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    • 2. 发明申请
    • PRETREATMENT OF LIGNOCELLULOSIC BIOMASS THROUGH REMOVAL OF INHIBITORY COMPOUNDS
    • 通过去除抑制性化合物预处理细菌生物量
    • US20120329116A1
    • 2012-12-27
    • US13555645
    • 2012-07-23
    • Frank A. DOTTORIRobert Ashley Cooper BENSONRegis-Olivier BENECH
    • Frank A. DOTTORIRobert Ashley Cooper BENSONRegis-Olivier BENECH
    • D21B1/36C12P7/14
    • D21B1/36C12P2201/00D21C1/02D21C5/005D21C11/0007
    • A process for the pretreatment of lignocellulosic biomass is disclosed, which includes the steps of pretreating the lignocellulosic biomass to hydrolyze and solubilize hemicelluloses in the biomass; explosively decomposing the biomass into fibers; and extracting from the resulting solids fraction a liquefied portion of the lignocellulosic biomass before or after explosive decomposition. This removes compounds from the lignocellulosic biomass which are inhibitory to enzymatic cellulose hydrolysis and sugar fermentation to ethanol. For improved economy, the inhibitory compounds are not completely removed. The extraction step is controlled on the basis of the xylose equivalent content in the reaction mixture and the extracting step is discontinued once a xylose equivalent content of 4-8% w/w of xylose in the dry matter of the solids fraction is achieved. This most economically balances the practical need for inhibitory compound removal with the economical need to minimize the costs of the overall ethanol production process.
    • 公开了一种用于木质纤维素生物质的预处理的方法,其包括预处理木质纤维素生物质以在生物质中水解和增溶半纤维素的步骤; 将生物质爆炸分解成纤维; 并从所得固体部分提取在爆炸性分解之前或之后的木质纤维素生物质的液化部分。 这从木质纤维素生物质中除去抑制酶纤维素水解和糖发酵成乙醇的化合物。 为了改善经济性,抑制性化合物不能完全去除。 提取步骤基于反应混合物中的木糖当量含量进行控制,一旦实现固体部分的干物质中木糖当量含量为4-8%w / w的木糖,就停止萃取步骤。 这最经济地平衡了抑制化合物去除的实际需要与经济需要最小化整个乙醇生产过程的成本。
    • 3. 发明申请
    • TWO STAGE CONTINUOUS PRE-TREATMENT OF LIGNOCELLULOSIC BIOMASS
    • 两阶段连续预处理细菌生物量
    • US20130029406A1
    • 2013-01-31
    • US13554601
    • 2012-07-20
    • Frank A. DOTTORIRobert Ashley Cooper BENSONRegis-Olivier BENECH
    • Frank A. DOTTORIRobert Ashley Cooper BENSONRegis-Olivier BENECH
    • C12S3/02C08B37/00
    • C08H8/00C08B37/0057Y02E50/16Y02E50/343
    • Disclosed is a method of pretreating biomass in two pretreatment stages as part of a biofuel production process. The first stage pretreatment is carried out by heating the biomass to a first stage temperature of 140° C. to 180° C. for a first stage time of 30 minutes to 2 hours at a first stage pressure of 105 to 150 psig; and the second stage is carried out by heating the biomass to a second stage temperature of 190° C. to 210° C. for a second stage time of 2 to 10 minutes at a second stage pressure of 167 to 262 psig. The biomass may be initially conditioned prior to the first pretreatment stage by atmospheric steam heating and adjusting the moisture content of the biomass. Hemicellulose and inhibitors (inhibitory compounds) to downstream hydrolysis and fermentation are preferably removed between the first and second pretreating stages, more preferably after each pretreatment stage.
    • 公开了在两个预处理阶段中预处理生物质的方法,作为生物燃料生产过程的一部分。 第一阶段预处理通过在105至150psig的第一阶段压力下将生物质加热至140℃至180℃的第一阶段温度进行30分钟至2小时的第一阶段时间; 并且第二阶段通过在167-226psig的第二阶段压力下将生物质加热至190℃至210℃的第二阶段温度进行2至10分钟的第二阶段时间。 生物质可以在第一预处理阶段之前通过大气蒸汽加热和调节生物量的水分含量进行初始调节。 优选在第一和第二预处理阶段之间去除下游水解和发酵的半纤维素和抑制剂(抑制化合物),更优选在每个预处理阶段之后。