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    • 86. 发明授权
    • Plasma enhanced chemical vapor deposition method of forming titanium silicide comprising layers
    • 等离子体增强化学气相沉积法形成含硅化钛的层
    • US06767823B2
    • 2004-07-27
    • US10094580
    • 2002-03-06
    • Cem BasceriIrina VasilyevaAmmar DerraaPhilip H. CampbellGurtej S. Sandhu
    • Cem BasceriIrina VasilyevaAmmar DerraaPhilip H. CampbellGurtej S. Sandhu
    • H01L214763
    • H01L21/28518C23C16/42H01L21/28556
    • Chemical vapor deposition methods of forming titanium silicide comprising layers on substrates are disclosed. TiCl4 and at least one silane are first fed to the chamber at or above a first volumetric ratio of TiCl4 to silane for a first period of time. The ratio is sufficiently high to avoid measurable deposition of titanium silicide on the substrate. Alternately, no measurable silane is fed to the chamber for a first period of time. Regardless, after the first period, TiCl4 and at least one silane are fed to the chamber at or below a second volumetric ratio of TiCl4 to silane for a second period of time. If at least one silane was fed during the first period of time, the second volumetric ratio is lower than the first volumetric ratio. Regardless, the second feeding is effective to plasma enhance chemical vapor deposit a titanium silicide comprising layer on the substrate.
    • 公开了在衬底上形成包含层的硅化钛的化学气相沉积方法。 首先将TiCl 4和至少一种硅烷以等于或高于TiCl 4与硅烷的第一体积比率进料到室中。 该比例足够高以避免钛硅化物在衬底上的可测量沉积。 或者,在第一时间段内没有可测量的硅烷进料到室中。 无论如何,在第一阶段之后,将TiCl 4和至少一种硅烷以等于或低于第二体积比的TiCl 4与硅烷进料至室中第二时间段。 如果在第一时间段内进料至少一种硅烷,则第二体积比率低于第一体积比。 无论如何,第二次进料对于等离子体有效地增强化学气相沉积在基底上的包含硅化钛的层。
    • 90. 发明授权
    • DRAM processing methods
    • DRAM处理方法
    • US06579756B2
    • 2003-06-17
    • US10055512
    • 2001-10-25
    • Cem BasceriGurtej S. Sandhu
    • Cem BasceriGurtej S. Sandhu
    • H01L218242
    • H01L28/55
    • A capacitor processing method includes forming a capacitor comprising first and second electrodes having a capacitor dielectric region therebetween. The first electrode interfaces with the capacitor dielectric region at a first interface. The second electrode interfaces with the capacitor dielectric region at a second interface. The capacitor dielectric region has a plurality of oxygen vacancies therein. After forming the capacitor, an electric field is applied to the capacitor dielectric region to cause oxygen vacancies to migrate towards one of the first and second interfaces. Oxygen atoms are preferably provided at the one interface effective to fill at least a portion of the oxygen vacancies in the capacitor dielectric region. Preferably at least a portion of the oxygen vacancies in the high k capacitor dielectric region are filled from oxide material comprising the first or second electrode most proximate the one interface. In one implementation, a DRAM processing method includes forming DRAM circuitry comprising DRAM array capacitors having a common cell electrode, respective storage node electrodes, and a high k capacitor dielectric region therebetween. A voltage is applied to at least one of the first and second electrodes to produce a voltage differential therebetween under conditions effective to cause oxygen vacancies in the high k capacitor dielectric region to migrate toward one of the cell electrode or the respective storage node electrodes and react with oxygen to fill at least a portion of the oxygen vacancies in the capacitor dielectric region.
    • 电容器处理方法包括形成电容器,该电容器包括在其间具有电容器电介质区域的第一和第二电 第一电极在第一界面处与电容器介电区域接合。 第二电极在第二界面处与电容器介电区域接合。 电容器电介质区域中具有多个氧空位。 在形成电容器之后,电场被施加到电容器电介质区域,以引起氧空位向第一和第二界面之一迁移。 氧原子优选设置在有效填充电容器电介质区域中的氧空位的至少一部分的一个界面处。 优选地,高k电容器介电区域中的氧空位的至少一部分由包括最靠近一个界面的第一或第二电极的氧化物材料填充。 在一个实现中,DRAM处理方法包括形成DRAM电路,其包括DRAM阵列电容器,其具有公共单元电极,各自的存储节点电极和它们之间的高k电容器电介质区域。 电压施加到第一和第二电极中的至少一个,以在有效地引起高k电容器介电区域中的氧空位迁移到电池电极或相应存储节点电极之一的条件下产生它们之间的电压差,并且反应 用氧气填充电容器介质区域中的氧空位的至少一部分。