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81. 发明申请

US20170130349A1 COVALENT ORGANIC FRAMEWORKS AS POROUS SUPPORTS FOR NON-NOBLE METAL BASED WATER SPLITTING ELECTROCATALYSTS 审中-公开
公开(公告)号：US20170130349A1
公开(公告)日：2017-05-11
申请号：US15348670
申请日：2016-11-10
申请人： Indian Educational and Research Institute
发明人： Vaidhyanathan RAMANATHAN , Dinesh MULLANGI , Shyamapada NANDI
IPC分类号： C25B11/04 , C25B1/04 , C25B11/03 , C01B13/02
CPC分类号： C25B11/0489 , C01B13/0207 , C25B1/04 , C25B11/035 , C25B11/0405 , C25B11/0415 , Y02E60/366
摘要： The present invention discloses porous covalent organic frameworks (COF) supported noble metal-free nanoparticles which are useful as electrocatalysts for a water splitting system, and to the process for preparation of such electrocatalysts. The covalent organic frameworks (COF) supported noble metal-free nanoparticles have general formula (I): COF_AxBy(M)n (Formula I) wherein COF is selected from a Tris (4-formylphenyl)amine terephthaldehyde polymer or a benzimidazole-phloroglucinol polymer; ‘A’ and ‘B’ each independently represent a transition metal selected from the group consisting of Ni, Co, Fe, Mn, Zn, and mixtures thereof; or ‘A’ and ‘B’ together represent a transition metal selected from the group consisting of Ni, Co, Fe, Mn, Zn, and mixtures thereof; ‘M’ represents hydroxide or a nitride ion; ‘x’ and ‘y’ represent the weight % of the metal loadings; or a ratio of x:y is between 0:1 and 1:0; and ‘n’ is an integer 1 or 2 or 3.

82. 发明申请

US20170122129A1 SYSTEM AND METHOD FOR LOAD BALANCING OF INTERMITTENT RENEWABLE ENERGY FOR AN ELECTRICITY GRID 审中-公开
公开(公告)号：US20170122129A1
公开(公告)日：2017-05-04
申请号：US15315476
申请日：2014-06-16
申请人： Siemens Aktiengesellschaft
发明人： Oliver Heid , Paul Beasley , Timothy Hughes
IPC分类号： F01K3/02 , C01B3/02 , C25B1/04 , H02P9/04 , F03D9/25 , F01K25/10 , H02K7/18 , C01C1/04 , F03D9/10
CPC分类号： F01K3/02 , C01B3/025 , C01B13/0207 , C01C1/0405 , C01C1/0417 , C25B1/04 , F01K25/106 , F03D9/10 , F03D9/19 , F03D9/255 , F05B2220/61 , H02K7/1807 , H02P9/04 , Y02E60/366 , Y02E70/10 , Y02P20/133 , Y02P20/52
摘要： A system and method for load balancing of intermittent renewable energy for an electricity grid includes a production unit for producing Hydrogen and Nitrogen, a mixing unit to receive and mix the Hydrogen and the Nitrogen, an Ammonia source for receiving and processing the Hydrogen-Nitrogen mixture, an Ammonia power generator for generating energy for the energy grid, a Hydrogen injection system for extracting a Hydrogen portion from a stage of the system and for adding extracted Hydrogen to the gas stream to be provided to the Ammonia power generator, and a Hydrogen control system for controlling a flow rate of Hydrogen from the Hydrogen injection system to the gas stream to be provided to the Ammonia power generator, the flow rate determined in accordance with a data set which contains information about actual working conditions of the Ammonia power generator and which is received by the Hydrogen control system.

83. 发明申请

US20170106359A1 WATER OXIDATION CATALYSTS AND METHODS OF USE THEREOF 审中-公开
公开(公告)号：US20170106359A1
公开(公告)日：2017-04-20
申请号：US14338384
申请日：2014-07-23
申请人： EMORY UNIVERSITY
发明人： Craig L. Hill , Yurii V. Gueletii , Djamaladdin G. Musaev , Qiushi Yin , Bogdan Botar
IPC分类号： B01J35/00 , B01J23/888 , H01M8/0606 , B01J23/00 , C01B13/02 , B01J27/188 , B01J23/652
CPC分类号： B01J35/004 , B01J23/002 , B01J23/6527 , B01J23/888 , B01J27/188 , B01J27/199 , B01J35/0033 , B01J2523/00 , B01J2523/15 , B01J2523/51 , C01B3/042 , C01B13/0207 , C01G51/006 , C01G55/002 , C01P2002/82 , C01P2002/84 , C01P2002/86 , C01P2002/88 , C01P2006/40 , H01M8/0606 , Y02E60/364 , Y02E60/50 , B01J2523/12 , B01J2523/69 , B01J2523/845 , B01J2523/13 , B01J2523/14 , B01J2523/41 , B01J2523/821
摘要： Homogeneous water oxidation catalysts (WOCs) for the oxidation of water to produce hydrogen ions and oxygen, and methods of making and using thereof are described herein. In a preferred embodiment, the WOC is a polyoxometalate WOC which is hydrolytically stable, oxidatively stable, and thermally stable. The WOC oxidized waters in the presence of an oxidant. The oxidant can be generated photochemically, using light, such as sunlight, or electrochemically using a positively biased electrode. The hydrogen ions are subsequently reduced to form hydrogen gas, for example, using a hydrogen evolution catalyst (HEC). The hydrogen gas can be used as a fuel in combustion reactions and/or in hydrogen fuel cells. The catalysts described herein exhibit higher turn over numbers, faster turn over frequencies, and/or higher oxygen yields than prior art catalysts.

84. 发明申请

US20160368789A1 ELECTROLYTIC ENRICHMENT METHOD FOR HEAVY WATER 有权
标题翻译：用于重水的电解质富集方法
公开(公告)号：US20160368789A1
公开(公告)日：2016-12-22
申请号：US14902363
申请日：2014-07-24
申请人： INDUSTRIE DE NORA S.p.A.
发明人： Akiyoshi MANABE , Yoshinori NISHIKI , Akira KUNIMATSU
IPC分类号： C02F1/461 , B01D59/40 , C25B1/04 , C01B5/02 , C01B13/02
CPC分类号： C02F1/461 , B01D59/40 , C01B5/02 , C01B13/0207 , C02F2001/4619 , C02F2201/46185 , C25B1/04 , G21F9/007 , G21F9/08 , Y02E60/366
摘要： An electrolytic enrichment method for heavy water includes enriching heavy water by electrolysis using an alkaline water electrolysis cell including an anode chamber that holds an anode, a cathode chamber that holds a cathode, and a diaphragm. In the method, an electrolyte prepared by adding high-concentration alkaline water to raw material water containing heavy water is circularly supplied to the anode chamber and the cathode chamber from a circulation tank; an anode-side gas-liquid separator and an anode-side water-seal device are connected to the anode chamber, and a cathode-side gas-liquid separator and a cathode-side water-seal device are connected to the cathode chamber; and electrolysis is continued while the alkali concentration in the electrolyte supplied to both electrolysis chambers is maintained at a constant concentration by circularly supplying, to the circulation tank, the electrolyte from which the gas generated from the anode-side gas-liquid separator and the cathode-side gas-liquid separator is separated.
摘要翻译：用于重水的电解富集方法包括通过使用包括保持阳极的阳极室，保持阴极的阴极室和隔膜的碱性水电解池电解来富集重水。在该方法中，通过向含有重水的原料水中添加高浓度碱性水而制备的电解质从循环罐向阳极室和阴极室循环供给; 阳极侧气液分离器和阳极侧水封装置连接到阳极室，阴极侧气液分离器和阴极侧水封装置连接到阴极室; 并且通过向循环罐循环供给从阳极侧气液分离器和阴极产生的气体的电解质，向供给到两个电解室的电解质中供给的电解质中的碱浓度保持恒定浓度，继续进行电解侧气液分离器分离。

85. 发明申请

US20160367968A1 Photocatalysts 审中-公开
标题翻译：光催化剂
公开(公告)号：US20160367968A1
公开(公告)日：2016-12-22
申请号：US15031738
申请日：2014-10-24
申请人： QUEEN MARY UNIVERSITY OF LONDON
发明人： Igor Larrosa Guerrero , Steven Colin Dunn , Armando Marsden Lacerda Neto
IPC分类号： B01J23/44 , B01J21/06 , B01J37/34 , B01D53/00 , C01B3/04 , A61L9/18 , C02F1/30 , B01J35/00 , B01J37/06
CPC分类号： B01J23/44 , A61L9/18 , A61L2209/12 , B01D53/007 , B01D2255/802 , B01D2259/802 , B01J21/063 , B01J23/42 , B01J27/24 , B01J35/0013 , B01J35/002 , B01J35/004 , B01J37/06 , B01J37/345 , C01B3/042 , C01B13/0207 , C02F1/30 , C02F2101/308 , C02F2303/04 , C02F2305/08 , C02F2305/10 , Y02E60/364 , Y02W10/37
摘要： The present invention provides photocatalysts capable of catalytic activity in the visible range of light comprising platinum group metal nanoparticles deposited on a metal oxide support. The nanoparticles have surface plasmon resonance in the visible range of light. The invention also provides processes for preparing the photocatalysts, methods of liquid and gas purification using the photocatalysts of the invention and devices for the same.
摘要翻译：本发明提供能够在包含沉积在金属氧化物载体上的铂族金属纳米颗粒的光的可见光范围内具有催化活性的光催化剂。纳米颗粒在可见光范围内具有表面等离子体共振。本发明还提供了制备光催化剂的方法，使用本发明的光催化剂的液体和气体净化方法及其用途。

86. 发明申请

US20160339413A1 TIO2 MATERIAL THAT IS ABSORBET IN THE VISIBLE SPECTRUM AND METHOD FOR PRODUCING SAME 有权
标题翻译： TIO2材料是可见光谱中的吸收材料及其生产方法
公开(公告)号：US20160339413A1
公开(公告)日：2016-11-24
申请号：US15114757
申请日：2015-01-27
申请人： TOTAL SA , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE-CNRS , ECOLE NATIONAL SUPERIEURE DE CHIMIE DE MONTPELLIER
发明人： Paolo Boscaro , Vasile Hulea , Nathalie Marcotte , François Fajula , Anne Galarneau , Francis Luck
IPC分类号： B01J21/06 , B01J35/06 , B01J35/04 , B01J37/06 , B01J37/04 , C02F1/72 , B01J21/18 , B01J27/24 , C01B3/04 , C01B13/02 , B01D53/00 , C02F1/32 , B01J35/00 , B01J37/08
CPC分类号： B01J21/063 , A61L9/18 , B01D53/007 , B01D2255/20707 , B01D2255/802 , B01D2258/06 , B01D2259/802 , B01J21/18 , B01J27/20 , B01J27/24 , B01J35/004 , B01J35/023 , B01J35/026 , B01J35/04 , B01J35/06 , B01J35/1033 , B01J35/1061 , B01J35/1076 , B01J37/033 , B01J37/036 , B01J37/04 , B01J37/06 , B01J37/08 , C01B3/042 , C01B13/0207 , C02F1/32 , C02F1/725 , C02F2305/10 , Y02E60/364 , Y02W10/37
摘要： The invention relates to a method for the production of a TiO2 material comprising: preliminary mixing a titanium alkoxide with an acid; adding water, a phase separator and of an N source to the mixture thereby obtaining a TiO2 gel; washing the TiO2 gel with isopropanol; drying and calcining the TiO2 gel to produce the material. The invention also relates to a TiO2 material exhibiting an absorbance in the visible spectrum and in particular a light absorption at 500 nm which is greater than 50% of the light absorption at 400 nm, and its use as photocatalyst for the degradation of pollutants in air or water and water splitting into H2, under radiation in the visible spectrum.
摘要翻译：本发明还涉及在可见光谱中表现出吸光度的TiO 2材料，特别是在500nm处的光吸收大于400nm处的光吸收的50％，并且其用作光催化剂用于降低空气中的污染物或水和水分解成H2，在可见光谱下辐射。

87. 发明申请

US20160327310A1 EFFICIENT DISSOCIATION OF WATER VAPOR IN ARRAYS OF MICROCHANNEL PLASMA DEVICES 审中-公开
标题翻译：水蒸汽在微波等离子体装置阵列中的有效分解
公开(公告)号：US20160327310A1
公开(公告)日：2016-11-10
申请号：US15150107
申请日：2016-05-09
申请人： The Board of Trustees of the University of Illinois
发明人： Zhen Dai , Thomas J. Houlahan , J. Gary Eden , Sung-Jin Park
IPC分类号： F24H1/18 , B01J19/08 , C01B3/04
CPC分类号： F24H1/186 , B01J19/0093 , B01J19/088 , B01J2219/00786 , B01J2219/00795 , B01J2219/00824 , B01J2219/0084 , B01J2219/00853 , B01J2219/0086 , B01J2219/00959 , B01J2219/0841 , B01J2219/0894 , C01B3/045 , C01B13/0207 , C01B2203/0861 , Y02E60/364
摘要： The invention provides methods and systems for water dissociation with microplasma generated in microchannel plasma arrays or chips. Preferred methods and systems introduce water vapor into a microchannel plasma array. Electrical power is applied to the microchannel plasma array to create a plasma chemical reaction of the water vapor in the micorchannel plasma array. Dissociated hydrogen and/or oxygen gas is collected at an output of the microchannel plasma array. The water vapor can be entrained in a carrier gas, but is preferably introduced without carrier gas. Direct introduction of water vapor has been demonstrated to provide efficiencies at an above 60%. The use of carrier gas reduces efficiency, but still exceeds efficiencies of prior methods discussed in the background.
摘要翻译：本发明提供了在微通道等离子体阵列或芯片中产生的用于水解离的微生物的方法和系统。优选的方法和系统将水蒸气引入微通道等离子体阵列。将电功率施加到微通道等离子体阵列以产生微通道等离子体阵列中的水蒸气的等离子体化学反应。在微通道等离子体阵列的输出处收集离解的氢和/或氧气。水蒸汽可以夹带在载气中，但优选在没有载气的情况下引入。已经证明直接引入水蒸汽提供了高于60％的效率。载气的使用降低了效率，但是仍然超过了在背景技术中讨论的现有方法的效率。

88. 发明申请

US20160193596A1 PHOTOCATALYST FOR WATER SPLITTING, PRODUCTION METHOD FOR SAME, AND PHOTOELECTRODE FOR WATER SPLITTING 有权
标题翻译：用于水分离的光致抗蚀剂，其生产方法和用于水分离的光电
公开(公告)号：US20160193596A1
公开(公告)日：2016-07-07
申请号：US15072923
申请日：2016-03-17
申请人： FUJIFILM Corporation , Japan Technological Research Association of Artificial Photosynthetic Chemical Process , THE UNIVERSITY OF TOKYO
发明人： Takashi HISATOMI , Kazunari DOMEN , Chisato KATAYAMA
IPC分类号： B01J35/00 , C01B3/04 , B01J37/08 , B01J27/24 , B01J37/04
CPC分类号： B01J35/004 , B01J23/20 , B01J23/75 , B01J27/24 , B01J35/002 , B01J37/04 , B01J37/08 , C01B3/04 , C01B3/042 , C01B13/0207 , C23C8/24 , Y02E60/364
摘要： The present invention provides a photocatalyst for water splitting which includes barium niobium oxynitride and exhibits excellent water splitting performance and a production method for the same, and a water splitting photoelectrode. The photocatalyst for water splitting of the present invention is a photocatalyst for water splitting including: an optical semiconductor and a promoter supported by the optical semiconductor, in which the optical semiconductor includes barium niobium oxynitride, and the promoter includes at least one substance selected from a group consisting of cobalt oxides and metallic cobalt.
摘要翻译：本发明提供一种水分解用光催化剂，其包含氮氧化铌钡并且显示出优异的水分解性能及其制备方法和水分解光电极。本发明的水分解用光催化剂是水分解用光催化剂，包括光学半导体和由光学半导体支持的促进剂，其中光学半导体包括氮化铌铌，并且该促进剂包括选自以下的至少一种物质：由钴氧化物和金属钴组成的组。

89. 发明申请

US20160006066A1 ENERGY CONVERSION SYSTEM 审中-公开
公开(公告)号：US20160006066A1
公开(公告)日：2016-01-07
申请号：US14700136
申请日：2015-04-29
申请人： John S. Robertson
发明人： John S. Robertson
IPC分类号： H01M8/06 , F01N3/00 , F02C3/20 , C01C1/04
CPC分类号： F02C3/20 , C01B3/025 , C01B3/08 , C01B13/0207 , C01B13/0248 , C01B21/04 , C01B2203/0233 , C01B2210/0048 , C01C1/003 , C01C1/0405 , C01C1/0488 , C25B1/00 , C25B1/04 , C25B15/08 , F01N3/00 , F02C3/00 , F03D9/007 , F03D9/008 , F03D9/19 , F05B2220/61 , F05B2220/62 , F23C2900/9901 , H01M8/0606 , H01M8/222 , Y02A20/141 , Y02E10/72 , Y02E60/366 , Y02E70/10 , Y02E70/20 , Y02P20/133 , Y02P20/52
摘要： An improved system of hardware and controls, known as a Hyper Hub, that absorbs electric power from any source, including hydropower, wind, solar, and other renewable energy resources, chemically stores the power in hydrogen-dense anhydrous ammonia, then reshapes the stored energy to the power grid with zero emissions by using anhydrous ammonia to fuel diesel-type, spark-ignited internal combustion, combustion turbine, fuel cell or other electric power generators, and for other purposes.

90. 发明申请

US20150251905A1 Separating Hydrogen From Disassociated Water 有权
标题翻译：从脱相水中分离氢
公开(公告)号：US20150251905A1
公开(公告)日：2015-09-10
申请号：US14201554
申请日：2014-03-07
申请人： Stellar Generation, Inc.
发明人： Jerome Lee Elkind
IPC分类号： C01B3/06 , C01B13/02
CPC分类号： C01B3/045 , B01J7/02 , B01J19/127 , B01J2219/00144 , B01J2219/2423 , C01B3/042 , C01B3/501 , C01B3/503 , C01B3/505 , C01B13/0207 , C01B13/0251 , C01B13/0255 , C01B2203/0405 , Y02E60/364
摘要： In some implementations, a system for producing hydrogen and oxygen from water includes a target, an oxygen selective membrane, a cooling chamber, and a hydrogen selective membrane. The target heats to at least a temperature that thermally decomposes water, receives water vapor, heats the received water vapor to the temperature that thermally decomposes water to form a heated vapor, and passes the heated vapor to an oxygen selective membrane. The oxygen selective membrane separates, at or near the temperature that thermally decomposes water, oxygen from the heated vapor to form a hydrogen-rich vapor. The cooling chamber cools the hydrogen-rich vapor to at least a specified temperature. The hydrogen selective membrane separates hydrogen in the hydrogen-rich vapor to leave substantially water vapor.
摘要翻译：在一些实施方案中，用于从水产生氢和氧的系统包括靶，氧选择性膜，冷却室和氢选择性膜。目标加热到至少一种使水分解的温度，接收水蒸汽，将接收到的水蒸气加热到热分解水形成加热的蒸气的温度，并将加热的蒸气通入氧选择性膜。氧气选择性膜在热分解水的温度或附近分离，来自加热的蒸气的氧气形成富氢蒸气。冷却室将富氢蒸气冷却至至少一定温度。氢选择性膜分离富氢蒸汽中的氢气以留下基本上水汽。

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