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    • 84. 发明申请
    • PRETREATMENT OF LIGNOCELLULOSIC BIOMASS THROUGH REMOVAL OF INHIBITORY COMPOUNDS
    • 通过去除抑制性化合物预处理细菌生物量
    • US20120329116A1
    • 2012-12-27
    • US13555645
    • 2012-07-23
    • Frank A. DOTTORIRobert Ashley Cooper BENSONRegis-Olivier BENECH
    • Frank A. DOTTORIRobert Ashley Cooper BENSONRegis-Olivier BENECH
    • D21B1/36C12P7/14
    • D21B1/36C12P2201/00D21C1/02D21C5/005D21C11/0007
    • A process for the pretreatment of lignocellulosic biomass is disclosed, which includes the steps of pretreating the lignocellulosic biomass to hydrolyze and solubilize hemicelluloses in the biomass; explosively decomposing the biomass into fibers; and extracting from the resulting solids fraction a liquefied portion of the lignocellulosic biomass before or after explosive decomposition. This removes compounds from the lignocellulosic biomass which are inhibitory to enzymatic cellulose hydrolysis and sugar fermentation to ethanol. For improved economy, the inhibitory compounds are not completely removed. The extraction step is controlled on the basis of the xylose equivalent content in the reaction mixture and the extracting step is discontinued once a xylose equivalent content of 4-8% w/w of xylose in the dry matter of the solids fraction is achieved. This most economically balances the practical need for inhibitory compound removal with the economical need to minimize the costs of the overall ethanol production process.
    • 公开了一种用于木质纤维素生物质的预处理的方法,其包括预处理木质纤维素生物质以在生物质中水解和增溶半纤维素的步骤; 将生物质爆炸分解成纤维; 并从所得固体部分提取在爆炸性分解之前或之后的木质纤维素生物质的液化部分。 这从木质纤维素生物质中除去抑制酶纤维素水解和糖发酵成乙醇的化合物。 为了改善经济性,抑制性化合物不能完全去除。 提取步骤基于反应混合物中的木糖当量含量进行控制,一旦实现固体部分的干物质中木糖当量含量为4-8%w / w的木糖,就停止萃取步骤。 这最经济地平衡了抑制化合物去除的实际需要与经济需要最小化整个乙醇生产过程的成本。
    • 87. 发明授权
    • Apparatus for hydrolyzing and drying lignocellulosic material
    • 用于水解和干燥木质纤维素材料的装置
    • US5454911A
    • 1995-10-03
    • US139152
    • 1993-10-21
    • Andrew J. Rafferty
    • Andrew J. Rafferty
    • B27N1/00C08H8/00C08L97/02D21B1/36D21C1/02D21C1/10D21H11/00D21J1/16D21C7/00D21C7/08D21C7/10
    • C08H8/00B27N1/00C08L97/02D21B1/36D21C1/02D21C1/10
    • An energy efficient process for hydrolyzing lignocellulosic materials which comprises using a primary system by providing a start-up energy input to operating saturated steam conditions and thereafter operating the primary system with substantially constant energy input, the condition of the hydrolyzing saturated steam being controlled by water injection and/or steam bleeding from the primary system. The dwell time of the solids stream in the primary sustem is controlled by controlling its passage with flashing off of steam into a secondary system where drying occurs together with some small measure of hydrolysis in a lower pressure superheated steam environment, there being an energy input into the secondary system using steam bled from the primary system. The output solids material stream is preferably capable of being self polymerized into a formed shape eg a board.
    • 用于水解木质纤维素材料的能量有效的方法,其包括通过提供启动能量输入来操作饱和蒸汽条件并且此后以基本上恒定的能量输入来操作初级系统来使用主要系统,水解饱和蒸汽的条件由水控制 注射和/或蒸汽从主系统出血。 主要维持物中固体物流的停留时间通过控制其通过蒸汽闪蒸进入二次系统来控制,其中干燥与低压过热蒸汽环境中的一些少量水解一起进行,其中有能量输入 二次系统使用从主系统排出的蒸汽。 输出固体物质流优选能够自聚合为成形形状,例如板。
    • 88. 发明授权
    • Method of extracting chemical preservatives from treated wood
    • 从经处理的木材中提取化学防腐剂的方法
    • US5262004A
    • 1993-11-16
    • US914546
    • 1992-07-16
    • Roland GilbertAndre BesnerPierre Tetreault
    • Roland GilbertAndre BesnerPierre Tetreault
    • D21B1/02D21B1/36D21B1/12
    • D21B1/023D21B1/021D21B1/36
    • Preservatives and oil are extracted from treated wood. For this purpose, treated wood that is intended to be discarded is comminuted, the chips are impregnated with an alkaline solution until softening of the chips and modification of the chemical state of the products to be extracted. Possibly, the chips may be treated with saturated steam at a temperature between 170.degree. C. and 210.degree. C. followed by an explosive decompression giving wood fragments. This is followed by a refining operation in a crusher permitting the grinding of the wood. The result is a substantial release of the preservatives and oil from the wood chips which are at least partly disintegrated. The chemical preservatives and the oil are collected separately from the wood chips in the aqueous phases which are produced in the impregnation, steam cooking-explosive decompression and refining steps.
    • 防腐剂和油从被处理的木材中提取。 为此目的,粉碎被处理的待处理木材,用碱性溶液浸渍碎屑直到芯片软化,并改变要提取的产品的化学状态。 可能的是,可以在170℃和210℃之间的温度下用饱和蒸汽处理碎屑,然后进行爆炸减压以产生木屑。 之后是在允许研磨木材的破碎机中进行精炼操作。 结果是从至少部分分解的木片中的防腐剂和油的实质释放。 化学防腐剂和油分别从在浸渍,蒸汽烹饪 - 爆炸减压和精炼步骤中生产的水相中的木片中分离收集。