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    • 81. 发明授权
    • Extrusion process for preparing orientated polyolefins
    • 制备取向聚烯烃的挤出方法
    • US4948545A
    • 1990-08-14
    • US418992
    • 1989-10-06
    • Zahir BashirAndrew KellerJeffrey A. Odell
    • Zahir BashirAndrew KellerJeffrey A. Odell
    • B29C47/00B29C55/00B29C55/30B29K23/00C08F2/00C08F8/00C08F10/00D01F6/04D01F6/30
    • D01F6/04B29C55/00B29K2023/00
    • An orientated polyolefin composition comprising an olefin (co)polymer having a weight average molecular weight (Mw) from 30,000 to 1,000,000 and a high molecular weight tail extending to molelcular weights above 1,000,000, and has a microstructure which is substantially parallel chain extended cores of the component polymer(s) and associated lamellar overgrowths extending in planes normal to the cores in which the lamellar overgrowths on adjacent cores intermesh and are capable of sustaining a haul off tension of at least 10 MPa without breaking during its extrusion, is produced by extruding an olefin copolymer through a die under a pressure of about 5-10 MPa, at a temperature above the self-blocking temperature thereof and by hauling off the extrudate at a tension of at least 10 MPa without breaking. The extrudates so produced have a high modulus.
    • 一种取向的聚烯烃组合物,其包含重均分子量(Mw)为30,000至1,000,000的烯烃(共)聚合物和延伸至高于1,000,000的摩尔重量的高分子量尾部,并且具有基本平行的链延伸芯的微结构 组分聚合物和相关的层状过度生长在垂直于芯的平面中延伸,其中在相邻芯上的层状过度生长相互啮合并且能够在其挤出期间能够承受至少10MPa的牵引张力而不断裂,通过挤出 烯烃共聚物通过模具在约5-10MPa的压力下,在高于其自身阻塞温度的温度下,并且以至少10MPa的张力牵引挤出物而不破裂。 如此制造的挤出物具有高模量。