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1. 发明授权

US5665321A Process for the reaction and absorption of gaseous air pollutants, apparatus therefor and method of making same 失效
标题翻译：气态空气污染物的反应和吸收方法，设备及其制备方法
公开(公告)号：US5665321A
公开(公告)日：1997-09-09
申请号：US489987
申请日：1995-06-12
申请人： Larry E. Campbell , Robert Danziger , Eugene D. Guth , Sally Padron
发明人： Larry E. Campbell , Robert Danziger , Eugene D. Guth , Sally Padron
IPC分类号： B01J20/08 , B01D53/50 , B01D53/56 , B01D53/62 , B01D53/86 , B01D53/94 , B01J8/26 , B01J20/04 , B01J21/12 , B01J23/02 , B01J23/28 , B01J23/40 , B01J23/42 , B01J23/74 , B01J23/96 , B01J37/02 , F01N3/08 , F01N13/04 , F23R3/40 , B01D53/74
CPC分类号： B01D53/9481 , B01D53/508 , B01D53/56 , B01D53/62 , B01D53/8609 , B01D53/8628 , B01D53/864 , B01D53/945 , B01J23/02 , B01J37/0221 , B01J37/0244 , F01N13/011 , F01N3/0814 , F01N3/0842 , F01N3/085 , F01N3/0857 , F01N3/0878 , F01N3/0885 , F23R3/40 , B01D2255/91 , F01N2250/12 , F01N2290/00 , F01N2410/12 , F01N2570/04 , F01N2570/14 , Y02T10/22
摘要： A method of decreasing the level of NOx, CO and SO.sub.2 emissions in a gas turbine is disclosed. A catalyst absorber, preferably made of alumina/platinum/carbonate salt, is used to oxidize the pollutant oxides and absorb them. The catalyst absorber can then be regenerated and reused. An apparatus for treating the stack gases, and a method of making the catalyst absorber are also described.
摘要翻译：公开了一种降低燃气轮机中的NOx，CO和SO 2排放水平的方法。优选使用由氧化铝/铂/碳酸盐形成的催化剂吸收剂来氧化污染物并吸收它们。然后可以再生和重复使用催化剂吸收剂。还描述了用于处理烟道气体的装置，以及制造催化剂吸收体的方法。

2. 发明授权

US5451558A Process for the reaction and absorption of gaseous air pollutants, apparatus therefor and method of making the same 失效
标题翻译：气态空气污染物的反应和吸收方法及其制备方法及其制备方法
公开(公告)号：US5451558A
公开(公告)日：1995-09-19
申请号：US192003
申请日：1994-02-04
申请人： Larry E. Campbell , Robert Danziger , Eugene D. Guth , Sally Padron
发明人： Larry E. Campbell , Robert Danziger , Eugene D. Guth , Sally Padron
IPC分类号： B01J20/08 , B01D53/50 , B01D53/56 , B01D53/62 , B01D53/86 , B01D53/94 , B01J8/26 , B01J20/04 , B01J21/12 , B01J23/02 , B01J23/28 , B01J23/40 , B01J23/42 , B01J23/74 , B01J23/96 , B01J37/02 , F01N3/08 , F01N13/04 , F23R3/40 , B01J23/00 , B01J23/58 , B01J20/00
CPC分类号： B01D53/9481 , B01D53/508 , B01D53/56 , B01D53/62 , B01D53/8609 , B01D53/8628 , B01D53/864 , B01D53/945 , B01J23/02 , B01J37/0221 , B01J37/0244 , F01N13/011 , F01N3/0814 , F01N3/0842 , F01N3/085 , F01N3/0857 , F01N3/0878 , F01N3/0885 , F23R3/40 , B01D2255/91 , F01N2250/12 , F01N2290/00 , F01N2410/12 , F01N2570/04 , F01N2570/14 , Y02T10/22
摘要： A method of decreasing the level of NOx, CO and SO.sub.2 emissions in a gas turbine is disclosed. A catalyst absorber, preferably made of alumina/platinum/carbonate salt, is used to oxidize the pollutant oxides and absorb them. The catalyst absorber can then be regenerated and reused. An apparatus for treating the stack gases, and a method of making the catalyst absorber are also described.
摘要翻译：公开了一种降低燃气轮机中的NOx，CO和SO 2排放水平的方法。优选使用由氧化铝/铂/碳酸盐形成的催化剂吸收剂来氧化污染物并吸收它们。然后可以再生和重复使用催化剂吸收剂。还描述了用于处理烟道气体的装置，以及制造催化剂吸收体的方法。

3. 发明授权

US5607650A Apparatus for removing contaminants from gaseous stream 失效
标题翻译：用于从气流中除去污染物的装置
公开(公告)号：US5607650A
公开(公告)日：1997-03-04
申请号：US529519
申请日：1995-09-18
申请人： Lawrence Debbage , Eugene Kelley , Eugene D. Guth , Larry E. Campbell , Robert N. Danziger , Sally Padron
发明人： Lawrence Debbage , Eugene Kelley , Eugene D. Guth , Larry E. Campbell , Robert N. Danziger , Sally Padron
IPC分类号： B01J20/08 , B01D53/50 , B01D53/56 , B01D53/62 , B01D53/86 , B01D53/94 , B01J8/26 , B01J20/04 , B01J21/12 , B01J23/02 , B01J23/28 , B01J23/40 , B01J23/42 , B01J23/74 , B01J23/96 , B01J37/02 , F01N3/08 , F01N13/04 , F23R3/40 , B01D53/34
CPC分类号： B01D53/9481 , B01D53/508 , B01D53/56 , B01D53/62 , B01D53/8609 , B01D53/8628 , B01D53/864 , B01D53/945 , B01J23/02 , B01J37/0221 , B01J37/0244 , F01N13/011 , F01N3/0814 , F01N3/0842 , F01N3/085 , F01N3/0857 , F01N3/0878 , F01N3/0885 , F23R3/40 , B01D2255/91 , F01N2250/12 , F01N2290/00 , F01N2410/12 , F01N2570/04 , F01N2570/14 , Y02T10/22
摘要： A method of decreasing the level of NOx, CO and SO.sub.2 emissions in a gas turbine is disclosed. A catalyst absorber, preferably made of alumina/platinum/carbonate salt, is used to oxidize the pollutant oxides and absorb them. The catalyst absorber can then be regenerated and reused. An apparatus for treating the stack gases and a method of making the catalyst absorber are also described.
摘要翻译：公开了一种降低燃气轮机中的NOx，CO和SO 2排放水平的方法。优选使用由氧化铝/铂/碳酸盐形成的催化剂吸收剂来氧化污染物并吸收它们。然后可以再生和重复使用催化剂吸收剂。还描述了用于处理堆叠气体的装置和制造催化剂吸收剂的方法。

4. 发明授权

US5650127A NOx removal process 失效
标题翻译： NOx去除过程
公开(公告)号：US5650127A
公开(公告)日：1997-07-22
申请号：US355030
申请日：1994-12-13
申请人： Larry E. Campbell , Eugene D. Guth , Robert Danziger
发明人： Larry E. Campbell , Eugene D. Guth , Robert Danziger
IPC分类号： B01D53/04 , B01D53/75 , B01D53/86 , B01D53/94 , B01J23/42 , C01B21/36 , B01J8/02
CPC分类号： C01B21/36 , B01D53/75 , B01D53/8625 , B01D53/8628 , B01D53/864 , B01D53/9409 , B01D53/9445 , B01J23/42 , B01D2253/102 , B01D2253/104 , B01D2253/3425 , B01D2255/91 , B01D2257/404 , B01D2257/504 , B01D2258/01 , B01D2259/40 , Y02P20/152 , Y02T10/22
摘要： A method of decreasing the level of NOx and CO emissions in a gas turbine is disclosed. The method includes the steps of oxidizing NO and CO in the gas stream to corresponding NO.sub.2 and CO.sub.2, and then absorbing the nitrogen oxide pollutants on an absorption bed. The method can achieve levels of 0 to 2 ppm CO and 0.35 to 1.5 ppm NO in the resultant stream.
摘要翻译：公开了一种降低燃气轮机中NOx和CO排放水平的方法。该方法包括将气流中的NO和CO氧化为相应的NO 2和CO 2，然后在吸收床上吸收氮氧化物污染物的步骤。该方法可以在所得流中达到0至2ppm CO和0.35至1.5ppm NO的水平。

5. 发明授权

US5599758A Regeneration of catalyst/absorber 失效
标题翻译：催化剂/吸收剂的再生
公开(公告)号：US5599758A
公开(公告)日：1997-02-04
申请号：US371274
申请日：1994-12-23
申请人： Eugene D. Guth , Larry E. Campbell
发明人： Eugene D. Guth , Larry E. Campbell
IPC分类号： B01J20/30 , B01J23/92 , B01J23/96 , B01J38/04 , B01J38/10 , B01J20/34 , B01J38/36
CPC分类号： B01J38/10 , B01J23/96 , B01J38/04
摘要： Hydrogen or carbon monoxide in a carrier of nitrogen or steam is passed over a devitalized catalyst/carbonate or bicarbonate absorber which has absorbed or adsorbed nitrates and nitrites from engine exhaust to restore the carbonate form and regenerate the devitalized catalyst/absorber for reuse.
摘要翻译：在氮气或蒸汽的载体中的氢或一氧化碳通过失活的催化剂/碳酸盐或碳酸氢盐吸收器，其吸收或吸附来自发动机排气的硝酸盐和亚硝酸盐以还原碳酸盐形式并再生失活的催化剂/吸收剂以供再利用。

6. 发明授权

US5953911A Regeneration of catalyst/absorber 失效
标题翻译：催化剂/吸收剂的再生
公开(公告)号：US5953911A
公开(公告)日：1999-09-21
申请号：US18720
申请日：1998-02-04
申请人： Eugene D. Guth , Larry E. Campbell , Gregory J. Wagner
发明人： Eugene D. Guth , Larry E. Campbell , Gregory J. Wagner
IPC分类号： F01N3/10 , B01D53/86 , B01D53/94 , B01D53/96 , B01J23/90 , B01J23/96 , B01J38/04 , F01N3/08 , F01N3/20 , F01N3/00
CPC分类号： B01J38/04 , B01D53/8631 , B01D53/8643 , B01D53/9431 , B01D53/96 , B01J23/90
摘要： Hydrocarbon in a carrier of nitrogen or steam is passed over a devitalized supported noble metal/alkali or alkaline earth catalyst/absorber, such as Pt on an alumina monolith coated with potassium carbonate, which has sorbed NOx from engine exhaust to restore and regenerate the devitalized catalyst/absorber for reuse. The hydrocarbon undergoes a shift reaction to produce CO in situ which is the reactant gas for the regeneration.
摘要翻译：在氮气或蒸汽载体中的碳氢化合物通过在碳酸钾涂覆的氧化铝整体上的失活的负载型贵金属/碱土金属/碱土金属/碱土催化剂/吸收剂（例如Pt）上，其吸收来自发动机排气的NOx以恢复和再生失活的催化剂/吸收剂用于再利用。烃经历转移反应以产生原位CO，其是用于再生的反应气体。

7. 发明授权

US4288408A Apparatus for the diacritic cracking of hydrocarbon feeds for the selective production of ethylene and synthesis gas 失效
标题翻译：用于选择性生产乙烯和合成气的碳氢化合物进料的裂变裂化装置
公开(公告)号：US4288408A
公开(公告)日：1981-09-08
申请号：US922675
申请日：1978-07-07
申请人： Eugene D. Guth , LeGrand A. Daly , John K. Arand
发明人： Eugene D. Guth , LeGrand A. Daly , John K. Arand
IPC分类号： C10G9/38 , B01J7/00 , B01J10/00
CPC分类号： C10G9/38 , C10G2400/20 , Y02P30/40
摘要： Apparatus for the diacritic cracking of heavy hydrocarbon feeds includes a combustor for burning a fuel, to provide the hot combustion products to the reactor. The combustor is water cooled and includes gas filming with an appropriate gas such as N.sub.2 or CO.sub.2 to avoid coking in the combustor by preventing impingement of the fuel and combustion products on the combustor walls. The reactor is of reduced cross-section, also preferably utilizing gas filming to avoid coking on the reactor walls. Feed stock injectors are provided adjacent the reactor inlet. Adjacent the outlet end of the reactor is a quench section designed for the rapid injection of a quench fluid to reduce the stream temperature below that at which further cracking will take place, with the quench injectors also being gas filmed to avoid the coking thereof. Thereafter a tubular heat exchanger is provided to remove additional heat from the primary flow stream from the reactor for recovery purposes, the heat exchanger again using gas filming to minimize the build-up of coking and tar build-up, particularly encouraged by the rapidly decreasing temperatures. The gaseous products are then further quenched and cooled for processing by conventional means.
摘要翻译：用于重烃进料的裂变裂化的装置包括用于燃烧燃料的燃烧器，以将热燃烧产物提供给反应器。燃烧器是水冷的，并且包括用合适的气体例如N 2或CO 2进行气体成膜，以避免燃烧器中的燃料和燃烧产物撞击在燃烧器壁上。反应器的横截面减小，还优选利用气体成膜以避免焦化在反应器壁上。在反应器入口附近提供原料喷射器。邻近反应器的出口端是淬火部分，其设计用于快速注入骤冷流体，以将物流温度降低到低于将发生进一步裂化的流温度，同时骤冷喷射器也被气相成膜以避免焦化。此后，提供管状热交换器以从用于回收目的的反应器的主流流中除去额外的热量，热交换器再次使用气体成膜以最小化焦化和焦油堆积的积聚，特别是由快速降低温度。然后将气体产物进一步骤冷和冷却以通过常规方法进行处理。

8. 发明授权

US4166830A Diacritic cracking of hydrocarbon feeds for selective production of ethylene and synthesis gas 失效
标题翻译：用于选择性生产乙烯和合成气的碳氢化合物进料的开裂裂纹
公开(公告)号：US4166830A
公开(公告)日：1979-09-04
申请号：US917462
申请日：1978-06-21
申请人： Eugene D. Guth , LeGrand A. Daly , John K. Arand
发明人： Eugene D. Guth , LeGrand A. Daly , John K. Arand
IPC分类号： C10G9/38 , C07C3/08
CPC分类号： C10G9/38 , C10G2400/26 , Y10S585/95 , Y10S585/953
摘要： A continuous process for the selective production of ethylene by the diacritic cracking of heavy hydrocarbon feeds such as residual oils, heavy vacuum gas oils, atmospheric gas oils, crude oils and coal-derived liquids. The diacritic cracking takes place in a non-tubular multi-zone reactor at elevated pressures (e.g. 70-1000 p.s.i.a.) A fuel is combusted with oxygen in the first section of the multi-zone reactor. The high temperature products of combustion of the first zone pass into a second section of the reactor where the feed is atomized and cracked to yield products including ethylene, acetylene and synthesis gas. The reaction products of the second zone then pass into a third section in which they are quenched. In each stage of the reactor the present process seeks to prevent the build-up of coke deposits on the walls of the reactor. In the first two stages, a film of gas such as CO.sub.2 or N.sub.2 is injected along the inner walls to prevent build-up of coke. In the quench section, the liquid material introduced as the quenching fluid also acts as a barrier to prevent coking.
摘要翻译：用于通过重烃进料例如残油，重真空瓦斯油，常压瓦斯油，原油和煤源液体的裂解反应来选择性生产乙烯的连续方法。间断裂化在非管状多区域反应器中在升高的压力（例如70-1000p.s.i.a.）下进行。燃料在多区域反应器的第一部分中与氧气一起燃烧。第一区域的高温燃烧产物进入反应器的第二部分，其中进料被雾化和裂化以产生包括乙烯，乙炔和合成气的产物。然后第二区的反应产物进入第三段，在其中淬火。在反应器的每个阶段，本方法试图防止焦炭沉积物堆积在反应器的壁上。在前两个阶段，沿内壁注入气体如二氧化碳或氮气，以防止焦炭的积聚。在淬火部分中，作为淬火流体引入的液体材料也用作防止焦化的屏障。

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