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    • 82. 发明申请
    • PARTIALLY AROMATIC POLYAMIDE MOULDING COMPOSITIONS AND THEIR USES
    • 部分芳族聚酰胺模塑组合物及其用途
    • US20120022194A1
    • 2012-01-26
    • US13179177
    • 2011-07-08
    • Andreas BAYERManfred HEWEL
    • Andreas BAYERManfred HEWEL
    • C08L77/00C08K5/5313B82Y30/00
    • C08G69/265C08K3/016C08K5/0066C08K5/51C08L23/0876C08L77/06C08L2666/06
    • An unreinforced, halogen-free polyamide moulding composition which is provided with flame retardants and from which it is possible to produce electric and/or electronic components which can be reliably soldered, i.e. in particular without blisters being formed in the soldering process, in particular at 260° C. and possibly higher temperatures after water absorption and in the case of critical designs of the components, and which have an elongation at break of at least 5% and reliably achieve the UL94 classification V0. These polyamide moulding compositions have the following composition: (A) 62-87% by weight of a partially aromatic, partially crystalline copolyamide having a melting point of 270° C. to 320° C. and made up of 100% by weight of diacid fraction composed of: 50-100% by weight of terephthalic acid (TPA) and/or naphthalenedicarboxylic acid; 0-50% by weight of isophthalic acid (IPA), and 100% by weight of diamine fraction composed of at least one diamine selected from the group consisting of: butanediamine, pentanediamine, hexanediamine, octanediamine, methyloctanediamine, nonanediamine, decanediamine, undecanediamine and dodecanediamine; (B) 5-15% by weight of ionomer; (C) 8-18% by weight of flame retardants; (D) 0-5% by weight of additives; where the components (A)-(D) add up to 100% by weight.
    • 一种无增强的无卤素聚酰胺模塑组合物,其具有阻燃剂,并且可以从其制备能够可靠地焊接的电气和/或电子部件,特别是在焊接过程中形成的泡罩,特别是在 260℃,吸水后可能较高的温度,在组分的关键设计的情况下,断裂伸长率至少为5%,可靠地达到UL94分级V0。 这些聚酰胺模塑组合物具有以下组成:(A)62-87重量%的部分芳族部分结晶的共聚酰胺,其熔点为270℃至320℃,并由100重量%的二酸组成 组分:50-100重量%的对苯二甲酸(TPA)和/或萘二甲酸; 0-50重量%的间苯二甲酸(IPA)和100重量%的由选自丁二胺,戊二胺,己二胺,辛二胺,甲基辛二胺,壬二胺,癸二胺,十一烷二胺中的至少一种二胺组成的二胺部分和 十二烷二胺 (B)5-15重量%的离聚物; (C)8-18重量%的阻燃剂; (D)0-5重量%的添加剂; 其中组分(A) - (D)加起来为100重量%。
    • 86. 发明申请
    • SEMIAROMATIC POLYAMIDE COMPRISING A CHAIN ENDING
    • 包含链末端的半纤维状聚酰胺
    • US20110206881A1
    • 2011-08-25
    • US13057828
    • 2009-08-06
    • Thierry BriffaudPhilippe Blondel
    • Thierry BriffaudPhilippe Blondel
    • C08L77/06C08G63/44B32B1/08
    • C09D177/06B32B1/08C08G69/26C08G69/265C08G69/28C08G69/36C08K3/32C08L37/00C08L77/06Y10T428/1386Y10T428/139Y10T428/1393Y10T428/1397Y10T428/29Y10T428/2982Y10T428/31725
    • The invention relates to a copolyamide comprising at least two different units corresponding to the following general formulation: A/X.T A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine)·(Cb diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36, advantageously between 9 and 18, X.T denotes a unit obtained from the polycondensation of a Cx diamine and of terephthalic acid, with x representing the number of carbon atoms of the Cx diamine, x being between 9 and 36, advantageously between 10 and 18, characterized in that said copolyamide exhibits: a content of amine chain ends of greater than or equal to 20 μeq/g, a content of acid chain ends of less than or equal to 100 μeq/g, and a content of unreactive chain ends of greater than or equal to 20 μeq/g, and to the process for the preparation of said copolyamide, to a composition comprising this copolyamide and to the use of this copolyamide and of such a composition.
    • 本发明涉及包含对应于以下一般配方的至少两个不同单元的共聚酰胺:A / XT A选自从氨基酸获得的单元,从内酰胺获得的单元和对应于式(Ca二胺)的单元 )·(Cb二酸),其表示二胺的碳原子数,b表示二酸的碳原子数,a和b各自在4和36之间,有利地在9和18之间,XT表示单元 由C x二胺和对苯二甲酸的缩聚获得,x表示C x二胺的碳原子数,x在9和36之间,有利地在10和18之间,其特征在于所述共聚酰胺表现出:胺的含量 大于或等于20μeq/ g的链端,酸链端的含量小于或等于100μeq/ g,非活性链端含量大于或等于20μeq/ g,并且 准备的过程 在该共聚酰胺上,使用包含该共聚酰胺的组合物和该共聚酰胺和这种组合物的用途。