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81. 发明授权

US4596644A Method of polymerization 失效
标题翻译：聚合方法
公开(公告)号：US4596644A
公开(公告)日：1986-06-24
申请号：US752287
申请日：1985-07-05
申请人： Christopher P. Banks , Edward Irving
发明人： Christopher P. Banks , Edward Irving
IPC分类号： C08F2/00 , C08F2/58 , C08G8/04 , C08G59/72 , C08G65/26 , C08G75/06 , C08G85/00 , C08L61/00 , C09D5/44 , C25D13/00
CPC分类号： C08G65/2654 , C08G59/72 , C08G75/06 , C08G8/04 , C08L61/00 , C09D5/4476 , Y10T428/31529
摘要： Cationically polymerizable materials, such as epoxide resins, phenoplasts, and aminoplasts, are polymerized by passing an electric current through a composition comprising(A) the cationically polymerizable material, and(B) a boron trifluoride complex,between an anode and a cathode in contact with the composition, whereby polymerized material is deposited on the anode.Typical complexes (B) are those of boron trifluoride with primary, secondary, or tertiary amines or with trialkyl or triaryl phosphines.The method is a particularly suitable means for coating conductive substrates, giving a rapid cure without the need for special formulations to render the polymers electrodepositable.
摘要翻译：通过使电流通过包含（A）阳离子聚合性材料的组合物和（B）三氟化硼配合物，在接触的阳极和阴极之间聚合阳离子可聚合材料，例如环氧树脂，酚醛树脂和氨基塑料。其中聚合材料沉积在阳极上。典型的络合物（B）是三氟化硼与伯，仲或叔胺或三烷基或三芳基膦的络合物。该方法是用于涂覆导电基材的特别合适的方法，可快速固化，而无需特殊配方使聚合物电沉积。

82. 发明授权

US4578425A Phenolic resins, carboxylic resins and the elastomers containing adhesive 失效
标题翻译：酚醛树脂，羧酸树脂和含有粘合剂的弹性体
公开(公告)号：US4578425A
公开(公告)日：1986-03-25
申请号：US701205
申请日：1985-02-13
申请人： Michael Santorelli
发明人： Michael Santorelli
IPC分类号： C08L61/00 , B32B15/08 , B32B15/092 , B32B27/04 , C08G59/00 , C08G59/18 , C08G59/62 , C08L13/00 , C08L21/00 , C08L23/08 , C08L33/00 , C08L33/02 , C08L33/06 , C08L61/04 , C08L61/06 , C08L63/00 , C09J123/02 , C09J123/08 , C09J159/00 , C09J161/06 , C09J163/00 , C09J187/00 , H05K1/00 , H05K3/38 , C08L63/02
CPC分类号： H05K3/386 , B32B27/04 , C09J123/0869 , C09J161/06 , C09J163/00 , C08L13/00 , C08L21/00 , C08L23/0869 , C08L33/00 , C08L63/00 , H05K1/0393 , H05K2201/0133 , H05K2201/0154 , H05K2201/0355 , Y10T428/31522 , Y10T428/31681 , Y10T428/31688
摘要： An adhesive is disclosed for use in flexible circuitry, laminates and electrical products. The adhesive has improved flexibility and adhesive properties. It may be applied in solution form or may be cast as a free-standing film which is later heated and compressed to give adhesive properties. The adhesive comprises a phenolaldehyde resin or other phenolic resin, an epoxy resin and an elastomer.
摘要翻译：公开了用于柔性电路，层压板和电气产品的粘合剂。粘合剂具有改善的柔性和粘合性能。它可以以溶液形式施用，或者可以作为独立的膜浇铸，其随后被加热和压缩以产生粘合性质。粘合剂包括酚醛树脂或其它酚醛树脂，环氧树脂和弹性体。

83. 发明授权

US4576969A Spherical ion exchange resin having matrix-bound metal hydroxide, method for producing the same and method for adsorption treatment using the same 失效
标题翻译：具有基质结合金属氢氧化物的球形离子交换树脂，其制造方法以及使用其的吸附处理方法
公开(公告)号：US4576969A
公开(公告)日：1986-03-18
申请号：US541646
申请日：1983-10-13
申请人： Yoshiaki Echigo , Yoshiyuki Suematsu , Tadashi Ishikura
发明人： Yoshiaki Echigo , Yoshiyuki Suematsu , Tadashi Ishikura
IPC分类号： C08L61/00 , B01J39/08 , B01J39/16 , B01J39/18 , B01J41/08 , B01J41/12 , B01J43/00 , B01J45/00 , B01J47/00 , C02F1/28 , C02F1/42 , C08G8/00 , C08L61/04 , C08F8/10
CPC分类号： C02F1/288 , B01J39/165 , B01J39/185 , B01J41/12 , B01J47/007 , C02F1/42 , C02F2101/103
摘要： A spherical ion exchange resin composed of a phenolic resin and a metal hydroxide is disclosed. The metal hydroxide is enclosed and bound with the phenolic resin. A method for producing such an ion exchange resin and a method for selectively adsorbing ions using the same is also disclosed. The ion exchange resin is capable of efficiently recovering ions contained or dissolved in water in trace amounts and, hence, can be applied to any aqueous solution containing ions. For example, it can be used to recover useful substances from sea water and to purify waste waters from nonferrous refineries and nuclear power plants.
摘要翻译：公开了一种由酚醛树脂和金属氢氧化物组成的球形离子交换树脂。金属氢氧化物被封闭并与酚醛树脂结合。还公开了这种离子交换树脂的制造方法和使用该离子交换树脂选择性吸附离子的方法。离子交换树脂能够有效地回收微量含有或溶解在水中的离子，因此可以应用于任何含有离子的水溶液。例如，它可用于从海水中回收有用物质，并从有色炼油厂和核电厂净化废水。

84. 发明授权

US4575542A Thermosettable polystyrylpyridine prepolymer terminated with ethylenically unsaturated groups and cured products therefrom 失效
标题翻译：用乙烯基不饱和基团封端的可热固化的聚苯乙烯基吡啶预聚物及其固化产物
公开(公告)号：US4575542A
公开(公告)日：1986-03-11
申请号：US726554
申请日：1985-04-23
申请人： Duane S. Treybig
发明人： Duane S. Treybig
IPC分类号： C08F2/44 , C08F290/00 , C08F299/02 , C08G16/00 , C08G16/02 , C08G16/04 , C08G73/12 , C08J5/24 , C08L61/00 , C08F283/04 , C08G2/26
CPC分类号： C08F299/022 , C08G16/0268 , C08G73/12 , C08J5/24 , C08L61/00 , Y10S525/912
摘要： Thermosettable compositions are disclosed which are prepared by reacting (A) a pyridine compound containing at least two substituent groups which have at least one hydrogen atom attached to a carbon atom which is attached to the ring or mixture of such pyridines; (B) at least one material having at least two aldehyde groups; and (C) at least one aldehyde containing at least one polymerizable unsaturated group; wherein components (A), (B) and (C) are employed in quantities which provide a mole ratio of (C):(B):(A) of from about 0.25:0.25:1 to about 4:4:1. These thermosettable compositions can be cured by heat and pressure or by homopolymerization in the presence of or by copolymerization with an N,N'-bis-imide. The compositions are useful as light weight fire resistant interior and exterior parts or panels for the aerospace and/or aircraft industry and the like.
摘要翻译：公开了通过使（A）含有至少两个具有至少一个氢原子的取代基的吡啶化合物与附着在该环或这种吡啶的混合物上的碳原子连接而制备的可热熔组合物; （B）至少一种具有至少两个醛基的材料; 和（C）至少一种含有至少一个可聚合不饱和基团的醛; 其中组分（A），（B）和（C）以使得（C）：（B）：（A）的摩尔比为约0.25:0.25:1至约4:4:1的量使用。这些可热固组合物可以通过加热和压力或通过在N，N'-二酰亚胺的存在下或通过与N，N'-双酰亚胺的共聚来均聚来固化。所述组合物可用作用于航空航天和/或飞机工业等的轻质防火内部和外部部件或面板。

85. 发明授权

US4564466A Method for the manufacture of a polymer 失效
标题翻译：制造聚合物的方法
公开(公告)号：US4564466A
公开(公告)日：1986-01-14
申请号：US563871
申请日：1983-12-21
申请人： Gerd Weddigen , Robert Huber , Birgit Schmidt , Hartmut Schneider
发明人： Gerd Weddigen , Robert Huber , Birgit Schmidt , Hartmut Schneider
IPC分类号： C08L61/00 , C08G8/00 , C08G8/04 , C08G8/28 , C08G12/08 , C08G12/40 , C08G16/02 , C08G16/04 , C08G18/54 , C08L61/04 , H01B1/12 , C08G14/12
CPC分类号： C08G8/28 , C08G12/08 , C08G12/40 , C08G16/0212 , C08G16/04 , C08G18/54 , C08G8/04 , H01B1/121
摘要： Method for the manufacture of a polymer with triaromatic methane units as basic building blocks, the electric conductivity of which is obtained through the formation of charge transfer complexes. Electron donors and/or electron acceptors are added to the synthetic polymer during or after its preparation, for forming charge transfer complexes.
摘要翻译：制备具有三芳甲烷单元作为基本构件的聚合物的方法，其电导率通过形成电荷转移络合物获得。在制备期间或之后，将电子给体和/或电子受体加入到合成聚合物中，以形成电荷转移络合物。

86. 发明授权

US4559373A Weldable sealants for metal and method of use 失效
标题翻译：金属可焊接密封剂和使用方法
公开(公告)号：US4559373A
公开(公告)日：1985-12-17
申请号：US514667
申请日：1983-07-18
申请人： James L. Guthrie , Helen F. Roberts , Christian B. Lundsager
发明人： James L. Guthrie , Helen F. Roberts , Christian B. Lundsager
IPC分类号： B29C65/02 , B29C65/34 , C09J5/06 , C09J201/00 , C08K3/08 , C08L61/00
CPC分类号： C09J201/00 , B23K11/11 , B23K11/34 , C09J5/06
摘要： A weldable sealant composition is made by adding ferrous metal particles to a sealant having a viscosity of at least 6 million centipoises. The sealant composition is placed between two metal plates and permits resistance welding, i.e. spot welding, to take place.
摘要翻译：通过将黑色金属颗粒添加到具有至少600万厘泊的粘度的密封剂中来制备可焊接的密封剂组合物。将密封剂组合物放置在两个金属板之间，并允许发生电阻焊接，即点焊。

87. 发明授权

US4555552A Phenolic modified urethane elastomer 失效
标题翻译：酚醛改性聚氨酯弹性体
公开(公告)号：US4555552A
公开(公告)日：1985-11-26
申请号：US361282
申请日：1982-03-24
申请人： Aubert Y. Coran , Raman Patel
发明人： Aubert Y. Coran , Raman Patel
IPC分类号： C08G18/83 , C08L61/06 , C08L75/04 , C08L77/00 , C08G71/04 , C08L61/00
CPC分类号： C08L61/06 , C08G18/831 , C08L75/04 , C08L77/00
摘要： Urethane elastomer is described having methylol phenolic groups grafted thereto which modified elastomer is useful for preparing improved polymer blends.
摘要翻译：描述了具有接枝到其上的羟甲基酚基的聚氨酯弹性体，改性弹性体可用于制备改进的聚合物共混物。

88. 发明授权

US4540770A Polystyrylpyridine resins having an increased toughness, and composite materials comprising these resins 失效
标题翻译：具有增加的韧性的聚苯乙烯基吡啶树脂和包含这些树脂的复合材料
公开(公告)号：US4540770A
公开(公告)日：1985-09-10
申请号：US643651
申请日：1984-08-23
申请人： Sammy Chevallier
发明人： Sammy Chevallier
IPC分类号： C08L61/00 , C08G16/00 , C08G16/02 , C08J5/24 , C08L61/34 , C08G12/02
CPC分类号： C08J5/24 , C08G16/0268 , C08J2361/00
摘要： The present invention relates to polystyrylpyridine-type resins having increased toughness, and composite materials containing these resins.The resin of the invention contains a polycondensation product of at least two reactive methylated substituents, the said resin having the following general formula (I): U.sub.x V.sub.y W.sub.z in which: ##STR1## U denotes the grouping ##STR2## V denotes the grouping ##STR3## W denotes the grouping in which:R, R.sub.1 are identical or different and denote a chain segment consisting of hydrocarbon radicals and able to contain hetero atoms,A, A.sub.1 are identical or different and denote an atom or group forming a bridge between the segment R and an aromatic nucleus of the styrylpyridine chain, containing stereomobile bonds,R.sub.2 denotes hydrogen, or a methyl or ethyl radical, x, y, z denote integers that may be equal to 0, the sum y+z being at least equal to 1.Advantageously, A, A.sub.1 denotes an oxygen atom. The resins of the invention have better mechanical properties than conventional polystyrylpyridine (PSP) resins, particularly at ambient temperature, yet preserve the excellent thermostability and moisture resistance properties characteristic of PSP resins. This resin may be used as matrix in a laminate.
摘要翻译：本发明涉及韧性提高的聚苯乙烯基吡啶型树脂，以及包含这些树脂的复合材料。本发明的树脂含有至少两个反应性甲基化取代基的缩聚产物，所述树脂具有以下通式（I）：Ux Vy Wz，其中：U表示分组 V表示分组，图像W表示其中：R，R 1相同或不同并且表示由烃基组成并能够含有杂原子的链段的分组，A，A1相同或不同，并且表示在原子或基团之间形成桥段R和苯乙烯基吡啶链的芳香核，含有立体移动键，R2表示氢或甲基或乙基，x，y，z表示可等于0的整数，y + z之和至少等于有利地，A，A1表示氧原子。本发明的树脂具有比常规聚苯乙烯基吡啶（PSP）树脂更好的机械性能，特别是在环境温度下，同时保持了PSP树脂的优异的耐热性和耐湿性。该树脂可以用作层压体中的基质。

89. 发明授权

US4529751A Resin coated sand for casting 失效
标题翻译：树脂涂层砂铸造
公开(公告)号：US4529751A
公开(公告)日：1985-07-16
申请号：US542914
申请日：1983-10-17
申请人： Yukio Saeki
发明人： Yukio Saeki
IPC分类号： C08L61/00 , B22C1/22 , C08G8/00 , C08G8/04 , C08G8/10 , C08G8/20 , C08L61/04 , C08L61/06 , C08K5/06
CPC分类号： B22C1/2253 , C08G8/04 , C08L61/06 , Y10T428/2993
摘要： A phenolic resin for application in foundry shell molding operations having improved properties is disclosed. The phenolic resin is prepared by reacting aldehydes and a mixture of bisphenol A and bisphenol F to prepare a phenolic resin for coating foundry aggregates or sand to prepare shell molds having low thermal expansion and improved shake out properties.
摘要翻译：公开了一种用于具有改进性能的铸造壳成型操作中的酚醛树脂。酚醛树脂通过使醛和双酚A和双酚F的混合物反应来制备用于涂覆铸造聚集体或砂的酚醛树脂以制备具有低热膨胀和改善的摇摆性能的壳模。

90. 发明授权

US4526924A Thermosettable compositions convertible to vitreous carbon and process for preparation thereof 失效
标题翻译：可转变成玻璃碳的可热熔组合物及其制备方法
公开(公告)号：US4526924A
公开(公告)日：1985-07-02
申请号：US470978
申请日：1983-03-01
申请人： Louis L. Korb , Phillip A. Waitkus
发明人： Louis L. Korb , Phillip A. Waitkus
IPC分类号： C08K3/04 , C08L61/00 , C08L61/04 , C08L61/06 , C08L61/10
CPC分类号： C08K3/04 , C08L61/06 , Y10S524/904
摘要： The compositions disclosed herein are suitable for thermosetting and conversion to vitreous carbon. They comprise intimate uniform mixtures of powder or otherwise blendable form of 20-80% by weight of a solid phenolic-aldehyde Novolak resin and of 20-80% by weight of a solid phenolic-aldehyde resol resin, the percentages being based on the combined weight of the Novolak and resol resins, and the aldehyde in said Novolak resin comprising at least 50 molar percent, preferably substantially 100 percent, furfuraldehyde, together with a carbonaceous filler, preferably graphite, in a proportion as high as 76% by weight based on the total composition. Generally the graphite may comprise 30-70%, advantageously 35-65% and preferably 40-60% of the molding composition. The vitreous carbon produced from these compositions have improved properties in electrical properties and in the capability of being suitably molded and carburized into large thin plates which are much more stress-free than otherwise produced. The composition may also contain 0-12 parts, preferably 0.12-8 parts hexamethylenetetramine per 100 parts of Novolak resin. The intimate mixture of these resins is advantageously made by blending resin components having a particle size of less than 40 mesh, preferably less than 100 mesh.
摘要翻译：本文公开的组合物适用于热固化和转化为玻璃碳。它们包括20-80重量％固体酚醛酚醛清漆树脂和20-80重量％固体酚醛树脂树脂的粉末或其它可混合形式的均匀混合物，百分比基于组合酚醛清漆树脂和甲阶酚醛树脂的重量，所述酚醛清漆树脂中的醛包含至少50摩尔％，优选基本上100％的糠醛，以及碳质填料，优选石墨，其比例高达76重量％，基于总组成。通常，石墨可以包含模制组合物的30-70％，有利地35-65％，优选40-60％。由这些组合物生产的玻璃碳具有改善的电性能，以及适当地模塑和渗碳成与其它方法相比无压力的大的薄板的能力。组合物还可以含有每100份酚醛清漆树脂0-12份，优选0.12-8份六亚甲基四胺。这些树脂的紧密混合物有利地通过混合具有小于40目，优选小于100目的粒度的树脂组分来制备。

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