氧化碳和水的进料与有效催化量的包含高度分散的金的催化剂在硫酸化氧化锆上接触，并从水煤气变换反应区收集包含氢气和二氧化碳的流出物。本发明还提供催化剂组合物和制备催化剂的方法。还公开了使用该催化剂的CO氧化的方法。在具体实施方案中，本发明提供了一种在与燃料电池相关联的燃料处理器中进行水煤气变换反应的方法。

7. 发明授权

US07166146B2 Mixed matrix membranes with small pore molecular sieves and methods for making and using the membranes 有权
标题翻译：具有小孔分子筛的混合基质膜和制备和使用膜的方法
公开(公告)号：US07166146B2
公开(公告)日：2007-01-23
申请号：US10745992
申请日：2003-12-24
申请人： Stephen J. Miller , Alexander Kuperman , De Q. Vu
发明人： Stephen J. Miller , Alexander Kuperman , De Q. Vu
IPC分类号： B01D53/22
CPC分类号： B01D69/148 , B01D53/228 , B01D67/0079 , B01D71/028 , Y10S55/05
摘要： A mixed matrix membrane is provided which comprises a continuous phase organic polymer and small pore molecular sieves dispersed therein. The molecular sieves have a largest minor crystallographic free diameter of 3.6 Angstroms or less. When these molecular sieves are properly interspersed with a continuous phase polymer, the membrane will exhibit a mixed matrix membrane effect, i.e., a selectivity increase of at least 10% relative to a neat membrane containing no molecular sieves. Finally, methods for making and using such mixed matrix membranes to separate gases from a mixture containing two or more gases are also disclosed.
摘要翻译：提供了一种混合基质膜，其包含分散在其中的连续相有机聚合物和小孔分子筛。分子筛的最小次晶界自由直径为3.6埃或更小。当这些分子筛适当地散布有连续相聚合物时，膜将表现出混合的基质膜效应，即相对于不含分子筛的纯净膜的选择性增加至少为10％。最后，还公开了制造和使用这种混合基质膜从含有两种或多种气体的混合物中分离气体的方法。

8. 发明授权

US07138006B2 Mixed matrix membranes with low silica-to-alumina ratio molecular sieves and methods for making and using the membranes 有权
标题翻译：具有低二氧化硅 - 氧化铝比分子筛的混合基质膜以及制备和使用膜的方法
公开(公告)号：US07138006B2
公开(公告)日：2006-11-21
申请号：US10745976
申请日：2003-12-24
申请人： Stephen J. Miller , Alexander Kuperman , De Q. Vu
发明人： Stephen J. Miller , Alexander Kuperman , De Q. Vu
IPC分类号： B01D53/22
CPC分类号： B01D69/148 , B01D53/228 , B01D67/0079 , B01D71/024 , B01D71/025 , B01D71/028 , B01D71/06 , B01D71/64 , Y02C10/10 , Y10S55/05
摘要： A mixed matrix membrane is provided which comprises a continuous phase organic polymer and small pore alumina containing molecular sieves dispersed therein. The molecular sieves have a silica-to-alumina molar ratio of less than 1.0, more preferably, less than 0.3, and most preferably less than 0.1. In some cases, the molecular sieves have no appreciable amounts of silica. Exemplary compositions include aluminophosphates (AlPO) and silicoaluminophosphates (SAPO). When these molecular sieves are properly interspersed with a continuous phase polymer, the membrane will exhibit a mixed matrix membrane effect, i.e., a selectivity increase of at least 10% relative to a neat membrane containing no molecular sieves. The molecular sieves have pores with a largest minor crystallographic free diameter of 4.0 Angstroms or less. Finally, methods for making and using such mixed matrix membranes to separate gases from a mixture containing two or more gases are also disclosed.
摘要翻译：提供了一种混合基质膜，其包含连续相有机聚合物和分散在其中的分子筛的小孔氧化铝。分子筛的二氧化硅与氧化铝的摩尔比小于1.0，更优选小于0.3，最优选小于0.1。在某些情况下，分子筛没有明显量的二氧化硅。示例性组合物包括铝磷酸盐（AlPO）和硅铝磷酸盐（SAPO）。当这些分子筛适当地散布有连续相聚合物时，膜将表现出混合的基质膜效应，即相对于不含分子筛的纯净膜的选择性增加至少为10％。分子筛具有最小次晶界自由直径为4.0埃或更小的孔。最后，还公开了制造和使用这种混合基质膜从含有两种或多种气体的混合物中分离气体的方法。

9. 发明申请

US20060006102A1 Process for removing aluminum contaminants from fischer-tropsch feed streams using dicarboxylic acid 有权
标题翻译：使用二羧酸从费 - 托进料流中除去铝污染物的方法
公开(公告)号：US20060006102A1
公开(公告)日：2006-01-12
申请号：US10886320
申请日：2004-07-07
申请人： Alexander Kuperman , Lucy Bull , Dennis O'Rear , Donald Kuehne
发明人： Alexander Kuperman , Lucy Bull , Dennis O'Rear , Donald Kuehne
IPC分类号： C10G17/00
CPC分类号： C10G2/32 , C10G17/04
摘要： A process for removing aluminum contaminants from the product of a Fischer-Tropsch synthesis reaction wherein said contaminants comprise at least 1 ppm of aluminum expressed as elemental metal in aluminum-containing contaminants having an effective diameter of less than 1 micron, said process comprising the steps of (a) collecting the contaminated Fischer-Tropsch product from the Fischer-Tropsch reactor; (b) forming a mixture comprising the contaminated Fischer-Tropsch product, at least an equal molar amount of a dicarboxylic acid containing from 2 to about 8 carbon atoms based upon the amount of aluminum present, and sufficient water for the dicarboxylic acid to form hydrogen ions; (c) maintaining the mixture under pre-selected conditions for a time sufficient for the aluminum contaminant and the dicarboxylic acid to form an aluminum containing precipitate having an effective diameter of greater than about 1 micron; (d) passing the mixture of step (c) through a particulate removal zone capable of removing substantially all of the aluminum-containing precipitate; and (e) recovering from the particulate removal zone a Fischer-Tropsch product containing less than about 1 ppm total aluminum.
摘要翻译：一种从费 - 托合成反应产物中除去铝污染物的方法，其中所述污染物包含至少1ppm铝，其表示为元素金属，其含铝有机污染物的有效直径小于1微米，所述方法包括步骤（a）从费 - 托反应器收集受污染的费 - 托产品; （b）基于所存在的铝的量，形成包含受污染的费 - 托产物，至少等摩尔量的含有2至约8个碳原子的二羧酸的混合物，以及用于二羧酸形成氢的足够水离子（c）将混合物保持在预选条件下足以使铝污染物和二羧酸形成有效直径大于约1微米的含铝沉淀物的时间; （d）使步骤（c）的混合物通过能够去除基本上所有含铝沉淀物的颗粒去除区; 和（e）从颗粒去除区回收含有小于约1ppm总铝的费 - 托产品。

10. 发明授权

US09446998B2 Paraffinic jet and diesel fuels and base oils from vegetable oils via a combination of hydrotreating, paraffin disproportionation and hydroisomerization 有权
标题翻译：通过加氢处理，石蜡歧化和加氢异构化的组合，来自植物油的石蜡喷气和柴油燃料和基础油
公开(公告)号：US09446998B2
公开(公告)日：2016-09-20
申请号：US14729831
申请日：2015-06-03
申请人： Cong-Yan Chen , Dennis John O'Rear , Thomas Francis Finger , Stephen Joseph Miller , Alexander Kuperman
发明人： Cong-Yan Chen , Dennis John O'Rear , Thomas Francis Finger , Stephen Joseph Miller , Alexander Kuperman
IPC分类号： C07C6/00 , C07C6/02 , C07C6/08 , C07C5/03 , C10L1/08 , C10L1/04 , C07C5/333 , C07C6/04 , C10G3/00 , B01J23/652 , C07C5/27 , B01J35/00 , B01J23/30 , B01J23/58 , B01J37/02
CPC分类号： C07C6/04 , B01J23/30 , B01J23/58 , B01J23/6527 , B01J35/0006 , B01J37/0201 , C07C5/03 , C07C5/2775 , C07C5/333 , C07C6/00 , C07C6/02 , C07C6/08 , C07C2523/652 , C07C2529/85 , C10G3/42 , C10G3/44 , C10G3/47 , C10G3/48 , C10G3/50 , C10G2300/1011 , C10G2300/1014 , C10G2300/1018 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/10 , C10L1/04 , C10L1/08 , C10L2200/0469 , C10L2270/026 , C10L2270/04 , Y02P30/20
摘要： The present invention relates to a new process which comprises the steps of hydrotreating, paraffin disproportionation and hydroisomerization to convert biological hydrocarbonaceous oxygenated oils comprising triglycerides into biologically-derived paraffinic jet/diesel fuels, solvents and base oils. A combination of conventional hydrogenation/dehydrogenation catalysts, such as Pt/Al2O3, and conventional olefin metathesis catalysts, such as WO3/SiO2, or inexpensive variations thereof, is generally employed in the paraffin disproportionation step.
摘要翻译：本发明涉及一种新方法，其包括加氢处理，石蜡歧化和加氢异构化以将包含甘油三酯的生物烃类含氧油转化为生物衍生的链烷烃喷射/柴油燃料，溶剂和基础油的步骤。常规的氢化/脱氢催化剂如Pt / Al 2 O 3和常规的烯烃复分解催化剂如WO 3 / SiO 2或其便宜的变体的组合通常用于石蜡歧化步骤。

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