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    • 3. 发明授权
    • Three-dimensional electrode (Law464)
    • 三维电极(Law464)
    • US5911859A
    • 1999-06-15
    • US900390
    • 1997-07-15
    • Mark Alan GreaneyPaul James Polini
    • Mark Alan GreaneyPaul James Polini
    • H01M4/02C10G32/02C25B11/02C25B11/00
    • C10G32/02C25B11/02
    • The invention provides a working electrode for use in an undivided electrochemical cell that is composed of at least one three dimensional accordion pleated sheet member having an open surface area of from zero to 50%. Typically suitable materials include metal mesh and woven fibers. The invention also includes an undivided electrochemical cell, containing the novel working electrode. Finally, the invention includes a method for electrochemically treating a metals-containing hydrocarbon stream in an undivided electrochemical cell by contacting a metals containing hydrocarbon stream with the novel pleated electrode. The invention has broad applicability for treating starting materials that produce electrochemically reversible (redox active) intermediates.
    • 本发明提供一种用于不分割的电化学电池的工作电极,其由至少一个具有零至50%的开放表面积的三维卷曲褶皱片材构成。 通常合适的材料包括金属网和编织纤维。 本发明还包括一个不分开的电化学电池,其包含新的工作电极。 最后,本发明包括通过使含有金属的烃流与新颖的打褶电极接触来对未分裂的电化学电池中的含金属烃流进行电化学处理的方法。 本发明对于处理产生电化学可逆(氧化还原活性)中间体的原料具有广泛的适用性。
    • 8. 发明授权
    • Method for demetallating petroleum streams
    • 石油流脱矿方法
    • US5855764A
    • 1999-01-05
    • US900391
    • 1997-07-15
    • Mark Alan GreaneyWilliam Neergaard Olmstead
    • Mark Alan GreaneyWilliam Neergaard Olmstead
    • C10G15/08C10G32/02C10G32/00
    • C10G32/02
    • The present invention provides for a method of decreasing the metals content of metal containing petroleum streams by forming a mixture of the petroleum fraction containing those metals and an aqueous electrolysis medium containing electron transfer agent, and passing an electric current through the mixture or through the pretreated aqueous electrolysis medium at a voltage, sufficient to remove the metals such as Ni, V and Fe from the stream (i.e. to produce a petroleum fraction having decreased content of the metals). The cathodic voltage is from 0 V to -3.0 V vs. SCE. The invention provides a method for enhancing the value of petroleum feeds that traditionally have limited use in refineries due to their metals, e.g., Ni and V content.
    • 本发明提供一种通过形成含有这些金属的石油馏分和含有电子转移剂的含水电解介质的混合物并使电流通过混合物或通过预处理的方法来降低含金属的石油流的金属含量的方法 水电解介质,其电压足以从流中除去诸如Ni,V和Fe的金属(即,产生具有降低的金属含量的石油馏分)。 阴极电压为0 V至-3.0 V,相对于SCE。 本发明提供了一种增强石油饲料价值的方法,其传统上由于其金属,例如Ni和V含量在炼油厂中的使用受限。
    • 10. 发明授权
    • Method for isolating enriched source of conducting polymers precursors
    • 用于分离导电聚合物前体的富集源的方法
    • US06642421B1
    • 2003-11-04
    • US09551659
    • 2000-04-18
    • Mark Alan GreaneyJohn N. Begasse
    • Mark Alan GreaneyJohn N. Begasse
    • C10G1700
    • C10G21/16C10G21/06
    • An embodiment of the present invention is a method for isolating conducting polymer precursors by contacting a non-basic heterocyclic nitrogen containing hydrocarbon stream having a boiling point of from 232° C. (450° F.) to 566° C. (1050° F.) with an effective amount of a treating agent selected from the group consisting of alkylene and polyalkylene glycols and glycol ethers and mixtures thereof, having a molecular weight of less than 1000 and 1200, respectively, at conditions effective to maintain the reactants in a liquid phase to produce a first stream enriched in non-basic heterocyclic nitrogen containing hydrocarbon compounds and a second treated stream having a decreased non-basic heterocyclic nitrogen content. Optionally, an effective amount of a mineral acid may be added to the treating agent to enhance the process.
    • 本发明的一个实施方案是通过使沸点为232℃(450°F)至566℃的非碱性杂环含氮烃物流接触来分离导电聚合物前体的方法(1050°F )与有效量的选自亚烷基和聚亚烷基二醇和二醇醚及其混合物的处理剂分别具有分子量小于1000和1200的条件下,在有效地将反应物保持在液体中的条件下 以产生富含非碱性杂环氮的烃化合物的第一流和具有降低的非碱性杂环氮含量的第二处理流。 任选地,可以将有效量的无机酸加入到处理剂中以增强该方法。