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    • 82. 发明授权
    • Process for separation of zirconium-88, rubidium-83 and yttrium-88
    • US5330731A
    • 1994-07-19
    • US981449
    • 1992-11-25
    • Richard C. HeatonDavid J. Jamriska, Sr.Wayne A. Taylor
    • Richard C. HeatonDavid J. Jamriska, Sr.Wayne A. Taylor
    • C01F11/00C01F17/00C22B3/24G21F9/00C01F11/16C22B34/00
    • C01F17/0006C01F11/005G21F9/007
    • A process for selective separation of strontium-82 and strontium-85 from proton irradiated molybdenum targets is provided and includes dissolving the molybdenum target in a hydrogen peroxide solution to form a first ion-containing solution, passing the first ion-containing solution through a first cationic resin whereby ions selected from the group consisting of molybdenum, niobium, technetium, selenium, vanadium, arsenic, germanium, zirconium and rubidium remain in the first ion-containing solution while ions selected from the group consisting of rubidium, zinc, beryllium, cobalt, iron, manganese, chromium, strontium, yttrium and zirconium are selectively adsorbed by the first resin, contacting the first resin with an acid solution capable of stripping adsorbed ions from the first cationic exchange resin whereby the adsorbed ions are removed from the first resin to form a second ion-containing solution, evaporating the second ion-containing solution for time sufficient to remove substantially all of the acid and water from the second ion-containing solution whereby a residue remains, dissolving the residue from the evaporated second-ion containing solution in a dilute acid to form a third ion-containing solution, said third ion-containing solution having an acid molarity adapted to permit said ions to be adsorbed by a cationic exchange resin, passing the third ion-containing solution through a second cationic resin whereby the ions are adsorbed by the second resin, contacting the second resin with a dilute sulfuric acid solution whereby the adsorbed ions selected from the group consisting of rubidium, zinc, beryllium, cobalt, iron, manganese, chromium, and zirconium are selectively removed from the second resin, and contacting the second resin with a dilute acid solution whereby the adsorbed strontium ions are selectively removed. Zirconium, rubidium, and yttrium radioisotopes can also be recovered with additional steps.
    • 88. 发明授权
    • Method for separating barium from water-soluble strontium compounds
    • 从水溶性锶化合物中分离钡的方法
    • US4842833A
    • 1989-06-27
    • US214382
    • 1988-07-01
    • Paul Jager
    • Paul Jager
    • C01F11/00C01F11/32C01F11/46
    • C01F11/00C01F11/32
    • A method for separating barium contaminants from soluble strontium compounds comprising adding sulfuric acid and a basic strontium compound in solid, suspended or dissolved form to an aqueous solution of a barium-contaminated soluble strontium compound in controlled amounts with thorough stirring to maintain the pH of the solution between about 3 and about 10; removing solids which precipitate from the solution; and thereafter recovering a strontium compound having a decreased barium content from the solution. The method may be carried out continuously or batch-wise, and the sulfuric acid and basic strontium compound can be added in repeated alternating portions or continuously.
    • 一种用于从可溶性锶化合物中分离钡污染物的方法,包括以充分搅拌的方式将硫酸和固体,悬浮或溶解形式的碱性锶化合物加入钡污染的可溶性锶化合物的水溶液中,以保持pH 约3至约10; 从溶液中除去沉淀的固体; 然后从溶液中回收钡含量降低的锶化合物。 该方法可以连续地或间歇地进行,硫酸和碱式锶化合物可以重复交替部分或连续加入。