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1. 发明授权

US06258913B1 Polymeric organosilicon compounds, their production and use 失效
标题翻译：聚合有机硅化合物，其生产和使用
公开(公告)号：US06258913B1
公开(公告)日：2001-07-10
申请号：US09341485
申请日：1999-08-13
申请人： Christian Herzig , Robert Banfic , Reinhard Stallbauer , Bernward Deubzer , David Heuttner
发明人： Christian Herzig , Robert Banfic , Reinhard Stallbauer , Bernward Deubzer , David Heuttner
IPC分类号： C08G7708
CPC分类号： C08G77/50 , C08G77/20 , C09D183/14 , Y10T428/31663 , C08L83/00
摘要： The invention relates to novel polymeric organosilicon compounds comprising hydrocarbon radicals with at least one aliphatic carbon-carbon double bond in a terminal position. To produce these compounds, (A) compounds containing at least one aliphatic carbon-carbon double bond per molecule, in a terminal position, are reacted with (B) oligomeric or polymeric organosilicon compounds containing units of the general formula R1R2SiO1/2 and units of the general formula HRSiO and/or HSiO3/2 and possibly units of the general formula R2SiO, where R is a monovalent, possibly substituted, hydrocarbon radical with between 1 and 18 carbon atoms per radical, which is free of aliphatic carbon-carbon double bonds, and R1 is a monovalent hydrocarbon radical with between 1 and 18 carbon atoms per radical which has at least one aliphatic carbon-carbon double bond in a terminal position, subject to the condition that the sum of the units HRSiO and R1R2SiO1/2 on average is greater than 2.0 if (B) contains no HSiO3/2 units, and the number of R1 radicals per molecule is greater than the number of Si-bonded hydrogen atoms, in the presence of (C) catalysts promoting the addition of Si-bonded hydrogen to aliphatic double-bonds. The ratio of aliphatic double bonds in components (A) and (B) to Si-bonded hydrogen in component (B) is between 1.5 and 10, subject to the condition that the polymeric organosilicon compounds on average contain more than two hydrocarbon radicals with at least one aliphatic carbon-carbon double bond in a terminal position.
摘要翻译：本发明涉及包含在最终位置具有至少一个脂族碳 - 碳双键的烃基的新型聚合物有机硅化合物。为了制备这些化合物，（A）在每个分子中含有至少一个脂族碳 - 碳双键的化合物在末端与（B）含有通式R 1 R 2 SiO 1/2单元的低聚或聚合有机硅化合物反应，通式HRSiO和/或HSiO3 / 2以及通式R2SiO的可能单元，其中R是每个基团具有1至18个碳原子的单价可能取代的烃基，其不含脂族碳 - 碳双键并且R 1是每个基团具有1至18个碳原子的单价烃基，其在末端具有至少一个脂族碳 - 碳双键，条件是平均来说单位HRSiO和R 1 R 2 SiO 1/2的总和如果（B）不含有HSiO3 / 2单元，并且在（C）催化剂的存在下，每分子的R1基团数目大于Si键合的氢原子的数目，则大于2.0，促进添加硅键键合到脂肪族双键。组分（B）中组分（A）和（B）中的脂族双键与Si键合的氢的比例为1.5至10，条件是聚合物有机硅化合物平均含有多于两个烃基，在末端位置具有至少一个脂族碳 - 碳双键。

2. 发明授权

US5691435A Crosslinkable compositions 失效
标题翻译：可交联组合物
公开(公告)号：US5691435A
公开(公告)日：1997-11-25
申请号：US782871
申请日：1997-01-14
申请人： Christian Herzig , Bernward Deubzer , Martina Bloechl , Robert Banfic
发明人： Christian Herzig , Bernward Deubzer , Martina Bloechl , Robert Banfic
IPC分类号： C08L83/05 , C07F7/08 , C08G77/12 , C08G77/48 , C08K5/5419 , C08L83/07 , C09D183/04 , C09D183/05 , C09D183/07 , C09J183/07 , C08G77/08
CPC分类号： C08K5/5419 , C07F7/0896 , C08G77/12 , C08G77/485 , C09D183/04
摘要： The present invention provides crosslinkable compositions comprising (A) an organosilicon compound having radicals containing aliphatic carbon-carbon multiple bonds, (B) an organosilicon compound having Si-bonded hydrogen atoms, (C) a catalyst which promotes the addition of Si-bonded hydrogen onto aliphatic multiple bond, and optionally (D) an agent which retards the addition of Si-bonded hydrogen onto aliphatic multiple bond at room temperature and to the use of the crosslinkable compositions for producing coatings which repel tacky substances. The present invention also relates to organosilicon compounds having Si-bonded hydrogen atoms, and to a process for their preparation.
摘要翻译：本发明提供可交联组合物，其包含（A）具有含有脂族碳 - 碳多重键的基团的有机硅化合物，（B）具有Si键合氢原子的有机硅化合物，（C）促进加入Si键合氢的催化剂和任选的（D）在室温下将Si键合的氢加成到脂肪族多键上的试剂，以及使用可交联组合物来制造排斥粘性物质的涂层。本发明还涉及具有Si键合的氢原子的有机硅化合物及其制备方法。

3. 发明授权

US06835419B2 Ammonio-containing organosilicon compounds 失效
标题翻译：含氨的有机硅化合物
公开(公告)号：US06835419B2
公开(公告)日：2004-12-28
申请号：US10333937
申请日：2003-07-30
申请人： Christian Herzig , Robert Banfic
发明人： Christian Herzig , Robert Banfic
IPC分类号： B05D300
CPC分类号： C04B41/009 , C03C17/30 , C04B41/4961 , C04B41/84 , C08G77/388 , D06M15/6436 , C04B41/463 , C04B33/00 , C04B14/00
摘要： The invention relates to novel organosilicon compounds comprising ammonium groups, said compounds being soluble in isopropanol or diethylene glycol monobutyl ether, and containing: a) at least one structural unit of general formula (I) wherein R2 represents a bivalent organic radical containing a hydroxyl group which is conditioned by a ring opening of an epoxy group; R3 represents a hydrogen atom or a monovalent hydrocarbon radical comprising 1 to 60 carbon atoms per radical, and can be split or substituted by at least one separate heteroatom chosen from the group consisting of nitrogen, oxygen, sulphur or halogen atoms; R4 represents a bivalent hydrocarbon radical comprising 1 to 10 carbon atoms per radical; n represents 0 or a whole number from 1 to 10; m represents a whole number from 1 to the total number of nitrogen atoms in (I); x represents 0 or 1; and X− represents an anion, b) at least one siloxane unit of general formula (II), and c) at least two siloxane units of general formula (III) wherein R, R1, a and b have the designation cited in patent claim (1), provided that the siloxane units of formula (III) are connected to the structural unit of formula (I) via the Si atoms via the R2 radicals.
摘要翻译：本发明涉及包含铵基的新型有机硅化合物，所述化合物可溶于异丙醇或二甘醇单丁醚，并含有：a）至少一种通式（I）的结构单元，其中R 2表示含二价有机基团由环氧基的开环调节的羟基; R 3表示氢原子或每个基团含有1至60个碳原子的单价烃基，并且可以被至少一个选自氮，氧，硫或卤素原子的独立杂原子分裂或取代; R 4表示每个基团含有1-10个碳原子的二价烃基; n表示0或1至10的整数; m表示（I）中从1到氮原子总数的整数; x表示0或1; 并且X 1表示阴离子，b）至少一个通式（II）的硅氧烷单元，和c）至少两个通式（III）的硅氧烷单元，其中R，R 1，a和b具有式（1）中引用的名称，条件是式（III）的硅氧烷单元经由R 2基团经由Si原子连接到式（I）的结构单元。

4. 发明授权

US06274692B1 Cross-linkable compounds, optionally containing MQ silicon resins 有权
标题翻译：可交联的化合物，任选地含有MQ硅树脂
公开(公告)号：US06274692B1
公开(公告)日：2001-08-14
申请号：US09381414
申请日：1999-09-30
申请人： Christian Herzig , Oliver Zoellner , Friedrich Hockemeyer , Robert Banfic
发明人： Christian Herzig , Oliver Zoellner , Friedrich Hockemeyer , Robert Banfic
IPC分类号： C08G7720
CPC分类号： C09D183/04 , C08G77/20 , C09D183/14 , C08L83/00
摘要： The invention relates to new, cross-linkable compounds containing (A1) linear organopolysiloxanes with aliphatically unsaturated hydrocarbon radicals, said organopolysiloxanes being of general formula (I) R1aR3-aSiO(R2SiO)c[R2Si—Y—SiR2O(R2SiO)c]dSiR3-bR1b, wherein R can be the same or different, and represents a monovalent, optionally halogenated hydrocarbon radical which is free of terminal aliphatic carbon—carbon multiple bonds, R1 represents a monovalent aliphatically unsaturated hydrocarbon radical, Y represents a bivalent organic radical which is free of terminal aliphatic carbon—carbon multiple bonds, a is 0 or 1, b is 0 or 1, and the sum of a+b per molecule is 1 or 2, c is a whole number to the value of 1 to 1000, d is 0 or a whole number to the value of 1 to 10, and optionally, (A2) MQ silicone resins which are soluble in (A1), on the condition that if MQ silicone resins (A2) are not used, the sum of a+b in the formula (I) is 1.3 to 1.9 on average and that if MQ silicone resins (A2) are used, the sum of a+b in formula (I) is 1.0 to 1.9 on average; (B) organo-silicon compounds with Si-bonded hydrogen atoms; (C) catalysts which promote the formation of an aliphatic multiple bond by Si-bonded hydrogen; and optionally, (D) agents which slow down the formation of an aliphatic multiple bond by Si-bonded hydrogen at room temperature.
摘要翻译：本发明涉及含有（A1）具有脂肪族不饱和烃基的线性有机聚硅氧烷的新的可交联化合物，所述有机聚硅氧烷具有通式（I）R1aR3-aSiO（R2SiO）c [R2Si-Y-SiR2O（R2SiO）c] dSiR3 -bR1b，其中R可以相同或不同，并且表示没有末端脂族碳 - 碳多重键的单价任选卤代烃基，R1表示一价脂族不饱和烃基，Y表示二价有机基团，其为没有末端脂肪族碳 - 碳多重键，a为0或1，b为0或1，每分子a + b的和为1或2，c为1至1000的整数，d （A1）中可溶的（A2）MQ有机硅树脂，如果不使用MQ有机硅树脂（A2），则为0或0〜1的整数，式（I）中的+ b平均为1.3〜1.9，如果MQ有机硅树脂（A2），式（I）中a + b的和平均为1.0〜1.9; （B）具有硅键合氢原子的有机硅化合物; （C）促进通过Si键合氢形成脂族多重键的催化剂; 和任选的（D）在室温下通过Si键合的氢减慢形成脂族多重键的试剂。

5. 发明授权

US08598108B2 Fabric care compositions comprising organosiloxane polymers 有权
公开(公告)号：US08598108B2
公开(公告)日：2013-12-03
申请号：US13569373
申请日：2012-08-08
申请人： Rajan Keshav Panandiker , Kerry Andrew Vetter , Bernard William Kluesener , Iskender Yilgor , Christian Herzig , Richard Becker , Rafael Trujillo Rosaldo , Leslie Dawn Waits , Janine A. Flood , Keith Homer Baker , Jennifer Beth Ponder , Mark Gregory Solinsky , Matthew Scott Wagner , Pradipta Sarkar , Emily Suzanne Klinker , Julie Ann O'Neil
发明人： Rajan Keshav Panandiker , Kerry Andrew Vetter , Bernard William Kluesener , Iskender Yilgor , Christian Herzig , Richard Becker , Rafael Trujillo Rosaldo , Leslie Dawn Waits , Janine A. Flood , Keith Homer Baker , Jennifer Beth Ponder , Mark Gregory Solinsky , Matthew Scott Wagner , Pradipta Sarkar , Emily Suzanne Klinker , Julie Ann O'Neil
IPC分类号： C11D3/37
CPC分类号： C11D3/3742 , C11D3/2072 , C11D3/373 , C11D3/3738 , C11D3/50 , C11D11/0017
摘要： The present composition relates to fabric care compositions comprising an organosiloxane polymer. Methods of using such compositions including contacting a fabric with the composition and rinsing the fabric are also disclosed.

6. 发明授权

US08263543B2 Fabric care compositions comprising organosiloxane polymers 有权
标题翻译：包含有机硅氧烷聚合物的织物护理组合物
公开(公告)号：US08263543B2
公开(公告)日：2012-09-11
申请号：US12752860
申请日：2010-04-01
申请人： Rajan Keshav Panandiker , Kerry Andrew Vetter , Bernard William Kluesener , Iskender Yilgor , Christian Herzig , Richard Becker , Rafael Trujillo Rosaldo , Leslie Dawn Waits , Janine A. Flood , Keith Homer Baker , Jennifer Beth Ponder , Mark Gregory Solinsky , Matthew Scott Wagner , Pradipta Sarkar , Emily Suzanne Klinker , Julie Ann O'Neil
发明人： Rajan Keshav Panandiker , Kerry Andrew Vetter , Bernard William Kluesener , Iskender Yilgor , Christian Herzig , Richard Becker , Rafael Trujillo Rosaldo , Leslie Dawn Waits , Janine A. Flood , Keith Homer Baker , Jennifer Beth Ponder , Mark Gregory Solinsky , Matthew Scott Wagner , Pradipta Sarkar , Emily Suzanne Klinker , Julie Ann O'Neil
IPC分类号： C11D3/37
CPC分类号： C11D3/3742 , C11D3/2072 , C11D3/373 , C11D3/3738 , C11D3/50 , C11D11/0017
摘要： The present composition relates to fabric care compositions comprising an organosiloxane polymer. Methods of using such compositions including contacting a fabric with the composition and rinsing the fabric are also disclosed.
摘要翻译：本发明组合物涉及包含有机硅氧烷聚合物的织物护理组合物。还公开了使用这种组合物的方法，包括使织物与组合物接触并漂洗织物。

7. 发明授权

US08084552B2 Method for producing silicone polyethers 有权
标题翻译：硅氧烷聚醚的制备方法
公开(公告)号：US08084552B2
公开(公告)日：2011-12-27
申请号：US12921044
申请日：2009-03-03
申请人： Christian Herzig
发明人： Christian Herzig
IPC分类号： C08F283/06 , C08F283/12 , C08G77/46
CPC分类号： C08G77/46 , C08G77/12
摘要： Silicone polyethers are prepared in a two stage process by reacting an unsaturated polyether with a first Si—H functional organopolysiloxane and then with a second organopolysiloxane, in which the weight ratio of silicon bonded hydrogen in the first and second organopolysiloxanes is at least 0.9. The reaction is more rapid than a single step process and produces a product with less unreacted Si—H content.
摘要翻译：通过使不饱和聚醚与第一Si-H官能的有机聚硅氧烷，然后与第二有机聚硅氧烷反应制备硅氧烷聚醚，其中第一和第二有机聚硅氧烷中硅键合氢的重量比至少为0.9。反应比单步法更快，并产生具有较少未反应的Si-H含量的产物。

8. 发明授权

US07645360B2 Defoamer formulations 有权
标题翻译：消泡剂配方
公开(公告)号：US07645360B2
公开(公告)日：2010-01-12
申请号：US11915941
申请日：2006-05-24
申请人： Willibald Burger , Christian Herzig , Josef Wimmer
发明人： Willibald Burger , Christian Herzig , Josef Wimmer
IPC分类号： D21H21/00
CPC分类号： C08G18/61 , B01D19/0409 , C08G77/458
摘要： Defoamer compositions of high effectiveness containing at least one siloxane-based antifoam and polysiloxane copolymers obtained by coupling a polysiloxane bearing active-hydrogen-containing hydrophilic polymer moieties by means of a di- or polyisocyanate.
摘要翻译：通过用二异氰酸酯或多异氰酸酯偶联含有含活性氢的亲水性聚合物部分的聚硅氧烷获得的含有至少一种基于硅氧烷的消泡剂和聚硅氧烷共聚物的高效消泡剂组合物。

9. 发明申请

US20090260769A1 METHOD FOR TREATING CELLULOSE-CONTAINING FIBERS OR PLANAR STRUCTURES CONTAINING CELLULOSE-CONTAINING FIBERS 审中-公开
标题翻译：用于处理含纤维素的纤维的含纤维素的纤维或平面结构的方法
公开(公告)号：US20090260769A1
公开(公告)日：2009-10-22
申请号：US12438312
申请日：2007-08-06
申请人： Christian Herzig , Willibald Burger , Monika Rappl
发明人： Christian Herzig , Willibald Burger , Monika Rappl
IPC分类号： D21H17/59 , D21H17/07 , D21H17/56
CPC分类号： D21H21/20 , C08G73/02 , C08G77/46 , C08J7/12 , C08J2301/00 , D21H17/53 , D21H17/55 , D21H17/56 , D21H17/59 , D21H27/002
摘要： Cellulosic substrates are treated with compound(s) containing at least two primary amino groups and compounds containing at least one β-ketocarbonyl group. The substrates exhibit good strength and hand properties.
摘要翻译：纤维素底物用含有至少两个伯氨基的化合物和含有至少一个β-酮羰基的化合物处理。基材表现出良好的强度和手感。

10. 发明申请

US20090176959A1 ORGANOSILICON COMPOUNDS THAT CONTAIN Beta-KETOAMIDE GROUPS AND ORGANIC POLYMERS BOUND VIA ENAMINE BONDS, AND METHOD FOR PRODUCING THEM 有权
标题翻译：含有β-KETAAMIDE组和有机聚合物的组氨酸化合物通过ENAMINE BONDS和其生产方法
公开(公告)号：US20090176959A1
公开(公告)日：2009-07-09
申请号：US12299545
申请日：2007-04-23
申请人： Christian Herzig , Siegfried Dormeier
发明人： Christian Herzig , Siegfried Dormeier
IPC分类号： C08G77/04 , C07F7/10 , C08G77/06
CPC分类号： C08G77/388 , C08G77/26
摘要： Organosilicon compounds containing β-ketoamide groups and organic polymer groups bound via enamine bonds are prepared by reaction of compounds bearing at least one β-ketocarbonyl functionality with organosilicon compounds bearing aminoalkylaminoalkyl groups. The products have the same uses as siloxanes containing polyether and acetoacetate groups.
摘要翻译：含有β-酮酰胺基团和通过烯胺键结合的有机聚合物基团的有机硅化合物通过具有至少一个β-酮羰基官能团的化合物与带有氨基烷基氨基烷基的有机硅化合物的反应来制备。该产品与含有聚醚和乙酰乙酸酯基团的硅氧烷具有相同的用途。

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