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81. 发明申请

US20160326093A1 HYDROGENATION REACTION METHOD 审中-公开
标题翻译：氢化反应方法
公开(公告)号：US20160326093A1
公开(公告)日：2016-11-10
申请号：US15111263
申请日：2015-01-27
申请人： NIPPON SHOKUBAI CO., LTD.
发明人： Yuichi KITA , Yoshiaki HIRANO
IPC分类号： C07C209/36 , C07C45/59 , C07C29/141 , C07C29/149 , B01J23/652 , C07C45/00 , C07C5/03 , B01J23/44 , B01J23/46 , B01J21/18 , C07C29/145 , C07C29/20
CPC分类号： C07C209/36 , B01J21/18 , B01J23/44 , B01J23/462 , B01J23/6525 , C01B3/08 , C07C5/03 , C07C29/132 , C07C29/14 , C07C29/141 , C07C29/143 , C07C29/145 , C07C29/147 , C07C29/149 , C07C29/20 , C07C29/60 , C07C45/00 , C07C45/41 , C07C45/59 , C07C2521/18 , C07C2523/44 , C07C2601/14 , C10G45/22 , C10G47/00 , C10G65/12 , Y02E60/36 , C07C33/22 , C07C31/205 , C07C31/26 , C07C31/225 , C07C35/08 , C07C31/125 , C07C211/46
摘要： The present invention provides a novel hydrogenation reaction and hydrogenolysis reaction, and does not require a large scale hydrogen supply equipment and a high-pressure facility for a respective reaction. The present invention relates to a method for producing a hydrogenated compound, characterized in reducing a compound to be hydrogenated (C) using a hydrogen-containing compound (A) and a reduced compound (B) to produce the hydrogenated compound (c).
摘要翻译：本发明提供了新的氢化反应和氢解反应，并且不需要大规模的氢气供应设备和用于各自反应的高压设备。本发明涉及一种氢化化合物的制造方法，其特征在于，使用含氢化合物（A）和还原化合物（B）将氢化化合物（C）还原，生成氢化化合物（c）。

82. 发明授权

US09283545B2 Efficient and recyclable heterogeneous nanocatalysts 有权
标题翻译：有效和可回收的异质纳米催化剂
公开(公告)号：US09283545B2
公开(公告)日：2016-03-15
申请号：US13396052
申请日：2012-02-14
申请人： Tewodros Asefa , Ankush V. Biradar , Yanfei Wang
发明人： Tewodros Asefa , Ankush V. Biradar , Yanfei Wang
IPC分类号： B01J21/08 , C07C45/64 , C07C45/58 , C07C209/36 , B01J31/06 , B01J31/28 , B01J23/44 , C07C5/11 , C07C5/03 , C07C29/145 , B01J31/26 , C07C29/132 , C07C5/08 , B82Y30/00 , B82Y40/00 , B01J21/06 , B01J23/06 , B01J23/24 , B01J23/32 , B01J23/72 , B01J23/74 , B01J33/00 , B01J35/00 , B01J35/08 , B01J37/00 , B01J37/02 , B01J35/10
CPC分类号： B01J21/08 , B01J21/066 , B01J23/06 , B01J23/24 , B01J23/32 , B01J23/44 , B01J23/72 , B01J23/74 , B01J33/00 , B01J35/0013 , B01J35/002 , B01J35/006 , B01J35/0086 , B01J35/08 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/0018 , B01J37/0203 , B01J37/0209 , B01J37/0217 , B01J37/0221 , B82Y30/00 , B82Y40/00 , C07C5/03 , C07C5/08 , C07C29/132 , C07C29/145 , C07C45/64 , C07C209/365 , C07C2601/14 , C07C211/52 , C07C15/073 , C07C13/18 , C07C9/15 , C07C15/18 , C07C31/10 , C07C49/17 , C07C33/22
摘要： Efficient and recyclable heterogeneous nanocatalysts and methods of synthesizing and using the same are provided.
摘要翻译：提供了高效和可回收的异质纳米催化剂及其合成和使用方法。

83. 发明授权

US09045381B2 Ruthenium complexes and their uses in processes for formation and/or hydrogenation of esters, amides and derivatives thereof 有权
标题翻译：钌络合物及其在酯，酰胺和衍生物的形成和/或氢化方法中的用途
公开(公告)号：US09045381B2
公开(公告)日：2015-06-02
申请号：US13880328
申请日：2011-10-11
申请人： David Milstein , Ekambaram Balaraman , Chidambaram Gunanathan , Boopathy Gnanaprakasam , Jing Zhang
发明人： David Milstein , Ekambaram Balaraman , Chidambaram Gunanathan , Boopathy Gnanaprakasam , Jing Zhang
IPC分类号： B01J31/18 , C07B41/08 , C07C29/136 , C07C29/149 , C07C29/17 , C07C41/16 , C07C45/00 , C07C51/23 , C07C67/00 , C07C67/03 , C07C209/62 , C07C213/00 , C07C231/02 , C07C231/10 , C07D207/08 , C07D213/38 , C07D241/08 , C07D241/12 , C07D295/023 , C07D307/14 , C07D307/33 , C07D307/83 , C07D309/30 , C07D487/14 , C07F9/58 , C07F15/00 , C08G69/00 , C07C51/02 , C07C51/295 , C07B41/02 , C07B41/12 , C07B43/06 , C07C209/00 , C07C213/02 , C07F9/6558 , C07K1/00
CPC分类号： C07K5/12 , B01J31/18 , B01J31/189 , B01J31/2404 , B01J31/2409 , B01J31/248 , B01J31/2485 , B01J2231/40 , B01J2231/49 , B01J2231/643 , B01J2231/763 , B01J2531/0244 , B01J2531/821 , C07B41/02 , C07B41/08 , C07B41/12 , C07B43/04 , C07B43/06 , C07C29/136 , C07C29/149 , C07C29/177 , C07C41/16 , C07C41/26 , C07C45/002 , C07C45/006 , C07C51/00 , C07C51/02 , C07C51/23 , C07C51/295 , C07C67/00 , C07C67/03 , C07C67/297 , C07C209/00 , C07C209/62 , C07C213/00 , C07C213/02 , C07C231/02 , C07C231/10 , C07C2601/08 , C07C2601/10 , C07C2601/14 , C07D207/06 , C07D207/08 , C07D211/12 , C07D213/38 , C07D241/08 , C07D241/12 , C07D295/023 , C07D295/027 , C07D295/185 , C07D305/06 , C07D307/14 , C07D307/33 , C07D307/44 , C07D307/52 , C07D307/83 , C07D309/30 , C07D487/14 , C07F9/58 , C07F9/65583 , C07F15/0046 , C07F15/0053 , C07K1/00 , C08G69/00 , Y02P20/52 , C07C233/05 , C07C235/06 , C07C233/07 , C07C235/16 , C07C235/14 , C07C235/10 , C07C211/27 , C07C211/07 , C07C211/35 , C07C211/46 , C07C211/10 , C07C215/28 , C07C217/58 , C07C69/14 , C07C69/24 , C07C31/125 , C07C31/12 , C07C49/78 , C07C49/04 , C07C49/10 , C07C49/08 , C07C49/403 , C07C31/205 , C07C31/202 , C07C31/04 , C07C31/08 , C07C33/20 , C07C33/22 , C07C31/1355 , C07C31/10 , C07C43/13 , C07C69/78 , C07C69/75 , C07C53/124 , C07C53/126 , C07C59/125 , C07C57/32 , C07C61/08 , C07C57/30 , C07C65/21 , C07C63/08 , C07C63/06
摘要： The present invention relates to novel Ruthenium catalysts and related borohydride complexes, and the use of such catalysts, inter alia, for (1) hydrogenation of amides (including polyamides) to alcohols and amines; (2) preparing amides from alcohols with amines (including the preparation of polyamides (e.g., polypeptides) by reacting dialcohols and diamines and/or by polymerization of amino alcohols); (3) hydrogenation of esters to alcohols (including hydrogenation of cyclic esters (lactones) or cyclic di-esters (di-lactones) or polyesters); (4) hydrogenation of organic carbonates (including polycarbonates) to alcohols and hydrogenation of carbamates (including polycarbamates) or urea derivatives to alcohols and amines; (5) dehydrogenative coupling of alcohols to esters; (6) hydrogenation of secondary alcohols to ketones; (7) amidation of esters (i.e., synthesis of amides from esters and amines); (8) acylation of alcohols using esters; (9) coupling of alcohols with water to form carboxylic acids; and (10) dehydrogenation of beta-amino alcohols to form pyrazines. The present invention further relates to the novel uses of certain pyridine Ruthenium catalysts.
摘要翻译：本发明涉及新的钌催化剂和相关的硼氢化物络合物，以及这种催化剂的用途，特别是（1）将酰胺（包括聚酰胺）氢化成醇和胺; （2）由醇与胺制备酰胺（包括通过使二醇和二胺反应和/或通过氨基醇的聚合反应制备聚酰胺（例如多肽）; （3）将酯氢化成醇（包括环酯（内酯）或环状二酯（二内酯）或聚酯）的氢化）; （4）将有机碳酸酯（包括聚碳酸酯）氢化成醇，并将氨基甲酸酯（包括聚氨基甲酸酯）或脲衍生物氢化成醇和胺; （5）醇与酯的脱氢偶联; （6）将仲醇醇化成酮类; （7）酯的酰胺化（即从酯和胺合成酰胺）; （8）使用酯酰化醇; （9）将醇与水偶联以形成羧酸; 和（10）β-氨基醇脱氢形成吡嗪。本发明还涉及某些吡啶钌催化剂的新用途。

84. 发明授权

US08962852B2 Asymmetric hydrogenation method for ketone compound 有权
标题翻译：酮类化合物的不对称加氢方法
公开(公告)号：US08962852B2
公开(公告)日：2015-02-24
申请号：US13447632
申请日：2012-04-16
申请人： Wanbin Zhang , Delong Liu , Hui Guo , Yangang Liu
发明人： Wanbin Zhang , Delong Liu , Hui Guo , Yangang Liu
IPC分类号： C07F15/00 , C07C29/145 , C07C37/00 , C07C41/26 , C07C213/00 , C07B53/00
CPC分类号： C07C29/145 , C07B53/00 , C07B2200/07 , C07C37/002 , C07C41/26 , C07C213/00 , C07C2102/08 , C07C2102/10 , C07C2602/08 , C07C2602/10 , C07C33/22 , C07C33/20 , C07C33/46 , C07C43/23 , C07C39/11 , C07C33/24 , C07C33/18 , C07C35/36 , C07C35/32 , C07C215/68
摘要： The invention relates to an asymmetric hydrogenation method for ketone compounds, comprising the step of: under hydrogen atmosphere, in the presence of an in situ catalyst derived from a chiral ligand and a ruthenium salt, adding a ketone compound and a base into a second solvent to carry out an asymmetric hydrogenation for the ketone compound. The invention can obtain a conversion of 100% and a highest asymmetric inducement effect of 99.7% for the ketone compound. The invention has the advantages including simple procedure, high conversion and selectivity, good atom economy and good prospect of industrial application.
摘要翻译：本发明涉及酮化合物的不对称氢化方法，包括以下步骤：在氢气氛下，在衍生自手性配体和钌盐的原位催化剂存在下，将酮化合物和碱加入到第二溶剂中对酮化合物进行不对称氢化。本发明可以获得酮化合物的100％转化率和99.7％的最高不对称诱导效果。本发明具有工艺简单，转化率高，选择性好，原子经济性好，工业应用前景好的优点。

85. 发明申请

US20150051417A1 RUTHENIUM-DIAMINE COMPLEX AND METHOD FOR PRODUCING OPTICALLY ACTIVE COMPOUND 有权
标题翻译：十二烷基二胺复合物和生产光学活性化合物的方法
公开(公告)号：US20150051417A1
公开(公告)日：2015-02-19
申请号：US14528093
申请日：2014-10-30
申请人： TAKASAGO INTERNATIONAL CORPORATION
发明人： Taichiro TOUGE , Tomohiko HAKAMATA , Hideki NARA
IPC分类号： C07F15/00
CPC分类号： C07F15/0046 , B01J31/1805 , B01J31/2282 , B01J2231/643 , B01J2531/0205 , B01J2531/0216 , B01J2531/821 , C07B53/00 , C07B2200/07 , C07C29/143 , C07C41/26 , C07C209/52 , C07C2602/12 , C07D311/22 , C07C43/23 , C07C33/20 , C07C33/18 , C07C33/34 , C07C33/22 , C07C33/46 , C07C35/23
摘要： Provided is a ruthenium complex that is represented by general formula (1*) and is useful as an asymmetric reduction catalyst. (In the formula, * is an asymmetric carbon atom; R1 is an arenesulfonyl group, and the like; R2 and R3 are a phenyl group, and the like; R13 through R14 are selected from a hydrogen atom, C1-10 alkyl group, and the like, but R13 through R14 are not simultaneously hydrogen atoms; X is a halogen atom and the like; j and k are each either 0 or 1; and j+k is 0 or 2.)
摘要翻译：提供由通式（1 *）表示的钌络合物，可用作不对称还原催化剂。（式中，*为不对称碳原子，R1为芳烯磺酰基等，R2，R3为苯基等; R13〜R14选自氢原子，C1-10烷基，但R 13至R 14不同时为氢原子; X为卤素原子等; j和k各自为0或1; j + k为0或2.）

86. 发明申请

US20150031920A1 PROCESS FOR PRODUCING OPTICALLY ACTIVE SECONDARY ALCOHOL 有权
标题翻译：生产光活性二级醇的方法
公开(公告)号：US20150031920A1
公开(公告)日：2015-01-29
申请号：US14340790
申请日：2014-07-25
申请人： KANTO KAGAKU KABUSHIKI KAISHA , NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITY
发明人： TAKEAKI KATAYAMA , KUNIHIKO TSUTSUMI , KUNIHIKO MURATA , TAKESHI OHKUMA , NORIYOSHI ARAI
IPC分类号： C07C29/20 , C07C41/20
CPC分类号： C07C41/26 , B01J31/1815 , B01J31/183 , B01J31/24 , B01J2231/643 , B01J2531/821 , C07B53/00 , C07B2200/07 , C07C29/145 , C07C2531/28 , C07C33/22 , C07C33/46 , C07C43/23
摘要： [Object]The object of this invention is to provide a method for producing an optically active secondary alcohol at a high optical purity by hydrogenating a substrate carbonyl compound at a high efficiency using as a catalyst a ruthenium complex bearing as a ligand certain optically active diphosphine compound and a readily synthesized amine compound.[Solution]The method of producing an optically active secondary alcohol according to the present invention is characterized in that a substrate carbonyl compound (provided that 3-quinuclidinone, 3-quinuclidinone derivative having a substituent, and a ketone having an aromatic hydrocarbon group and a heterocycle are excluded) is reacted with hydrogen and/or a hydrogen donating compound in the presence of a ruthenium complex selected from the compounds expressed by following general formula (1) RuXYAB (1) [in the general formula (1), X and Y are the same or different from each other and denote a hydrogen atom or an anionic group, A denotes an optically active diphosphine expressed by the general formula (2), B denotes an amine compound expressed by following general formula (3)].
摘要翻译：本发明的目的在于提供一种高光学纯度的光学活性仲醇的制造方法，该方法通过使用作为配体的钌络合物作为配位体将某种光学活性的二膦作为催化剂，高效地氢化底物羰基化合物化合物和容易合成的胺化合物。 [溶液]本发明的光学活性仲醇的制造方法的特征在于，将底物羰基化合物（具有取代基的3-奎宁环酮，具有取代基的3-奎宁环酮衍生物和具有芳香族烃基的酮和杂环被排除）与选自下列通式（1）表示的化合物的钌络合物存在下，与氢和/或供氢化合物反应：RuXYAB（1）[通式（1）中，X和Y 彼此相同或不同，表示氢原子或阴离子基团，A表示由通式（2）表示的光学活性二膦，B表示由通式（3）表示的胺化合物]。

87. 发明申请

US20140364580A1 METAL ALKOXIDE COMPLEX, CATALYST COMPOSITION, AND PRODUCTION METHOD OF POLYCAPROLACTONE OR POLYLACTIDE 有权
标题翻译：金属氧化物复合物，催化剂组合物和聚碳酸酯或聚酯的生产方法
公开(公告)号：US20140364580A1
公开(公告)日：2014-12-11
申请号：US14363281
申请日：2012-09-11
申请人： Dongmei Cui , Xinli Liu , Bo Liu , Shihui Li , Dongtao Liu , Chunji Wu
发明人： Dongmei Cui , Xinli Liu , Bo Liu , Shihui Li , Dongtao Liu , Chunji Wu
IPC分类号： C08G63/82 , C08G63/84 , C08G63/83 , C08G63/85
CPC分类号： C08G63/823 , B01J31/0212 , B01J2231/14 , B01J2531/22 , C07C29/70 , C07C31/28 , C07C31/30 , C07C33/22 , C07C33/24 , C07F3/04 , C07F5/069 , C08G63/826 , C08G63/83 , C08G63/84 , C08G63/85
摘要： The invention provides a metal alkoxide complex of Formula (I), wherein X, M, R1, R2, R3, m, n, y and z are as defined in the Description. The invention also provides a catalyst composition comprising the metal alkoxide complex and a hydroxy-containing compound, wherein the molar ratio of the metal alkoxide complex to the hydroxy-containing compound is 1:01-1000. The invention also provides a production method of poly-ε- caprolactone or polyactide, wherein an ε-caprolactone monomer or a lactide monomer is reacted in the presence of the metal alkoxide complex or catalyst composition to obtain poly-ε-caprolactone or polylactide. The metal alkoxide complex and the catalyst composition thereof can be used to catalyze the synthesis of poly-ε- caprolactone or polylactide with a high efficiency. The molecular weight of polycaprolactone or polylactide can be controlled by the molar ratio of the metal alkoxide complex and the hydroxy-containing compound, and is adjustable in the range of 1000-600,000, and wherein the molecular weight distribution is from 1.03 to 1.50. [Xn-mM(OCR1R2R3)m]y·(organic solvent)z (I)
摘要翻译：本发明提供式（I）的金属醇盐配合物，其中X，M，R 1，R 2，R 3，m，n，y和z如说明书中所定义。本发明还提供了包含金属醇盐配合物和含羟基化合物的催化剂组合物，其中金属醇盐配合物与含羟基化合物的摩尔比为1:1.0-1000。本发明还提供了一种聚己内酯或聚丙交酯的制备方法，其中在金属醇盐络合物或催化剂组合物的存在下，使己内酯单体或丙交酯单体反应得到聚己内酯或聚丙交酯金属醇盐络合物及其催化剂组合物可用于以高效率催化聚合 - 己内酯或聚丙交酯的合成。聚己内酯或聚丙交酯的分子量可以通过金属醇盐络合物和含羟基化合物的摩尔比来控制，并且可以在1000-600,000的范围内调节，其中分子量分布为1.03-1.50。 [Xn-mM（OCR1R2R3）m] y·（有机溶剂）z（I）

88. 发明申请

US20140363369A1 PROCESS FOR PRODUCING HYDROGEN OR HEAVY HYDROGENS, AND HYDROGENATION (PROTIATION, DEUTERATION OR TRITIATION) OF ORGANIC COMPOUNDS USING SAME 审中-公开
标题翻译：生产氢或重氢的方法，以及使用相同方法的有机化合物的氢化（抑制，去除或检测）
公开(公告)号：US20140363369A1
公开(公告)日：2014-12-11
申请号：US14459673
申请日：2014-08-14
申请人： Hironao SAJIKI , Yasunari MONGUCHI , Yoshinari SAWAMA , Shinichi KONDO
发明人： Hironao SAJIKI , Yasunari MONGUCHI , Yoshinari SAWAMA , Shinichi KONDO
IPC分类号： C01B3/10 , C01B4/00
CPC分类号： C01B3/10 , C01B3/08 , C01B4/00 , C01B2203/0277 , C01B2203/1047 , C01B2203/1064 , C07B31/00 , C07B35/02 , C07B35/06 , C07B59/00 , C07B2200/05 , C07C1/26 , C07C5/09 , C07C5/10 , C07C29/143 , C07C29/17 , C07C41/20 , C07C41/24 , C07C41/26 , C07C45/61 , C07C209/36 , C07C213/02 , C07C221/00 , C07C2523/745 , C07C2601/14 , Y02E60/364 , C07C215/68 , C07C211/58 , C07C217/84 , C07C225/22 , C07C33/20 , C07C43/2055 , C07C33/22 , C07C43/205 , C07C43/23 , C07C49/807 , C07C15/18 , C07C13/28 , C07C15/24 , C07C15/52 , C07C9/15
摘要： An object is to provide a process for providing hydrogen or heavy hydrogens conveniently without the necessity of large-scale equipment and a process capable of performing hydrogenation (protiation, deuteration or tritiation) reaction conveniently without the use of an expensive reagent and a special catalyst. The production process includes a process for producing hydrogen or heavy hydrogens, containing subjecting water or heavy water to mechanochemical reaction in the presence of a catalyst metal, and a process for producing a hydrogenated (protiated, deuterated or tritiated) organic compound, containing subjecting an organic compound and water or heavy water to mechanochemical reaction in the presence of a catalyst metal.
摘要翻译：本发明的目的是提供一种方便地提供氢或重氢的方法，而不需要大规模设备和能够方便地进行氢化（促进，氘化或氚化）反应的方法，而不需要使用昂贵的试剂和特殊的催化剂。生产方法包括生产氢或重氢的方法，包括在催化剂金属存在下使水或重水进行机械化学反应，以及生产氢化（肟化或氘代或氚化）有机化合物的方法，有机化合物和水或重水在催化剂金属存在下进行机械化学反应。

89. 发明授权

US08871980B2 Process for producing hydrogen or heavy hydrogens, and hydrogenation (protiation, deuteration or tritiation) of organic compounds using same 有权
标题翻译：生产氢或重氢的方法，以及使用它们的有机化合物的氢化（促进，氘化或氚化）
公开(公告)号：US08871980B2
公开(公告)日：2014-10-28
申请号：US13817637
申请日：2011-08-16
申请人： Hironao Sajiki , Yasunari Monguchi , Yoshinari Sawama , Shinichi Kondo
发明人： Hironao Sajiki , Yasunari Monguchi , Yoshinari Sawama , Shinichi Kondo
IPC分类号： B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60 , C07C209/00 , C07C45/61 , C07C41/24 , C07C41/26 , C01B3/08 , C07B35/02 , C01B4/00 , C07C29/17 , C07B35/06 , C07C5/10 , C07C221/00 , C07C29/143 , C07C213/02 , C07B59/00 , C07C209/36 , C07C1/26 , C07C5/09 , C07B31/00 , C07C41/20
CPC分类号： C01B3/10 , C01B3/08 , C01B4/00 , C01B2203/0277 , C01B2203/1047 , C01B2203/1064 , C07B31/00 , C07B35/02 , C07B35/06 , C07B59/00 , C07B2200/05 , C07C1/26 , C07C5/09 , C07C5/10 , C07C29/143 , C07C29/17 , C07C41/20 , C07C41/24 , C07C41/26 , C07C45/61 , C07C209/36 , C07C213/02 , C07C221/00 , C07C2523/745 , C07C2601/14 , Y02E60/364 , C07C215/68 , C07C211/58 , C07C217/84 , C07C225/22 , C07C33/20 , C07C43/2055 , C07C33/22 , C07C43/205 , C07C43/23 , C07C49/807 , C07C15/18 , C07C13/28 , C07C15/24 , C07C15/52 , C07C9/15
摘要： An object is to provide a process for providing hydrogen or heavy hydrogens conveniently without the necessity of large-scale equipment and a process capable of performing hydrogenation (protiation, deuteration or tritiation) reaction conveniently without the use of an expensive reagent and a special catalyst. The production process includes a process for producing hydrogen or heavy hydrogens, containing subjecting water or heavy water to mechanochemical reaction in the presence of a catalyst metal, and a process for producing a hydrogenated (protiated, deuterated or tritiated) organic compound, containing subjecting an organic compound and water or heavy water to mechanochemical reaction in the presence of a catalyst metal.
摘要翻译：本发明的目的是提供一种方便地提供氢或重氢的方法，而不需要大规模设备和能够方便地进行氢化（促进，氘化或氚化）反应的方法，而不需要使用昂贵的试剂和特殊的催化剂。生产方法包括生产氢或重氢的方法，包括在催化剂金属存在下使水或重水进行机械化学反应，以及生产氢化（肟化或氘代或氚化）有机化合物的方法，有机化合物和水或重水在催化剂金属存在下进行机械化学反应。

90. 发明授权

US08859815B2 Sulphonylated diphenylethylenediamines, method for their preparation and use in transfer hydrogenation catalysis 有权
标题翻译：磺酰化二苯基乙二胺，其制备方法和用于转移氢化催化
公开(公告)号：US08859815B2
公开(公告)日：2014-10-14
申请号：US13313889
申请日：2011-12-07
申请人： Beatriz Dominguez , Antonio Zanotti-Gerosa , Gabriela Alexandra Grasa , Jonathan Alan Medlock
发明人： Beatriz Dominguez , Antonio Zanotti-Gerosa , Gabriela Alexandra Grasa , Jonathan Alan Medlock
IPC分类号： C07C311/13 , C07C311/14 , C07C311/16 , C07C33/20 , C07C33/22 , C07C33/46 , C07C303/38 , B01J31/18 , C07C29/143 , C07C311/18
CPC分类号： B01J31/1805 , B01J2231/643 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07B2200/07 , C07C29/143 , C07C311/18 , C07C2602/10 , C07C33/46 , C07C33/22 , C07C35/32
摘要： A diamine of formula (I) is described in which A is hydrogen or a saturated or unsaturated C1-C20 alkyl group or an aryl group; B is a substituted or unsubstituted C1-C20 alkyl, cycloalkyl, alkaryl, alkaryl or aryl group or an alkylamino group and at least one of X1, X2, Y1, Y2 or Z is a C1-C10 alkyl, cycloalkyl, alkaryl, aralkyl or alkoxy substituting group. The chiral diamine may be used to prepare catalysts suitable for use in transfer hydrogenation reactions.
摘要翻译：描述了式（I）的二胺，其中A是氢或饱和或不饱和的C 1 -C 20烷基或芳基; B是取代或未取代的C 1 -C 20烷基，环烷基，烷芳基，烷芳基或芳基或烷基氨基，X 1，X 2，Y 1，Y 2或Z中的至少一个是C 1 -C 10烷基，环烷基，烷芳基，芳烷基或烷氧基取代基。手性二胺可用于制备适用于转移氢化反应的催化剂。

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