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81. 发明授权

US5068220A Biodegradable polyamides for providing a controlled release therapeutic drug 失效
标题翻译：可生物降解的聚酰胺，用于提供控释药物
公开(公告)号：US5068220A
公开(公告)日：1991-11-26
申请号：US534974
申请日：1990-06-08
申请人： David P. Vanderbilt , Donald R. Cowsar , Richard L. Dunn , James P. English
发明人： David P. Vanderbilt , Donald R. Cowsar , Richard L. Dunn , James P. English
IPC分类号： A61K9/20 , A61L17/10 , C08G18/60 , C08G69/26
CPC分类号： C08G69/265 , A61K9/2045 , A61L17/10 , C08G18/603
摘要： Biodegradable polyamides, useful as absorbable sutures and as controlled release binder materials, are prepared by condensing 4,4'-spirobibutyrolactone with a primary diamine, optionally in the presence of a nylon salt, leading to homopolymers containing lactam structural units, or to random copolymers.
摘要翻译：可用作吸收性缝合线和控制释放粘合剂材料的生物可降解聚酰胺通过任选在尼龙盐存在下使4,4'-螺二丁内酯与伯二胺缩合制备，导致含有内酰胺结构单元的均聚物，或无规共聚物。

82. 发明授权

US4954577A Lacquer binders, coating compositions and wire enamels based on polyamideimides and isocyanates carrying carbodiimide and/or uretone imine groups 失效
标题翻译：基于聚酰胺酰亚胺和携带碳二亚胺和/或脲酮亚胺基团的异氰酸酯的漆基粘合剂，涂料组合物和线搪瓷
公开(公告)号：US4954577A
公开(公告)日：1990-09-04
申请号：US184494
申请日：1988-04-18
申请人： Willi Dunwald , Hans Schlegel , Reinhard Halpaap , Josef Pedain
发明人： Willi Dunwald , Hans Schlegel , Reinhard Halpaap , Josef Pedain
IPC分类号： C08G18/60 , C08G18/34 , C08G18/64 , C08G18/79 , C08G18/80 , C09D5/25 , C09D175/00 , C09D179/08 , H01B3/30
CPC分类号： C08G18/8061 , C08G18/345 , C08G18/6438 , C08G18/797 , H01B3/30
摘要： Lacquer binders suitable for the production of highly heat-resistant films and coatings consisting of a mixture of(a) polyamide-imides based on trimellitic anhydride, lactams and diisocyanates,(b) organic compounds carrying (i) carbodiimide and/or uretone imine groups and (ii) blocked isocyanate groups and optionally,(c) auxiliaries and additives.The use of these binders in coating compositions for heat-resistant substrates and a process for the production of wire enamels using said coating compositions.
摘要翻译：适用于生产高耐热性薄膜和涂料的涂料粘合剂，包括（a）基于偏苯三酸酐，内酰胺和二异氰酸酯的聚酰胺 - 酰亚胺的混合物，（b）携带（i）碳二亚胺和/或脲酮亚胺基团的有机化合物和（ii）封端的异氰酸酯基团和任选的（c）助剂和添加剂。这些粘合剂在耐热基材的涂料组合物中的用途以及使用所述涂料组合物生产线搪瓷的方法。

83. 发明授权

US4950735A Biodegradable polyamides 失效
标题翻译：可生物降解聚酰胺
公开(公告)号：US4950735A
公开(公告)日：1990-08-21
申请号：US224316
申请日：1988-07-26
申请人： David P. Vanderbilt , Donald R. Cowsar , Richard L. Dunn , James P. English
发明人： David P. Vanderbilt , Donald R. Cowsar , Richard L. Dunn , James P. English
IPC分类号： A61K9/20 , A61L17/10 , C08G18/60 , C08G69/26
CPC分类号： A61L17/10 , A61K9/2045 , C08G18/603 , C08G69/265
摘要： Biodegradable polyamides, useful as absorable sutures and as controlled release binder materials, are prepared by condensing 4,4'-spirobibutyrolactone with a primary diamine, optionally in the presence of a nylon salt, leading to homopolymers containing lactam structural units, or to random copolymers.
摘要翻译：可用作吸收性缝合线和控制释放粘合剂材料的可生物降解聚酰胺可通过将4,4'-螺二丁内酯与一级二胺缩合制备，任选在尼龙盐存在下，导致含有内酰胺结构单元的均聚物，或无规共聚物。

84. 发明授权

US4746715A Process for the production of hydroxytelechelic polymers and their use as components of polyurethane elastomers 失效
标题翻译：用于生产羟基可可聚合物的方法及其作为聚氨酯弹性体组分的用途
公开(公告)号：US4746715A
公开(公告)日：1988-05-24
申请号：US840285
申请日：1986-03-14
申请人： Renate Dworczak , Bernd Trathnigg , Hans Junek , Andreas Schmidt
发明人： Renate Dworczak , Bernd Trathnigg , Hans Junek , Andreas Schmidt
IPC分类号： C08G18/00 , C08F4/00 , C08F4/04 , C08F36/00 , C08F36/04 , C08F36/06 , C08G18/38 , C08G18/60 , C08G18/62 , C08G18/69
CPC分类号： C08G18/62 , C08F36/04 , C08G18/696
摘要： The invention relates to a process for the production of polyurethanes, in particular of polyurethane elastomers under use of diols and diisocyanates as well as optionally chain extenders, comprising the improvement of using diols or optionally chain extenders having at least one terminal group of the formula ##STR1## wherein X is a straight or branched alkylene group with 2 to 12 C-atoms. The diols or chain extenders are mainly polymers or oligomers of ethylenically unsaturated monomers and preferably have a hydroxyl functionality in the proximity of 2, preferably of 1,9 to 2,1.The invention further relates to a process for the radical polymerization, comprising the improvement of polymerizing ethylenically unsaturated monomers in the presence of azo-bis-N,N'-isobutyric acid hydroxyalkyl amides of the general formula ##STR2## wherein X is a straight or branched alkylene group with 2 to 12 C-atoms.
摘要翻译：本发明涉及用于生产聚氨酯的方法，特别是使用二醇和二异氰酸酯以及任选的增链剂的聚氨酯弹性体的方法，该方法包括改进使用具有至少一个下式的末端基团的二醇或任选的增链剂： IMAGE>其中X是具有2至12个C原子的直链或支链亚烷基。二醇或扩链剂主要是烯键式不饱和单体的聚合物或低聚物，优选具有接近2，优选1.9至2.1的羟基官能度。本发明还涉及一种自由基聚合方法，其包括在通式为（I）的偶氮二-N，N'-异丁酸羟烷基酰胺存在下改进烯属不饱和单体的聚合，其中X为具有2至12个C原子的直链或支链亚烷基。

85. 发明授权

US4728697A Novel copolyamideimides, prepolymers therefor and method for their preparation 失效
标题翻译：新型共聚酰胺酰亚胺，其预聚物及其制备方法
公开(公告)号：US4728697A
公开(公告)日：1988-03-01
申请号：US780853
申请日：1985-09-27
申请人： Donald A. Bolon , Thomas B. Gorczyca
发明人： Donald A. Bolon , Thomas B. Gorczyca
IPC分类号： C08G18/40 , C08G18/38 , C08G18/60 , C08G18/64 , C08G73/10 , C08G73/12 , C08G73/14 , C08J3/24 , C09D5/25 , C09D179/08 , H01B3/30
CPC分类号： C08G73/1071 , C08G18/3821 , C08G18/6438 , C08G73/1014 , C08G73/105 , C08G73/106 , C08G73/14 , H01B3/306
摘要： Carboxy-terminated prepolymers are prepared by the reaction of a diamine, preferably an aromatic diamine, or a mixture thereof with a triamine, with a carboxy anhydride such as trimellitic anhydride and a dianhydride such as bisphenol A dianhydride. The prepolymers, or functional derivatives thereof, are then reacted with a diisocyanate or diamine, or a mixture thereof with a triisocyanate or triamine, preferably an aromatic diisocyanate, to produce copolyamideimides. The products prepared using triamines or triisocyanates are crosslinked. Other products containing alkyl or alicyclic groups attached to aromatic radicals can be oxidatively crosslinked, e.g., by heating in air.
摘要翻译：羧基封端的预聚物通过二胺，优选芳族二胺或其与三胺的混合物与羧酸酐如偏苯三酸酐和二酐如双酚A二酐的反应来制备。然后将预聚物或其官能衍生物与二异氰酸酯或二胺或其混合物与三异氰酸酯或三胺，优选芳族二异氰酸酯反应，生成共聚酰胺酰亚胺。使用三胺或三异氰酸酯制备的产物是交联的。含有与芳族基团连接的烷基或脂环族基团的其它产物可以氧化交联，例如通过在空气中加热。

86. 发明授权

US4689361A Coating powders based on polyamide and adhesion improving diisocyanate additive for use in melt film coating method 失效
标题翻译：基于聚酰胺的涂料粉末和改善粘合剂的二异氰酸酯添加剂，用于熔融涂膜法
公开(公告)号：US4689361A
公开(公告)日：1987-08-25
申请号：US841639
申请日：1986-03-20
申请人： Salih Mumcu , Rainer Feldmann
发明人： Salih Mumcu , Rainer Feldmann
IPC分类号： C09D5/03 , C08G18/60 , C08G18/80 , C08K5/16 , C08L77/00 , C09D5/46 , C09D177/00 , C08G69/46
CPC分类号： C09D177/00 , C08G18/603 , C08G18/807 , C08K5/16 , C08L77/00 , C08G2150/20 , Y10T428/31725
摘要： Coating powders for the melt film coating method, based on polyamides and adhesion improving additives. The polyamides are aliphatic homo- and/or copolyamides having at least six carbon atoms containing functional groups consisting of at least 80% of primary, secondary, or mixtures of primary and secondary amino groups. As the adhesion improving additive there is added from 0.1 to 10% by weight referred to the polyamides of an isophoronediisocyanate capped with lactams, an isophoronediisocyanate capped with acetonoxime or an isophoronediisocyanate capped with an oligomer of acetonoxime.
摘要翻译：基于聚酰胺和粘合改进添加剂的熔融涂膜方法的涂料粉末。聚酰胺是具有至少6个碳原子的脂肪族均聚物和/或共聚酰胺，其含有至少80％的伯和仲氨基的伯，仲或混合物的官能团。作为粘合改进添加剂，加入0.1至10重量％，称为用内酰胺封端的异佛尔酮二异氰酸酯的聚酰胺，用乙酮肟覆盖的异佛尔酮二异氰酸酯或用丙酮肟低聚物封端的异佛尔酮二异氰酸酯。

87. 发明授权

US4611083A Liquid, urea group-containing polyisocyanate mixtures 失效
标题翻译：液态，含脲基的多异氰酸酯混合物
公开(公告)号：US4611083A
公开(公告)日：1986-09-09
申请号：US674077
申请日：1984-11-23
申请人： Ingolf Buethe , Matthias Marx , Willibald Schonleben
发明人： Ingolf Buethe , Matthias Marx , Willibald Schonleben
IPC分类号： C07C265/12 , C07C275/28 , C08G18/32 , C08G18/42 , C08G18/44 , C08G18/48 , C08G18/50 , C08G18/56 , C08G18/60 , C08G18/72 , C08G18/78 , C08G18/80 , C08L75/00 , C08L75/04 , C07C119/048
CPC分类号： C07C265/12 , C07C275/28 , C08G18/3228 , C08G18/5024 , C08G18/7825 , C08G18/8038
摘要： The invention relates to urea group-containing polyisocyanate mixtures which are liquid at room temperature and have an isocyanate group content of from 15 to 30 weight percent and a diphenylmethane diisocyanate content of from 55 to 90 weight percent, obtained through the reaction of(A) polyoxyalkylene polyamines having a functionality of from 2 to 5 and an amine number from 20 to 250 with a polyisocyanate (B) selected from the group consisting of(B1) a mixture of diphenylmethane diisocyanates and polyphenyl polymethylene polyisocyanates having a diphenylmethane diisocyanate content of from 55 to 90 weight percent or(B2) at least one diphenylmethane diisocyanate isomer.The polyisocyanate mixtures claimed in the invention are used to prepare dense or cellular polyurethane and/or polyisocyanurate plastics, in particular, flexible polyurethane foams.
摘要翻译：本发明涉及含有脲基的多异氰酸酯混合物，其在室温下为液体，异氰酸酯基含量为15〜30重量％，二苯基甲烷二异氰酸酯含量为55〜90重量％，通过（A）具有2至5的官能度和20至250的胺数的聚氧化烯多胺与选自（B1）二苯基甲烷二异氰酸酯和聚苯基多亚甲基多异氰酸酯的混合物的多异氰酸酯（B）的二异氰酸酯含量为55 至90重量％或（B2）至少一种二苯基甲烷二异氰酸酯异构体。本发明要求保护的多异氰酸酯混合物用于制备致密或细胞聚氨酯和/或聚异氰脲酸酯塑料，特别是柔性聚氨酯泡沫塑料。

88. 发明授权

US4536525A Aqueous coating composition based on a cationic amino urea resin, process for applying and baking the composition and the coated substrate thus obtained 失效
标题翻译：基于阳离子氨基脲树脂的水性涂料组合物，由此获得的涂布和烘烤组合物和涂布基材的方法
公开(公告)号：US4536525A
公开(公告)日：1985-08-20
申请号：US629574
申请日：1984-07-11
申请人： Karl-Heinz Freese , Hans-Jurgen Munch
发明人： Karl-Heinz Freese , Hans-Jurgen Munch
IPC分类号： C08G18/00 , C08G18/08 , C08G18/60 , C08G59/40 , C09D5/44 , C09D163/00 , C09D167/00 , C09D175/00 , C09D175/02 , C08L63/00 , C08L67/00
CPC分类号： C09D167/00 , C08G18/0814 , C08G59/4021 , C09D163/00 , C09D175/02 , C09D5/4419
摘要： The invention provides an aqueous coating composition based on a cationic amino urea resin having an amine number of 3-250 and obtained by reacting an organic isocyanate with a polyamino amide having an amine number of 40-500 and built up from a mono- or dicarboxylic acid and a polyamine, said composition also containing a solid particulate epoxy group-containing compound and/or a solid particulate polyester having a melting point of at least 40.degree. C. The invention also pertains to the process for applying and baking said composition and to the coated substrate thus obtained.
摘要翻译：本发明提供一种基于阳离子氨基脲树脂的水性涂料组合物，其胺值为3-250，通过使有机异氰酸酯与胺值为40-500的聚氨基酰胺反应并由单羧酸或二羧酸酸和多胺，所述组合物还含有固体颗粒环氧基化合物和/或熔点至少为40℃的固体颗粒聚酯。本发明还涉及施用和烘烤所述组合物的方法，并且由此获得涂覆的基底。

89. 发明授权

US4431758A Heat resistant resin composition comprising reaction product of polyamideimide resin, alcohol and acid component. 失效
标题翻译：耐热树脂组合物，其包含聚酰胺酰亚胺树脂，醇和酸组分的反应产物。
公开(公告)号：US4431758A
公开(公告)日：1984-02-14
申请号：US363799
申请日：1982-03-31
申请人： Yuichi Osada , Shozo Kasai , Yasunori Okada , Isao Uchigasaki , Toyoji Oshima , Yoshiyuki Mukoyama , Hiroshi Nishizawa
发明人： Yuichi Osada , Shozo Kasai , Yasunori Okada , Isao Uchigasaki , Toyoji Oshima , Yoshiyuki Mukoyama , Hiroshi Nishizawa
IPC分类号： C08G18/00 , C08G18/28 , C08G18/34 , C08G18/79 , C08G73/00 , C08G73/14 , C08L67/00 , C08L79/08 , C09D5/25 , C09D179/08 , H01B3/30 , C08G18/60 , C08G18/83 , C08G69/48
CPC分类号： C08G18/2855 , C08G18/343 , C08G73/14 , C08L79/08 , H01B3/306 , H01B3/308 , Y10T428/2933 , Y10T428/294 , Y10T428/31681
摘要： A heat resistant resin produced by reacting (A) a polyamideimide resin with (B) an alcohol component and (C) an acid component with heating is soluble in a cresol type solvent and gives coatings excellent in heat resistance, thermal shock resistance, wear resistance, resistance to hydrolysis, etc., suitable for enamelled wire.
摘要翻译：通过（A）聚酰胺酰亚胺树脂与（B）醇组分和（C）酸组分的加热反应制得的耐热树脂可溶于甲酚型溶剂中，得到耐热性，耐热冲击性，耐磨性优异的涂料，耐水解等，适用于漆包线。

90. 发明授权

US4248994A Polyurethane compositions derived from polyols containing a controlled distribution of carboxamide groups 失效
标题翻译：衍生自含有受控分配的羧酰胺基团的多元醇的聚氨酯组合物
公开(公告)号：US4248994A
公开(公告)日：1981-02-03
申请号：US48395
申请日：1979-06-14
申请人： William H. Cook
发明人： William H. Cook
IPC分类号： C08G18/50 , C08G18/60 , C08G18/32
CPC分类号： C08G18/5039 , C08G18/606
摘要： Polyols containing at least one carboxamide group, --[NHC.dbd.O]--, in the polyol backbone impart to polyurethane resin-forming systems a unique combination of normal pot life and accelerated curing characteristics without sacrifice of final physical properties. Methods are given for preparation of such polyols which enable incorporation of a small, predetermined number of such carboxamide groups, not exceeding in number the hydroxyl functionality of the polyol, into each and every individual polyol molecule. The rapid-curing/property-development characteristics of derived polyurethane resin-forming systems are especially valuable in molding operations, where both mold cycle times and curing energy requirements are substantially reduced in comparison with conventional polyurethane resin-forming systems having similar final physical properties.
摘要翻译：在多元醇骨架中含有至少一个羧酰胺基团的多元醇 - [NHC = O] - 赋予聚氨酯树脂形成体系在正常适用期和加速固化特性的独特组合，而不牺牲最终物理性能。给出了制备这种多元醇的方法，其使得能够将小的，预定数量的这种羧酰胺基团（不超过多元醇的羟基官能度）并入每个单独的多元醇分子中。衍生的聚氨酯树脂形成系统的快速固化/性能开发特性在成型操作中特别有价值，与具有相似最终物理性能的常规聚氨酯树脂形成系统相比，模具循环时间和固化能量要求都显着降低。

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