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81. 发明授权

US4444624A Process for separating acetone from carbonylation mixtures 失效
标题翻译：从羰基化混合物中分离丙酮的方法
公开(公告)号：US4444624A
公开(公告)日：1984-04-24
申请号：US412225
申请日：1982-08-27
申请人： Heinz Erpenbach , Klaus Gehrmann , Winfried Lork , Peter Prinz
发明人： Heinz Erpenbach , Klaus Gehrmann , Winfried Lork , Peter Prinz
IPC分类号： C07C45/00 , C07C45/49 , C07C45/78 , C07C45/82 , C07C45/83 , C07C49/08 , C07C67/00 , B01D3/40
CPC分类号： C07C45/82 , C07C45/49 , C07C45/83
摘要： The disclosure relates to a process for separating acetone from reaction mixtures originating from the reaction of methyl acetate and/or dimethylether with carbon monoxide and optionally hydrogen in the presence of a catalyst system consisting of carbonyl complexes of noble metals of group VIII of the Periodic System of the elements, acetic acid, an organophosphorus or organonitrogen compound, methyl iodide and optionally carbonyl-yielding compounds of common metals. To this end, the disclosure provides for the reaction mixture containing acetic anhydride, acetic acid, ethylidene diacetate, methyl iodide, acetone and methyl acetate which is distilled off from the catalyst solution, or just its low boiler fraction consisting of methyl acetate, methyl iodide and acetone to be subjected wholly or partially to an extractive distillation with acetic acid and for pure methyl iodide to be distilled off; for an acetone/methyl acetate mixture to be distilled off from the acetic acid extract; for this mixture to be separated in known fashion and for the acetic acid extractant to be recycled into the extraction stage, if desired after separation of the final reaction products comprised of acetic anhydride; ethylidene diacetate and acetic acid.
摘要翻译：本公开内容涉及在由周期性系统VIII族的贵金属的羰基络合物组成的催化剂体系的存在下，从丙酸甲酯和/或二甲醚与一氧化碳和任选的氢气反应的反应混合物中分离丙酮的方法的元素，乙酸，有机磷或有机氮化合物，甲基碘和任选的产生羰基的常见金属化合物。为此，本公开内容提供了从催化剂溶液中蒸馏掉的乙酸酐，乙酸，亚乙基二乙酸酯，甲基碘，丙酮和乙酸甲酯的反应混合物，或仅仅是其由乙酸甲酯，甲基碘和丙酮完全或部分地进行与乙酸的萃取蒸馏，并将纯甲基碘蒸馏出; 对于从乙酸提取物中蒸出的丙酮/乙酸甲酯混合物; 为了将该混合物以已知方式分离，并且乙酸萃取剂再循环到萃取阶段，如果需要，在分离由乙酸酐组成的最终反应产物之后; 亚乙基二乙酸酯和乙酸。

82. 发明授权

US4414420A Aldehyde-ethers 失效
标题翻译：醛 - 醚
公开(公告)号：US4414420A
公开(公告)日：1983-11-08
申请号：US366166
申请日：1982-04-07
申请人： Norman Harris , Alan J. Dennis , George E. Harrison
发明人： Norman Harris , Alan J. Dennis , George E. Harrison
IPC分类号： B01J31/00 , B01J31/24 , C07B61/00 , C07C43/15 , C07C43/188 , C07C45/00 , C07C45/49 , C07C45/50 , C07C47/198 , C07C67/00
CPC分类号： C07C47/198 , C07C43/15 , C07C43/188 , C07C45/49
摘要： Aldehyde ethers of the general formula ##STR1## wherein R.sub.1 and R.sub.2 each, independently of the other, represent a C.sub.1 to C.sub.4 alkyl radical, and R.sub.3 and R.sub.4 each, independently of the other, represent a hydrogen atom or a C.sub.1 to C.sub.3 alkyl radical, or wherein R.sub.1 represents a C.sub.1 to C.sub.4 alkyl radical, R.sub.2 and R.sub.3 together with the carbon atoms to which they are attached form a 5-membered or 6-membered cycloaliphatic ring, and R.sub.4 represents a hydrogen atom or a C.sub.1 to C.sub.3 alkyl radical, and wherein Y represents --CH.sub.2 --CH.sub.2 --CH.sub.2 or --CH.sub.2 --CH (CH.sub.3)--, are prepared by hydroformylation of a corresponding compound of formula. ##STR2## by reaction with hydrogen and carbon monoxide in the presence of a hydroformylation catalyst, e.g. a rhodium complex catalyst. Preferred compounds include 4-t-butoxybutyraldehyde and 3-t-butoxy-2-methylpropionaldehyde. The compounds are useful chemical intermediates in the production of, for example, butane-1,4-diol, butyrolactone and tetrahydrofuran.

83. 发明授权

US4409405A Production of ethanol from methanol and synthesis gas 失效
标题翻译：从甲醇和合成气生产乙醇
公开(公告)号：US4409405A
公开(公告)日：1983-10-11
申请号：US377724
申请日：1982-05-13
申请人： Jiang-Jen Lin , John F. Knifton
发明人： Jiang-Jen Lin , John F. Knifton
IPC分类号： C07C29/32 , C07C45/49 , C07C29/00
CPC分类号： C07C29/32 , C07C45/49
摘要： Ethanol is formed by contacting a mixture of carbon monoxide, hydrogen and methanol with a catalyst comprising a cobalt-containing compound and a germanium-containing compound, such as dicobalt octacarbonyl and triphenylgermanium hydride in the presence of an inert, oxygenated hydrocarbon solvent at a temperature of about 50.degree. to about 350.degree. C. and at a pressure of about 500 psig or greater.
摘要翻译：通过使一氧化碳，氢气和甲醇的混合物与含有钴的化合物和含锗化合物如八羰基二钴和三苯基氢化锗在惰性的含氧烃溶剂的存在下，在温度约50℃至约350℃和约500psig或更大的压力。

84. 发明授权

US4390639A Upgrading synthesis gas 失效
标题翻译：升级合成气
公开(公告)号：US4390639A
公开(公告)日：1983-06-28
申请号：US332773
申请日：1981-12-21
申请人： Frederick A. Pesa , Anne M. Graham
发明人： Frederick A. Pesa , Anne M. Graham
IPC分类号： C07C1/04 , C07C1/22 , C07C29/157 , C07C45/49 , C07C51/10 , C07C7/163 , C07C29/15
CPC分类号： C07C29/157 , C07C1/0435 , C07C1/22 , C07C45/49 , C07C51/10 , C07C2523/06 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/52 , C07C2523/72 , C07C2523/745
摘要： A process for the upgrading of synthesis gas is provided wherein olefin and oxygenated hydrocarbons, particularly alcohol and carboxylic acid, products predominate. The process includes contacting synthesis gas at elevated temperature and pressure in the presence of a catalyst comprising partially reduced ruthenium oxide and elemental gold. The products may be recovered and contacted with hydrogen at elevated temperature and pressure in the presence of a hydrogenation catalyst to yield alkanes, alcohols and esters useful for fuels.
摘要翻译：提供了一种用于升级合成气的方法，其中烯烃和含氧烃，特别是醇和羧酸的产物占优势。该方法包括在包含部分还原的氧化钌和元素金的催化剂存在下，在升高的温度和压力下接触合成气。可以在氢化催化剂存在下，在升高的温度和压力下回收产物并与氢气接触，得到可用于燃料的烷烃，醇和酯。

85. 发明授权

US4361706A Process for preparing aldehydes 失效
标题翻译：醛的制备方法
公开(公告)号：US4361706A
公开(公告)日：1982-11-30
申请号：US289404
申请日：1981-08-03
申请人： Mohammad M. Habib , Wayne R. Pretzer
发明人： Mohammad M. Habib , Wayne R. Pretzer
IPC分类号： C07C47/07 , B01J31/00 , C07C45/00 , C07C45/49 , C07C67/00
CPC分类号： C07C45/49
摘要： A process for selectively producing aldehydes, particularly acetaldehyde, which comprises introducing into a reaction zone (1) methanol, (2) carbon monoxide, (3) hydrogen, (4) cobalt, (5) iodine and (6) a ligand containing atoms from Group VB of the Periodic Table separated by a sterically constrained carbon-carbon bond and then subjecting the contents of said reaction zone to an elevated temperature and an elevated pressure for a time sufficient to convert methanol to said aldehydes.
摘要翻译：选择性地生产醛，特别是乙醛的方法，其包括将甲醇，（2）一氧化碳，（3）氢，（4）钴，（5）碘和（6）含有原子的配体由空间限制的碳 - 碳键分隔的元素周期表的第VB族化合物，然后将所述反应区的内容物升温至升高的压力达足以将甲醇转化为所述醛的时间。

86. 发明授权

US4356327A Process for preparing propylene glycol monoalkyl ethers and alkoxyacetones 失效
标题翻译：丙二醇单烷基醚和烷氧基丙酮的制备方法
公开(公告)号：US4356327A
公开(公告)日：1982-10-26
申请号：US316193
申请日：1981-10-29
申请人： John F. Knifton
发明人： John F. Knifton
IPC分类号： C07C41/01 , C07C45/49
CPC分类号： C07C41/01 , C07C45/49
摘要： Propylene glycol monoalkyl ethers and alkoxyacetones are formed by contacting a mixture of carbon monoxide and hydrogen and (a) acetaldehyde or (b) an acetal and an alcohol, with a catalyst comprising a cobalt-containing compound and at least one tin- or germanium-containing promoter.
摘要翻译：丙烯二醇单烷基醚和烷氧基丙酮通过使一氧化碳和氢气的混合物与（a）乙醛或（b）缩醛和醇）的混合物与包含含钴化合物和至少一种锡 - 含有启动子。

87. 发明授权

US4351908A Process for the manufacture of acetic acid, acetic aldehyde and ethanol from synthesis gas 失效
标题翻译：从合成气制造乙酸，乙醛和乙醇的方法
公开(公告)号：US4351908A
公开(公告)日：1982-09-28
申请号：US310073
申请日：1981-10-09
申请人： Hans-Joachim Schmidt , Ernst I. Leupold
发明人： Hans-Joachim Schmidt , Ernst I. Leupold
IPC分类号： C07C53/08 , B01J23/00 , B01J23/38 , B01J23/46 , B01J23/74 , B01J27/00 , B01J27/06 , B01J31/00 , B01J31/20 , C07B61/00 , C07C27/00 , C07C27/06 , C07C29/151 , C07C29/158 , C07C31/08 , C07C45/49 , C07C47/06 , C07C51/00 , C07C51/10 , C07C67/00
CPC分类号： C07C45/49 , C07C29/1512 , C07C29/158 , C07C51/10
摘要： The invention provides a process for the manufacture of acetic acid, acetic aldehyde and ethanol by reaction in the gaseous phase of carbon monoxide and hydrogen in the presence of catalysts containing rhodium and optionally promoters, at elevated temperature and pressure. In this process, the temperature is raised in the starting phase, where the catalyst is heated to the working temperature T.sub.R intended for continuous operation, in a range of from T.sub.O to T.sub.R, T.sub.O being 75.degree. to 125.degree. C. below T.sub.R, continuously or in steps of 10.degree. C. at most, in a period of time of from 100 to 1,000 hours; the temperature being raised by 10.degree. C. at most within any 10 hour interval.
摘要翻译：本发明提供了一种通过在含有铑和任选的助催化剂的催化剂存在下，在升高的温度和压力下，在一氧化碳和氢气的气相中反应制备乙酸，乙醛和乙醇的方法。在这个过程中，在起始阶段，将催化剂加热到用于连续运行的工作温度TR，温度在TO至TR之间，TO低于TR的75°至125℃的范围内连续地升高或最多10℃的步骤，在100〜1000小时的时间内; 温度在任何10小时的间隔内最多升高10℃。

88. 发明授权

US4348539A Heteronuclear-bridged rhodium clusters 失效
标题翻译：异核桥接铑簇
公开(公告)号：US4348539A
公开(公告)日：1982-09-07
申请号：US260920
申请日：1981-05-06
申请人： Ernst Billig , Jackie D. Jamerson , Roy L. Pruett
发明人： Ernst Billig , Jackie D. Jamerson , Roy L. Pruett
IPC分类号： B01J31/18 , B01J31/24 , C07C45/49 , C07C45/50 , C07F15/00
CPC分类号： B01J31/2404 , B01J31/18 , C07C45/49 , C07C45/50 , C07F15/008 , B01J2231/321 , B01J2531/822
摘要： Heteronuclear-bridged rhodium clusters useful as catalysts in the hydroformylation of olefins.
摘要翻译：用作烯烃加氢甲酰化反应中的催化剂的异核桥连铑簇。

89. 发明授权

US4348322A Dioxolane derivatives 失效
标题翻译：二氧戊环衍生物
公开(公告)号：US4348322A
公开(公告)日：1982-09-07
申请号：US242529
申请日：1981-03-11
申请人： Philip N. Edwards , David M. G. Martin
发明人： Philip N. Edwards , David M. G. Martin
IPC分类号： C07C45/49 , C07C59/66 , C07D317/34
CPC分类号： C07D317/34 , C07C45/49 , C07C59/66
摘要： The invention is concerned with novel dioxolane derivatives of the formula: ##STR1## in which R.sub.a is hydrogen or (1-4C)alkyl and R.sub.b is (1-4C)alkyl or phenyl optionally bearing a halogeno substituent; their production; and their use for the manufacture of certain known anti-arthritic acids of the formula: ##STR2## and, in particular, those acids in which R.sub.a =R.sub.b =methyl or R.sub.a =ethyl and R.sub.b =phenyl, by a novel reduction process. The preferred reduction procedures involve the use of an alkali metal borohydride or cyanoborohydride in the presence of a noble metal catalyst, or the use of an .alpha.-branched alkyl or cycloalkyl Grignard agent.The use of the derivatives of formula I avoids the need for potentially toxic reagents and reactive intermediates in the previously known processes for the production of the acids of formula V.
摘要翻译：本发明涉及下式的新型二氧戊环衍生物：其中Ra为氢或（1-4C）烷基，Rb为（1-4C）烷基或任选带有卤素取代基的苯基; 他们的生产; 以及它们用于制备下式的某些已知的抗关节炎酸，特别是通过新的还原方法，其中Ra = Rb =甲基或Ra =乙基和Rb =苯基的那些酸。优选的还原方法包括在贵金属催化剂存在下使用碱金属硼氢化物或氰基硼氢化物，或使用α-支链烷基或环烷基格氏试剂。使用式I的衍生物避免了在以前已知的用于制备式V的酸的方法中对潜在有毒的试剂和反应性中间体的需要。

90. 发明授权

US4339610A Process for selective formation of C.sub.4 compounds and thiol-containing catalyst system used therein 失效
标题翻译：用于选择性形成C4化合物和其中使用的含硫醇催化剂体系的方法
公开(公告)号：US4339610A
公开(公告)日：1982-07-13
申请号：US215555
申请日：1980-12-11
申请人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
发明人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
IPC分类号： C07C29/32 , C07C45/49 , C07C27/22 , C07C45/50
CPC分类号： C07C29/32 , C07C45/49 , C12C11/02 , Y02P20/52
摘要： C.sub.4 compounds including n-butanol and n-butanal are produced by reacting methanol, hydrogen, and carbon monoxide, in the presence of a cobalt catalyst selected from the group consisting of (a) a cobalt carbonyl, (b) a hydrido cobalt carbonyl and (c) a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, an iodine promotor and a thiol defined by the formula:RSHwherein R is selected from the group consisting of saturated or unsaturated, straight or branched chain alkyl radicals having from one to 24 carbon atoms, cycloalkyl radicals having from three to 40 carbon atoms, aryl radicals having from six to 20 carbon atoms, aralkyl and alkaryl radicals having from six to 40 carbon atoms and halogen substituted derivatives thereof. A high degree of selectivity towards the formation of butanol and butanal is provided by using the cobalt entity and the thiol in a molar ratio in the range of about 2:1 to about 10:1, based on elemental cobalt and sulfur. The reaction is conducted at elevated temperature and pressure conditions for a time sufficient to convert methanol to n-butanol and n-butanal.
摘要翻译：包括正丁醇和正丁醛的C 4化合物通过甲醇，氢气和一氧化碳在钴催化剂存在下制备，所述钴催化剂选自（a）羰基钴，（b）羰基钴和（c）可转化为羰基钴或羰基钴的钴的物质，碘促进剂和由下式定义的硫醇：其中R选自饱和或不饱和的直链或支链烷基具有1至24个碳原子，具有3至40个碳原子的环烷基，具有6至20个碳原子的芳基，具有6至40个碳原子的芳烷基和烷芳基及其卤素取代的衍生物。基于元素钴和硫，通过使用钴实体和硫醇以约2:1至约10:1的摩尔比来提供对形成丁醇和丁醛的高度选择性。反应在升高的温度和压力条件下进行足以将甲醇转化为正丁醇和正丁醛的时间。

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