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    • 81. 发明授权
    • Method to decrease aldehyde content in polyolefin products
    • 降低聚烯烃产品中醛含量的方法
    • US06632874B2
    • 2003-10-14
    • US09846648
    • 2001-05-01
    • Mark RuleYu ShiLinda Hsiaohua LiuJohn V. Standish
    • Mark RuleYu ShiLinda Hsiaohua LiuJohn V. Standish
    • B29D2200
    • C08F6/006C08K5/00C08L23/06C08L23/10Y10T428/1352C08L23/02
    • Methods are provided for decreasing aldehyde content in polyolefin materials comprising combining with the polyolefin material an organic additive compound which reacts with aldehydes to form water and a resulting organic compound. The organic additive compound comprises at least two hydrogen-substituted heteroatoms bonded to carbons of the organic additive compound such that the organic additive compound is reactive with aldehydes present in the polyolefin to form water and the resulting organic compound, which comprises an unbridged five- or six-member ring including the at least two heteroatoms. The resulting organic compound advantageously neither imparts an off-taste to food and beverage products in contact with the polyolefin nor discolors the polyolefin. Preferred polyolefins include polypropylene and polyethylene.
    • 提供了用于降低聚烯烃材料中醛含量的方法,包括与聚烯烃材料结合的有机添加剂化合物与醛反应形成水和所得的有机化合物。 有机添加剂化合物包含至少两个与有机添加剂化合物的碳结合的氢取代的杂原子,使得有机添加剂化合物与存在于聚烯烃中的醛反应形成水,所得的有机化合物包含未桥连的五元或 六元环,包括至少两个杂原子。 所得到的有机化合物有利地既不会对与聚烯烃接触的食品和饮料产品产生异味,也不会使聚烯烃变色。 优选的聚烯烃包括聚丙烯和聚乙烯
    • 82. 发明授权
    • Resin dispersion for cationic electrodeposition and low temperature curable cationic electrodeposition coating composition including the same
    • 用于阳离子电沉积的树脂分散体和包含其的低温可固化阳离子电沉积涂料组合物
    • US06476102B1
    • 2002-11-05
    • US09927022
    • 2001-08-09
    • Hoon ChungSeung-Jae BaekJong-Myung HongKi-Myong Song
    • Hoon ChungSeung-Jae BaekJong-Myung HongKi-Myong Song
    • C08K320
    • C09D5/4473C08K3/32C08K5/00C09D5/4492
    • Disclosed are a resin dispersion and a low-temperature curable cationic electrodeposition coating composition including the same, in which the dried coating film of the electrodeposition paint is lead-free and has an epoxy-acrylic double-layered structure for displaying excellent properties, and in which an organic solvent content can be minimized. The resin dispersion includes a cationic electrodeposition resin, deionized water, an acid for a neutralization, a reaction product of manganese phosphate and an acid diluted to a concentration of 10% in deionized water and a cationic surfactant. The cationic electrodeposition resin can be prepared in the presence of an organic solvent from (a) a cationic electrodeposition synthetic resin produced by an epoxy-amino addition reaction (b) an acrylic cationic electrodeposition resin having an amino group (c) a fatty acid ester resin synthesized by an esterification reaction of styrene-allylalcohol copolymer and fatty acid and (d) polyurethane cross-linking agent produced from a mixture of blocked polymethylene polyphenyl polyisocyanate and blocked isophorone diisocyanate. The cationic electrodeposition coating composition has a superior low-temperature curability. The cured film has an epoxy-acrylic double-layered structure to give a high functionality, for improving properties such as weather-resistance, yellowing resistance, etc.
    • 公开了一种树脂分散体和包含该电解质涂料的干燥涂膜的无卤阳离子电沉积涂料组合物,并且具有显示优异性能的环氧丙烯酸双层结构, 有机溶剂含量可以最小化。 树脂分散体包括阳离子电沉积树脂,去离子水,用于中和的酸,磷酸锰的反应产物和在去离子水和阳离子表面活性剂中稀释至10%浓度的酸。 阳离子电沉积树脂可以在有机溶剂的存在下由(a)通过环氧 - 氨基加成反应制备的阳离子电沉积合成树脂(b)具有氨基(c)脂肪酸酯的丙烯酸阳离子电沉积树脂 通过苯乙烯 - 烯丙醇共聚物和脂肪酸的酯化反应合成的树脂和(d)由封闭的聚亚甲基多苯基多异氰酸酯和封闭的异佛尔酮二异氰酸酯的混合物制备的聚氨酯交联剂。 阳离子电沉积涂料组合物具有优异的低温固化性。 固化膜具有环氧 - 丙烯酸双层结构,以提供高功能性,用于改善耐候性,耐黄变性等性能。
    • 83. 发明申请
    • Nonaqueous compositions and additives therefor
    • 非水组合物及其添加剂
    • US20020123537A1
    • 2002-09-05
    • US09977824
    • 2001-10-15
    • Miguel A. DonesRamesh L. Narayan
    • C08G059/00C08J003/28C08G075/04C08G073/00
    • C08L71/02C08G59/04C08G65/337C08G2650/06C08G2650/16C08K5/00C08L63/00C08L2205/05C09D7/63C08L2666/04C08L71/00
    • Nonaqueous compositions comprising at least one product of the reaction between A) a linking agent of formula IR4(Y)3nullnull(I)Wherein each Y group is a halogen atom or one Y group is a halogen atom and two Y groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R4 group to form an epoxy group, and R4 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) a compound of formula IIR3(EO)n(PO)m(BO)pXnullnull(II)Wherein R3 is substituted or unsubstituted, saturated or unsaturated, organic oxy or thio group having from 1 to 36 carbon atoms or a primary or secondary amino group having from 1 to 36 carbon atoms; n is a number of from 0 to 50; m is a number of from 0 to 50; p is a number of from 0 to 50; and X is hydrogen, or X can be a mercapto group, an amino group, or a C1-C6 alkylamino group in place of a terminal nullOH group, provided that when X is mercapto, amino or a C1-C6 alkylamino, the sum of n, m, and p must be at least 1; and the mole ratio of I:II is from about 0.1:1 to about 5:1.
    • 包含至少一种式A的连接剂与式(I)中的反应的至少一种产物,其中在线式> R4(Y)3(I) 其中,Y基为卤素原子,Y基为卤素原子,Y基为氧基,R2相邻的碳原子形成环氧基,R4为烷基三乙酰基 含有3至10个碳原子; 和B)式II的化合物,其中R3是(Ⅰ)化合物,其中R3是 具有1至36个碳原子的取代或未取代的饱和或不饱和的有机氧基或硫基或具有1至36个碳原子的伯或仲氨基; n为0〜50的数; m是从0到50的数字; p是从0到50的数字; 并且X是氢,或X可以是巯基,氨基或C1-C6烷基氨基代替末端-OH基团,条件是当X是巯基,氨基或C1-C6烷基氨基时,总和 n,m和p必须至少为1; 且I:II的摩尔比为约0.1:1至约5:1。
    • 84. 发明授权
    • Unsaturated polyester resin compositions
    • 不饱和聚酯树脂组合物
    • US06358620B1
    • 2002-03-19
    • US09517403
    • 2000-03-02
    • Howard B. YokelsonJames Van FleetKaren E. Medema
    • Howard B. YokelsonJames Van FleetKaren E. Medema
    • B32B2706
    • C08L67/07B32B5/28C08G63/918C08K5/00Y10T428/31786
    • This invention is chemically resistant thermosetting resins having low contents of volatile organic components comprising (i) a minor amount by weight of ethylenically unsaturated reactive solvent, (ii) a major amount by weight of an unsaturated polyester produced by a process which comprises; (a) condensing dihydric alcohol with at least one dicarboxylic acid and/or anhydride of dicarboxylic acid to form a condensation polymer having an acid number (AN) in a range upward from about 5 mg KOH/g polymer, and (b) reacting the condensation polymer with an amount of glycidyl methacrylate such that the weight ratio of glycidyl methacrylate to condensation polymer is in a range of from about 0.001 AN to about 0.005 AN.
    • 本发明是具有低含量挥发性有机成分的耐化学性热固性树脂,其包含(i)少量的烯键式不饱和反应性溶剂,(ii)主要通过包括以下方法生产的不饱和聚酯的重量: (a)将二元醇与二羧酸的至少一种二羧酸和/或酸酐缩合以形成在约5mg KOH / g聚合物上方范围内的酸值(AN)的缩合物,和(b)使 具有一定量的甲基丙烯酸缩水甘油酯的缩合聚合物使得甲基丙烯酸缩水甘油酯与缩聚物的重量比在约0.001An至约0.005A AN的范围内。