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71. 发明申请

US20050049140A1 Activated catalyst systems from substituted dialuminoxane complexes 有权
公开(公告)号：US20050049140A1
公开(公告)日：2005-03-03
申请号：US10650471
申请日：2003-08-28
申请人： Matthew Holtcamp
发明人： Matthew Holtcamp
IPC分类号： B01J31/00 , C08F4/602 , C08F4/622 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16
CPC分类号： B01J31/0231 , B01J31/143 , B01J31/1616 , B01J31/1805 , B01J31/1815 , B01J31/2226 , B01J31/2243 , B01J31/2295 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F210/16 , C08F4/65916 , C08F210/14 , C08F2500/03
摘要： A catalyst composition and method for preparing a supported catalyst system for olefin polymerization is provided. In one aspect, the catalyst composition includes a reaction product of a dialuminoxane and a halogen substituted aryl borane, wherein the reaction takes place on a support and at conditions sufficient to exchange one or more ligands on the dialuminoxane for one or more ligands on the halogen substituted aryl borane while on the support. In one embodiment, the method for preparing the supported catalyst system includes combining a dialuminoxane with a support to form a treated catalyst support, and combining a halogen substituted aryl borane with the treated catalyst support at conditions sufficient to exchange one or more ligands on the dialuminoxane for one or more ligands on the halogen substituted aryl borane while on the support to form a supported activator. The method further includes reacting one or more polymerization catalysts with the supported activator.

72. 发明授权

US06858557B1 Supported constrained geometry olefin polymerization catalysts 失效
标题翻译：支持约束几何烯烃聚合催化剂
公开(公告)号：US06858557B1
公开(公告)日：2005-02-22
申请号：US09059095
申请日：1998-04-13
申请人： James C. Stevens
发明人： James C. Stevens
IPC分类号： C07F5/00 , C07F7/00 , C07F7/02 , C07F7/10 , C07F7/12 , C07F7/28 , C07F7/30 , C07F9/50 , C07F9/6596 , C07F17/00 , C08F4/44 , C08F4/60 , C08F4/602 , C08F4/623 , C08F4/64 , C08F4/642 , C08F4/643 , C08F4/659 , C08F4/6592 , C08F8/00 , C08F10/00 , C08F10/02 , C08F110/02 , C08F110/14 , C08F210/00 , C08F210/02 , C08F210/16 , C08F212/08 , C08L23/08 , C08L23/14 , C08L25/06
CPC分类号： C08F10/02 , C07F7/10 , C07F9/5045 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/14 , C08F210/02 , C08F210/16 , C08L23/08 , C08L23/0838 , C08L25/06 , C08L2203/14 , Y10S526/943 , C08F2/34 , C08L2666/04 , C08F2500/12 , C08F2500/03 , C08F212/08 , C08F214/08 , C08F210/14 , C08F2500/08 , C08F2500/20 , C08F2500/26 , C08F2500/02 , C08F2500/07 , C08F210/08 , C08F210/06 , C08F212/14
摘要： Metal complexes having constrained geometry and a process for preparation thereof, addition polymerization catalysts formed therefrom, processes for preparation of such addition polymerization catalysts, methods of use, and novel polymers formed thereby, including ElPE resins and pseudo-random copolymers, are disclosed and claimed.
摘要翻译：具有约束几何形状的金属络合物及其制备方法，由其形成的加成聚合催化剂，由此形成的加成聚合催化剂，使用方法和由其形成的新型聚合物的方法，包括ElPE树脂和假无规共聚物，。

73. 发明授权

US6162884A Olefin oligomerization and processes thereof 失效
标题翻译：烯烃低聚及其工艺
公开(公告)号：US6162884A
公开(公告)日：2000-12-19
申请号：US302133
申请日：1999-04-29
申请人： Helmut G. Alt , Alexander Koppl
发明人： Helmut G. Alt , Alexander Koppl
IPC分类号： C07C2/32 , C08F4/60 , C08F4/602 , C08F4/70 , C08F4/80 , C08F10/00
CPC分类号： C07C2/32 , C07C2531/22 , C08F10/00 , C08F4/7006
摘要： Novel catalyst systems which comprise 2-pyridine carboxaldimine nickel dihalide complexes can be used with an organoaluminum cocatalyst in slurry oligomerization or polymerization processes to oligomerize or polymerize mono-1-olefins and, optionally a higher alpha-olefin comonomer, to produce low molecular weight polymers or synthetic oils.
摘要翻译：包含2-吡啶甲醛亚胺镍二卤化物配合物的新型催化剂体系可以与有机铝助催化剂在淤浆低聚或聚合方法中一起使用以使单-1-烯烃和任选的较高级α-烯烃共聚单体低聚或聚合以产生低分子量聚合物或合成油。

74. 发明授权

US6124229A Process for the preparation of metallocene catalyst systems on inert support material using gas phase reactor 失效
标题翻译：使用气相反应器制备惰性载体材料上茂金属催化剂体系的方法
公开(公告)号：US6124229A
公开(公告)日：2000-09-26
申请号：US701238
申请日：1996-08-22
申请人： Ralf-Jurgen Becker , Rainer Rieger
发明人： Ralf-Jurgen Becker , Rainer Rieger
IPC分类号： C08F4/602 , B01J31/22 , C08F4/02 , C08F4/42 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/658 , C08F4/6592 , C08F10/00 , B01J31/00 , B01J37/00 , C08F4/60
CPC分类号： B01J31/143 , B01J31/1616 , B01J31/2295 , C08F10/00 , B01J21/08 , B01J2531/48 , C08F4/61912 , C08F4/61916 , C08F4/6192 , Y10S502/523
摘要： Disclosed is a process for preparing a supported metallocene catalyst by introducing, in a first stage, a gas stream comprising an organoaluminum compound, an inert support material and water, into a first gas phase reactor; allowing the mixture to react under conditions effective to form an aluminoxane supported on said inert support material; metering a second gas stream comprising a metallocene into said gas phase reactor; allowing said mixture to react under conditions effective to form a supported metallocene catalyst; and drying, in a second stage, said supported metallocene catalyst, wherein said drying is carried out in a gas phase reactor. An alternative process comprises introducing, in a first stage, a gas stream comprising an organoaluminum compound, an inert support material, a metallocene and water, into a first gas phase reactor; allowing the mixture to react under conditions effective to form an aluminoxane supported with said metallocene on said inert support material; and drying, in a second stage, said supported metallocene catalyst, wherein said drying is carried out in a gas phase reactor.
摘要翻译：公开了一种通过在第一阶段将包含有机铝化合物，惰性载体材料和水的气流引入第一气相反应器中来制备负载型茂金属催化剂的方法; 允许混合物在有效形成负载在所述惰性载体材料上的铝氧烷的条件下反应; 将包含茂金属的第二气流计量到所述气相反应器中; 允许所述混合物在有效形成负载型茂金属催化剂的条件下反应; 并在第二阶段中干燥所述负载的茂金属催化剂，其中所述干燥在气相反应器中进行。一种替代方法包括在第一阶段将包含有机铝化合物，惰性载体材料，茂金属和水的气流引入第一气相反应器中; 允许混合物在有效形成在所述惰性载体材料上与所述茂金属担载的铝氧烷的条件下反应; 并在第二阶段中干燥所述负载的茂金属催化剂，其中所述干燥在气相反应器中进行。

75. 发明授权

US6110858A Olefin polymerization catalysts and process for producing olefin polymers 失效
标题翻译：烯烃聚合催化剂和烯烃聚合物的制备方法
公开(公告)号：US6110858A
公开(公告)日：2000-08-29
申请号：US991658
申请日：1997-12-16
申请人： Toshiyuki Kaneko , Akihiro Yano
发明人： Toshiyuki Kaneko , Akihiro Yano
IPC分类号： C08F4/02 , C08F4/602 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F10/00 , C08F110/06 , C08F210/16 , C08F210/18 , B01J29/00
CPC分类号： C08F10/00 , C08F110/06 , C08F210/16 , C08F210/18 , C08F4/61912 , C08F4/61916 , C08F4/61922
摘要： Catalysts for olefin polymerization which consist essentially of a transition metal compound, a modified clay compound and an organic aluminum compound, wherein the modified clay compound comprises a reaction product of a clay mineral and a proton acid salt of a specific amine compound, as well as a method of polymerizing olefins using such catalysts. It is possible thereby to obtain olefin polymers with high productivity and low ash content.
摘要翻译：用于烯烃聚合的催化剂，其基本上由过渡金属化合物，改性粘土化合物和有机铝化合物组成，其中改性粘土化合物包括粘土矿物和特定胺化合物的质子酸盐的反应产物，以及使用这种催化剂聚合烯烃的方法。从而可以获得具有高生产率和低灰分含量的烯烃聚合物。

76. 发明授权

US6060418A Supported hydrocarbylsiloxy-aluminoxane catalyst compositions 有权
标题翻译：负载型烃基甲硅烷氧基 - 铝氧烷催化剂组合物
公开(公告)号：US6060418A
公开(公告)日：2000-05-09
申请号：US301649
申请日：1999-04-28
申请人： Samuel A. Sangokoya
发明人： Samuel A. Sangokoya
IPC分类号： C07F5/06 , C07F7/08 , C08F4/60 , C08F4/602 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08L83/04 , B01J31/00 , C07F7/02
CPC分类号： C08F10/00 , C07F5/068 , C07F7/0847 , C08F4/61912 , C08F4/61922 , Y10S526/943
摘要： Catalysts deposited on a support are described. The catalyst itself is formed by combining (i) a metallocene of a transition, lanthanide or actinide metal and (ii) a siloxy-aluminoxane composition which comprises an aluminoxane which contains hydrocarbyl-siloxane moieties which are free of Si-OH groups, wherein the molar ratio of aluminum to hydrocarbylsiloxane is from about 1:1 to 1000:1. The siloxy-aluminoxane composition used is free of Si-OH groups, and the aluminoxane of the siloxy-aluminoxane composition was formed by partial hydrolysis of trialkylaluminum. Supports for the catalysts are particulate inorganic oxides, preferably silica, alumina, silica-alumina, or a mixture thereof, or resinous polyolefin support materials.
摘要翻译：描述沉积在载体上的催化剂。催化剂本身通过组合（i）过渡金属茂，镧系元素或锕系金属和（ii）甲硅烷氧基铝氧烷组合物形成，所述组合物包含含有不含Si-OH基团的烃基 - 硅氧烷部分的铝氧烷，其中，铝与烃基硅氧烷的摩尔比为约1:1至1000:1。所用的甲硅烷氧基铝氧烷组合物不含Si-OH基团，并且通过三烷基铝的部分水解形成甲硅烷氧基 - 铝氧烷组合物的铝氧烷。催化剂的载体是颗粒无机氧化物，优选二氧化硅，氧化铝，二氧化硅 - 氧化铝或其混合物，或树脂聚烯烃载体材料。

77. 发明授权

US06054404A Bridged bis-fluorenyl metallocenes, process for the preparation thereof and use thereof in catalysts for the polymerization of olefins 失效
标题翻译：桥联双芴基金属茂，其制备方法及其在烯烃聚合催化剂中的应用
公开(公告)号：US06054404A
公开(公告)日：2000-04-25
申请号：US123385
申请日：1998-07-27
申请人： Luigi Resconi , Robert L. Jones
发明人： Luigi Resconi , Robert L. Jones
IPC分类号： B01J31/00 , C07F7/08 , C07F7/30 , C07F17/00 , C08F4/44 , C08F4/60 , C08F4/602 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06
CPC分类号： C07F17/00 , C08F10/00 , C08F110/06 , C08F4/61912 , C08F4/61927 , C08F4/65912 , Y10S526/943
摘要： Metallocene compounds having two fluorenyl ligands bridged with a single silicon or germanium atom, said atom having two substituent groups containing a total of at least four carbon atoms, are useful as catalyst components for the polymerization of olefins. Particularly, it is possible to prepare high molecular weight atactic polypropylene with improved yields with respect to the known catalysts.
摘要翻译：具有两个与单个硅或锗原子桥接的芴基配体的金属茂化合物，所述原子具有两个含有至少四个碳原子的取代基，可用作烯烃聚合的催化剂组分。特别地，相对于已知的催化剂，可以制备具有提高的产率的高分子量无规立构聚丙烯。

78. 发明授权

US6028151A Catalyst composition having improved comonomer reactivity 失效
标题翻译：催化剂组合物具有改善的共聚单体反应性
公开(公告)号：US6028151A
公开(公告)日：2000-02-22
申请号：US30436
申请日：1998-02-25
申请人： Eric Paul Wasserman , Sun Chueh Kao , Frederick John Karol
发明人： Eric Paul Wasserman , Sun Chueh Kao , Frederick John Karol
IPC分类号： C08F4/44 , C08F4/602 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/02 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/6192 , Y10S526/901 , Y10S526/943
摘要： A process for producing an olefin polymer, which comprises contacting at least two olefin monomers under polymerization conditions with a catalyst composition comprising A) an aluminoxane-impregnated support prepared by contacting an aluminoxane with an inert carrier material and heating to a temperature of at least about 80.degree. C.; B) a metallocene of the formula:(L).sub.y (L')MY.sub.(x-y-1)wherein M is a metal from groups IIIB to VIII of the Periodic Table; each L and L' is independently a cycloalkadienyl group bonded to M; each Y is independently hydrogen, an aryl, alkyl, alkenyl, alkylaryl, or arylalkyl radical having 1-20 carbon atoms, a hydrocarboxy radical having from 1-20 carbon atoms, a halogen, RCO.sub.2 --, or R.sub.2 N--, wherein R is a hydrocarbyl group containing 1 to about 20 carbon atoms; y is 0, 1, or 2; x is 1, 2, 3, or 4; and x-y.gtoreq.1; C) a bulky aluminum alkyl of the formula:AlR.sup.1.sub.x R.sup.2.sub.(3-x)wherein R.sup.1 is a hydrocarbyl group having 1 to 12 carbon atoms; x is an integer from 0 to 2; R.sup.2 is a hydrocarbyl group of the formula --(CH2).sub.y -- R.sup.3, wherein y is an integer from 1 to 8; and R.sup.3 is a saturated or unsaturated hydrocarbyl group having 3 to 12 carbon atoms containing at least one ring, and D) methylaluminoxane is provided. The catalyst composition may be used to prepare olefin polymers having increased short chain branching frequency.
摘要翻译：一种制备烯烃聚合物的方法，其包括使聚合条件下的至少两种烯烃单体与催化剂组合物接触，所述催化剂组合物包含：A）通过使铝氧烷与惰性载体材料接触而制备的铝氧烷浸渍的载体，并加热至至少约 80℃。 B）下式的茂金属：（L）y（L'）MY（x-y-1）其中M是元素周期表IIIB至VIII族的金属; 每个L和L'独立地是与M键合的环二烯基; 每个Y独立地是氢，具有1-20个碳原子的芳基，烷基，烯基，烷基芳基或芳基烷基，具有1-20个碳原子的烃基，卤素，RCO2-或R2N-，其中R是含有1至约20个碳原子的烃基; y为0,1或2; x是1，2，3或4; 和x-y> / = 1; C）下式的大体积的烷基铝：AlR 1 R 2（3-x）其中R 1是具有1至12个碳原子的烃基; x是0到2的整数; R 2是式 - （CH 2）y -R 3的烃基，其中y是1至8的整数; R3为含有至少一个环的碳原子数为3〜12的饱和或不饱和烃基，提供D）甲基铝氧烷。催化剂组合物可用于制备具有增加的短链支化频率的烯烃聚合物。

79. 发明授权

US6013745A Phosphorus based catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的磷基催化剂
公开(公告)号：US6013745A
公开(公告)日：2000-01-11
申请号：US905650
申请日：1997-08-04
申请人： Ian McKay , Alison Ciupa , Arpad F. Somogyvari , Beth Lorraine Creed , Alan Rodney Sanger , David John Law , Ronald George Cavell
发明人： Ian McKay , Alison Ciupa , Arpad F. Somogyvari , Beth Lorraine Creed , Alan Rodney Sanger , David John Law , Ronald George Cavell
IPC分类号： C08F4/44 , C08F4/602
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16
摘要： The present invention relates to the polymerization of one or more alpha olefins in the presence of a transition metal catalyst having either a heterobifunctional ligand, having a phosphorus and a nitrogen atom, or a bis-phosphinimine ligand having two nitrogen atoms, in the presence of an activator.
摘要翻译：本发明涉及一种或多种α-烯烃的聚合反应，所述α-烯烃在具有磷和氮原子的异双官能配体或具有两个氮原子的双膦基亚胺配体的过渡金属催化剂的存在下，激活剂。

80. 发明授权

US5990035A Polymerization catalyst systems, their preparation, and use 失效
标题翻译：聚合催化剂体系，其制备和用途
公开(公告)号：US5990035A
公开(公告)日：1999-11-23
申请号：US955219
申请日：1997-10-21
申请人： Alexander Koppl , Helmut G. Alt , Syriac J. Palackal , M. Bruce Welch
发明人： Alexander Koppl , Helmut G. Alt , Syriac J. Palackal , M. Bruce Welch
IPC分类号： C08F4/602 , C08F4/659 , C08F4/6592 , C08F10/00 , B01D31/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC分类号： C08F10/00 , C08F110/02 , C08F4/65912 , C08F4/65922
摘要： A solid cocatalyst is prepared by combining (1) a first material capable of affixing an organoaluminum compound with (2) an organic liquid and then adding an organoaluminum compound and then contacting that product with water dispersed in an inert gas. Further catalyst compositions prepared from that cocatalyst and the use of such catalyst compositions to polymerize olefins is disclosed.
摘要翻译：通过将（1）能够固定有机铝化合物的第一材料与（2）有机液体组合，然后加入有机铝化合物，然后使该产物与分散在惰性气体中的水接触来制备固体助催化剂。公开了由该助催化剂制备的其它催化剂组合物和这种催化剂组合物用于聚合烯烃的用途。

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