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    • 81. 发明授权
    • Solid particle dispersions for imaging elements
    • 用于成像元件的固体颗粒分散体
    • US5750323A
    • 1998-05-12
    • US698378
    • 1996-08-15
    • Raymond Peter ScaringeDavid Darrell MillerMary Christine BrickLeslie ShuttleworthMargaret Jones HelberSteven Evans
    • Raymond Peter ScaringeDavid Darrell MillerMary Christine BrickLeslie ShuttleworthMargaret Jones HelberSteven Evans
    • B01J13/00G03C1/005G03C1/83G03C7/388G03C1/06G03C1/10G03C1/38
    • G03C1/83G03C1/005G03C7/388G03C1/832
    • Solid particle dispersions of compounds useful in imaging elements can be made with substantially improved stability to particle growth by dispersing the compound of interest in the presence of a relatively small amount of a second compound that is structurally similar to the compound of interest. This second compound is combined with the compound of interest prior to dispersing the compound of interest, i.e., prior to milling in the case of milled dispersions, and prior to precipitation in the case of pH or solvent precipitated dispersions. While being distinct, the second compound has a similar chemical structure to the main compound. More specifically, the second compound and first compound each comprise an identical structural section thereof which makes up at least 75% of the total molecular weight of the first compound, and the second compound has at least one substituent bonded to the identical structural section which has a molecular weight higher than the corresponding substituent of the first compound. In preferred embodiments of the invention, the compound useful in imaging elements is a compound useful in photographic or thermal transfer printing elements, and the resulting stabilized dispersion is used in preparing a photographic or thermal transfer printing element.
    • 用于成像元件的化合物的固体颗粒分散体可以通过在相当少量的结构上类似于感兴趣的化合物的相对少量的第二化合物的存在下分散感兴趣的化合物,从而具有显着提高的颗粒生长稳定性。 在分散感兴趣的化合物之前,即在研磨的分散体的情况下,在研磨之前,并且在pH或溶剂沉淀分散体的情况下,在沉淀之前,将该第二化合物与感兴趣的化合物组合。 虽然不同,第二化合物与主要化合物具有相似的化学结构。 更具体地,第二化合物和第一化合物各自包含相同的结构部分,其占第一化合物的总分子量的至少75%,并且第二化合物具有至少一个与相同结构部分键合的取代基,其具有 分子量高于第一化合物的相应取代基。 在本发明的优选实施方案中,可用于成像元件的化合物是用于照相或热转印打印元件的化合物,所得稳定的分散体用于制备照相或热转印打印元件。
    • 90. 发明授权
    • Yellow dye mixture for thermal color proofing
    • US5045524A
    • 1991-09-03
    • US628817
    • 1990-12-14
    • Derek D. ChapmanSteven Evans
    • Derek D. ChapmanSteven Evans
    • B41M5/385B41M5/035B41M5/26B41M5/388B41M5/39C09B67/22G03F3/10
    • B41M5/388Y10S428/913Y10S428/914Y10S430/146
    • A yellow dye-donor element for thermal dye transfer comprises a support having thereon a dye layer comprising a mixture of yellow dyes dispersed in a polymeric binder, at least one of the yellow dyes having the formula: ##STR1## wherein: each R.sup.1 independently represents a substituted or unsubstituted alkyl group of from 1 to about 10 carbon atoms, a cycloalkyl group of from about 5 to about 7 carbon atoms; a substituted or unsubstituted allyl group; an aryl group of from about 6 to about 10 carbon atoms; a hetaryl group of from 5 to 10 atoms; acyl; arylsulfonyl; aminocarbonyl; aminosulfonyl; fluorosulfonyl; halogen; nitro; alkylthio; or arylthio;or any two adjacent R.sup.1 's together represent the atoms necessary to form a 5- or 6-membered fused ring;n represents an integer from 0-4;R.sup.2 represents hydrogen; a substituted or unsubstituted alkyl, cycloalkyl, allyl, aryl or hetaryl group as described above for R.sup.1 ; cyano; acyl; alkylsulfonyl; arylsulfonyl; or alkoxycarbonyl;Z represents cyano; alkoxycarbonyl; acyl; nitro; arylsulfonyl or alkylsulfonyl;Y represents hydrogen; a substituted or unsubstituted alkyl, cycloalkyl, allyl, aryl or hetaryl group as described above for R.sup.1 ; amino; alkylamino; arylamino; acylamino; or sulfonylamino;and at least one of the other of the dyes having the formula: ##STR2## wherein: R.sup.3 and R.sup.4 each independently represents the same groups as R.sup.1 above;R.sup.5 represents H, a substituted or unsubstituted alkyl, allyl, aryl or hetaryl group as described above for R.sup.1 ; halogen; carbamoyl; cyano; or alkoxycarbonyl;each R.sup.6 independently represents substituted or unsubstituted alkyl, aryl, allyl or hetaryl groups such as those listed above for R.sup.1 ; hydroxy, alkoxy, aryloxy, acyloxy, aminocarbonyl, aminosulfonyl, carbamoyloxy, halogen, aryl, cyano, nitro, trifluoromethyl, fluorosulfonyl, acylamido, alkoxycarbonyl, alkylthio, arylthio, alkylsulfonyl, arylsulfonyl, alkylsulfonamido or arylsulfonamido; or two adjacent R.sup.6 's together represent the atoms necessary to complete a 5- or 6-membered fused saturated or aromatic ring;X represents CR.sup.7 or N;R.sup.7 represents the same groups as R.sup.5 ; andm is an integer from 0 to 5.