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71. 发明授权

US5922416A Method for fabricating metal oxide free fluoroelastomer fusing member 失效
标题翻译：制造不含金属氧化物的含氟弹性体定影材料的方法
公开(公告)号：US5922416A
公开(公告)日：1999-07-13
申请号：US570783
申请日：1995-12-12
申请人： Chris F. DelRosario , James A. Lentz
发明人： Chris F. DelRosario , James A. Lentz
IPC分类号： G03G15/20 , C08F2/46 , C08F8/00 , C08F14/22 , C08F14/28 , C08F214/22 , C08F214/28 , C08F259/08 , C08J7/00 , C08K5/04 , C08K5/103 , C08K5/1515 , C08K5/17 , C08K5/3477 , C08L27/12 , C08L27/16
CPC分类号： C08L27/16 , C08F259/08 , Y10S428/906 , Y10T428/3154 , Y10T428/31663 , Y10T428/31678
摘要： A method of forming a fuser roll by disposing a substantially uncured fluoroelastomer composition which is substantially free of metal containing material on a substrate, and curing the fluoroelastomer material. The fluoroelastomer has at least about 23.4 mole percent hexafluoropropylene and can be cured by electron beam treatment, fugitive base treatment or by the use of blocked/hindered bases.
摘要翻译：通过将基本上不含金属的材料的基本上未固化的含氟弹性体组合物设置在基材上并固化含氟弹性体材料来形成定影辊的方法。含氟弹性体具有至少约23.4摩尔％的六氟丙烯，并且可以通过电子束处理，短暂的碱处理或使用封闭/阻碍的碱固化。

72. 发明授权

US5883177A Amorphous perfluoropolymers 失效
标题翻译：无定形全氟聚合物
公开(公告)号：US5883177A
公开(公告)日：1999-03-16
申请号：US845145
申请日：1997-04-21
申请人： Pasqua Colaianna , Giulio Brinati , Vincenzo Arcella
发明人： Pasqua Colaianna , Giulio Brinati , Vincenzo Arcella
IPC分类号： C08F16/38 , C08F214/18 , C08F214/24 , C08F214/26 , C08F214/28 , C08F216/14 , C09D127/18 , C09D145/00 , C08K5/02
CPC分类号： C09D145/00 , C09D127/18
摘要： Use of amorphous perfluoropolymers based on homopolymers of the TTD dioxole or its amorphous copolymers to prepare solutions in fluoro-containing solvents, to obtain solutions for coatings, wherein TTD has the formula: ##STR1## wherein R.sub.F is a perfluoroalkylic radical with 1-5 carbon atoms, linear or branched when possible; X.sub.1 and X.sub.2 equal to or different from each other being F or CF.sub.3 ; the TTD amount ranges from 40 to 100% by moles.
摘要翻译：使用基于TTD二氧杂环戊烯或其无定形共聚物的均聚物的无定形全氟聚合物在含氟溶剂中制备溶液，以获得涂料溶液，其中TTD具有下式：其中RF是具有1-5个碳的全氟烷基原子，可以是直链或支链的; X 1和X 2彼此相同或不同，是F或CF 3; TTD量为40-100摩尔％。

73. 发明授权

US5637663A Amorphous tetrafluoroethylene-hexafluoropropylene copolymers 失效
标题翻译：无定形四氟乙烯 - 六氟丙烯共聚物
公开(公告)号：US5637663A
公开(公告)日：1997-06-10
申请号：US596932
申请日：1996-02-05
申请人： Colin Anolick , Viacheslav A. Petrov , Bruce E. Smart , Charles W. Stewart , Robert C. Wheland , William B. Farnham , Andrew E. Feiring , Weiming Qiu
发明人： Colin Anolick , Viacheslav A. Petrov , Bruce E. Smart , Charles W. Stewart , Robert C. Wheland , William B. Farnham , Andrew E. Feiring , Weiming Qiu
IPC分类号： C07C317/04 , C08F214/18 , C08F214/22 , C08F214/26 , C08F214/28 , C08L23/02 , C08L27/18 , C09D127/20 , C08F14/18
CPC分类号： C09D127/20 , C07C317/04 , C08F214/18 , C08F214/22 , C08F214/26 , C08F214/265 , C08F214/28 , C08L23/02 , C08L23/06 , C08L27/18
摘要： Disclosed herein are novel amorphous tetrafluoroethylene-hexafluoropropylene (TFE-HFP) dipolymers, and other copolymers containing TFE, HFP and a third monomer, many of which are more random than previous amorphous TFE-HFP copolymers, as well as a novel high productivity continuous process for making these polymers. The polymers are particularly useful in the form of coatings, films and encapsulants.
摘要翻译：本文公开了新型无定形四氟乙烯 - 六氟丙烯（TFE-HFP）二元聚合物，以及含有TFE，HFP和第三单体的其它共聚物，其中许多比以前的无定形TFE-HFP共聚物更随机，以及新颖的高生产率连续方法用于制备这些聚合物。聚合物特别可用于涂料，薄膜和密封剂的形式。

74. 发明授权

US5169915A Fluorine-containing copolymer and curable composition containing the same 失效
标题翻译：含氟的共聚物和含有它的可固化组合物
公开(公告)号：US5169915A
公开(公告)日：1992-12-08
申请号：US723073
申请日：1991-06-28
申请人： Haruhiko Mohri , Yoshiki Shimizu , Hideya Saito , Akira Chida
发明人： Haruhiko Mohri , Yoshiki Shimizu , Hideya Saito , Akira Chida
IPC分类号： C08F14/18 , C08F14/24 , C08F14/28 , C08F16/14 , C08F16/16 , C08F22/10 , C08F24/00 , C08F30/08 , C08F210/00 , C08F214/18 , C08F214/24 , C08F214/26 , C08F214/28 , C08F216/14 , C08F218/02 , C08F220/02 , C08F220/04 , C08F220/10 , C08F220/18 , C08F222/10 , C08F224/00 , C08F230/08 , C08G18/62 , C08K5/04 , C08L23/18 , C08L27/12 , C08L31/02 , C08L31/04 , C08L33/00 , C08L33/04 , C08L33/06 , C08L87/00 , C09D5/44 , C09D123/18 , C09D127/12 , C09D131/02 , C09D133/00 , C09D133/04
CPC分类号： C08F214/186 , C08F210/00 , C08L27/12 , C08L33/06
摘要： A fluorine-containing copolymer comprising 20 to 60% by mole of the fluoroolefin unit (1), 5 to 45% by mole of the .beta.-methyl substituted .alpha.-olefin unit (2), 1 to 45% by mole of the unit (3) derived from a monomer having a chemically curable functional group, 1 to 45% by mole of the unit (4) derived from a monomer having ester moieties in the side chains and 0 to 45% by mole of the unit (5) derived from a copolymerizable monomer other than the above monomers, if necessary, 0.1 to 15% by mole of the unit (6) derived from a monomer having carboxyl groups. The copolymer can provide a curable composition alone or with an acrylic polymer. The fluorine-containing copolymer is excellent in solvent-solubility, compatibility with curing agents, additives and other polymers, pigment dispersibility, curing reactivity, dispersibility to water, pot life, film forming ability, coating properties, and the like. The coating film prepared from the copolymer has a high weatherability and is excellent in film properties such as stain resistance, heat-yellowing resistance, dechlorination resistance, optical properties, adhesion to a substrate, mechanical properties, heat resistance, chemical resistance, solvent (gasoline) resistance, water resistance and good appearance of finished products.

75. 发明授权

US4985520A Fluoroelastomer having excellent processability 失效
标题翻译：具有优异加工性能的氟弹性体
公开(公告)号：US4985520A
公开(公告)日：1991-01-15
申请号：US382395
申请日：1989-07-20
申请人： Kenichi Hayashi , Yoshito Matsuoka
发明人： Kenichi Hayashi , Yoshito Matsuoka
IPC分类号： C08F14/22 , C08F14/28 , C08F214/22 , C08F214/28
CPC分类号： C08F214/22
摘要： A fluoroelastomer is disclosed which comprises vinylidene fluoride units and hexafluoropropylene units, optionally together with tetrafluoroethylene units, and wherein the amount of tetrafluoroethylene units is 35 to 0% by weight and the weight ratio of vinylidene fluoride units to hexafluoropropylene units is in the range of 80:20 to 40:60. The fluoroelastomer has a relatively low limiting viscosity number and a specific molecular weight distribution. The fluoroelastomer has excellent processability, e.g., excellent roll processability, mold release characteristics and metal-adhesion properties, and is capable of providing a vulcanized rubber having excellent mechanical strength and compression set resistance. The vulcanized rubber is advantageous in the manufacture of O-rings, oil seals, packings, gaskets, diaphragm materials and the like.

76. 发明授权

US4784915A Polymer piezoelectric film 失效
标题翻译：聚合物压电薄膜
公开(公告)号：US4784915A
公开(公告)日：1988-11-15
申请号：US640835
申请日：1984-08-15
申请人： Teruo Sakagami , Kenichi Nakamura , Naohiro Murayama
发明人： Teruo Sakagami , Kenichi Nakamura , Naohiro Murayama
IPC分类号： H01L41/193 , H01L41/08 , C08F214/28 , H01L41/18
CPC分类号： H01L41/193 , Y10S310/80 , Y10T428/3154 , Y10T428/31544 , Y10T428/31678
摘要： A polymer piezoelectric film comprising a poled film of a vinylidene fluoride copolymer having a high molecular weight as defined by an inherent viscosity within a specific range comprising 40 to 90 mol. % of vinylidene fluoride and 10 to 60 mol. % of trifluoroethylene. Such a high molecular weight vinylidene fluoride copolymer can give a preferable state of molecular arrangement during film formation, particularly preferably formation by casting, to provide a film excellent in piezoelectric characteristic and secondary processing characteristic.
摘要翻译：一种聚合物压电薄膜，其包含偏二氟乙烯共聚物的极化膜，所述聚偏二氟乙烯共聚物具有由特定范围内的特性粘度所限定的高分子量，所述比浓对数粘度在40至90mol之间。％偏二氟乙烯和10至60mol。％的三氟乙烯。这种高分子量偏二氟乙烯共聚物可以在成膜期间提供分子排列的优选状态，特别优选通过铸造形成，以提供压电特性和二次加工特性优异的膜。

77. 发明授权

US4696989A Fluorine-containing elastomeric copolymer 失效
标题翻译：含氟弹性共聚物
公开(公告)号：US4696989A
公开(公告)日：1987-09-29
申请号：US849734
申请日：1986-04-09
申请人： Masahiko Oka , Yutaka Ueta , Hideo Kano , Masayasu Tomoda , Shoji Kawachi
发明人： Masahiko Oka , Yutaka Ueta , Hideo Kano , Masayasu Tomoda , Shoji Kawachi
IPC分类号： C08F14/28 , C08F214/18 , C08F214/22 , C08F214/26 , C08F214/28 , H01B3/44 , C08F14/18 , C08F14/22
CPC分类号： H01B3/445 , C08F214/18
摘要： A copolymer comprising repeating units derived from tetrafluoroethylene, vinylidene fluoride and hexafluoropropylene in a molar ratio within an area defined on a tetrafluoroethylene, vinylidene fluoride and hexafluoropropylene ternary composition diagram by a hexagon with its first vertex A at 34.0% by weight of tetrafluoroethylene, 8.5% by weight of vinylidene fluoride and 57.5% by weight of hexafluoropropylene; its second vertex B at 26.5% by weight of tetrafluoroethylene, 14.5% by weight of vinylidene fluoride and 59.0% by weight of hexafluoropropylene; its third vertex C at 31.0% by weight of tetrafluoroethylene, 24.0% by weight of vinylidene fluoride and 45.0% by weight of hexafluoropropylene; its fourth vertex D at 49.0% by weight of tetrafluoroethylene, 26.5% by weight of vinylidene fluoride and 24.5% by weight of hexafluoropropylene; its fifth vertex E at 49.0% by weight of tetrafluoroethylene, 11.0% by weight of vinylidene fluoride and 40.0% by weight of hexafluoropropylene; and its sixth vertex F at 50.0% by weight of tetrafluoroethylene, 9.0% by weight of vinylidene fluoride and 41.0% by weight of hexafluoropropylene having not only good flexibility, heat resistance and flame retardance but also good insulating performance and moldability.
摘要翻译：包含衍生自四氟乙烯，偏二氟乙烯和六氟丙烯的重复单元的摩尔比在四氟乙烯，偏二氟乙烯和六氟丙烯三元组成图中的四边形组成图中，其第一顶点A为34.0重量％的四氟乙烯，8.5重量％的偏二氟乙烯和57.5重量％的六氟丙烯; 其第二顶点B为26.5重量％的四氟乙烯，14.5重量％的偏二氟乙烯和59.0重量％的六氟丙烯; 其第三顶点C为31.0重量％的四氟乙烯，24.0重量％的偏二氟乙烯和45.0重量％的六氟丙烯; 其第四顶点D为49.0重量％的四氟乙烯，26.5重量％的偏二氟乙烯和24.5重量％的六氟丙烯; 其第五顶点E为49.0重量％的四氟乙烯，11.0重量％的偏二氟乙烯和40.0重量％的六氟丙烯; 其第四顶点F为40.0重量％的四氟乙烯，9.0重量％的偏二氟乙烯和41.0重量％的六氟丙烯，不仅具有良好的柔韧性，耐热性和阻燃性，而且具有良好的绝缘性能和成型性。

78. 发明授权

US4640966A Fluoroolefin copolymer, process for production thereof and composition containing said copolymer 失效
标题翻译：氟烯烃共聚物，其制备方法和含有所述共聚物的组合物
公开(公告)号：US4640966A
公开(公告)日：1987-02-03
申请号：US795115
申请日：1985-11-05
申请人： Tomomasa Mitani , Ichiro Mihata
发明人： Tomomasa Mitani , Ichiro Mihata
IPC分类号： C08F214/18 , C08L27/12 , C08F214/24 , C08F214/26 , C08F214/28
CPC分类号： C08L27/12 , C08F214/188
摘要： A fluoroolefin copolymer having an inherent viscosity of from 0.05 to 2.0 dl/g and composed of(I) 10 to 70 mole % of monomeric units derived from a fluoroolefin represented by the general formula ##STR1## wherein X is H, Cl, F, CF.sub.3, OCF.sub.3 or OC.sub.3 F.sub.7, (II) 5 to 60 mole % of monomeric units derived from a vinyl carboxylate represented by the general formula ##STR2## wherein R.sub.1 represents an aliphatic, aromatic or alicyclic hydrocarbon group having 1 to 17 carbon atoms,(III) 5 to 70 mole % of monomeric units derived from a vinyl ether having an alkyl group with 1 to 8 carbon atoms, and(IV) 0 to 30 mole % of monomeric units derived from a hydroxyl-containing vinyl ether represented by the general formula ##STR3## wherein R.sub.2 represents an alkylene group having 1 to 6 carbon atoms.
摘要翻译：特性粘度为0.05〜2.0dl / g的氟烯烃共聚物，由（I）10〜70摩尔％的由通式（IMAGE）表示的氟代烯烃衍生的单体单元组成，其中X为H，Cl，F， CF 3，OCF 3或OC 3 F 7，（II）5〜60摩尔％的由通式（IMAGE）表示的羧酸乙烯酯衍生的单体单元，其中R1表示碳原子数1〜17的脂肪族，芳香族或脂环族烃基，（III ）5〜70摩尔％的衍生自具有1〜8个碳原子的烷基的乙烯基醚的单体单元，和（IV）0〜30摩尔％的由通式（1）表示的含羟基乙烯基醚的单体单元其中，R 2表示碳原子数1〜6的亚烷基。

79. 发明授权

US4564662A Fluorocarbon elastomer 失效
标题翻译：氟碳弹性体
公开(公告)号：US4564662A
公开(公告)日：1986-01-14
申请号：US582926
申请日：1984-02-23
申请人： Loren D. Albin
发明人： Loren D. Albin
IPC分类号： C08F16/00 , C08F2/22 , C08F14/00 , C08F14/18 , C08F14/22 , C08F14/26 , C08F16/14 , C08F214/18 , C08F214/22 , C08F214/26 , C08F214/28 , C08F216/14 , C08F16/24
CPC分类号： C08F214/282 , C08F214/188 , C08F214/222
摘要： Peroxide-curable fluorocarbon elastomers having interpolymerized units derived from a cure site monomer containing bromine or iodine. The fluorocarbon elastomer gums are prepared by copolymerizing with the principal monomers normally used in preparing fluorocarbon elastomers, e.g. vinylidene fluoride, hexafluoropropene, and (optionally) tetrafluoroethylene, a small amount of a novel cure site monomer which is a vinyl ether in which at least one of the two vinylic (or double-bonded) carbon atoms thereof is bonded to at least one bromine or iodine atom, e.g. CF.sub.3 CH.sub.2 OCF.dbd.CFBr. The cured fluorocarbon elastomers of this invention have useful properties normally associated with fluorocarbon elastomers, such as acid resistance, thermal stability, and high tensile strength. These properties of shaped articles made from these fluorocarbon elastomers are not adversely affected upon exposure to high temperatures for extended periods.
摘要翻译：具有衍生自含溴或碘的固化位点单体的共聚单元的过氧化物可固化氟碳弹性体。通过与通常用于制备氟碳弹性体的主要单体共聚制备氟碳弹性体胶。偏二氟乙烯，六氟丙烯和（任选的）四氟乙烯，少量新型固化部位单体，其中乙烯基醚的两个乙烯基（或双键）碳原子中的至少一个与至少一个溴或碘原子，例如 CF3CH2OCF = CFBr。本发明固化的碳氟化合物弹性体具有通常与氟碳弹性体相关的有用的性质，例如耐酸性，热稳定性和高拉伸强度。由这些氟碳弹性体制成的成型制品的这些性能在长时间暴露于高温下不会受到不利影响。

80. 发明授权

US4335238A Fluoropolymer hexafluoropropene, tetrafluorethene and 1,1-difluoroethene 失效
标题翻译：含氟聚合物六氟丙烯，四氟乙烯和1,1-二氟乙烯
公开(公告)号：US4335238A
公开(公告)日：1982-06-15
申请号：US193375
申请日：1980-10-06
申请人： Albert L. Moore , Clare A. Stewart, Jr. , Isadore Swerlick
发明人： Albert L. Moore , Clare A. Stewart, Jr. , Isadore Swerlick
IPC分类号： C08F14/00 , C08F14/28 , C08F214/22 , C08F214/26 , C08J7/04 , C08F214/28
CPC分类号： C08J7/047 , C08F214/22 , C08F214/26 , C08J2427/00 , Y10T428/3154
摘要： Terpolymer consisting of 12 to 48% by weight TFE units, 7 to 24% by weight HFP units and 30 to 81% by weight VF.sub.2 units, provided that when the content of TFE units is less than 42% by weight, the content of HFP units is less than 15% by weight. Heat-stable films such as polyimide film can be coated with a coating comprising the terpolymer to provide heat-sealable film useful as wire insulation.
摘要翻译：由12至48重量％的TFE单元，7至24重量％的HFP单元和30至81重量％的VF 2单元组成的三元共聚物，条件是当TFE单元的含量小于42重量％时，HFP的含量单位小于15重量％。可以用包含三元共聚物的涂层涂覆聚酰亚胺膜等热稳定膜，以提供可用作电线绝缘的可热封膜。

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