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    • 76. 发明授权
    • Method for the production of α-alane
    • 生产α-烯烃的方法
    • US07238336B2
    • 2007-07-03
    • US11329201
    • 2006-01-09
    • Gary K. LundJami M. HanksHarold E Johnston
    • Gary K. LundJami M. HanksHarold E Johnston
    • C10L1/12C07F5/06C01B6/00
    • C01B6/06
    • A method of forming α-alane. The method includes reacting aluminum trichloride and an alkali metal hydride to form an alane-ether complex solution. An aqueous diethyl ether solution is optionally added to the alane-ether complex solution to form a partially hydrolyzed ether/alane-ether complex solution. A solution of a first crystallization additive is added to the alane-ether complex solution or to the aqueous ether/alane-ether complex solution to form a crystallization solution. The first crystallization additive is selected from the group consisting of polystyrene, polybutadiene, polystyrene-co-polybutadiene, polyisoprene, poly-alpha-methylstyrene, polystyrene-co-polyindene, poly-alpha-pinene, and mixtures thereof. Optionally, a second crystallization additive is added to the crystallization solution. The second crystallization additive is selected from the group consisting of squalene, cyclododecatriene, norbornylene, norbornadiene, a phenyl terminated polybutadiene, 2,4-dimethyl anisole, 3,5-dimethyl anisole, 2,6-dimethyl anisole, polydimethyl siloxane, and mixtures thereof. Solvents are removed from the crystallization solution to crystallize the α-alane.
    • 形成α-烯烃的方法。 该方法包括使三氯化铝与碱金属氢化物反应以形成丙烯 - 醚络合物溶液。 任选将乙醚水溶液加入到丙烷 - 醚络合物溶液中以形成部分水解的醚/丙烷 - 醚络合物溶液。 将第一结晶添加剂的溶液加入到丙烷 - 醚络合物溶液或乙醚/丙烷 - 醚络合物水溶液中以形成结晶溶液。 第一结晶添加剂选自聚苯乙烯,聚丁二烯,聚苯乙烯 - 共聚丁二烯,聚异戊二烯,聚-α-甲基苯乙烯,聚苯乙烯 - 共 - 多烯,聚-α-蒎烯及其混合物。 任选地,向结晶溶液中加入第二结晶添加剂。 第二结晶添加剂选自角鲨烯,环十二碳三烯,降冰片烯,降冰片二烯,苯基封端的聚丁二烯,2,4-二甲基苯甲醚,3,5-二甲基苯甲醚,2,6-二甲基苯甲醚,聚二甲基硅氧烷和混合物 其中。 将溶剂从结晶溶液中除去以使α-烷烃结晶。
    • 77. 发明申请
    • Method for the production of alpha-alane
    • 生产α-烯烃的方法
    • US20070066839A1
    • 2007-03-22
    • US11329201
    • 2006-01-09
    • Gary LundJami HanksHarold Johnston
    • Gary LundJami HanksHarold Johnston
    • C07F5/06
    • C01B6/06
    • A method of forming α-alane. The method includes reacting aluminum trichloride and an alkali metal hydride to form an alane-ether complex solution. An aqueous diethyl ether solution is optionally added to the alane-ether complex solution to form a partially hydrolyzed ether/alane-ether complex solution. A solution of a first crystallization additive is added to the alane-ether complex solution or to the aqueous ether/alane-ether complex solution to form a crystallization solution. The first crystallization additive is selected from the group consisting of polystyrene, polybutadiene, polystyrene-co-polybutadiene, polyisoprene, poly-alpha-methylstyrene, polystyrene-co-polyindene, poly-alpha-pinene, and mixtures thereof. Optionally, a second crystallization additive is added to the crystallization solution. The second crystallization additive is selected from the group consisting of squalene, cyclododecatriene, norbornylene, norbornadiene, a phenyl terminated polybutadiene, 2,4-dimethyl anisole, 3,5-dimethyl anisole, 2,6-dimethyl anisole, polydimethyl siloxane, and mixtures thereof Solvents are removed from the crystallization solution to crystallize the α-alane.
    • 形成α-烯烃的方法。 该方法包括使三氯化铝与碱金属氢化物反应以形成丙烯 - 醚络合物溶液。 任选将乙醚水溶液加入到丙烷 - 醚络合物溶液中以形成部分水解的醚/丙烷 - 醚络合物溶液。 将第一结晶添加剂的溶液加入到丙烷 - 醚络合物溶液或乙醚/丙烷 - 醚络合物水溶液中以形成结晶溶液。 第一结晶添加剂选自聚苯乙烯,聚丁二烯,聚苯乙烯 - 共聚丁二烯,聚异戊二烯,聚-α-甲基苯乙烯,聚苯乙烯 - 共 - 多烯,聚-α-蒎烯及其混合物。 任选地,向结晶溶液中加入第二结晶添加剂。 第二结晶添加剂选自角鲨烯,环十二碳三烯,降冰片烯,降冰片二烯,苯基封端的聚丁二烯,2,4-二甲基苯甲醚,3,5-二甲基苯甲醚,2,6-二甲基苯甲醚,聚二甲基硅氧烷和混合物 其溶剂从结晶溶液中除去以使α-烷烃结晶。
    • 78. 发明申请
    • METHOD FOR THE PRODUCTION OF ALPHA-ALANE
    • ALPHA-ALANE生产方法
    • US20050222445A1
    • 2005-10-06
    • US10947078
    • 2004-09-22
    • Gary LundJami HanksHarold Johnston
    • Gary LundJami HanksHarold Johnston
    • C01B3/00C01B6/06C07F5/06
    • C01B6/06C01B3/00Y02E60/324
    • A method of forming alpha-alane. The method includes reacting aluminum trichloride and an alkali metal hydride to form an alane-ether complex solution. An aqueous ether solution is optionally added to the alane-ether complex solution to form a partially hydrolyzed ether/alane-ether complex solution. A solution of a crystallization additive is added to the alane-ether complex solution or to the aqueous ether/alane-ether complex solution to form a crystallization solution. The crystallization additive is selected from the group consisting of squalene, cyclododecatriene, norbomylene, norbomadiene, a phenyl terminated polybutadiene, 2,4-dimethyl anisole, 3,5-dimethyl anisole, 2,6-dimethyl anisole, polydimethyl siloxane, and mixtures thereof. Ether is removed from the crystallization solution to crystallize the alpha-alane.
    • 形成α-烯烃的方法。 该方法包括使三氯化铝与碱金属氢化物反应以形成丙烯 - 醚络合物溶液。 任选将乙醚水溶液加入到丙烷 - 醚络合物溶液中以形成部分水解的醚/丙烷 - 醚络合物溶液。 将结晶添加剂的溶液加入到丙烷 - 醚络合物溶液或醚/丙醚 - 醚络合物水溶液中以形成结晶溶液。 结晶添加剂选自角鲨烯,环十二碳三烯,降冰片烯,降冰片二烯,苯基封端的聚丁二烯,2,4-二甲基苯甲醚,3,5-二甲基苯甲醚,2,6-二甲基苯甲醚,聚二甲基硅氧烷及其混合物 。 从结晶溶液中除去乙醚以结晶α-丙烯。
    • 80. 发明授权
    • Method for the preparation of aluminum hydride (AlH.sub.3) by reacting
magnesium hydride with aluminum halide
    • 通过氢化镁与卤化铝反应制备氢化铝(AlH3)的方法
    • US5565183A
    • 1996-10-15
    • US329936
    • 1994-10-27
    • Wilfried Knott
    • Wilfried Knott
    • C01B6/06C01B6/00C01B6/04
    • C01B6/06
    • A method for the preparation of aluminum hydride (AlH.sub.3) by the reaction of magnesium hydride with aluminum halide in presence of solvents is utilized with the distinguishing feature that the magnesium hydride is obtained by the reaction of magnesium with hydrogen at a temperature of at least 250.degree. C. and a pressure of 0.5 to 5 MPa with the proviso that, before the hydrogenation, magnesium hydride with a particle size not greater than 400 .mu.m is added before the hydrogenation in amounts of at least 1.2% by weight, based on the magnesium to be hydrogenated, to the magnesium that is to be hydrogenated, and the reaction between magnesium hydride and aluminum halide is carried out at a temperature ranging from 20.degree. to 110.degree. C. for a period of 30 minutes to 5 hours while constantly grinding the reactants, MgH.sub.2 and AlX.sub.3 (X being halogen), in the molar ratio of at least 3:2 in 1,4 dioxane.
    • 利用氢化镁与卤化铝在溶剂存在下的反应制备氢化铝(AlH 3)的方法,其特征在于氢化镁是通过镁与氢在至少250℃的温度下反应获得的 ℃,压力为0.5-5MPa,条件是在氢化之前,在氢化之前加入粒径不大于400μm的氢化镁至少为1.2重量%,基于 待氢化的镁,待被氢化的镁,氢化铝和卤化铝之间的反应在20℃至110℃的温度下进行30分钟至5小时,同时持续研磨 反应物,MgH 2和AlX 3(X为卤素),在1,4-二恶烷中的摩尔比至少为3:2。