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    • 72. 发明授权
    • Foamed thermoplastic resin particles and method of producing the foamed particles
    • 发泡热塑性树脂颗粒和发泡颗粒的制造方法
    • US08148439B2
    • 2012-04-03
    • US11909717
    • 2006-03-20
    • Fuminobu HiroseToshio MiyagawaKenichi Senda
    • Fuminobu HiroseToshio MiyagawaKenichi Senda
    • C08J9/00C08J9/04C08G63/00
    • C08J9/18C08J2203/14C08J2367/02C08J2367/04
    • It is intended to provide resin foamed particles having a high environmental compatibility. Furthermore, it is intended to provide an economical and easy-to-use method of producing resin foamed particles having biodegradability without using a crosslinking agent, which should be handled with care, in the step of producing foamed resin particles. It is also intended to provide a molded article made of foamed particles having an extremely high heat insulating property and a biodegradability. Thermoplastic polyester-type resin foamed particles, in which the ratio of cells with diameter of 50 μm or less amounts to 20% or more in an arbitrary two-dimensional section of a thermoplastic polyester-type resin foamed particles, are first produced and then a molded article is produced with the use of these resin foamed particles.
    • 旨在提供具有高环境相容性的树脂发泡颗粒。 此外,本发明提供一种经济且易于使用的制造发泡树脂颗粒的步骤中生产具有生物降解性的树脂发泡颗粒的方法,而不使用应谨慎处理的交联剂。 本发明还提供一种由绝热性和生物降解性极高的发泡粒子制成的成型体。 首先制造热塑性聚酯类树脂发泡粒子的任意二维截面中直径为50μm以下的细胞的比率为20%以上的热塑性聚酯型树脂发泡粒子, 使用这些树脂发泡粒子制造成型品。
    • 74. 发明申请
    • PROCESS FOR PRODUCING FLAME-RETARDANT PU FOAMS
    • 制造阻燃PU粉的方法
    • US20110257284A1
    • 2011-10-20
    • US13084753
    • 2011-04-12
    • Bernd BRUCHMANNDaniel SCHONFELDERJens FERBITZAndrea EISENHARDTMaxim PERETOLCHIN
    • Bernd BRUCHMANNDaniel SCHONFELDERJens FERBITZAndrea EISENHARDTMaxim PERETOLCHIN
    • C08J9/04C08G18/64C08G18/50
    • C08G18/5024C08G18/4063C08G18/4072C08G18/4081C08G18/482C08G18/603C08G18/632C08G18/6415C08G2101/0008C08G2101/005C08G2101/0083C08J9/141C08J9/142C08J9/144C08J9/147C08J2203/12C08J2203/14C08J2203/142C08J2203/144C08J2375/04
    • The present invention describes a process for producing flame-retardant polyurethane foams. The process of the invention includes the use of hyperbranched, nitrogen-containing polymers for providing flame retardancy to polyurethane foams. The amounts used of the hyperbranched compounds are preferably from 5 to 20% by weight, based on the polyol component. The N content of preferred nitrogen-containing compounds is at least 2% by weight. The N content of the polyurethane foams of the invention is from 1 to 8% by weight from the hyperbranched polymer. Compounds in particular used are hyper-branched polyureas, hyperbranched polyamides, and in particular hyperbranched polylysines, hyperbranched polyisocyanurates, and hyperbranched polyesteramides.An advantage of the use of the compounds of the invention is that the polyurethane foams can be rendered flame-retardant without the use of, or by using markedly reduced amounts of, halogen-containing flame retardants. It is likewise possible to achieve a marked reduction in, or to avoid, the use of additive, halogen-free flame retardants. The processing profile and the mechanical properties of the polyurethane foams are thus significantly improved. The compounds of the invention are preferably used in such a way that the foams are rendered flame-retardant without use of halogen.The hyperbranched polymers of the invention can provide flame retardancy either to flexible polyurethane foam or to rigid polyurethane foam.
    • 本发明描述了制造阻燃聚氨酯泡沫体的方法。 本发明的方法包括使用超支化的含氮聚合物来为聚氨酯泡沫提供阻燃性。 基于多元醇组分,超支化化合物的用量优选为5至20重量%。 优选的含氮化合物的N含量为至少2重量%。 本发明的聚氨酯泡沫的N含量为超支化聚合物的1〜8重量%。 特别使用的化合物是超支化聚脲,超支化聚酰胺,特别是超支化聚赖氨酸,超支化聚异氰脲酸酯和超支化聚酯酰胺。 使用本发明化合物的优点在于,聚氨酯泡沫体可以在不使用或显着减少量的含卤阻燃剂的情况下变成阻燃剂。 同样可以实现显着减少或避免添加剂,无卤素阻燃剂的使用。 因此,显着改善了聚氨酯泡沫的加工轮廓和机械性能。 本发明的化合物优选以不使用卤素使泡沫成为阻燃剂的方式使用。 本发明的超支化聚合物可以提供柔性聚氨酯泡沫或硬质聚氨酯泡沫的阻燃性。
    • 75. 发明申请
    • AZEOTROPIC AND AZEOTROPE-LIKE COMPOSITIONS OF E-1,1,1,4,4,4-HEXAFLUORO-2-BUTENE
    • E-1,1,1,4,4,4-HEXAFLOROR-2-BUTENE的AZEOTROPIC和AZEOTROPE-like组合物
    • US20110220832A1
    • 2011-09-15
    • US13112043
    • 2011-05-20
    • Mark L. Robin
    • Mark L. Robin
    • C09K5/04A62D1/00H01B3/56C09K3/00C09K3/30C11D7/60C09K3/14
    • C09K5/045A62D1/0057A62D1/0092C08J9/146C08J9/149C08J2203/02C08J2203/14C08J2207/04C09K3/30C09K2205/126C11D7/505C11D7/5054C11D7/5072C11D7/5086
    • Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions are mixtures of E-1,1,1,4,4,4-hexafluoro-2-butene with methyl formate, n-pentane, 2-methylbutane, trans-1,2-dichloroethylene, 1,1,1,3,3-pentafluoropropane, n-butane or isobutane. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as heat transfer media. Also disclosed is a process of extinguishing or suppressing a fire by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as dielectrics.
    • 公开了共沸或类共沸组合物。 共沸或类共沸组合物是E-1,1,1,4,4,4-六氟-2-丁烯与甲酸甲酯,正戊烷,2-甲基丁烷,反式-1,2-二氯乙烯,1 ,1,1,3,3-五氟丙烷,正丁烷或异丁烷。 还公开了通过使用这种共沸或类共沸组合物作为发泡剂制备热塑性或热固性泡沫的方法。 还公开了通过使用这种共沸或类共沸组合物生产制冷的方法。 还公开了使用这种共沸或类共沸组合物作为溶剂的方法。 还公开了通过使用这种共沸或类共沸组合物生产气溶胶产品的方法。 还公开了使用这种共沸或类共沸组合物作为传热介质的方法。 还公开了通过使用这种共沸或类共沸组合物扑灭或抑制火的过程。 还公开了使用这种共沸或类共沸组合物作为电介质的方法。