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1. 发明授权

US09777204B2 Epoxide and fluorinated epoxide stabilizers for fluoroolefins 有权
公开(公告)号：US09777204B2
公开(公告)日：2017-10-03
申请号：US14817337
申请日：2015-08-04
申请人： THE CHEMOURS COMPANY FC, LLC
发明人： Andrew Edward Feiring , Viacheslav A Petrov , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C Mouli , Thomas Joseph Leck , Jon Lee Howell
IPC分类号： C09K5/04 , F25B39/02
CPC分类号： C09K5/045 , C09K2205/10 , C09K2205/102 , C09K2205/104 , C09K2205/11 , C09K2205/126 , C09K2205/132 , C09K2205/134 , C09K2205/24 , F25B39/02
摘要： The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be an epoxide, fluorinated epoxide or oxetane, or a mixture thereof with other stabilizers. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.

2. 发明授权

US09234155B2 Refrigerator oil composition, method for producing same, and working fluid composition for refrigerators 有权
标题翻译：冰箱油组合物，其制造方法，以及冰箱用工作液组合物
公开(公告)号：US09234155B2
公开(公告)日：2016-01-12
申请号：US14379363
申请日：2013-02-19
申请人： JX NIPPON OIL & ENERGY CORPORATION
发明人： Masanori Saito , Takeshi Okido , Hiroshi Eto , Kuniko Adegawa
IPC分类号： C09K5/04 , C10M169/04 , C10M135/20 , C10M137/04 , C10M105/32 , C10M105/38 , C10M129/74 , C10M171/00
CPC分类号： C10M169/04 , C09K5/042 , C09K5/045 , C09K2205/11 , C09K2205/12 , C09K2205/126 , C09K2205/22 , C09K2205/24 , C10M105/32 , C10M105/38 , C10M129/74 , C10M135/20 , C10M137/04 , C10M171/008 , C10M2207/283 , C10M2207/2835 , C10M2219/082 , C10M2219/083 , C10M2219/087 , C10M2223/04 , C10M2223/041 , C10N2220/022 , C10N2220/028 , C10N2220/302 , C10N2220/303 , C10N2230/06 , C10N2240/30
摘要： A refrigerating machine oil composition comprising at least one ester additive selected from tetraesters of pentaerythritol and one selected from fatty acids having 5 to 18 carbon atoms and hexaesters of dipentaerythritol and one selected from fatty acids having 5 to 18 carbon atoms, and a base oil that is an ester other than the ester additive, in which the content of the ester additive is 2 to 20 mass % based on the total amount of the refrigerating machine oil composition, and the kinematic viscosity of the refrigerating machine oil composition at 40° C. is 3 to 500 mm2/s.
摘要翻译：一种制冷机油组合物，其包含至少一种选自季戊四醇四酯和选自具有5至18个碳原子的脂肪酸和二季戊四醇六酯和选自具有5至18个碳原子的脂肪酸的酯添加剂的酯添加剂和基油，是酯添加剂以外的酯，其中酯添加剂的含量相对于冷冻机油组合物的总量为2〜20质量％，冷冻机油组合物的运动粘度为40℃。为3〜500mm 2 / s。

3. 发明授权

US09028707B2 Compositions comprising refrigerant and lubricant and methods for replacing CFC and HCFC refrigerants without flushing 有权
标题翻译：包含制冷剂和润滑剂的组合物和用于更换CFC和HCFC制冷剂而不冲洗的方法
公开(公告)号：US09028707B2
公开(公告)日：2015-05-12
申请号：US13391913
申请日：2010-09-03
申请人： Barbara Haviland Minor
发明人： Barbara Haviland Minor
IPC分类号： C09K5/04 , C10M171/00
CPC分类号： C09K5/045 , C09K2205/11 , C09K2205/12 , C10M171/008 , C10M2203/0206 , C10M2203/1006 , C10M2203/1065 , C10M2207/085 , C10M2207/2835 , C10M2209/043 , C10M2209/1023 , C10N2220/302 , C10N2220/303
摘要： A composition comprising a refrigerant and a lubricant is disclosed, wherein the refrigerant comprises (i) a fluorocarbon selected from the group consisting of R125, R134a, R32, R152a, R143a, R218 and mixtures thereof, and (ii) a hydrocarbon selected from the group consisting of propane, n-butane, isobutane, n-pentane, isopentane, dimethyl ether, and mixtures thereof; the lubricant comprises (iii) a hydrocarbon-based lubricant component; and (iv) a synthetic lubricant component; and the synthetic lubricant component is less than 30% by weight of the total lubricant. Also disclosed are methods of replacing refrigerants in refrigeration or air conditioning systems containing a refrigerant comprising a CFC or HCFC and a lubricant. The methods involve adding to the system (a) a replacement refrigerant comprising (i) a fluorocarbon selected from the group consisting of R125, R134a, R152a, R32, R143a, R218 and mixtures thereof, and (ii) a hydrocarbon selected from the group consisting of propane, n-butane, isobutane, n-pentane, isopentane, dimethyl ether, and mixtures thereof; and (b) a synthetic lubricant component; wherein after refrigerant replacement the synthetic lubricant component is less than 30% by weight of the total amount of lubricant in the system.
摘要翻译：公开了包含制冷剂和润滑剂的组合物，其中制冷剂包含（i）选自R125，R134a，R32，R152a，R143a，R218及其混合物的碳氟化合物，和（ii）选自由丙烷，正丁烷，异丁烷，正戊烷，异戊烷，二甲醚及其混合物组成的组; 润滑剂包括（iii）烃基润滑剂组分; 和（iv）合成润滑剂组分; 并且合成润滑剂组分小于总润滑剂的30重量％。还公开了在包含CFC或HCFC和润滑剂的制冷剂的制冷或空调系统中替换制冷剂的方法。所述方法包括向系统（a）添加替代的制冷剂，其包含（i）选自R125，R134a，R152a，R32，R143a，R218及其混合物的碳氟化合物，和（ii）选自以下的烃：由丙烷，正丁烷，异丁烷，正戊烷，异戊烷，二甲醚及其混合物组成; 和（b）合成润滑剂组分; 其中在制冷剂更换后，合成润滑剂组分小于体系中润滑剂总量的30重量％。

4. 发明申请

US20150028252A1 REFRIGERATOR OIL COMPOSITION, METHOD FOR PRODUCING SAME, AND WORKING FLUID COMPOSITION FOR REFRIGERATORS 有权
标题翻译：制冷剂油组合物，其制造方法以及制冷剂的流体组合物
公开(公告)号：US20150028252A1
公开(公告)日：2015-01-29
申请号：US14379363
申请日：2013-02-19
申请人： JX NIPPON OIL & ENERGY CORPORATION
发明人： Masanori Saito , Takeshi Okido , Hiroshi Eto , Kuniko Adegawa
IPC分类号： C10M169/04 , C09K5/04
CPC分类号： C10M169/04 , C09K5/042 , C09K5/045 , C09K2205/11 , C09K2205/12 , C09K2205/126 , C09K2205/22 , C09K2205/24 , C10M105/32 , C10M105/38 , C10M129/74 , C10M135/20 , C10M137/04 , C10M171/008 , C10M2207/283 , C10M2207/2835 , C10M2219/082 , C10M2219/083 , C10M2219/087 , C10M2223/04 , C10M2223/041 , C10N2220/022 , C10N2220/028 , C10N2220/302 , C10N2220/303 , C10N2230/06 , C10N2240/30
摘要： A refrigerating machine oil composition comprising at least one ester additive selected from tetraesters of pentaerythritol and one selected from fatty acids having 5 to 18 carbon atoms and hexaesters of dipentaerythritol and one selected from fatty acids having 5 to 18 carbon atoms, and a base oil that is an ester other than the ester additive, in which the content of the ester additive is 2 to 20 mass % based on the total amount of the refrigerating machine oil composition, and the kinematic viscosity of the refrigerating machine oil composition at 40° C. is 3 to 500 mm2/s.
摘要翻译：一种制冷机油组合物，其包含至少一种选自季戊四醇四酯和选自具有5至18个碳原子的脂肪酸和二季戊四醇六酯和选自具有5至18个碳原子的脂肪酸的酯添加剂的酯添加剂和基油，是酯添加剂以外的酯，其中酯添加剂的含量相对于冷冻机油组合物的总量为2〜20质量％，冷冻机油组合物的运动粘度为40℃。为3〜500mm 2 / s。

5. 发明申请

US20150014575A1 WORKING FLUID COMPOSITION FOR REFRIGERATOR, REFRIGERATION OIL, AND METHOD FOR PRODUCING SAME 有权
标题翻译：用于制冷剂，制冷油的工作流体组合物及其生产方法
公开(公告)号：US20150014575A1
公开(公告)日：2015-01-15
申请号：US14381829
申请日：2013-02-28
申请人： JX NIPPON OIL & ENERGY CORPORATION
发明人： Masanori Saito , Takeshi Okido , Ken Sawada , Kuniko Adegawa
IPC分类号： C09K5/04
CPC分类号： C09K5/042 , C09K2205/11 , C09K2205/12 , C10M171/008 , C10M2203/1006 , C10M2207/026 , C10M2207/042 , C10M2207/2835 , C10M2207/301 , C10M2209/1055 , C10M2215/064 , C10M2215/086 , C10M2223/041 , C10N2220/023 , C10N2220/303 , C10N2230/02 , C10N2230/06 , C10N2230/08 , C10N2230/10 , C10N2230/70 , C10N2240/30 , C10M2209/108 , C10N2220/021
摘要： A working fluid composition for a refrigerating machine of the present invention comprises: a refrigerating machine oil comprising a complex ester as a base oil; and a hydrocarbon refrigerant having 2 to 4 carbon atoms, the complex ester being obtainable by further esterifying, with at least one selected from a monohydric alcohol having 1 to 20 carbon atoms and a fatty acid having 2 to 20 carbon atoms, an ester intermediate obtained by reacting a neopentyl polyol with a dibasic acid, and having an acid value of 0.5 mgKOH/g or less, the refrigerating machine oil having a kinematic viscosity at 100° C. of 2 to 50 mm2/s.
摘要翻译：本发明的冷冻机用工作流体组合物包括：包含作为基础油的复合酯的冷冻机油; 和具有2至4个碳原子的烃制冷剂，所述络合酯可通过使用至少一种选自具有1至20个碳原子的一元醇和具有2至20个碳原子的脂肪酸进一步酯化获得，得到的酯中间体通过使新戊基多元醇与二元酸反应，酸值为0.5mgKOH / g以下，在100℃下的运动粘度为2〜50mm 2 / s的冷冻机油。

6. 发明申请

US20140075969A1 HEAT-TRANSFER COMPOSITIONS EXHIBITING IMPROVED MISCIBILITY WITH THE LUBRICATING OIL 有权
标题翻译：换热组合物展示改善与润滑油的相容性
公开(公告)号：US20140075969A1
公开(公告)日：2014-03-20
申请号：US14115542
申请日：2012-03-28
申请人： Sophie Guerin , Laurent Abbas , Wissam Rached
发明人： Sophie Guerin , Laurent Abbas , Wissam Rached
IPC分类号： C09K5/04 , F25B45/00
CPC分类号： C09K5/045 , C09K2205/11 , C09K2205/122 , C09K2205/126 , C09K2205/22 , C10M171/008 , C10M2209/1033 , C10N2220/022 , C10N2240/30 , F25B45/00
摘要： The invention relates to the use of 1,1,1,2-tetrafluoroethane for increasing the miscibility of 2,3,3,3-tetrafluoropropene with a lubricating oil, and in particular with a polyalkylene glycol oil. In this regard, the invention provides heat-transfer compositions and also equipment and processes using these compositions.
摘要翻译：本发明涉及1,1,1,2-四氟乙烷用于提高2,3,3,3-四氟丙烯与润滑油，特别是聚亚烷基二醇油的混溶性的用途。在这方面，本发明提供了传热组合物，以及使用这些组合物的设备和方法。

7. 发明授权

US08535555B2 Epoxide and fluorinated epoxide stabilizers for fluoroolefins 有权
公开(公告)号：US08535555B2
公开(公告)日：2013-09-17
申请号：US12377454
申请日：2007-08-31
申请人： Andrew Edward Feiring , Viacheslav A. Petrov , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Thomas J. Leck , Jon Lee Howell
发明人： Andrew Edward Feiring , Viacheslav A. Petrov , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Thomas J. Leck , Jon Lee Howell
IPC分类号： C09K5/04
CPC分类号： C09K5/045 , C09K2205/10 , C09K2205/102 , C09K2205/104 , C09K2205/11 , C09K2205/126 , C09K2205/132 , C09K2205/134 , C09K2205/24 , F25B39/02
摘要： The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be an epoxide, fluorinated epoxide or oxetane, or a mixture thereof with other stabilizers. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.

8. 发明申请

US20120117991A1 HEAT TRANSFER PROCESS 有权
标题翻译：换热过程
公开(公告)号：US20120117991A1
公开(公告)日：2012-05-17
申请号：US13386719
申请日：2010-06-23
申请人： Wissam Rached
发明人： Wissam Rached
IPC分类号： F25D15/00
CPC分类号： F01K25/08 , C09K5/045 , C09K2205/106 , C09K2205/11 , C09K2205/112 , C09K2205/12 , C09K2205/122 , C09K2205/126 , C10M171/008 , C10M2207/2835 , C10M2209/043 , C10M2209/1033 , C10N2220/30 , C10N2220/301 , C10N2220/302 , C10N2220/303 , C10N2220/306
摘要： The present invention relates to the use of a refrigerant in organic Rankine cycle systems comprising at least one hydrofluoroolefin, having at least four carbon atoms represented by the formula (I) R1CH═CHR2 in which R1 and R2 independently represent alkyl groups having from 1 to 6 carbon atoms, substituted with at least one fluorine atom, optionally with at least one chlorine atom.
摘要翻译：本发明涉及在有机兰金循环系统中使用制冷剂，其包括至少一种具有至少四个由式（I）表示的碳原子的氢氟烯烃，其中R 1和R 2独立地表示具有1至 6个碳原子，被至少一个氟原子任选地与至少一个氯原子取代。

9. 发明申请

US20110252801A1 COMPOSITIONS COMPRISING Z-1,2-DIFLUOROETHYLENE AND USES THEREOF 有权
标题翻译：包含Z-1,2-二氟乙烯的组合物及其用途
公开(公告)号：US20110252801A1
公开(公告)日：2011-10-20
申请号：US13086914
申请日：2011-04-14
申请人： BARBARA HAVILAND MINOR , ROBERT L. WATERLAND
发明人： BARBARA HAVILAND MINOR , ROBERT L. WATERLAND
IPC分类号： F01K13/00 , F25D31/00 , F28D15/02 , C09K5/04
CPC分类号： C09K5/045 , B01F17/0085 , C08J9/149 , C08J2203/146 , C08J2203/182 , C09K3/30 , C09K5/044 , C09K2205/11 , C09K2205/12 , C09K2205/122 , C09K2205/126 , C09K2205/134 , C09K2205/22 , C09K2205/24 , C09K2205/32 , C09K2205/40 , F25B45/00 , F25B2345/001 , F25B2345/002 , Y02B30/12 , Y02B30/52 , Y02P20/124
摘要： The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises Z-1,2-difluoroethylene (Z-HFO-1132a). The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and power cycle working fluids.
摘要翻译：本发明涉及用于制冷，空调和热泵系统的组合物，其中组合物包含Z-1,2-二氟乙烯（Z-HFO-1132a）。本发明的组合物可用于制造冷却或加热的方法，作为传热流体，发泡剂，气溶胶推进剂和动力循环工作流体。

10. 发明申请

US20110204279A1 COMPOSITIONS COMPRISING A FLUOROOLEFIN 有权
标题翻译：包含氟化物的组合物
公开(公告)号：US20110204279A1
公开(公告)日：2011-08-25
申请号：US13096259
申请日：2011-04-28
申请人： BARBARA HAVILAND MINOR , VELLIYUR NOTT MALLIKARJUNA RAO
发明人： BARBARA HAVILAND MINOR , VELLIYUR NOTT MALLIKARJUNA RAO
IPC分类号： C09K5/04 , C08J9/14 , C09K3/30 , F25D15/00 , F28D15/00
CPC分类号： C09K5/045 , A62D1/0057 , A62D1/0071 , B01F17/0035 , B60H1/3204 , C08J9/127 , C08J9/146 , C08J9/149 , C08J2203/06 , C08J2203/12 , C08J2203/14 , C08J2203/142 , C08J2203/162 , C08J2203/182 , C08J2207/04 , C08J2375/04 , C09K3/30 , C09K2205/106 , C09K2205/11 , C09K2205/12 , C09K2205/122 , C09K2205/126 , C09K2205/132 , C09K2205/134 , C09K2205/22 , C09K2205/32 , C10M171/008 , C10M2203/022 , C10M2203/024 , C10M2203/065 , C10M2203/1006 , C10M2205/0206 , C10M2207/2835 , C10M2209/043 , C10M2209/1033 , C10N2220/302 , C10N2220/303 , C10N2240/30 , F25B45/00
摘要： The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.
摘要翻译：本发明涉及用于制冷，空调和热泵系统的组合物，其中组合物包含氟烯烃和至少一种其它组分。本发明的组合物可用于制备冷却或加热的方法，作为传热流体，发泡剂，气溶胶推进剂，灭火和灭火剂。

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