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81. 发明授权

US09399690B2 Silica support, preparation method thereof and metallocene catalyst using the same 有权
标题翻译：二氧化硅载体及其制备方法和使用其的金属茂催化剂
公开(公告)号：US09399690B2
公开(公告)日：2016-07-26
申请号：US14426656
申请日：2014-02-05
申请人： LG CHEM, LTD.
发明人： Dae Sik Hong , Ki Soo Lee , Heon Yong Kwon , Hyeon-Gook Kim , Eun Kyoung Song , Yong Ho Lee
IPC分类号： C08F4/02 , C08F4/6592 , C08F10/00 , C08F210/02 , C08F4/659 , C07F7/08 , C08F10/02 , B01J21/08 , B01J31/06 , B01J31/14 , B01J31/16 , B01J31/22 , C08F110/02
CPC分类号： C08F110/02 , B01J21/08 , B01J31/069 , B01J31/143 , B01J31/1616 , B01J31/2295 , B01J37/0209 , B01J2531/48 , C07F3/02 , C07F5/066 , C07F7/087 , C07F7/0876 , C07F17/00 , C08F4/02 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/02 , C08F210/02 , C08F2410/01 , Y02P20/52
摘要： This disclosure relates to a silica support for a metallocene catalyst used for olefin polymerization, a preparation method thereof, a metallocene catalyst using the same, and olefin polymer. Specifically, according to the present invention, a silica support used for preparing a metallocene supported catalyst is treated with a specific halogenized metal compound, thereby diversifying reaction sites to a cocatalyst when preparing a metallocene catalyst, and thus, the molecular weight distribution of produced olefin polymer may be much broadened and polymer having high molecular weight may be obtained compared to the existing support, even if the same metallocene catalyst is supported.
摘要翻译：本公开内容涉及用于烯烃聚合的茂金属催化剂的二氧化硅载体，其制备方法，使用它的金属茂催化剂和烯烃聚合物。具体地，根据本发明，用于制备茂金属负载的催化剂的二氧化硅载体用特定的卤化金属化合物处理，从而在制备茂金属催化剂时将反应位点分散到助催化剂上，因此，制备的烯烃的分子量分布聚合物可能会变宽，即使支持相同的茂金属催化剂，也可以获得与现有载体相比具有高分子量的聚合物。

82. 发明授权

US09394388B2 Hybrid supported metallocene catalyst, method for preparing the same, and process for preparing polyolefin using the same 有权
标题翻译：杂化负载型茂金属催化剂及其制备方法以及使用其制备聚烯烃的方法
公开(公告)号：US09394388B2
公开(公告)日：2016-07-19
申请号：US14382807
申请日：2013-03-05
申请人： SK Innovation Co., Ltd. , SK Global Chemical Co., Ltd.
发明人： Ho Seong Lee , Dong Cheol Shin , Sung Seok Chae , Kyu Cheol Cho , Seung Yeol Han , Jong Sok Hahn
IPC分类号： C08F4/653 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F4/659 , C08F210/16
CPC分类号： C08F110/02 , C08F4/65904 , C08F4/65916 , C08F4/6592 , C08F210/16
摘要： Provided are a hybrid supported metallocene catalyst, a method for preparing the same, and a process for preparing an olefin polymer using the same, and more particular, a hybrid supported metallocene catalyst characterized in that two kinds of metallocene compounds containing a new cyclopenta[b]fluorenyl transition metal compound are supported on an inorganic or organic porous carrier surface-treated with an ionic compound and a co-catalyst, a method for preparing the same, and a process for preparing an olefin polymer using the hybrid supported metallocene catalyst.
摘要翻译：提供了一种杂化负载型茂金属催化剂及其制备方法，以及使用该方法制备烯烃聚合物的方法，更具体地，涉及一种混合载体茂金属催化剂，其特征在于两种含有新的环戊二烯[b ]芴基过渡金属化合物负载在用离子化合物和助催化剂表面处理的无机或有机多孔载体上，其制备方法，以及使用该杂化载体金属茂催化剂制备烯烃聚合物的方法。

83. 发明授权

US09394382B2 Process and apparatus for the polymerisation of olefins 有权
标题翻译：用于烯烃聚合的方法和设备
公开(公告)号：US09394382B2
公开(公告)日：2016-07-19
申请号：US13988794
申请日：2011-12-14
申请人： Andrew David Bell , Jean-Louis Chamayou , Kevin Peter Ramsay
发明人： Andrew David Bell , Jean-Louis Chamayou , Kevin Peter Ramsay
IPC分类号： C08F2/34 , B01J8/24 , B01J8/44 , C08F10/00 , C08F110/02
CPC分类号： C08F10/00 , C08F2/34 , C08F110/02 , C08F2/007
摘要： Process for gas phase polymerization of olefins in a fluidized bed reactor by (a) passing a fluidizing gas containing at least one olefin monomer through a fluidized bed of polymer particles in the presence of a polymerization catalyst to produce polymer at a polymer production rate of C Tonnes/hour, (b) withdrawing a first gaseous stream containing solid particles from the top of the reactor, (c) passing the first gaseous stream to a gas/solids separator, separating solid particles therefrom, and forming a second gaseous stream containing residual solid particles, (d) passing a portion of the second gaseous stream to at least one heat exchanger to remove heat of reaction whereby residual solid particles contact the heat exchanger, and (e) recycling a portion of the cooled stream from step (d) as the fluidizing gas in step (a). The heat exchangers have a heat exchange surface area which totals less than 120×C m2.
摘要翻译：在流化床反应器中通过（a）在聚合催化剂存在下使包含至少一种烯烃单体的流化气体通过聚合物颗粒的流化床将烯烃气相聚合的方法以聚合物生产速率C 吨/小时，（b）从反应器顶部排出含有固体颗粒的第一气态流，（c）将第一气流送至气体/固体分离器，从其中分离固体颗粒，并形成含有残留物的第二气流固体颗粒，（d）将第二气流的一部分通入至少一个热交换器以除去反应热，由此残留的固体颗粒接触热交换器，和（e）将来自步骤（d）的冷却流的一部分再循环，作为步骤（a）中的流化气体。热交换器的热交换面积总计小于120×Cm2。

84. 发明申请

US20160200642A1 ZEOLITE CATALYSTS FOR THE CONVERSION OF ALKYL HALIDES TO OLEFINS 审中-公开
标题翻译：用于将烯烃转化成烯烃的沸石催化剂
公开(公告)号：US20160200642A1
公开(公告)日：2016-07-14
申请号：US14899003
申请日：2015-06-29
申请人： Ashim Kumar GHOSH , Mike MIER , SABIC GLOBAL TECHNOLOGIES B.V.
发明人： Ashim Kumar Ghosh , Mike Mier
IPC分类号： C07C1/30 , C01B39/38 , C08F10/00 , B01J29/40
CPC分类号： B01J29/40 , B01J29/90 , C01B39/38 , C07C1/26 , C07C2529/40 , C08F10/00 , Y02P20/52 , Y02P20/584 , C07C11/04 , C07C11/06 , C07C11/08
摘要： Disclosed is a method for converting an alkyl halide to an olefin. The method can include contacting a zeolite catalyst comprising HZSM-5 having a silica to alumina (SAR) ratio of at least 30 with a feed that includes an alkyl halide under reaction conditions sufficient to produce an olefin hydrocarbon product comprising C2 to C4 olefins, wherein the selectivity of the C2 to C4 olefins is at least 85% at 20% alkyl halide conversion.
摘要翻译：公开了将烷基卤转化为烯烃的方法。该方法可以包括使包含至少30的二氧化硅与氧化铝（SAR）比率的HZSM-5的沸石催化剂与足以产生包含C 2 -C 4烯烃的烯烃产物的反应条件下的包含烷基卤的进料接触，其中在20％烷基卤转化时，C2至C4烯烃的选择性至少为85％。

85. 发明授权

US09382377B2 Polymer mixtures as deposit inhibitors in water-bearing systems 有权
标题翻译：聚合物混合物作为含水系统中的沉积抑制剂
公开(公告)号：US09382377B2
公开(公告)日：2016-07-05
申请号：US13569538
申请日：2012-08-08
申请人： Jürgen Detering , Torben Gädt , Stephan Nied , Andreas Kempter , Bolette Urtel , Jessica Neumann
发明人： Jürgen Detering , Torben Gädt , Stephan Nied , Andreas Kempter , Bolette Urtel , Jessica Neumann
IPC分类号： C02F5/08 , C02F5/10 , C08F20/06 , C08F120/06 , C08F220/06 , C08F20/04 , C08F120/04 , C08F220/04 , C08F110/10 , C08G63/60 , C08L73/00 , C08L33/00 , C08F10/10 , C08F210/10 , C08F20/08 , C08F16/02 , C02F1/00 , C02F5/02 , C08F16/12 , C08F116/12 , C08F216/12 , C08F10/00 , C02F103/02 , C02F103/08
CPC分类号： C08G63/60 , C02F5/10 , C02F2103/023 , C02F2103/08 , C08F10/10 , C08F16/02 , C08F16/12 , C08F20/06 , C08F20/08 , C08F110/10 , C08F210/10 , C23F11/08 , C23F11/173 , C23F14/02
摘要： A polymer mixture in solid or aqueous form includes a content of from 5 to 95% by weight of a first polymer and a content of from 5 to 95% by weight of a second polymer. The first polymer is a water-soluble or water-dispersible polymer having a weight-average molecular weight of 1000 to 20 000 g/mol. The second polymer is a water-soluble or water-dispersible polymer having a weight-average molecular weight of 1000 to 50 000 g/mol. The polymer mixture can inhibit precipitation and sedimentation of calcium salts and magnesium salts in water-bearing systems.
摘要翻译：固体或水性形式的聚合物混合物包含5至95重量％的第一聚合物和5至95重量％的第二聚合物的含量。第一聚合物是重均分子量为1000至200000g / mol的水溶性或水分散性聚合物。第二聚合物是重均分子量为1000至50 000g / mol的水溶性或水分散性聚合物。聚合物混合物可以抑制含水体系中钙盐和镁盐的沉淀和沉淀。

86. 发明授权

US09382347B2 Ziegler-Natta catalysts doped with non-group IV metal chlorides 有权
标题翻译：掺杂非IV族金属氯化物的齐格勒 - 纳塔催化剂
公开(公告)号：US09382347B2
公开(公告)日：2016-07-05
申请号：US13028393
申请日：2011-02-16
申请人： Lei Zhang , David Knoeppel
发明人： Lei Zhang , David Knoeppel
IPC分类号： C08F4/06 , C08F4/72 , C08F4/70 , C08F4/64 , C08F4/80 , C08F4/02 , C08F4/60 , B01J37/00 , B01J31/00 , C08F10/00 , C08F110/02
CPC分类号： C08F4/6421 , C08F10/00 , C08F10/02 , C08F110/02 , C08F2410/03 , C08F4/6557 , C08F4/6574 , C08F2500/04 , C08F2500/07 , C08F2500/11 , C08F2500/12 , C08F2500/17 , C08F2500/18 , C08F2500/20 , C08F2500/23 , C08F2500/26
摘要： Ziegler-Natta catalysts, processes of forming the same and using the same are described herein. The process generally includes contacting a metal component with a magnesium dihalide support material to form a Ziegler-Natta catalyst precursor; contacting the support material with a dopant including a non-Group IV metal halide to form a doped catalyst precursor; and activating the doped catalyst precursor by contact with an organoaluminum compound to form a Ziegler-Natta catalyst.
摘要翻译：齐格勒 - 纳塔催化剂，其形成方法和使用它们的方法在本文中描述。该方法通常包括使金属组分与二卤化镁载体材料接触以形成齐格勒 - 纳塔催化剂前体; 使载体材料与包含非IV族金属卤化物的掺杂剂接触以形成掺杂的催化剂前体; 并通过与有机铝化合物接触来活化掺杂的催化剂前体以形成齐格勒 - 纳塔催化剂。

87. 发明授权

US09376517B2 Polymerisation process 有权
标题翻译：聚合过程
公开(公告)号：US09376517B2
公开(公告)日：2016-06-28
申请号：US14368397
申请日：2012-12-20
申请人： Ineos Europe AG
发明人： Andrew David Bell , Pierre-Marie Cagna , Fabrice Betton , David Heslop , Kevin Peter Ramsay
IPC分类号： C08F2/34 , C08F2/38 , C08F2/00 , C08F210/16 , C08F10/00
CPC分类号： C08F210/16 , C08F10/00 , C08F2/00 , C08F2/007 , C08F2/34
摘要： Process for the polymerization of monomer in a polymerization system having at least one component attached thereto which is flushed with a flush medium which enters the polymerization system. Initially, the component is flushed with a first flush medium, and subsequently the component is flushed with a second flush medium which differs in composition from the first flush medium. A flush gas containing monomer is used as the flush medium when the polymer production rate is above 10 Te/h.
摘要翻译：在具有至少一种附着于其上的组分的聚合体系中聚合单体的方法，其用进入聚合体系的冲洗介质冲洗。最初，用第一冲洗介质冲洗组分，随后用第二冲洗介质冲洗组分，组合物与第一冲洗介质的组成不同。当聚合物生产速率高于10 Te / h时，使用含冲洗气体的单体作为冲洗介质。

88. 发明授权

US09353197B2 Catalyst component for olefin polymerization and preparation method thereof 有权
标题翻译：烯烃聚合用催化剂组分及其制备方法
公开(公告)号：US09353197B2
公开(公告)日：2016-05-31
申请号：US13502508
申请日：2010-04-19
申请人： Xianzhi Xia , Jin Zhao , Yuexiang Liu , Jigui Zhang , Weili Li , Yang Tan , Suzhen Qiao , Renqi Peng , Ping Gao , Maoping Yin , Tianyi Zhang
发明人： Xianzhi Xia , Jin Zhao , Yuexiang Liu , Jigui Zhang , Weili Li , Yang Tan , Suzhen Qiao , Renqi Peng , Ping Gao , Maoping Yin , Tianyi Zhang
IPC分类号： C08F4/76 , C08F4/654 , C08F4/658 , C08F4/649 , C08F10/00 , C08F110/06
CPC分类号： C08F10/00 , C08F110/06 , Y02P20/52 , C08F4/6543 , C08F4/651
摘要： A catalyst component for olefin polymerization is disclosed, which comprises at least one diol ester type electron donor compound (a) and at least one diether type electron donor compound (b) among others, wherein the molar ratio of a to b is 0.55-50. A preparation method of the catalyst component, a catalyst comprising the catalyst component, and an olefin polymerization method using the catalyst which can especially be used for preparation of polypropylenes of low ash contents are also disclosed.
摘要翻译：公开了一种用于烯烃聚合的催化剂组分，其包含至少一种二醇酯型电子给体化合物（a）和至少一种二醚型电子给体化合物（b）等，其中a与b的摩尔比为0.55-50 。还公开了催化剂组分的制备方法，包含催化剂组分的催化剂和使用该催化剂的烯烃聚合方法，其可特别用于制备低灰分含量的聚丙烯。

89. 发明授权

US09348060B2 Polymeric triarylmethane dye, blue resin composition including for color filter including the polymeric dye and color filter using the resin composition 有权
标题翻译：聚合三芳基甲烷染料，包括用于滤色器的蓝色树脂组合物，包括聚合物染料和使用树脂组合物的滤色器
公开(公告)号：US09348060B2
公开(公告)日：2016-05-24
申请号：US14649058
申请日：2013-03-20
申请人： KYUNG-IN SYNTHETIC CO., LTD.
发明人： Soonhyun Park , Jung Rok Kim , Jeong Gi Kim , Hyun Jae Chun , Do Kyung Lee , Min-Jung Lee , Youna Lee
IPC分类号： G02B5/23 , G02B1/04 , G03F7/04 , C09B11/12 , C09B69/10 , G02B5/22 , G02F1/1335 , G03F1/00 , C08F10/00 , C08F132/08 , C08F136/00 , C08F232/08 , C08F236/00 , C08F32/08 , C08F36/00
CPC分类号： G02B1/04 , C09B11/12 , C09B69/103 , G02B5/223 , G02B5/23 , G03F7/0007 , G03F7/027 , G03F7/04 , G03F7/105
摘要： The present invention relates to a polymeric triarylmethane dye, a blue resin composition for a color filter including the polymeric dye, and a color filter using the resin composition. The blue resin composition of the present invention is highly soluble in solvents and has excellent luminance, contrast, heat resistance, and chemical resistance due to the use of the polymeric triarylmethane dye. Particularly, the blue resin composition exhibits higher luminance and contrast than blue resin compositions using existing pigments. In addition, the blue resin composition of the present invention has greatly improved heat resistance and chemical resistance compared to blue resin compositions using existing triarylmethane dye monomers.
摘要翻译：本发明涉及聚合三芳基甲烷染料，用于包含聚合染料的滤色剂的蓝色树脂组合物和使用该树脂组合物的滤色器。本发明的蓝色树脂组合物在溶剂中高度溶解，并且由于使用聚合三芳基甲烷染料而具有优异的亮度，对比度，耐热性和耐化学性。特别地，与使用现有颜料的蓝色树脂组合物相比，蓝色树脂组合物显示出更高的亮度和对此外，与使用现有的三芳基甲烷染料单体的蓝色树脂组合物相比，本发明的蓝色树脂组合物具有大大改善的耐热性和耐化学性。

90. 发明授权

US09315605B2 Method for producing an elastomer using a transition metal catalyst 有权
标题翻译：使用过渡金属催化剂制造弹性体的方法
公开(公告)号：US09315605B2
公开(公告)日：2016-04-19
申请号：US13340404
申请日：2011-12-29
申请人： Eun-Jung Lee , Sung-Soo Park , Beom-Doo Seo , Cheon-Il Park , Choong-Hoon Lee , Jong-Joo Ha , Jung-A Lee
发明人： Eun-Jung Lee , Sung-Soo Park , Beom-Doo Seo , Cheon-Il Park , Choong-Hoon Lee , Jong-Joo Ha , Jung-A Lee
IPC分类号： C08F4/6592 , C08F4/642 , C08F4/643 , C08F210/16 , C08F236/00 , C08F210/06 , C08F10/00 , C08F210/18 , C08F4/659
CPC分类号： C08F210/06 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/18 , C08F236/00 , C08F2420/01 , C08F2420/02 , C08F236/20 , C08F2500/01 , C08F2500/08 , C08F2500/12 , C08F2500/17 , C08F2500/21
摘要： The present invention relates to a method of producing an elastomer. Specifically, the method of producing an elastomer according to the present invention comprises a step of polymerizing ethylene, propylene, and optionally, a diene monomer in the presence of a catalyst composition containing a transition metal compound. The method of producing an elastomer according to the present invention makes it possible to prepare a high molecular weight, ethylene-propylene or ethylene-propylene-diene, elastic copolymer at a high temperature.
摘要翻译：本发明涉及弹性体的制造方法。具体而言，根据本发明的弹性体的制造方法包括在含有过渡金属化合物的催化剂组合物存在下聚合乙烯，丙烯和任选的二烯单体的步骤。根据本发明的制备弹性体的方法使得可以在高温下制备高分子量的乙烯 - 丙烯或乙烯 - 丙烯 - 二烯弹性共聚物。

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