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71. 发明授权

US5866501A Dispersed anion-modified iron oxide catalysts for hydroconversion processes 失效
标题翻译：用于加氢转化法的分散的阴离子改性的氧化铁催化剂
公开(公告)号：US5866501A
公开(公告)日：1999-02-02
申请号：US609759
申请日：1996-02-23
申请人： Vivek R. Pradhan , Alfred G. Comolli , Lap-Keung Lee
发明人： Vivek R. Pradhan , Alfred G. Comolli , Lap-Keung Lee
IPC分类号： B01J23/74 , B01J23/745 , B01J23/84 , B01J23/881 , B01J27/053 , B01J27/185 , B01J27/19 , B01J35/12 , C10G1/00 , C10G1/08 , C10G1/10 , C10G47/02 , C10G47/26 , C10G49/12 , C10G65/10 , B01J27/043 , C10G1/06
CPC分类号： B01J27/053 , B01J23/745 , B01J23/881 , B01J27/1853 , B01J35/12 , C10G1/002 , C10G1/006 , C10G1/086 , C10G1/10 , C10G47/02 , C10G47/26 , C10G49/12 , C10G65/10 , B01J23/74 , B01J23/84 , B01J27/19
摘要： A dispersed fine-sized anion-modified iron oxide slurry catalyst having high surface area exceeding about 100 m.sup.2 /gm and high catalytic activity, and which is useful for hydrogenation and hydroconversion reactions for carbonaceous feed materials is disclosed. The catalyst is synthesized by rapid aqueous precipitation from saturated salt solutions such as ferric alum or ferric sulfate, and is promoted with at least one active metal such as cobalt, molybdenum, nickel, tungsten and combinations thereof. The iron-based dispersed catalysts are modified during their preparation with anionic modifiers such as molybdate (MoO.sub.4.sup.2-), phosphate (PO.sub.4.sup.3-), sulfate (SO.sub.4.sup.2-), or tungstate (WO.sub.4.sup.2-). The resulting catalyst usually has primary particle size smaller than about 50 Angstrom units, and may be used in the form of a gel or wet cake which can be easily mixed with a hydrocarbonaceous feed material such as coal, heavy petroleum fractions, mixed waste plastics or mixtures thereof. Alternatively, the catalyst can be dried and/or calcined so as to be in a fine dry particulate form suitable for adding to the feed material. The invention includes methods for making the catalyst and processes for using the catalyst for hydroprocessing of the carbonaceous feed materials.
摘要翻译：公开了一种具有超过约100m 2 / gm的高表面积和高催化活性的分散的细尺寸阴离子改性氧化铁浆料催化剂，其可用于含碳原料的氢化和加氢转化反应。通过从饱和盐溶液如三价铁或硫酸铁中的快速含水沉淀合成催化剂，并用至少一种活性金属如钴，钼，镍，钨及其组合进行促进。铁基分散催化剂在制备过程中用钼酸盐（MoO42-），磷酸盐（PO43-），硫酸盐（SO42-）或钨酸盐（WO42-））等阴离子改性剂进行改性。所得到的催化剂通常具有小于约50埃单位的初级粒度，并且可以以凝胶或湿饼的形式使用，其可以容易地与诸如煤，重质石油馏分，混合废塑料的烃类进料混合，或其混合物。或者，可以将催化剂干燥和/或煅烧成适于添加到进料中的细干燥颗粒形式。本发明包括制备催化剂的方法和使用该催化剂加氢处理含碳原料的方法。

72. 发明授权

US5853570A Process for desulfurizing catalytically cracked gasoline 失效
标题翻译：催化裂化汽油脱硫工艺
公开(公告)号：US5853570A
公开(公告)日：1998-12-29
申请号：US701957
申请日：1996-08-23
申请人： Shigeto Hatanaka , Osamu Sadakane , Satoru Hikita , Tadao Miyama
发明人： Shigeto Hatanaka , Osamu Sadakane , Satoru Hikita , Tadao Miyama
IPC分类号： C10G35/00 , B01J23/16 , B01J23/74 , C10G45/08 , C10G45/60
CPC分类号： C10G45/08 , C10G2400/02
摘要： A catalytically cracked gasoline feedstock is desulfurized under reaction conditions of a hydrogen feed rate measured at the reactor inlet of from 1 to 5 mols per mol of the feedstock oil and of from 5 to 50 mols per mol of the olefin components contained in the feedstock oil, a reaction temperature of from 200.degree. to 300.degree. C., a total pressure inside the reactor of from 10 to 20 kg/cm.sup.2 G, and a liquid hourly space velocity of from 2 to 8 l/hr, and using a catalyst which comprises a support mainly comprising alumina and having a surface area of 200 m.sup.2 /g or larger, wherein MoO.sub.3 in an amount of from 10 to 20 wt % and CoO in an amount of from 3 to 6 wt % in terms of inner content are fixed to the support, and the weight ratio of MoO.sub.3 to CoO is from 2.5 to 4.5.
摘要翻译：催化裂化汽油原料在反应器入口处测量的氢进料速率为每摩尔原料油1至5摩尔的反应条件和每摩尔原料油中所含的5至50摩尔烯烃组分的反应条件下脱硫反应温度为200-300℃，反应器内的总压为10至20kg / cm2G，液时空速为2-8升/小时，并使用包含主要包含氧化铝并且表面积为200m 2 / g或更大的载体，其中含量为10至20重量％的MoO 3和以内含量计为3至6重量％的CoO固定为载体，MoO 3与CoO的重量比为2.5〜4.5。

73. 发明授权

US5817594A Catalyst and hydrotreating process 失效
公开(公告)号：US5817594A
公开(公告)日：1998-10-06
申请号：US556888
申请日：1995-11-02
申请人： David John McNamara , Willem Hartmann Jurriaan Stork
发明人： David John McNamara , Willem Hartmann Jurriaan Stork
IPC分类号： B01J23/20 , B01J21/04 , B01J23/22 , B01J23/24 , B01J23/40 , B01J23/74 , B01J23/85 , B01J27/14 , B01J27/185 , B01J27/188 , B01J27/19 , B01J35/10 , C10G45/04 , B01J23/00
CPC分类号： B01J27/188 , B01J21/04 , B01J23/85 , B01J27/19 , B01J35/023 , B01J35/1009 , B01J35/1014 , B01J35/1038 , B01J35/1057 , B01J35/1066 , B01J35/108 , C10G45/04
摘要： Catalyst comprising a porous inorganic refractory oxide wherein the catalyst has: (a) a total pore volume in the range of from 0.2 to 0.5 ml/g, (b) a macroporosity of at least 0.1 ml/g, (c) a microporosity of at least 0.05 ml/g, and (d) a surface area of at least 5 m.sup.2 /g. Process for reducing the amount of solid contaminants and the amount or dissolved metallic contaminants, wherein a hydrocarbon oil containing such contaminants is contacted with hydrogen under hydrotreating conditions in the presence of the above catalyst.

74. 发明授权

US5607891A Process for reducing the benzine content of petrols 失效
标题翻译：降低汽油汽油含量的方法
公开(公告)号：US5607891A
公开(公告)日：1997-03-04
申请号：US638313
申请日：1996-04-26
申请人： Christine Travers , Philippe Courty , Patrick Sarrazin
发明人： Christine Travers , Philippe Courty , Patrick Sarrazin
IPC分类号： B01J27/128 , B01J23/40 , B01J23/74 , B01J27/13 , C07C5/22 , C10G35/06 , C10G35/085 , C10G45/60 , B01J27/06
CPC分类号： B01J23/74 , B01J23/40 , C10G45/60
摘要： The invention concerns an isomerization catalyst comprising 4 to 15% of at least one halogen and at least one metal from group VIII deposited on a support composed of a mixture of specific proportions of eta alumina and gamma alumina. The invention also concerns a process for reducing the benzene content of gasoline fractions and isomerizing paraffins in the presence of this catalyst, in which isomerization is carried out on a mixture of a) a feed with the following composition by weight: 40% to 80% of paraffins, 0.5% to 7% of cyclic hydrocarbons and 6% to 45% of aromatics, and with a maximum distillation temperature of between 70.degree. C. and 90.degree. C., and b) a C.sub.5 -C.sub.6 cut which is generally a straight run cut.
摘要翻译：本发明涉及一种异构化催化剂，其包含4至15％的至少一种卤素和至少一种沉积在由特定比例的氧化铝和γ氧化铝的混合物构成的载体上的来自第VIII族的金属。本发明还涉及在该催化剂存在下降低汽油馏分的苯含量和异构化烷烃的方法，其中异构化在a）以下重量组成的进料的混合物中进行：40％至80％的链烷烃，0.5％至7％的环烃和6％至45％的芳族化合物，最高蒸馏温度在70℃至90℃之间，和b）C5-C6馏分，通常为直跑

75. 发明授权

US5607650A Apparatus for removing contaminants from gaseous stream 失效
标题翻译：用于从气流中除去污染物的装置
公开(公告)号：US5607650A
公开(公告)日：1997-03-04
申请号：US529519
申请日：1995-09-18
申请人： Lawrence Debbage , Eugene Kelley , Eugene D. Guth , Larry E. Campbell , Robert N. Danziger , Sally Padron
发明人： Lawrence Debbage , Eugene Kelley , Eugene D. Guth , Larry E. Campbell , Robert N. Danziger , Sally Padron
IPC分类号： B01J20/08 , B01D53/50 , B01D53/56 , B01D53/62 , B01D53/86 , B01D53/94 , B01J8/26 , B01J20/04 , B01J21/12 , B01J23/02 , B01J23/28 , B01J23/40 , B01J23/42 , B01J23/74 , B01J23/96 , B01J37/02 , F01N3/08 , F01N13/04 , F23R3/40 , B01D53/34
CPC分类号： B01D53/9481 , B01D53/508 , B01D53/56 , B01D53/62 , B01D53/8609 , B01D53/8628 , B01D53/864 , B01D53/945 , B01J23/02 , B01J37/0221 , B01J37/0244 , F01N13/011 , F01N3/0814 , F01N3/0842 , F01N3/085 , F01N3/0857 , F01N3/0878 , F01N3/0885 , F23R3/40 , B01D2255/91 , F01N2250/12 , F01N2290/00 , F01N2410/12 , F01N2570/04 , F01N2570/14 , Y02T10/22
摘要： A method of decreasing the level of NOx, CO and SO.sub.2 emissions in a gas turbine is disclosed. A catalyst absorber, preferably made of alumina/platinum/carbonate salt, is used to oxidize the pollutant oxides and absorb them. The catalyst absorber can then be regenerated and reused. An apparatus for treating the stack gases and a method of making the catalyst absorber are also described.
摘要翻译：公开了一种降低燃气轮机中的NOx，CO和SO 2排放水平的方法。优选使用由氧化铝/铂/碳酸盐形成的催化剂吸收剂来氧化污染物并吸收它们。然后可以再生和重复使用催化剂吸收剂。还描述了用于处理堆叠气体的装置和制造催化剂吸收剂的方法。

76. 发明授权

US5601701A Process for the elimination of mercury from hydrocarbons by passage over a presulphurated catalyst 失效
标题翻译：通过经过预硫化催化剂从烃中消除汞的方法
公开(公告)号：US5601701A
公开(公告)日：1997-02-11
申请号：US193590
申请日：1994-02-08
申请人： Charles Cameron , Jean Cosyns , Patrick Sarrazin , Jean Paul Boitiaux , Philippe Courty
发明人： Charles Cameron , Jean Cosyns , Patrick Sarrazin , Jean Paul Boitiaux , Philippe Courty
IPC分类号： B01J20/02 , B01J23/24 , B01J23/44 , B01J23/74 , B01J27/04 , B01J37/20 , C10G45/04 , C10G45/10 , C10G67/06
CPC分类号： C10G67/06 , B01J37/20 , C10G45/04 , B01J23/24 , B01J23/44 , B01J23/74
摘要： The invention concerns a process for the elimination of mercury from hydrocarbons by passage of the feedstock with hydrogen over a catalyst then bringing the product obtained into contact with a mercury retention bed, the catalyst comprising at least one element selected from the group constituted by iron, nickel, cobalt, molybdenum, tungsten, palladium, wherein at least 5% is in the sulphide state. Any arsenic present in the feedstock is also eliminated.In accordance with the invention, the catalyst is simultaneously presulphurated and reduced.The invention results in a considerable reduction in operation period and high retention efficiency at temperatures between 120.degree. C. and 250.degree. C. and in the presence of 0-1000 mg of sulphur/kg of feed.
摘要翻译：本发明涉及一种通过使原料通过原料与氢气在催化剂上消除汞的方法，然后将所得产物与汞保留床接触，所述催化剂包含至少一种选自铁，镍，钴，钼，钨，钯，其中至少5％处于硫化物状态。原料中存在的任何砷也被消除。根据本发明，催化剂同时被预硫化并还原。本发明导致在120℃至250℃的温度和0-1000mg硫/ kg进料存在下的操作周期和高保留效率的显着降低。

77. 发明授权

US5476958A Process for the removal of olefins from silanes 失效
标题翻译：从硅烷中除去烯烃的方法
公开(公告)号：US5476958A
公开(公告)日：1995-12-19
申请号：US418218
申请日：1995-04-06
申请人： Konrad Mautner , Anton Schinabeck
发明人： Konrad Mautner , Anton Schinabeck
IPC分类号： B01J23/40 , B01J23/74 , C07B63/02 , C07F7/12 , C07F7/16 , C07F7/20 , C07F7/08
CPC分类号： C07F7/20 , C07F7/121 , C07F7/16
摘要： In the process for the removal of olefins from the silanes or silane mixtures obtained during methylchlorosilane synthesis, the olefins are reacted with hydrogen in the presence of hydrogenation catalysts.
摘要翻译：在甲基氯硅烷合成过程中从硅烷或硅烷混合物中除去烯烃的过程中，烯烃与氢气在氢化催化剂存在下反应。

78. 发明授权

US5451558A Process for the reaction and absorption of gaseous air pollutants, apparatus therefor and method of making the same 失效
标题翻译：气态空气污染物的反应和吸收方法及其制备方法及其制备方法
公开(公告)号：US5451558A
公开(公告)日：1995-09-19
申请号：US192003
申请日：1994-02-04
申请人： Larry E. Campbell , Robert Danziger , Eugene D. Guth , Sally Padron
发明人： Larry E. Campbell , Robert Danziger , Eugene D. Guth , Sally Padron
IPC分类号： B01J20/08 , B01D53/50 , B01D53/56 , B01D53/62 , B01D53/86 , B01D53/94 , B01J8/26 , B01J20/04 , B01J21/12 , B01J23/02 , B01J23/28 , B01J23/40 , B01J23/42 , B01J23/74 , B01J23/96 , B01J37/02 , F01N3/08 , F01N13/04 , F23R3/40 , B01J23/00 , B01J23/58 , B01J20/00
CPC分类号： B01D53/9481 , B01D53/508 , B01D53/56 , B01D53/62 , B01D53/8609 , B01D53/8628 , B01D53/864 , B01D53/945 , B01J23/02 , B01J37/0221 , B01J37/0244 , F01N13/011 , F01N3/0814 , F01N3/0842 , F01N3/085 , F01N3/0857 , F01N3/0878 , F01N3/0885 , F23R3/40 , B01D2255/91 , F01N2250/12 , F01N2290/00 , F01N2410/12 , F01N2570/04 , F01N2570/14 , Y02T10/22
摘要： A method of decreasing the level of NOx, CO and SO.sub.2 emissions in a gas turbine is disclosed. A catalyst absorber, preferably made of alumina/platinum/carbonate salt, is used to oxidize the pollutant oxides and absorb them. The catalyst absorber can then be regenerated and reused. An apparatus for treating the stack gases, and a method of making the catalyst absorber are also described.
摘要翻译：公开了一种降低燃气轮机中的NOx，CO和SO 2排放水平的方法。优选使用由氧化铝/铂/碳酸盐形成的催化剂吸收剂来氧化污染物并吸收它们。然后可以再生和重复使用催化剂吸收剂。还描述了用于处理烟道气体的装置，以及制造催化剂吸收体的方法。

79. 发明授权

US5395813A Particulate solids for catalyst supports and heat transfer materials 失效
标题翻译：用于催化剂载体和传热材料的颗粒状固体
公开(公告)号：US5395813A
公开(公告)日：1995-03-07
申请号：US60334
申请日：1993-05-11
申请人： LeRoy R. Clavenna , Stephen M. Davis , Rocco A. Fiato , Geoffrey R. Say
发明人： LeRoy R. Clavenna , Stephen M. Davis , Rocco A. Fiato , Geoffrey R. Say
IPC分类号： B01J21/06 , B01J23/83 , C01B3/40 , B01J23/10 , B01J23/74 , B01J35/02
CPC分类号： B01J21/066 , B01J23/83 , C01B3/40 , C01B2203/1052 , C01B2203/1064 , C01B2203/1082 , Y02P20/52
摘要： A particulate, precalcined low silica content zirconia, especially one stabilized with yttria, is useful as a catalyst support or as a heat transfer solids component for conducting chemical reactions at high temperature, in oxidizing, reducing or hydrothermal conditions, especially in syn gas operations. An admixture of precalcined particulate low silica content zirconia, particularly a low silica content yttria-stabilized zirconia, is employed in a preferred embodiment as a heat transfer solid, in concentrations ranging generally from about 10 wt. % to about 99.9 wt. %, with a particulate catalyst, notably a nickel-on-alumina catalyst, in concentration ranging generally from about 0.1 wt. % to about 90 wt. %. Such an admixture provides a particularly useful catalytic contact mass in high temperature oxidizing, reducing and hydrothermal environments, notably in conducting synthesis gas generation operations. This type of bed promotes continuous, highly efficient heat and mass transfer within the reacting gas phase. The presence of the heat transfer solid as a bed component maintains excellent bed fluidization characteristics, suppressing the normal tendency of the catalyst to sinter or agglomerate; tendencies which promote defluidization of the bed. Moreover, the heat transfer particles of the bed are highly attrition resistant, and are chemically compatible with the catalyst particles of the admixture.
摘要翻译：颗粒状预煅烧的低二氧化硅含量的氧化锆，特别是用氧化钇稳定的氧化锆，可用作催化剂载体或用作在高温，氧化，还原或水热条件下进行化学反应的传热固体组分，特别是在合成气操作中。预先煅烧的颗粒状低二氧化硅含量的氧化锆，特别是低二氧化硅含量氧化钇稳定的氧化锆的混合物在优选的实施方案中用作传热固体，浓度通常为约10重量％％至约99.9wt。％的颗粒催化剂，特别是镍 - 氧化铝催化剂，其浓度通常为约0.1wt。％至约90wt。％。这种混合物在高温氧化，还原和水热环境中特别是在进行合成气生成操作中提供特别有用的催化接触物质。这种类型的床促进在反应气相内的连续，高效的热和质量传递。作为床成分的传热固体的存在保持了优异的床流化特性，抑制了催化剂烧结或附聚的正常趋势; 促进床层流变的趋势。此外，床的传热颗粒是高度耐磨性的，并且与混合物的催化剂颗粒化学相容。

80. 发明授权

US5389690A Activation of hydrocarbon synthesis catalyst 失效
标题翻译：烃合成催化剂的活化
公开(公告)号：US5389690A
公开(公告)日：1995-02-14
申请号：US166336
申请日：1993-12-13
申请人： Willard N. Mitchell
发明人： Willard N. Mitchell
IPC分类号： B01J23/46 , B01J23/74 , B01J23/889 , B01J37/18 , C07C1/06 , C10G2/00
CPC分类号： C10G2/331 , B01J37/18 , C07C1/066 , B01J23/462 , B01J23/74 , B01J23/8896 , C07C2521/06 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C10G2300/703
摘要： A fresh, reduced hydrocarbon synthesis catalyst is activated by contact with hydrogen at elevated temperatures and pressures and in the presence of liquid hydrocarbons, preferably, sufficient to immerse the catalyst therein.
摘要翻译：新鲜的还原烃合成催化剂通过在升高的温度和压力下和在液体烃存在下与氢接触来活化，优选足以将催化剂浸入其中。

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