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81. 发明授权

US07842773B2 Process for the preparation of organosilicon compounds having urethane groups 有权
标题翻译：制备具有氨基甲酸酯基团的有机硅化合物的方法
公开(公告)号：US07842773B2
公开(公告)日：2010-11-30
申请号：US11743691
申请日：2007-05-03
申请人： Christian Herzig
发明人： Christian Herzig
IPC分类号： C08G77/26
CPC分类号： C08G77/458 , C08K5/544
摘要： Organosilicon compounds containing urethane groups are prepared by reacting aminofunctional organosilicon compounds containing at least one siloxane unit AR a ⁢ SiO 3 - a 2 ( I ) per molecule and at least two siloxane units of the formula XR b ⁢ SiO 3 - b 2 ( II ) in which R are monovalent, optionally substituted C1-18 hydrocarbon radicals, A is a radical —R1(—NR2—R1)z—NR2—H (III), where R1 is a divalent C1-18 organic radical, R2 is a hydrogen atom or C1-18 hydrocarbon radical, X is a group capable of condensation, a is 0 or 1, b is 1 or 2, z is 0 or an integer from 1 to 10, are reacted with organic carbonates (2) containing a group of the formula —O—C(═O)O— (IV), and, in a second stage, the first stage reaction products are optionally condensed with silanes (3) bearing groups capable of condensation, to give higher molecular weight organosilicon compounds containing urethane groups.
摘要翻译：含有氨基甲酸酯基的有机硅化合物是通过使每分子含有至少一个硅氧烷单元AR a SiO 3 -a 2（I）的氨基官能有机硅化合物和至少两个式XR b SiO 3 -b 2（II ）其中R为单价，任选取代的C 1-18烃基，A为基团-R 1（-NR 2 -R 1）z -NR 2 -H（III），其中R 1为二价C 1-18有机基团，R 2为氢原子或C1-18烃基，X为能够缩合的基团，a为0或1，b为1或2，z为0或1至10的整数，与有机碳酸酯（2）反应，基团-O-C（= O）O-（IV），并且在第二阶段中，第一阶段反应产物任选地与具有能够缩合的基团的硅烷（3）缩合，得到较高分子量的有机硅含氨基甲酸酯基团的化合物。

82. 发明授权

US07655811B2 Method for producing OH-terminal organo hydrogen polysiloxanes 有权
标题翻译：生产OH-末端有机氢聚硅氧烷的方法
公开(公告)号：US07655811B2
公开(公告)日：2010-02-02
申请号：US12088967
申请日：2006-09-29
申请人： Gilbert Geisberger , Christian Herzig , Tassilo Lindner
发明人： Gilbert Geisberger , Christian Herzig , Tassilo Lindner
IPC分类号： C07F7/00
CPC分类号： C08G77/12
摘要： Hydroxyl-terminal organopolysiloxanes having diorganosiloxy groups and Si—H groups are prepared by reacting the appropriate chlorosilanes with less than 0.5 mol water per mol of hydrolyzable chlorine in a first step and recovering gaseous HCl, and more fully hydrolyzing with additional water in a second step.
摘要翻译：具有二有机甲硅烷氧基和Si-H基团的羟基末端有机聚硅氧烷是通过在第一步骤中使合适的氯硅烷与小于0.5mol水/ mol可水解氯反应制备的，并回收气态HCl，并在第二步中用额外的水进一步完全水解。

83. 发明申请

US20090197081A1 Beta-KETOCARBONYL-FUNCTIONAL SILOXANE POLYMER-CONTAINING COMPOSITIONS 审中-公开
标题翻译：含有β-甲基丙烯酰氧基官能的含硅氧烷聚合物的组合物
公开(公告)号：US20090197081A1
公开(公告)日：2009-08-06
申请号：US12438440
申请日：2007-08-06
申请人： Christian Herzig , Siegfried Dormeier
发明人： Christian Herzig , Siegfried Dormeier
IPC分类号： C08G16/00 , D02G3/00
CPC分类号： C08G77/38 , C08L83/06 , D06M15/643 , D06M2200/25 , Y10T428/2915 , Y10T428/2962
摘要： β-ketocarbonyl-functional organosilicon compounds in combination with an Si-free polyamine having at least two primary amino groups, provide storage stable compositions useful for fabric treating. The treated fabrics show less propensity toward yellowing.
摘要翻译： β-酮羰基官能的有机硅化合物与具有至少两个伯氨基的不含Si的多胺组合提供用于织物处理的储存稳定的组合物。经处理的织物显示较少的黄变倾向。

84. 发明申请

US20080045672A1 Chelate Polymerization 审中-公开
标题翻译：螯合物聚合
公开(公告)号：US20080045672A1
公开(公告)日：2008-02-21
申请号：US11836314
申请日：2007-08-09
申请人： Christian Herzig , Christine Weizhofer
发明人： Christian Herzig , Christine Weizhofer
IPC分类号： C08L79/02 , C08L83/04
CPC分类号： C08G77/58 , C08G77/38 , C08G77/388 , C09D183/14
摘要： Polymer-containing compositions contain: a) a polymer (I) containing at least two functional groups selected from the group consisting of β-ketocarbonyl and β-enaminocarbonyl functions, b) a compound (II) of a metal selected from the group consisting of the transition metals and the lanthanides and main groups 1, 2, 3 and 4 with the exception of the boron and carbon.
摘要翻译：含有聚合物的组合物含有：a）含有至少两个选自β-酮羰基和β-烯氨基羰基官能团的官能团的聚合物（I），b）选自以下的金属化合物（II）：选自过渡金属和镧系元素以及主要的1,2,3和4族，除了硼和碳之外。

85. 发明授权

US07135513B2 Branched organosilicon compounds as antimisting additives for silicone coating compositions 失效
标题翻译：支链有机硅化合物作为有机硅涂料组合物的防霉添加剂
公开(公告)号：US07135513B2
公开(公告)日：2006-11-14
申请号：US10506656
申请日：2003-02-20
申请人： Hans Lautenschlager , Christian Herzig , Christine Weizhofer
发明人： Hans Lautenschlager , Christian Herzig , Christine Weizhofer
IPC分类号： C08K5/5419
CPC分类号： C09D183/14 , Y10T428/31663
摘要： Branched organosilicon compounds bearing aliphatic multiple bonds, prepared by reacting a branched organosilicon compound having Si-bonded hydrogen atoms with an organosiloxane or organopolysiloxane having terminal aliphatic multiple bonds and optionally equilibrating with further organopolysiloxanes are useful as antimisting additives in the high speed coating of substrates with crosslinkable silicone compositions.
摘要翻译：通过使具有Si键合氢原子的支链有机硅化合物与具有末端脂族多重键的有机硅氧烷或有机聚硅氧烷进一步与其它有机聚硅氧烷平衡而制备的带有脂肪族多键的支链有机硅化合物可用作基材高速涂层中的抗吸附添加剂，可交联硅氧烷组合物。

86. 发明申请

US20050272862A1 Hydrophilic siloxane copolymers and process for the preparation thereof 有权
标题翻译：亲水硅氧烷共聚物及其制备方法
公开(公告)号：US20050272862A1
公开(公告)日：2005-12-08
申请号：US11139900
申请日：2005-05-27
申请人： Christian Ochs , Christian Herzig
发明人： Christian Ochs , Christian Herzig
IPC分类号： C08L83/12 , C08G18/08 , C08G18/28 , C08G18/32 , C08G18/61 , C08G18/83 , C08G77/26 , C08G77/458 , C08G77/46 , D06M15/643 , D06M15/647 , D06M15/653 , C08K3/20
CPC分类号： D06M15/647 , C08G18/2865 , C08G18/2875 , C08G18/61 , C08G77/458 , C08G77/46 , D06M15/6436 , D06M2200/00
摘要： Hydrophilic siloxane copolymers are prepared by (a) reacting organopolysiloxanes having at least one Si-bonded hydrogen atom with substantially linear oligomeric or polymeric compounds of formula R1-(A-CnH2n)m-A1-H (I) where R1 is a monovalent optionally substituted, hydrosilylatable hydrocarbyl radical, A is a bivalent polar organic radical selected from —O—, —C(O)—O—, —O—C(O)—, —O—C(O)—O—, —C(O)—NH—, —NH—C(O)—, urethane radicals and urea radicals, A1 is a bivalent polar organic radical selected from —O—, —NH— and —NR′—, n is an integer from 1 to 20, and m is zero or a positive integer, (b) reacting the resulting intermediate with organic compounds which have two or more isocyanate groups, in the presence of further organic compounds (6) reactive toward isocyanate groups and containing at least one tertiary amine group, and (c) quaternizing the amino-group-containing intermediate from step (b) with an alkylating agent (8), with the proviso that the water content of the compounds (1) and (2) is lower than 2000 weight ppm.
摘要翻译：亲水硅氧烷共聚物通过（a）使具有至少一个与Si键合的氢原子的有机聚硅氧烷与基本上线性的低级或高分子化合物（β）在线式描述=“In-Line Formulas”end =“lead” R 1 - （C 1 H 2n - ） - - - - - - - - - - - - - - - - - - - H（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 1是单价任选取代的可氢化可硅烷基化烃基，A是二价选自-O - ， - C（O）-O-，-OC（O） - ， - OC（O）-O - ， - C（O）-NH-，-NH-C（O） - ，氨基甲酸酯基和脲基，A 1是选自-O - ， - NH-和-NR'-的二价极性有机基团，n是1至20的整数，m是（b）使得到的中间体与具有两个或更多个异氰酸酯基团的有机化合物在存在对异氰酸酯基团反应的另外的有机化合物（6）的存在下反应并含有至少一个叔胺基团，和（c）用烷基化剂（8）使步骤（b）中含氨基的中间体季铵化，条件是化合物（1）和（2）的水含量为低于2000重量ppm。

87. 发明授权

US06956096B2 Alkenyl-functional siloxane copolymers as antimisting additives for silicone coating compositions 失效
标题翻译：烯基官能硅氧烷共聚物作为有机硅涂料组合物的防霉添加剂
公开(公告)号：US06956096B2
公开(公告)日：2005-10-18
申请号：US10797987
申请日：2004-03-11
申请人： Christian Herzig , Hans Lautenschlager , Martina Bloechl
发明人： Christian Herzig , Hans Lautenschlager , Martina Bloechl
IPC分类号： B05D7/24 , C08G77/50 , C09D183/04 , C09D183/05 , C09D183/07 , C09K3/18 , C08G77/04
CPC分类号： C08G77/50 , C09D183/04 , Y10T428/31663 , C08L83/00
摘要： Antimisting additives are used in crosslinkable silicone coating compositions for reducing aerosol formation, the antimisting additives being alkenyl-functional siloxane copolymers prepared by reacting a hydrocarbon containing at least three aliphatic double bonds, and with an organosiloxane (2) having terminal Si-bonded hydrogen atoms in the presence of a hydrosilylation catalyst (3) at a ratio of Si-bonded hydrogen to aliphatic double bonds of from 1.3 to 10, and subsequently reacting the resulting SiH-containing hydrocarbon-siloxane copolymer with an α,ω-dialkenylsiloxane polymer (4) in the presence of a hydrosilylation catalyst (3) at a ratio of aliphatic double bonds to Si-bonded hydrogen of from 1.2 to 10, and optionally, in another step, equilibrating the resulting alkenyl-functional siloxane copolymers with an organopolysiloxane (5).
摘要翻译：抗变性添加剂用于可还原气溶胶形成的可交联硅氧烷涂料组合物中，抗反应添加剂是通过使含有至少三个脂族双键的烃反应制备的烯基官能硅氧烷共聚物和与具有末端Si键合的氢原子的有机硅氧烷（2）在硅键合氢与脂族双键的比例为1.3至10的情况下，在氢化硅烷化催化剂（3）存在下，随后使所得含SiH的烃 - 硅氧烷共聚物与α，ω-二烯基硅氧烷聚合物（4 ）在氢化硅烷化催化剂（3）存在下，脂族双键与Si键合氢的比例为1.2至10，并且任选地，在另一步骤中，使所得烯基官能硅氧烷共聚物与有机聚硅氧烷（5）平衡，。

88. 发明申请

US20050137412A1 Process for preparing organosilicon compounds 有权
标题翻译：制备有机硅化合物的方法
公开(公告)号：US20050137412A1
公开(公告)日：2005-06-23
申请号：US11007423
申请日：2004-12-08
申请人： Christian Ochs , Christian Herzig
发明人： Christian Ochs , Christian Herzig
IPC分类号： C07F7/18 , C08G77/06 , C08G77/38 , C08G77/46 , C07F7/04
CPC分类号： C08G77/38 , C08G77/06 , C08G77/46
摘要： The present invention relates to a process for adding Si-bonded hydrogen to aliphatically unsaturated compounds containing carbon-carbon multiple bonds and ether oxygen atoms in the presence of carbinol groups, wherein the reaction mixture comprises, as a further component, at least one cyclic ether.
摘要翻译：本发明涉及在甲醇基团存在下，将含硅键合氢加成到含有碳 - 碳多键和醚氧原子的脂族不饱和化合物的方法，其中反应混合物作为另外的组分包含至少一种环醚。

89. 发明授权

US06835419B2 Ammonio-containing organosilicon compounds 失效
标题翻译：含氨的有机硅化合物
公开(公告)号：US06835419B2
公开(公告)日：2004-12-28
申请号：US10333937
申请日：2003-07-30
申请人： Christian Herzig , Robert Banfic
发明人： Christian Herzig , Robert Banfic
IPC分类号： B05D300
CPC分类号： C04B41/009 , C03C17/30 , C04B41/4961 , C04B41/84 , C08G77/388 , D06M15/6436 , C04B41/463 , C04B33/00 , C04B14/00
摘要： The invention relates to novel organosilicon compounds comprising ammonium groups, said compounds being soluble in isopropanol or diethylene glycol monobutyl ether, and containing: a) at least one structural unit of general formula (I) wherein R2 represents a bivalent organic radical containing a hydroxyl group which is conditioned by a ring opening of an epoxy group; R3 represents a hydrogen atom or a monovalent hydrocarbon radical comprising 1 to 60 carbon atoms per radical, and can be split or substituted by at least one separate heteroatom chosen from the group consisting of nitrogen, oxygen, sulphur or halogen atoms; R4 represents a bivalent hydrocarbon radical comprising 1 to 10 carbon atoms per radical; n represents 0 or a whole number from 1 to 10; m represents a whole number from 1 to the total number of nitrogen atoms in (I); x represents 0 or 1; and X− represents an anion, b) at least one siloxane unit of general formula (II), and c) at least two siloxane units of general formula (III) wherein R, R1, a and b have the designation cited in patent claim (1), provided that the siloxane units of formula (III) are connected to the structural unit of formula (I) via the Si atoms via the R2 radicals.
摘要翻译：本发明涉及包含铵基的新型有机硅化合物，所述化合物可溶于异丙醇或二甘醇单丁醚，并含有：a）至少一种通式（I）的结构单元，其中R 2表示含二价有机基团由环氧基的开环调节的羟基; R 3表示氢原子或每个基团含有1至60个碳原子的单价烃基，并且可以被至少一个选自氮，氧，硫或卤素原子的独立杂原子分裂或取代; R 4表示每个基团含有1-10个碳原子的二价烃基; n表示0或1至10的整数; m表示（I）中从1到氮原子总数的整数; x表示0或1; 并且X 1表示阴离子，b）至少一个通式（II）的硅氧烷单元，和c）至少两个通式（III）的硅氧烷单元，其中R，R 1，a和b具有式（1）中引用的名称，条件是式（III）的硅氧烷单元经由R 2基团经由Si原子连接到式（I）的结构单元。

90. 发明授权

US06437015B2 Radiation-curing compositions 失效
标题翻译：辐射固化组合物
公开(公告)号：US06437015B2
公开(公告)日：2002-08-20
申请号：US09775767
申请日：2001-02-02
申请人： Jochen Dauth , Christian Herzig , Josef Wolferseder , Oliver Zoellner
发明人： Jochen Dauth , Christian Herzig , Josef Wolferseder , Oliver Zoellner
IPC分类号： C08J328
CPC分类号： C09D183/06 , C09D183/14 , C08L2666/28
摘要： Radiation-curable compositions containing linear organopolysiloxanes bearing (meth)acryloxy groups and a photosensitizer are useful for release coatings particularly release coatings with enhanced adhesion to the substrate onto which they are coated, for example those used for adhesives such as pressure sensitive adhesive labels.
摘要翻译：含有带有（甲基）丙烯酰氧基的线性有机聚硅氧烷和光敏剂的可辐射固化组合物可用于脱模涂层，特别是具有增强的与其所涂覆的基材的粘附性的剥离涂层，例如用于粘合剂如压敏粘合剂标签的那些。

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