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    • 4. 发明授权
    • Yellow dye mixture for thermal color proofing
    • 黄色染料混合物用于热色印
    • US5081101A
    • 1992-01-14
    • US676922
    • 1991-03-28
    • Steven EvansDerek D. Chapman
    • Steven EvansDerek D. Chapman
    • B41M5/382B41M5/26B41M5/385B41M5/388B41M5/39B41M5/50B41M5/52G03F3/10
    • B41M5/3854G03F3/108Y10S428/913Y10S428/914Y10S430/146
    • A yellow dye-donor element for thermal dye transfer comprises a support having thereon a dye layer comprising a mixture of yellow dyes dispersed in a polymeric binder, at least one of the yellow dyes having the formula: ##STR1## wherein: R.sup.1 is a substituted or unsubstituted alkyl group of from 1 to about 10 carbon atoms; a cycloalkyl group of from about 5 to about 7 carbon atoms; or a substituted or unsubstituted allyl group;R.sup.2 is any of the groups for R.sup.1 or represents the atoms which when taken together with Z form a 5- or 6-membered ring;Z is hydrogen; any of the groups for R.sup.1 ; alkoxy; halogen; aryloxy; or represents the atoms which when taken together with R.sup.2 forms a 5- or 6-membered ring;Y is any of the groups for R.sup.1 ; alkoxy of from 1 to about 10 carbon atoms; halogen; or represents the atoms necessary to complete a 5- or 6-membered ring, thus forming a fused ring system; andn is a positive integer from 1 to 3; and at least one of the other of the dyes having the formula: ##STR2## wherein: R.sup.6 represents a substituted or unsubstituted alkyl group of from 1 to about 10 carbon atoms; a cycloalkyl group of from about 5 to about 7 carbon atoms; a substituted or unsubstituted allyl group; or an aryl group having from about 6 to about 10 carbon atoms;R.sup.7 represents a substituted or unsubstituted alkoxy group having from 1 to about 10 carbon atoms; a substituted or unsubstituted aryloxy group having from about 6 to about 10 carbon atoms; NHR.sup.8 ; NR.sup.8 R.sup.9 or the atoms necessary to complete a 6-membered ring fused to the benzene ring;R.sup.3 and R.sup.4 each represents any of the groups for R.sup.6 ; or R.sup.3 and R.sup.4 can be joined together to form, along with the nitrogen to which they are attached, a 5- or 6-membered heterocyclic ring; or either or both of R.sup.3 and R.sup.4 can be joined to the carbon atom of the benzene ring at a position ortho to the position of attachment of the anilino nitrogen to form a 5- or 6-membered ring, thus forming a polycyclic system;R.sup.5 represents hydrogen; a substituted or unsubstituted alkyl group of from 1 to about 10 carbon atoms; a cycloalkyl group of from about 5 to about 7 carbon atoms; a substituted or unsubstituted allyl group; carbamoyl; or alkoxycarbonyl;R.sup.8 and R.sup.9 each independently represents any of the groups for R.sup.6 ; or R.sup.8 and R.sup.9 may be joined together to form, along with the nitrogen to which they are attached, a 5- or 6-membered heterocyclic ring;m is a positive integer from 1 to 3; andG represents a substituted or unsubstituted alkyl or alkoxy group of from 1 to about 10 carbon atoms; halogen; aryloxy; or represents the atoms necessary to complete a 5- or 6-membered ring, thus forming a fused ring system.In a preferred embodiment of the invention, a third yellow dye is employed having the formula: ##STR3## wherein: R.sup.10 represents OR.sup.13 or NHR.sup.13 ;R.sup.11 represents any of the groups for R.sup.4 ;R.sup.12 represents any of the groups for R.sup.4 ;R.sup.13 represents any of the groups for R.sup.6 ;J represents any of the groups for G; andp is a positive integer from 1 to 3.
    • 10. 发明授权
    • Yellow dye mixture for thermal color proofing
    • US5043317A
    • 1991-08-27
    • US628537
    • 1990-12-14
    • Derek D. ChapmanSteven Evans
    • Derek D. ChapmanSteven Evans
    • B41M5/385B41M5/035B41M5/26B41M5/388B41M5/39C09B67/22G03F3/10
    • B41M5/3858B41M5/3854B41M5/388Y10S428/913Y10S428/914Y10S430/146
    • A yellow dye-donor element for thermal dye transfer comprises a support having thereon a dye layer comprising a mixture of yellow dyes dispersed in a polymeric binder, at least one of the yellow dyes having the formula: ##STR1## wherein R.sup.1 is a substituted or unsubstituted alkyl group of from 1 to about 10 carbon atoms; a substituted or unsubstituted cycloalkyl group of from about 5 to about 7 carbon atoms; an allyl group; a substituted or unsubstituted aryl group; or a substituted or unsubstituted hetaryl group of from about 5 to about 10 atoms;R.sup.2 is any of the groups for R.sup.1 or represents the atoms which when taken together with Z form a 5- or 6-membered ring;Z is hydrogen; any of the groups for R.sup.1 ; alkoxy; halogen; aryloxy; or represents the atoms which when taken together with R.sup.2 forms a 5- or 6-membered ring;each Y independently represents any of the groups for R.sup.1 ; alkoxy of from 1 to about 10 carbon atoms; halogen; or two adjacent Y's together represent the atoms necessary to complete a 5- or 6-membered ring, thus forming a fused ring system; andn is a positive integer from 1 to 3;and at least one of the other of the dyes having the formula: ##STR2## wherein: R.sup.3 and R.sup.4 each independently represents the same groups as R.sup.1 above;R.sup.5 represents H, a substituted or unsubstituted alkyl, allyl, aryl or hetaryl group as described above for R.sup.1 ; halogen; carbamoyl; cyano; or alkoxycarbonyl;each R.sup.6 independently represents substituted or unsubstituted alkyl, aryl, allyl or hetaryl groups such as those listed above for R.sup.1 ; hydroxy, alkoxy, aryloxy, acyloxy, aminocarbonyl, aminosulfonyl, carbamoyloxy, halogen, aryl, cyano, nitro, trifluoromethyl, fluorosulfonyl, acylamido, alkoxycarbonyl, alkylthio, arylthio, alkylsulfonyl, arylsulfonyl, alkylsulfonamido or arylsulfonamido; or two adjacent R.sup.6 's together represent the atoms necessary to complete a 5- or 6-membered fused saturated or aromatic ring;X represents CR.sup.7 or N;R.sup.7 represents the same groups as R.sup.5 ; andm is an integer from 0 to 5.