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    • 84. 发明授权
    • Process for trichromatic dyeing or printing
    • 三色染色或印刷方法
    • US5399183A
    • 1995-03-21
    • US157852
    • 1993-11-24
    • Jean-Marie Adam
    • Jean-Marie Adam
    • C09B67/22D06P3/16D06P3/24D06P3/82C09BD06P3/06D06P3/14
    • D06P3/16D06P3/241D06P3/8209Y10S8/917Y10S8/924
    • Process for the trichromatic dyeing or printing of natural or synthetic polyamide fibre materials, which comprises using at least one blue-dyeing anthraquinone dye of the formula ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4, independently of one another, are hydrogen or C.sub.1 -C.sub.6 alkyl, the sum of the carbon atoms of the radicals R.sub.1, R.sub.2, R.sub.3 and R.sub.4 being 4, 5 or 6 and the sulfo group in the anthraquinone dye of the formula (1) being attached in the position designated as 6 or 7, together with at least one red-dyeing dye of the formula (2) and at least one of the yellow- or orange-dyeing dyes of the formulae (3), (4) and (5), the dyes of the formulae (2), (3), (4) and (5) being as defined in claim 1.The process according to the invention is suitable for dyeing natural or synthetic polyamide materials from an aqueous liquor or for printing with printing pastes.
    • 天然或合成聚酰胺纤维材料的三色染色或印刷方法,其包括使用至少一种式(1)的蓝染色蒽醌染料,其中R 1,R 2,R 3和R 4彼此独立地是 是氢或C 1 -C 6烷基,基团R 1,R 2,R 3和R 4的碳原子总数为4,5或6,并且式(1)的蒽醌染料中的磺基被附加在指定为 6或7,连同至少一种式(2)的染色染料和至少一种式(3),(4)和(5)的黄色或橙色染色剂中的染料, 式(2),(3),(4)和(5)如权利要求1所定义。根据本发明的方法适用于从水性液体中染色天然或合成聚酰胺材料或用印刷浆料印刷。
    • 85. 发明授权
    • Red dye mixtures and their use: dyeing natural or synthetic polyamides
    • 红色混合物及其用途:染色天然或合成多胺
    • US5090964A
    • 1992-02-25
    • US615536
    • 1990-11-19
    • Dieter Mausezahl
    • Dieter Mausezahl
    • C09B67/22D06P3/06
    • C09B67/0051D06P3/06Y10S8/917Y10S8/924
    • The invention relates to a dye mixture containing a dye of the formula ##STR1## in which R.sub.1 is methyl or ethyl and at least one dye of the formula ##STR2## in which R.sub.2 is substituted or unsubstituted C.sub.1 -C.sub.8 alkyl is halogen, benzoylamino which unsubstituted or substituted in the phenyl ring by halogen, or 1-azacycloheptane-N-sulfonyl or ##STR3## in which R.sub.5 is C.sub.1 14 C.sub.8 alkyl or phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, and R.sub.6 is hydrogen or C.sub.1 -C.sub.8 alkyl, R.sub.3 is hydrogen, halogen or C.sub.1 -C.sub.8 alkyl, and R.sub.4 is hydrogen or halogen. The dye mixture is distinguished by generally good properties, in particular by good exhaustion.
    • 本发明涉及含有式(1)的染料的染料混合物,其中R1是甲基或乙基,以及至少一种式(2)的染料,其中R 2是取代或未取代的C 1 -C 8烷基 是未取代的或被苯基环被卤素取代的苯甲酰基氨基,或1-氮杂环庚烷-N-磺酰基或其中R 5是C 11-14 C 8烷基或被C 1 -C 4烷基取代的苯基,R 6是氢或 C1-C8烷基,R3是氢,卤素或C1-C8烷基,R4是氢或卤素。 染料混合物的特征在于通常具有良好的性能,特别是通过良好的耗尽。
    • 88. 发明授权
    • Process for dyeing fiber material made of natural polyamides with
anionic wool dyes at pH 4.5 to 5.5 in the presence of a dyeing assistant
    • 在染色助剂存在下,使用阴离子羊毛染料在pH 4.5至5.5下染色由天然聚酰胺制成的纤维材料的方法
    • US4444564A
    • 1984-04-24
    • US474352
    • 1983-03-11
    • Heinz SalatheHermann FlensbergHarry Schaetzer
    • Heinz SalatheHermann FlensbergHarry Schaetzer
    • D06P1/60D06P1/607D06P3/06D06P3/14
    • D06P1/6076D06P3/06Y10S8/917
    • The invention relates to a process for the non-skittery and level dyeing of fibre material made of natural polyamides, with dyes or mixtures of dyes in the presence of a mixture of dyeing assistants, which comprises using for dyeing these materials an aqueous liquor which contains at least one anionic wool dye which, under the defined dyeing conditions at 1/1 standard depth, exhausts to at least 95%, and a dyeing assistant mixture containing an anionic compound of the formula ##STR1## in which R is an alkyl or alkenyl radical having 12 to 22 carbon atoms, M is hydrogen, an alkali metal or ammonium, and m and n are integers such that the sum of m and n is 2 to 14, a quaternary compound of the formula ##STR2## in which R', independently of R, is what R has been defined as, A is an anion, Q is a substituted or unsubstituted alkyl radical, and p and q are integers such that the sum of p and q is 20 to 50 , and a non-ionic compound of the formula ##STR3## in which R", independently of R, is what R has been defined as, and x and y are integers such that the sum of x and y is 80 to 140, and which liquor can, if desired, also contain an ammonium or alkali metal salt, and finishing the dyeing regardless of its depth at pH 4.5-5.5 and at a temperature of 95.degree. to 105.degree. C. The process according to the invention is suitable for dyeing natural polyamide materials, especially wool, but also wool/nylon, wool/polyester, wool/cellulose or wool/polyacrylonitrile blends and silk, giving, with various types of dye or mixtures of dyes of identical or different dye types, non-skittery and level dyeings having good fastness properties.
    • 本发明涉及一种在染色助剂的混合物存在下,用天然聚酰胺,染料或染料混合物制成的纤维材料的无污染和水平染色方法,该方法包括用于将含有 至少一种阴离子羊毛染料,其在规定的染色条件下以1/1标准深度排出至少95%,以及含有下式的阴离子化合物(1)的染色助剂混合物,其中R为 具有12至22个碳原子的烷基或烯基,M是氢,碱金属或铵,m和n是整数,使得m和n的和为2至14,式(I)的季化合物 2)其中R'与R独立地是R被定义为A是阴离子,Q是取代或未取代的烷基,p和q是整数,使得p和q之和为20〜 50,和式(3)的非离子化合物,其中R“独立地为氢 y的R是R被定义为,x和y是整数,使得x和y之和为80〜140,如果需要的话,也可以含有铵或碱金属盐,以及整理 无论其深度在pH 4.5-5.5以及95至105℃的温度下均可进行染色。本发明的方法适用于染色天然聚酰胺材料,特别是羊毛,还适用于羊毛/尼龙,羊毛/聚酯, 羊毛/纤维素或羊毛/聚丙烯腈混合物和丝绸,与各种类型的染料或具有相同或不同染料类型的染料的混合物,具有良好牢度性质的非污渍和水平染色。
    • 90. 发明授权
    • Aniline azo dyes from 1,2,3,4-tetrahydroquinoline and
2,3-dihydro-1,4-benzoxazine couplers containing sulfate alkyl groups
    • 苯胺偶氮染料来自1,2,3,4-四氢喹啉和2,3-二氢-1,4-苯并恶嗪成色剂,其含硫酸烷基
    • US4305874A
    • 1981-12-15
    • US94144
    • 1979-11-14
    • Max A. WeaverRalph R. Giles
    • Max A. WeaverRalph R. Giles
    • C09B29/08C09B29/36C09B29/44C09B31/047C09B31/14C09B29/01D06P3/06
    • C09B29/0803C09B29/3643C09B29/3686C09B31/047C09B31/14
    • Disclosed are novel dyes which comprise aniline diazo moieties and certain aromatic amine couplers having sulfate groups. These dyes are substantially water soluble and are particularly useful for dyeing polyamide, wool and the like and exhibit, for example, excellent dyeability properties and fastness to light and gas. The dyes correspond to the general formula: ##STR1## wherein ring A may be unsubstituted or substituted with 1-3 of a variety of groups which themselves may be substituted such as alkyl, alkoxy, chloro, bromo, iodo, trifluoromethyl, thiocyano, cyano, phenylazo, acyl, and the like; R.sub.1 is a group such as alkyl, alkoxy, halogen, acylamido, alkylthio, and aryloxy; m is 0, 1, or 2; R.sub.2 represents the linking groups necessary to form a 1,2,3,4-tetrahydroquinoline or a 2,3-dihydro-1,4-benzoxazine structure, which may be substituted, in combination with the phenylene ring; Z is a linking group such as alkylene; and M is H.sup.+, Na.sup.+, K.sup.+, or NH.sub.4.sup.+.
    • 公开了包含苯胺重氮部分和具有硫酸根基团的某些芳族胺成色剂的新型染料。 这些染料基本上是水溶性的,并且特别可用于染色聚酰胺,羊毛等,并且显示出例如优异的可染性和耐光性。 染料对应于以下通式:其中环A可以是未取代的或被1-3个各自可以被取代的基团取代,例如烷基,烷氧基,氯,溴,碘,三氟甲基,氰基氰基,氰基 ,苯偶氮,酰基等; R1是烷基,烷氧基,卤素,酰氨基,烷硫基和芳氧基等基团; m为0,1或2; R2表示与亚苯基环结合形成可被取代的1,2,3,4-四氢喹啉或2,3-二氢-1,4-苯并恶嗪结构所必需的连接基团; Z是亚烷基等连接基团; M是H +,Na +,K +或NH 4 +。