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81. 发明申请

US20060116538A1 Azeotrope compositions comprising 1,1,3,3,3-pentafluoropropene and hydrogen fluoride and uses thereof 审中-公开
标题翻译：包含1,1,3,3,3-五氟丙烯和氟化氢的共沸组合物及其用途
公开(公告)号：US20060116538A1
公开(公告)日：2006-06-01
申请号：US11264209
申请日：2005-11-01
申请人： Ralph Newton Miller , Mario Joseph Nappa , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
发明人： Ralph Newton Miller , Mario Joseph Nappa , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
IPC分类号： C07C17/38
CPC分类号： C07C21/18 , C07C17/25 , C07C17/38 , C07C17/383 , C07C17/386 , Y02P20/582
摘要： Disclosed herein are azeotrope and near-azeotrope compositions comprising 1,1,3,3,3-pentafluoropentene (HFC-1225zc) and hydrogen fluoride. These compositions are useful in processes to produce and purify HFC-1225zc. Also disclosed are processes comprising pyrolyzing CF3CH2CF3 to CF3CH═CF2. Also disclosed herein are processes for the manufacture of HFC-1225zc comprising pyrolyzing 1,1,1,3,3,3-hexafluoropropane (HFC-236fa) in the absence of dehydrofluorination catalyst in a reactor having a reaction zone.
摘要翻译：本文公开了包含1,1,3,3,3-五氟戊烯（HFC-1225zc）和氟化氢的共沸物和近共沸组合物。这些组合物可用于生产和纯化HFC-1225zc的方法。还公开了包括将CF 3 CH 2 CH 3 CF 3向CF 3 CH-CF 2 2进行热解的方法。本文还公开了制备HFC-1225zc的方法，其包括在具有反应区的反应器中在不存在脱氟化氢催化剂的情况下热解1,1,1,3,3,3-六氟丙烷（HFC-236fa）。

82. 发明申请

US20060106263A1 Processes for production and purification of hydrofluoroolefins 有权
公开(公告)号：US20060106263A1
公开(公告)日：2006-05-18
申请号：US11264183
申请日：2005-11-01
申请人： Ralph Miller , Mario Joseph Nappa , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
发明人： Ralph Miller , Mario Joseph Nappa , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
IPC分类号： C07C17/25
CPC分类号： C07C17/383 , C01B7/196 , C07C17/25 , C07C17/38 , C07C17/386 , C07C21/18 , Y02P20/582
摘要： Disclosed herein are processes for the production of hydrofluoroolefins by dehydrofluorination. Also disclosed herein are processes for separation of hydrofluoroolefins from hydrofluorocarbons and from hydrogen fluoride.

83. 发明授权

US06291730B1 Process for the manufacture of halocarbons and selected compounds and azeotropes with HF 失效
标题翻译：用于制造卤代烃和所选化合物以及与HF共沸的方法
公开(公告)号：US06291730B1
公开(公告)日：2001-09-18
申请号：US09011401
申请日：1998-01-28
申请人： Ralph Thomas Baker , Viacheslav Alexandrovich Petrov , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
发明人： Ralph Thomas Baker , Viacheslav Alexandrovich Petrov , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
IPC分类号： C07C1710
CPC分类号： C07C19/10 , C07C17/206 , C07C17/275 , C07C17/278 , C07C17/38 , C07C17/386 , C07C19/08 , Y02P20/582 , C07C19/01 , C07C19/16
摘要： A liquid phase process is disclosed for producing halogenated alkane adducts of the formula: CAR1R2CBR3R4 (where A, B, R1, R2, R3, and R4 are as defined in the specification) which involves contacting a corresponding halogenated alkane, AB, with a corresponding olefin, CR1R2═C3R4 in a dinitrile or cyclic carbonate ester solvent which divides the reaction mixture into two liquid phases and in the presence of a catalyst system containing: (i) at least one catalyst selected from monovalent and divalent copper; and optionally (ii) a promoter selected from aromatic or aliphatic heterocyclic compounds which contain at least one carbon-nitrogen double bond in the heterocyclic ring. When hydrochlorofluorocarbons are formed, the chlorine content may be reduced by reacting the hydrochlorofluorocarbons with HF. New compounds disclosed include CF3CF2CCl2CH2CCl3, CF3CCl2CH2CH2Cl and CF3CCl2CH2CHClF. These compounds are useful as intermediates for producing hydrofluorocarbons. Azeotropes of CClF2CH2CF3 with HF and azeotropes of CF3CH2CHF2 with HF are also disclosed; as are processes for producing such azeotropes. A process for purification of certain hydrofluorocarbons and/or chloroprecursors thereof from mixtures of such compounds with HF is also disclosed.
摘要翻译：公开了制备下式的卤化烷烃加成物的液相方法：CAR1R2CBR3R4（其中A，B，R1，R2，R3和R4如说明书中所定义），其涉及使相应的卤代烷烃AB与相应的烯烃，CR1R2 = C3R4在二腈或环状碳酸酯溶剂中，其将反应混合物分成两个液相，并且在催化剂体系存在下，包含：（i）至少一种选自单价和二价铜的催化剂; 和任选地（ii）选自在杂环中含有至少一个碳 - 氮双键的芳族或脂族杂环化合物的促进剂。当形成氢氯氟烃时，可以通过氢氯氟烃与HF反应来降低氯含量。所公开的新化合物包括CF 3 CF 2 CCl 2 CH 2 ClCl 3，CF 3 CCl 2 CH 2 CH 2 Cl和CF 3 CCl 2 CH 2 CHClF。这些化合物可用作生产氢氟烃的中间体。还公开了CClF 2 CH 2 CF 3与HF的共沸物和CF 3 CH 2 CHF 2与HF的共沸物质; 生产这种共沸物的方法也是如此。还公开了从这些化合物与HF的混合物中纯化某些氢氟烃和/或其氯前体的方法。

84. 发明授权

US6034289A Treatment of chromium oxide and catalytic manufacture of vinyl fluoride 失效
标题翻译：氧化铬的处理和催化制造氟乙烯
公开(公告)号：US6034289A
公开(公告)日：2000-03-07
申请号：US973379
申请日：1997-12-03
申请人： Frank J. Christoph , George W. Coulston , Velliyur Nott Mallikarjuna Rao
发明人： Frank J. Christoph , George W. Coulston , Velliyur Nott Mallikarjuna Rao
IPC分类号： C01G37/02 , B01J21/02 , B01J23/26 , B01J27/132 , B01J37/06 , B01J37/26 , C07B61/00 , C07C17/25 , C07C21/18
CPC分类号： B01J37/06 , B01J21/02 , B01J23/26 , B01J27/132 , B01J37/26 , C07C17/25 , Y02P20/582
摘要： Advantageous processes are disclosed for the production of vinyl fluoride. Also disclosed are advantageous methods which may be employed for the preparation of catalysts useful in such processes. Included are methods which involve (i) reducing surface B.sub.2 O.sub.3 present in a bulk chromium oxide composition containing surface B.sub.2 O.sub.3 by treating said composition with HF at an elevated temperature and/or (ii) treating a bulk chromium oxide composition containing B.sub.2 O.sub.3 to enrich the B.sub.2 O.sub.3 present on its surface by heating said composition in oxygen or an oxygen-containing environment (e.g., air) at an elevated temperature for a time sufficient to enrich the B.sub.2 O.sub.3 on the surface of the composition by at least a factor of two compared to the surface analysis of the untreated bulk composition. Processes are provided herein which involve contacting 1,1-difluoroethane in the vapor phase with a trivalent chromium catalyst (preferably a trivalent chromium catalyst having primarily the morphology of alpha-chromium oxide and/or containing less than 1000 ppm alkali metal as the alkali metal oxide) wherein chromium is at least 95 atom percent of the metallic cations of said catalyst, at a temperature between about 225.degree. C. and 375.degree. C. Advantageous embodiments of these processes are disclosed wherein (i) the catalyst is prepared by reducing B.sub.2 0.sub.3 present in a bulk chromium oxide composition as indicated above, (ii) chromium is at least 99 atom percent of the metallic cations of the catalyst and/or (iii) the space velocity is from about 200 volumes to 2000 volumes of 1,1-difluoroethane per volume of catalyst per hour.
摘要翻译： PCT No.PCT / US96 / 09752 Sec。 371日期1997年12月3日第 102（e）日期1997年12月3日PCT提交1996年6月7日PCT公布。公开号WO96 / 41679 日期1996年12月27日公开了用于生产氟乙烯的有利的方法。还公开了可用于制备可用于这些方法的催化剂的有利方法。包括以下方法：（i）通过在高温下用HF处理所述组合物和/或（ii）处理含有B 2 O 3的本体氧化铬组合物以富集B 2 O 3，从而减少存在于含有表面B 2 O 3的本体氧化铬组合物中的表面B 2 O 3 在表面上通过在氧气或含氧环境（例如空气）中在升高的温度下加热所述组合物足以使组合物表面上的B 2 O 3与表面分析相比至少增加2倍的时间的未处理的散装组合物。本文提供了将气相中的1,1-二氟乙烷与三价铬催化剂（优选主要具有α-氧化铬形态的三价铬催化剂和/或含有少于1000ppm碱金属作为碱金属的三价铬催化剂）氧化物），其中铬为所述催化剂的金属阳离子的至少95原子％，温度为约225℃至375℃。公开了这些方法的有利实施方案，其中（i）催化剂通过还原B 2 O 3 存在于如上所述的本体氧化铬组合物中，（ii）铬是催化剂的金属阳离子的至少99原子％，和/或（iii）空间速度为约200体积至2000体积的1,1- 每单位体积催化剂每小时二氟乙烷。

85. 发明授权

US5847242A Catalysts for halogenated hydrocarbon processing, their precursors and their preparation and use 失效
标题翻译：用于卤代烃加工的催化剂，其前体及其制备和用途
公开(公告)号：US5847242A
公开(公告)日：1998-12-08
申请号：US737942
申请日：1996-11-21
申请人： Velliyur Nott Mallikarjuna Rao , Munirpallam A. Subramanian
发明人： Velliyur Nott Mallikarjuna Rao , Munirpallam A. Subramanian
IPC分类号： C07C17/087 , C07C17/20 , C07C17/37 , C07C17/00
CPC分类号： C07C17/37 , C07C17/087 , C07C17/206
摘要： A process is disclosed for changing the fluorine content of halogenated hydrocarbons containing from 1 to 6 carbon atoms, in the presence of a multiphase catalyst, which is characterized by preparing certain single phase solid catalyst precursors containing two metal components (e.g., a divalent component of Mn, Co, Zn, Mg and/or Cd and a trivalent component of Al, Ga, Cr and/or V) which have structures that collapse at about 600.degree. C. or less; and producing said catalyst by heating the precursor to produce a multiphase composition wherein a phase containing one of the metal components is homogeneously dispersed with a phase containing the other metal component, and at least when the precursor contains no fluoride, contacting said multiphase composition with a vaporizable fluorine-containing fluorination compound at a temperature of from about 200.degree. C. to 450.degree. C. Also disclosed are single phase fluoride compositions having the formula MM'F.sub.5 (H.sub.2 O).sub.2 wherein M is a divalent component selected from Mn, Co, Zn, Mg and/or Cd and M' is a trivalent component selected from Al, Ga, Cr and/or V (provided that Cr is not more than about 10 atom percent of M'); preparation of certain homogeneously dispersed multiphase catalyst compositions containing fluorides of those divalent and trivalent metal components; and certain homogeneously dispersed multiphase catalyst compositions containing fluorides of those divalent and trivalent metal components (provided that when Co is used another of said divalent elements is also used).
摘要翻译： PCT No.PCT / US95 / 05861 Sec。 371日期：1996年11月21日 102（e）1996年11月21日PCT PCT 1995年5月19日PCT公布。 WO95 / 32799 PCT出版物日期1995年12月7日公开了一种在多相催化剂存在下改变含有1至6个碳原子的卤代烃的氟含量的方法，其特征在于制备含有两种金属组分的某些单相固体催化剂前体（例如，Mn，Co，Zn，Mg和/或Cd的二价成分和Al，Ga，Cr和/或V的三价成分），其结构在约600℃以下塌陷; 并通过加热前体制备所述催化剂以产生多相组合物，其中含有一种金属组分的相与含有其它金属组分的相均匀地分散，并且至少当前体不含氟化物时，使所述多相组合物与可蒸发的含氟氟化化合物在约200℃至450℃的温度下。还公开了具有式MM'F5（H 2 O）2的单相氟化物组合物，其中M是选自Mn，Co， Zn，Mg和/或Cd，M'是选自Al，Ga，Cr和/或V的三价成分（条件是Cr不大于M'的约10原子％）; 制备含有这些二价和三价金属成分的氟化物的某些均匀分散的多相催化剂组合物; 以及含有这些二价和三价金属组分的氟化物的某些均匀分散的多相催化剂组合物（条件是当使用Co时，也使用另一种所述二价元素）。

86. 发明授权

US08535556B2 Compositions comprising iodotrifluoromethane and stabilizers 失效
标题翻译：包含三氟甲烷和稳定剂的组合物
公开(公告)号：US08535556B2
公开(公告)日：2013-09-17
申请号：US12161842
申请日：2007-03-26
申请人： Thomas J. Leck , Nandini C. Mouli , Jon Lee Howell , Velliyur Nott Mallikarjuna Rao , Andrew Edward Feiring , Viacheslav A. Petrov , Allen Capron Sievert , Mario Joseph Nappa , Barbara Haviland Minor , Ekaterina N. Swearingen , Schmitz Corneille , Deepak Perti
发明人： Thomas J. Leck , Nandini C. Mouli , Jon Lee Howell , Velliyur Nott Mallikarjuna Rao , Andrew Edward Feiring , Viacheslav A. Petrov , Allen Capron Sievert , Mario Joseph Nappa , Barbara Haviland Minor , Ekaterina N. Swearingen , Schmitz Corneille , Deepak Perti
IPC分类号： C09K5/04
CPC分类号： C09K5/045 , C09K2205/122
摘要： The present invention relates to compositions comprising iodotrifluoromethane and an effective amount of at least one stabilizer selected from the group consisting of hindered phenols, thiophosphates, butylated triphenylphosphorothionates, organo phosphates, phosphites, aryl alkyl ethers, terpenes, terpenoids, epoxides, fluorinated epoxides, oxetanes, ascorbic acid, thiols, lactones, thioethers, amines, nitromethane, alkylsilanes, benzophenone derivatives, aryl sulfides, divinyl terephalic acid, diphenyl terephalic acid, ionic liquids, and mixtures thereof. These stabilized iodotrifluoromethane compositions may be useful as working fluids in multiple applications including cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps.
摘要翻译：本发明涉及包含三氟甲烷和有效量的至少一种选自受阻酚，硫代磷酸酯，丁基化三苯基硫代磷酸酯，有机磷酸酯，亚磷酸酯，芳基烷基醚，萜烯，萜类化合物，环氧化物，氟化环氧化物，氧杂环丁烷，抗坏血酸，硫醇，内酯，硫醚，胺，硝基甲烷，烷基硅烷，二苯甲酮衍生物，芳基硫醚，二乙烯基对苯二酸，二苯基对苯二酸，离子液体及其混合物。这些稳定的三氟甲烷组合物可用作多种应用中的工作流体，包括冷却装置，例如制冷，空调，冷却器和热泵。

87. 发明授权

US08496846B2 Phenol stabilizers for fluoroolefins 有权
标题翻译：苯酚稳定剂用于氟烯烃
公开(公告)号：US08496846B2
公开(公告)日：2013-07-30
申请号：US13289259
申请日：2011-11-04
申请人： Velliyur Nott Mallikarjuna Rao , Mario Joseph Nappa , Barbara Haviland Minor , Thomas J. Leck , Nandini C. Mouli
发明人： Velliyur Nott Mallikarjuna Rao , Mario Joseph Nappa , Barbara Haviland Minor , Thomas J. Leck , Nandini C. Mouli
IPC分类号： C09K5/04
CPC分类号： C09K5/044 , C09K5/045 , C09K2205/126
摘要： The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be at least one phenol or a mixture of at least one phenol with other stabilizers. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.
摘要翻译：本发明涉及包含至少一种氟烯烃和有效量的稳定剂的组合物，其可以是至少一种苯酚或至少一种苯酚与其它稳定剂的混合物。稳定的组合物可用于冷却装置，例如制冷，空调，冷却器和热泵，以及作为泡沫发泡剂，溶剂，气溶胶推进剂，灭火剂和灭菌剂的应用。

88. 发明授权

US08398882B2 Processes for the production of fluoropropanes and halopropenes and azeotropic compositions of 2-chloro-3,3,3-trifluoro-1-propene with HF and of 1,1,1,2,2-pentafluoropropane with HF 有权
标题翻译：制备氟丙烷和卤代丙烯的方法和2-氯-3,3,3-三氟-1-丙烯与HF和1,1,1,2,2-五氟丙烷与HF的共沸组合物
公开(公告)号：US08398882B2
公开(公告)日：2013-03-19
申请号：US12444470
申请日：2007-10-31
申请人： Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
发明人： Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
IPC分类号： C09K5/04 , C07C21/18
CPC分类号： C07C17/21 , B01J23/26 , B01J23/864 , B01J37/26 , C07C17/00 , C07C17/087 , C07C17/20 , C07C17/206 , C07C17/23 , C07C17/25 , C07C17/35 , C07C19/08 , C07C21/18
摘要： A process is disclosed for making CF3CF2CH3, CF3CF═CH2 and/or CF3CCl═CH2. The process involves reacting at least one starting material selected from the group consisting of halopropanes of the formula CX3CHClCH2X, halopropenes of the formula CClX2CCl═CH2 and halopropenes of the formula CX2═CClCH2X, wherein each X is independently F or Cl, with HF in a reaction zone to produce a product mixture comprising HF, HCl, CF3CF2CH3, CF3CF═CH2 and CF3CCl═CH2; and recovering the CF3CF2CH3, CF3CF═CH2 and/or CF3CCl═CH2 from the product mixture.
摘要翻译：公开了一种制备CF 3 CF 2 CH 3，CF 3CF≡CH2和/或CF 3 CCl = CH 2的方法。该方法包括使至少一种选自式CX 3 CHClCH 2 X的卤代丙烷，式CClX 2 CCl = CH 2的卤代丙烯和式CX2 = CClCH2X的卤代丙烯，其中每个X独立地为F或Cl的起始物质与HF在反应区以产生包含HF，HCl，CF 3 CF 2 CH 3，CF 3CF≡CH2和CF 3 CCl = CH 2的产物混合物; 并从产物混合物中回收CF 3 CF 2 CH 3，CF 3CF≡CH2和/或CF 3 CCl = CH 2。

89. 发明授权

US08318992B2 Processes for the production of fluoropropanes and halopropenes 有权
标题翻译：制备氟丙烷和卤代丙烯的方法
公开(公告)号：US08318992B2
公开(公告)日：2012-11-27
申请号：US12444462
申请日：2007-10-31
申请人： Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
发明人： Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
IPC分类号： C07C17/20
CPC分类号： C07C17/21 , C07C17/10 , C07C17/206 , C07C17/25 , C07C19/08 , C07C21/18
摘要： A process is disclosed for making CF3CF2CH3, CF3CF═CH2 and/or CF3CCl═CH2. The process involves reacting at least one starting material selected from the group consisting of halopropanes of the formula CX3CH2CH2X, halopropenes of the formula CX3CH═CH2 and halopropenes of the formula CX2═CHCH2X, wherein each X is independently F or Cl, with HF and Cl2 in a reaction zone to produce a product mixture comprising HF, HCl, CF3CF2CH3, CF3CF═CH2, and CF3CCl═CH2; and recovering the CF3CF2CH3, CF3CF═CH2 and/or CF3CCl═CH2 from the product mixture. Also disclosed is a process for making CF3CH2CHF2, CF3CH═CHF, and/or CF3CH═CHCl. This process involves reacting at least one starting material selected from the group consisting of halopropenes of the formula CX3CH═CH2 and halopropenes of the formula CX2═CHCH2X, wherein each X is independently F or Cl, with HF and Cl2 in a reaction zone to produce a product mixture comprising HF, HCl, CF3CH2CHF2, CF3CH═CHF and CF3CH═CHCl; and recovering the CF3CH2CHF2, CF3CH═CHF, and/or CF3CH═CHCl from the product mixture. The molar ratio of HF to the total amount of starting materials fed to the reaction zone for both of these processes is at least stoichiometric, and the molar ratio of Cl2 to total amount of starting material fed to the reaction zone for both of these processes is 2:1 or less.
摘要翻译：公开了一种制备CF 3 CF 2 CH 3，CF 3CF≡CH2和/或CF 3 CCl = CH 2的方法。该方法包括使选自式CX3CH2CH2X的卤代丙烷，式CX3CH = CH2的卤代丙烯和式CX2 = CHCH2X的卤代丙烯，其中每个X独立地为F或Cl的至少一种原料与HF和Cl 2反应在反应区中产生包含HF，HCl，CF 3 CF 2 CH 3，CF 3 CF = CH 2和CF 3 CCl = CH 2的产物混合物; 并从产物混合物中回收CF 3 CF 2 CH 3，CF 3CF≡CH2和/或CF 3 CCl = CH 2。还公开了制备CF 3 CH 2 CHF 2，CF 3 CH = CHF和/或CF 3 CH = CHCl的方法。该方法包括使选自式CX3CH = CH2的卤代丙烯和式CX2 = CHCH2X的卤代丙烯，其中每个X独立地为F或Cl的至少一种起始材料与HF和Cl 2在反应区中反应以产生包含HF，HCl，CF 3 CH 2 CHF 2，CF 3 CH = CHF和CF 3 CH = CHCl的产物混合物; 并从产物混合物中回收CF 3 CH 2 CHF 2，CF 3 CH = CHF和/或CF 3 CH = CHCl。对于这两种方法，HF与进料到反应区的起始原料的总量的摩尔比至少为化学计量，并且对于这两种方法，进料到反应区的Cl 2与原料的总量的摩尔比为 2：1或更少。

90. 发明授权

US08288597B2 Dehydrofluorination process to manufacture hydrofluoroolefins 有权
标题翻译：脱氟化氢工艺制造氢氟烯烃
公开(公告)号：US08288597B2
公开(公告)日：2012-10-16
申请号：US12440062
申请日：2007-09-05
申请人： Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert , Mario Joseph Nappa
发明人： Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert , Mario Joseph Nappa
IPC分类号： C07C17/00
CPC分类号： C09K5/045 , C07C17/25 , C09K2205/126 , C07C21/18
摘要： Disclosed is a process for the manufacture of hydrofluoroolefins of the structure CF3CF═CHY, wherein Y can be H or F, comprising reacting at least one fluoropropane reactant of the structure CF3CFXCFYH, wherein X can be either F or H, and Y can be either F or H, provided that both X and Y′ are not both F, with a basic aqueous solution in the presence of a non-aqueous, non-alcoholic solvent, and in the presence of a phase transfer catalyst.
摘要翻译：公开了一种制备结构CF 3 CF = CHY的氢氟烯烃的方法，其中Y可以是H或F，包括使至少一种结构CF 3 CFXCFYH的氟丙烷反应物，其中X可以是F或H，Y可以是 F或H，条件是在非水非醇溶剂的存在下，并且在相转移催化剂的存在下，X和Y'都不是F都与碱性水溶液一起使用。

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