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    • 2. 发明申请
    • THERMOPLASTIC RESIN COMPOSITION FOR VEHICULAR LAMP HOUSING
    • 热塑性树脂组合物用于车辆灯泡住房
    • US20110224355A1
    • 2011-09-15
    • US13062968
    • 2009-09-09
    • Hajime TomitaTokuo TatsudaTetsuya YamamotoSeiji Tamai
    • Hajime TomitaTokuo TatsudaTetsuya YamamotoSeiji Tamai
    • C08L51/04C08L51/00B82Y30/00
    • C08F265/04B29C65/06B29C65/1616B29C65/1635B29C65/1654B29C65/1677B29C65/20B29C66/71B29C66/73921B29C66/919B29C66/939B29K2096/02B29L2031/747B60Q1/00C08F285/00C08L25/12C08L25/16C08L35/00C08L35/06C08L51/003C08L51/04F21S41/29F21S41/37C08L2666/02
    • The present invention provides a thermoplastic resin composition for a vehicular lamp housing, which is excellent in balance of physical properties with regard to such as impact resistance and fluidity, and of which hot plate weldability, vibration weldability and laser weldability are improved when a vehicular lamp housing is welded with other members.A thermoplastic resin composition for a vehicular lamp housing, comprising a graft copolymer (A) and a (co)polymer (C) is provided, wherein the graft copolymer (A) is obtained by emulsion graft polymerization of an acrylic acid ester-based rubbery polymer having a weight average particle diameter of 70 to 250 nm with at least one monomer selected from the group consisting of an aromatic vinyl-based monomer, a vinyl cyanide-based monomer, a (meth)acrylic acid ester-based monomer and a maleimide-based monomer, wherein the acrylic acid ester-based rubbery polymer is obtained by emulsion polymerization of 60 to 95% by weight of an acrylic acid ester-based monomer in the presence of 5 to 40% by weight of an aromatic vinyl-based polymer having a weight average particle diameter of 10 to 150 nm; the (co)polymer (C) is obtained by polymerization of at least one monomer selected from the group consisting of an aromatic vinyl-based monomer, a vinyl cyanide-based monomer, a (meth)acrylic acid ester-based monomer and a maleimide-based monomer.
    • 本发明提供一种用于车灯壳体的热塑性树脂组合物,其在耐冲击性和流动性方面的物理性能的平衡优异,并且当车灯灯具 外壳与其他部件焊接。 提供了一种包含接枝共聚物(A)和(共)聚合物(C)的车辆灯壳体的热塑性树脂组合物,其中接枝共聚物(A)通过丙烯酸酯系橡胶质 重均粒径为70〜250nm的聚合物与至少一种选自芳香族乙烯基系单体,乙烯基氰系单体,(甲基)丙烯酸酯系单体和马来酰亚胺 的基于丙烯酸酯的单体,其中丙烯酸酯基橡胶状聚合物通过在5-40重量%的芳族乙烯基类聚合物的存在下,通过乳液聚合得到60〜95重量%的丙烯酸酯系单体 重均粒径为10〜150nm; (共)聚合物(C)通过聚合至少一种选自芳族乙烯基类单体,乙烯基氰化物系单体,(甲基)丙烯酸酯系单体和马来酰亚胺 的单体。
    • 3. 发明申请
    • Method of producing copolymer latex using for aqueous paint
    • 制备用于水性涂料的共聚物胶乳的方法
    • US20050043477A1
    • 2005-02-24
    • US10909375
    • 2004-08-03
    • Toshiyasu NishiokaAkira KamimuraMakoto Itagaki
    • Toshiyasu NishiokaAkira KamimuraMakoto Itagaki
    • C08F2/22C08F236/04C08L45/00C09D5/02C09D109/08C09D109/10C09D151/00
    • C08F2/22
    • A copolymer latex for chipping-resistant aqueous paint capable of remarkably improving balance of chipping-resistance, strength of adherence with metal, water-resistance and high resistance for cycles of cool and heat is provided. This is achieved by a method for producing a copolymer latex using for chipping-resistant aqueous paint, the method comprising emulsion-polymerizing 20 to 80 parts by weight of a conjugated diene as a monomer, 0.5 to 15 parts by weight of an ethylenically unsaturated carboxylic acid as a monomer, 5 to 40 parts by weight of an aromatic vinyl compound as amonomer, 5 to 40 parts by weight of an unsaturated alkyl carboxylate as a monomer and optionally not more than 69.5 parts by weight of other compound having vinyl group copolymerizable therewith as a monomer based on 100 parts by weight in the total of the monomers, wherein 100 wt % of the amount of conjugated diene, 100 wt % of the amount of ethylenically unsaturated carboxylic acid, 95 to 50 wt % of the amount of aromatic vinyl compound and 95 to 50 wt % of the amount of the unsaturated alkyl carboxylate are added in the former stage of the emulsion-polymerization, and 5 to 50 wt % of the amount of the aromatic vinyl compound and 5 to 50 wt % of the amount of the unsaturated alkyl carboxylate are added at the later stage of emulsion-polymerization.
    • 提供了一种能够显着提高耐崩裂性,与金属粘附强度,耐水性和耐热循环性高的耐破碎性水性涂料的共聚物胶乳。 这是通过一种制备用于耐崩裂性水性涂料的共聚物胶乳的方法实现的,该方法包括将20至80重量份作为单体的共轭二烯进行乳液聚合,0.5至15重量份的烯键式不饱和羧酸 酸作为单体,5〜40重量份作为单体的芳香族乙烯基化合物,5〜40重量份作为单体的不饱和烷基羧酸酯和任选不大于69.5重量份的可与其共聚的具有乙烯基的其它化合物 作为单体的总量为100重量份的单体,其中共轭二烯的量为100重量%,烯属不饱和羧酸的量为100重量%,芳香族乙烯基的量为95〜50重量% 在乳液聚合的前一阶段加入不饱和羧酸烷基酯的95〜50重量%,芳香族乙烯基化合物的5〜50重量%,5〜50重量% 在乳液聚合的后期加入50重量%的不饱和羧酸烷基酯的量。