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1. 发明授权

US10501396B2 Continuous production method for 2-methylene alkanals 有权
公开(公告)号：US10501396B2
公开(公告)日：2019-12-10
申请号：US16325950
申请日：2017-09-05
申请人： OXEA GmbH
发明人： Kurt Schalapski , Jan-Henry Rahe , Christoph Balzarek , Gregor Meier , Heinz Strutz
IPC分类号： C07C45/75 , B01J19/00 , B01J19/24 , C07C47/21
CPC分类号： C07C45/75 , B01J19/0013 , B01J19/2415 , C07C47/21 , B01J2219/00051 , B01J2219/00164 , B01J2219/3322
摘要： The present invention relates to the continuous production of 2-methylene alkanals in a tube reactor, wherein in the 2-position non-branched alkanals are reacted with formaldehyde under acid-base catalysis in the presence of secondary amines and carboxylic acids under laminar flow conditions.

2. 发明授权

US09714201B2 Isononylamines from 2-ethylhexanol, processes for their preparation, and their use 有权
公开(公告)号：US09714201B2
公开(公告)日：2017-07-25
申请号：US14413444
申请日：2013-06-19
申请人： Oxea GmbH
发明人： Jens Theuerkauf , Guido D. Frey , Matthias Eisenacher , Kristina Kockrick , Heinz Strutz
IPC分类号： C07C1/24 , C07C209/26 , C07C211/03 , C07C333/16 , C07C45/50 , C10M135/18
CPC分类号： C07C1/24 , C07C45/50 , C07C209/26 , C07C211/03 , C07C333/16 , C07C2521/04 , C10M135/18 , C07C11/02 , C07C47/02
摘要： Process for preparing isononylamines starting out from 2-ethylhexanol, characterized in that (a) 2-ethylhexanol is dehydrated in the presence of a catalyst to form octene; (b) the octene obtained in step a) is reacted with carbon monoxide and hydrogen in the presence of a transition metal compound of group VIII of the Periodic Table of the Elements to form isononanal; and (c) the isononanal obtained in step b) is converted into isononylamines.

3. 发明授权

US09580378B2 Method for post-treating polyol esters 有权
标题翻译：后处理多元醇酯的方法
公开(公告)号：US09580378B2
公开(公告)日：2017-02-28
申请号：US14915448
申请日：2014-08-29
申请人： Oxea GmbH
发明人： Jens Kubitschke , Thorsten Kreickmann , Jörg Arnold , Matthias Kramer , Heinz Strutz
IPC分类号： C07C67/60 , C07C67/08 , C07C67/56
CPC分类号： C07C67/60 , C07C67/08 , C07C67/56 , C07C69/28
摘要： A batchwise process for aftertreatment of polyol esters prepared by reacting polyols of the general formula (II) H—(—O—[—CR1R2—]m—)o—OH (II) in which R1 and R2 are each independently hydrogen, an alkyl radical having 1 to 5 carbon atoms, preferably methyl, ethyl or propyl, or a hydroxyalkyl radical having 1 to 5 carbon atoms, preferably the hydroxymethyl radical, m is an integer from 1 to 10, preferably 1 to 8 and especially 1, 2, 3 or 4, o is an integer from 2 to 15, preferably 2 to 8 and especially 2, 3, 4 or 5, with excess linear or branched aliphatic monocarboxylic acids having 3 to 20 carbon atoms and having a lower boiling point than the polyols used. The process is carried out in the presence of a Lewis acid and in the presence of an adsorbent, while removing the water formed, characterized in that the excess monocarboxylic acid is removed by distillation and water is added to the crude ester obtained at a temperature below the boiling point of water at the particular pressure and the crude ester with added water is aftertreated with avoidance of basic compounds, and the sparingly soluble conversion products and the adsorbent present in the esterification reaction are filtered off.
摘要翻译：用于后处理多元醇酯的分批方法，其通过使通式（II）的多元醇H - （ - O - [ - CR 1 R 2 - ] m - ）o-OH（II）反应制备，其中R 1和R 2各自独立地为氢，具有1至5个碳原子的烷基，优选甲基，乙基或丙基，或具有1至5个碳原子的羟烷基，优选羟甲基，m为1至10，优选1至8，特别是1,2 ，3或4，o是2至15，优选2至8，特别是2，4或5的整数，其中具有3至20个碳原子并具有比其低的沸点的过量的直链或支链脂肪族单羧酸使用多元醇该方法在路易斯酸存在下并且在吸附剂存在下进行，同时除去形成的水，其特征在于通过蒸馏除去过量的单羧酸，并将水加入到在低于在特定压力下的水的沸点和加入水的粗酯进行后处理，避免碱性化合物，并且滤出酯化反应中存在的微溶的转化产物和吸附剂。

4. 发明授权

US09115110B2 Method for recovering di-trimethylolpropane and trimethylolpropane-enriched product streams from the side streams of trimethylolpropane production 有权
标题翻译：从三羟甲基丙烷生产的侧流回收二羟甲基丙烷和三羟甲基丙烷富集产物流的方法
公开(公告)号：US09115110B2
公开(公告)日：2015-08-25
申请号：US14351159
申请日：2012-10-24
申请人： Oxea GmbH
发明人： Guido D. Frey , Kurt Schalapski , Dirk Bermann , Norman Nowotney , Heinz Strutz , Donald K. Raff
IPC分类号： C07C29/80 , C07C41/42 , C07C41/44 , C07D319/06 , C07C29/90 , C07C29/10 , C07C29/84
CPC分类号： C07D319/06 , C07C29/10 , C07C29/80 , C07C29/84 , C07C29/90 , C07C41/42 , C07C41/44 , C07C31/22 , C07C43/132
摘要： Process for obtaining ditrimethylolpropane and trimethylolpropane-enriched product streams from the high-boiling fractions and residues which are obtained in the distillative purification of trimethylolpropane includes three stage distillation characterized in that second and third stages are configured as thin film evaporators with a column attachment with the second stage facilitating trimethylopropane recovery and the third stage facilitating ditrimethylolpropane recovery.
摘要翻译：从三沸石馏分和在三水羟基丙烷的蒸馏提纯中获得的残余物获得三羟甲基丙烷和三羟甲基丙烷富集产物流的方法包括三步蒸馏，其特征在于第二和第三阶段构成薄膜蒸发器，第二阶段促进三羟甲基丙烷回收和促进二羟甲基丙烷回收的第三阶段。

5. 发明授权

US09018417B2 Process for recovering aliphatic monocarboxylic acids from distillation 有权
标题翻译：从蒸馏中回收脂族一元羧酸的方法
公开(公告)号：US09018417B2
公开(公告)日：2015-04-28
申请号：US14358239
申请日：2012-11-20
申请人： Oxea GmbH
发明人： Guido D. Frey , Jörg Arnold , Wolfgang Höfs , Matthias Kramer , Thomas Müller , Heinz Strutz
IPC分类号： C07C51/50 , C07C51/02 , C07C51/235 , C07C51/44 , C07C51/48
CPC分类号： C07C51/50 , C07C51/02 , C07C51/235 , C07C51/44 , C07C51/48 , C07C53/128 , C07C53/126
摘要： A process is provided for recovering aliphatic monocarboxylic acids having from 4 to 11 carbon atoms from the distillation residue obtained in the oxidation of the corresponding aldehyde by means of oxygen or oxygen-containing gas mixtures in the presence of alkali metal carboxylates or alkaline earth metal carboxylates to form the corresponding monocarboxylic acid and subsequent distillation, characterized in that the distillation residue is reacted with an aqueous acid in a tube reactor and the two-phase mixture flowing out from the tube reactor is introduced into a settling vessel in which the organic phase which separates out has a pH of 4.5 or less.
摘要翻译：提供了一种方法，用于在碱金属羧酸盐或碱土金属羧酸盐存在下，通过氧或含氧气体混合物从相应醛氧化得到的蒸馏残余物中回收具有4至11个碳原子的脂肪族单羧酸形成相应的一元羧酸并随后蒸馏，其特征在于蒸馏残余物与管式反应器中的含水酸反应，从管式反应器流出的两相混合物被引入沉降容器中，其中有机相分离出的pH值在4.5以下。

6. 发明授权

US08987523B2 Method for obtaining ditrimethylolpropane and trimethylolpropane-enriched product streams from the side-streams in trimethylolpropane production 有权
标题翻译：在三羟甲基丙烷生产中从侧流获得二羟甲基丙烷和三羟甲基丙烷富集产物流的方法
公开(公告)号：US08987523B2
公开(公告)日：2015-03-24
申请号：US13810723
申请日：2011-07-28
申请人： Thorsten Kreickmann , Guido D. Frey , Norman Nowotny , Heinz Strutz
发明人： Thorsten Kreickmann , Guido D. Frey , Norman Nowotny , Heinz Strutz
IPC分类号： C07C41/34 , C07C29/74 , C07C29/10 , C07C29/80 , C07C29/90 , C07C41/42 , C07C41/44
CPC分类号： C07C29/74 , C07C29/10 , C07C29/80 , C07C29/90 , C07C41/34 , C07C41/42 , C07C41/44 , C07C31/22 , C07C43/132
摘要： The present invention relates to a process for obtaining ditrimethylolpropane and trimethylolpropane-enriched product streams from the high-boiling fractions and residues which are obtained in the distillative purification of trimethylolpropane, wherein an aqueous solution of these fractions and residues is catalytically hydrogenated in the presence of an acidic compound and, after removing solids, contacted both with basic and with acidic ion exchangers. A trimethylolpropane-enriched product stream can be distilled out of the aqueous eluate obtained, leaving ditrimethylolpropane as the distillation residue.
摘要翻译：本发明涉及从三沸石馏分中获得的二羟甲基丙烷和三羟甲基丙烷富集产物流以及在三羟甲基丙烷的蒸馏提纯中获得的残留物的方法，其中这些级分和残基的水溶液在在除去固体后，与碱性和酸性离子交换剂接触。富含三羟甲基丙烷的产物流可以从获得的水溶液中蒸馏掉，留下二羟甲基丙烷作为蒸馏残余物。

7. 发明申请

US20140220342A1 Vinyl Acetate/Vinyl 3,5,5-trimethylhexanoate Copolymer Binder Resins 有权
标题翻译：乙酸乙烯酯/ 3,5,5-三甲基己酸乙烯酯共聚物粘合剂树脂
公开(公告)号：US20140220342A1
公开(公告)日：2014-08-07
申请号：US14342655
申请日：2011-09-12
申请人： Mapei S.p.A. , Oxea GmbH
发明人： Antonietta Schiro , Tito Zanetta , Christoph Balzarek , Olivier Borgmeier , Guido Frey , Leif Johnen , Donald Raff , Heinz Strutz
IPC分类号： C09J11/06 , C09D7/12
CPC分类号： C09J11/06 , C08F218/08 , C08F218/10 , C08F220/18 , C09D7/63 , Y10T428/2933
摘要： The present invention relates to a copolymer composition comprising 5-95 pphwm of vinyl acetate and 95-5 pphwm of vinyl 3,5,5-trimethylhexanoate, wherein the corresponding 3,5,5-trimethylhexanoic acid has a content of the 3,5,5-trimethylhexanoic acid isomer of at least 88% by weight.Said copolymer is composed and synthesized so as to be useful in the formulation of binders for fibrous substrates such as woven or nonwoven products, paints, adhesives for porous or non-porous substrates, construction cementitious compositions, redispersible powders.
摘要翻译：本发明涉及包含5-95pphwm的乙酸乙烯酯和95-5pphwm的3,5,5-三甲基己酸乙烯酯的共聚物组合物，其中相应的3,5,5-三甲基己酸的含量为3,5 ，5-三甲基己酸异构体为至少88重量％。所述共聚物的组成和合成可用于纤维底物的粘合剂的制备，如织物或非织造产品，油漆，多孔或无孔基材的粘合剂，构造水泥组合物，可再分散的粉末。

8. 发明授权

US09745236B2 Method for recovering di-trimethylolpropane by distillation 有权
公开(公告)号：US09745236B2
公开(公告)日：2017-08-29
申请号：US14351306
申请日：2012-10-24
申请人： Oxea GmbH
发明人： Guido D. Frey , Norman Nowotny , Kurt Schalapski , Heinz Strutz
IPC分类号： B01D1/06 , B01D3/14 , C07C29/80 , C07C41/42 , C07C41/44 , C07C43/13
CPC分类号： C07C29/80 , B01D1/06 , B01D1/065 , B01D3/14 , B01D3/143 , B01D3/148 , C07C41/42 , C07C41/44 , C07C43/13 , C07C43/132
摘要： Distillative process for obtaining ditrimethylolpropane from solutions includes separating ditrimethylolpropane from the solution in a first distillation unit into a first tops fraction comprising low-boiling compounds having a lower boiling point than ditrimethylolpropane and a first bottoms fraction; introducing the first bottoms fraction into a second distillation unit having at least 5 theoretical plates, said unit being configured as a thin-film evaporator with a column attachment and drawing off a second tops fraction comprising intermediate-boiling compounds having a lower boiling point than ditrimethylolpropane as well as withdrawing a second bottoms fraction from the second distillation unit and introducing the second bottoms fraction into a third distillation unit having at least 4 theoretical plates, said unit being configured as a thin-film evaporator with a column attachment, such that ditrimethylolpropane is obtained as a third tops fraction and high boilers are removed as a third bottoms fraction.

9. 发明授权

US09353032B2 Method for the production of neopentyl glycol 有权
标题翻译：新戊二醇生产方法
公开(公告)号：US09353032B2
公开(公告)日：2016-05-31
申请号：US14427181
申请日：2013-09-28
申请人： Oxea GmbH
发明人： Matthias Eisenacher , Kurt Schalapski , Heinz Strutz
IPC分类号： C07C31/18 , C07C29/141 , B01J37/03 , B01J37/04 , B01J37/08 , B01J23/889 , C07C45/75
CPC分类号： C07C29/141 , B01J23/8892 , B01J37/031 , B01J37/04 , B01J37/08 , C07C45/75 , C07C47/19 , C07C31/20
摘要： A method for preparing neopentyl glycol by addition of isobutyraldehyde and formaldehyde in the presence of a tertiary alkylamine as catalyst to give hydroxypivalaldehyde with subsequent hydrogenation at a temperature of 80 to 140° C. and at a pressure of 2 to 18 MPa in the liquid phase, is characterized in that the hydrogenation is carried out in the presence of a copper chromite catalyst comprising the activators barium and manganese.
摘要翻译：在叔烷基胺作为催化剂的存在下加入异丁醛和甲醛制备新戊二醇的方法，得到羟基新戊醛，随后在80-140℃的温度和在2至18MPa的压力下在液相中氢化的特征在于氢化是在含有活化剂钡和锰的亚铬酸铜催化剂的存在下进行的。

10. 发明申请

US20150344400A1 Method for Producing Polyol Esters 有权
标题翻译：多元醇酯的制备方法
公开(公告)号：US20150344400A1
公开(公告)日：2015-12-03
申请号：US14427742
申请日：2013-08-10
申请人： OXEA GmbH
发明人： Guido D. FREY , Tonia WEBER , Jörg ARNOLD , Thorsten KREICKMANN , Heinz STRUTZ
IPC分类号： C07C67/08
CPC分类号： C07C67/08 , C07C69/28
摘要： A process for preparing polyol esters by reacting polyols with linear or branched aliphatic monocarboxylic acids having 3 to 20 carbon atoms, is characterized in that a mixture of the starting compounds is allowed to react in the presence of a Lewis acid containing at least one element of groups 4 to 14 of the periodic table of the elements as a catalyst and in the presence of an adsorbent with removal of the water formed, and then the crude ester obtained is aftertreated by adding a further adsorbent which is an acidic activated carbon having a pH of 1 to 6.5.
摘要翻译：多元醇与碳原子数为3〜20的直链或支链脂族一元羧酸反应制备多元醇酯的方法，其特征在于使起始化合物的混合物在含有至少一种元素的路易斯酸作为催化剂的元素周期表的4至14族，并且在除去所形成的水的吸附剂存在下，然后通过加入另外的吸附剂进行后处理，所述吸附剂是具有pH的酸性活性炭为1〜6.5。

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