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71. 发明授权

US06284696B1 Mesopore molecular sieve and process for the production thereof 失效
标题翻译： Mesopore分子筛及其制备方法
公开(公告)号：US06284696B1
公开(公告)日：2001-09-04
申请号：US09202046
申请日：1999-03-23
申请人： Masahiko Koya , Hitoshi Nakajima , Itsuho Aishima
发明人： Masahiko Koya , Hitoshi Nakajima , Itsuho Aishima
IPC分类号： B01J2906
CPC分类号： B01J29/0308 , C01B37/00 , C01B37/02
摘要： A mesopore molecular sieve having a hydrocarbon group bonded directly to a silicon atom in the metal oxide skeleton constituting the molecular sieve, wherein the content of said hydrocarbon group is from 0.01 to 0.6 mol per mol of the metal oxide. Also disclosed is a process for producing a mesopore molecular sieve having a hydrocarbon atom bonded to a silicon atom in the molecular sieve skeleton, which comprises synthesizing the mesopore molecular sieve, in the presence of a template, from: a silane compound represented by the following formula (1): RnSiX(4−n) (1) wherein R represents a hydrocarbon group selected from C1-16 hydrocarbon groups and hydrocarbon groups substituted with an N—, O-, S-, P- or halogen-containing group; n represents 1, 2 or 3; and X is selected from C1-6 alkoxy groups, aryloxy groups, a hydroxyl group and halogen atoms and a plurality of X may be the same or different; and a metal oxide and/or a precursor thereof. According to this process for producing a mesopore molecular sieve, a mesopore molecular sieve can be readily synthesized in one stage and, in addition, a mesopore molecular sieve having an excellent performance as an acid catalyst or oxidation catalyst can be obtained because the kind and amount of the hydrocarbon group can be easily adjusted.
摘要翻译：具有直接结合构成分子筛的金属氧化物骨架中的硅原子的烃基的中孔分子筛，其中所述烃基的含量相对于每摩尔金属氧化物为0.01〜0.6摩尔。还公开了一种制备具有与分子筛骨架中的硅原子键合的烃原子的中孔分子筛的方法，该方法包括在模板存在下合成中孔分子筛：由以下化合物表示的硅烷化合物式（1）：其中R表示选自C 1-6烃基和被N，O-，S-，P-或卤素基团取代的烃基的烃基; n表示1,2或3; X选自C 1-6烷氧基，芳氧基，羟基和卤原子，多个X可以相同或不同; 和金属氧化物和/或其前体。根据该中孔分子筛的制造方法，可以在一个阶段容易地合成中孔分子筛，另外可以得到作为酸催化剂或氧化催化剂的具有优异性能的中孔分子筛，因为种类和量的烃基可以容易地调节。

72. 发明申请

US20010007879A1 Fischer-tropsch processes using xerogel and aerogel catalysts by destabilizing aqueous colloids 失效
标题翻译：使用干凝胶和气凝胶催化剂通过使水性胶体失稳稳定的费 - 托法
公开(公告)号：US20010007879A1
公开(公告)日：2001-07-12
申请号：US09789987
申请日：2001-02-21
发明人： Leo E. Manzer , Kostantinos Kourtakis
IPC分类号： C07C027/00 , C07C027/06 , C07C027/08
CPC分类号： B01J23/894 , B01J21/06 , B01J21/063 , B01J21/066 , B01J23/462 , B01J23/74 , B01J23/8913 , B01J23/8933 , B01J29/0308 , B01J29/041 , B01J35/0013 , B01J37/0236 , C07C1/0435 , C10G2/331 , C10G2/332 , C10G2/333 , C10G2/334
摘要： A process is disclosed for producing hydrocarbons by contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. The process is characterized by using a catalyst prepared by a method involving (1) forming a catalyst gel by destabilizing an aqueous colloid comprising (a) at least one catalytic metal for Fischer-Tropsch reactions (e.g., iron, cobalt, nickel and/or ruthenium), (b) colloidal cerium oxide, zirconium oxide, titanium oxide and/or aluminum oxide, and optionally (c) Al(OR)3, Si(OR)4, Ti(OR)4 and/or Zr(OR)4 where each R is an alkyl group having from 1 to 6 carbon atoms; and (2) drying the gel.
摘要翻译：公开了通过使包含氢和一氧化碳的进料流与催化剂在保持在有效产生包含烃的流出物流的转化促进条件的反应区中接触的方法。该方法的特征在于使用通过以下方法制备的催化剂：（1）通过使包含（a）至少一种用于费 - 托反应的催化金属（例如铁，钴，镍和/或钌），（b）胶体氧化铈，氧化锆，氧化钛和/或氧化铝，以及任选的（c）Al（OR）3，Si（OR）4，Ti（OR）4和/或Zr 4，其中每个R是具有1至6个碳原子的烷基; 和（2）干燥凝胶。

73. 发明授权

US06204424B1 Highly acidic mesoporous synergistic solid catalyst and its applications 失效
标题翻译：高酸性介孔协同固体催化剂及其应用
公开(公告)号：US06204424B1
公开(公告)日：2001-03-20
申请号：US09211499
申请日：1998-12-14
申请人： Ganapati Dadasahab Yadav , Munivemmal Sellamuthupillai Krishnan , Nirav Shashikant Doshi , Ajit Atmaram Pujari , Mohamed Sheik Mohamed Mujeebur Rahuman
发明人： Ganapati Dadasahab Yadav , Munivemmal Sellamuthupillai Krishnan , Nirav Shashikant Doshi , Ajit Atmaram Pujari , Mohamed Sheik Mohamed Mujeebur Rahuman
IPC分类号： C07C202
CPC分类号： B01J35/1061 , B01J27/053 , B01J29/0308 , B01J35/1019 , B01J35/1038 , C07C2/12 , C07C37/16 , C07C45/46 , C07C209/68 , C07C2529/00 , Y02P20/588 , C07C211/45 , C07C39/06
摘要： An eco-friendly synergistic heterogeneous solid catalyst for use in reactions such as alkylation, acylation, oligomerization, isomerization, hydration, dehydration, etherification, esterification, hydrocracking and nitration of organic compounds comprising: a synergistic combination of sulfated metal oxide and mesoporous zeotypes comprising: Silicon (Si) 50-60 wt %, Zirconium (Zr) 40-50 wt %, Sulfur (S) 5-10 wt % and having a surface area in the range of 200-500 m2/g; a pore volume in the range of 0.1-0.3 m3/g; a pore diameter in the range of 25-35 Å; and a XRD peak at 2&thgr; being 0-3. The invention also covers the process of manufacture of the above catalysts and its use in particular for producing oligomers from alpha-olefins, Friedel-Crafts alkylation and acylation reactions.
摘要翻译：一种用于有机化合物的烷基化，酰化，低聚，异构化，水合，脱水，醚化，酯化，加氢裂化和硝化的反应中的环保协同的非均相固体催化剂，包括：硫酸化金属氧化物和中孔型锌型的协同组合，包括： 50-60重量％的硅（Si），40-50重量％的锆（Zr），5-10重量％的硫（S），在200-500米2 /克范围内的表面积; 0.1-0.3立方米/克;孔径在25-35埃; 并且在2θ处的XRD峰为0-3。本发明还涵盖了上述催化剂的制备方法及其用于生产α-烯烃，Friedel-Crafts烷基化和酰化反应的低聚物。

74. 发明授权

US06204217B1 Process for the preparation of micro-mesoporous gel 失效
标题翻译：微孔介孔凝胶的制备工艺
公开(公告)号：US06204217B1
公开(公告)日：2001-03-20
申请号：US09172268
申请日：1998-10-14
申请人： Giannino Pazzucconi , Gianluca Bassi , Roberto Millini , Carlo Perego , Giovanni Perego , Giuseppe Bellussi
发明人： Giannino Pazzucconi , Gianluca Bassi , Roberto Millini , Carlo Perego , Giovanni Perego , Giuseppe Bellussi
IPC分类号： B01J2108
CPC分类号： B01J35/10 , B01J21/12 , B01J29/0308 , B01J29/041 , B01J35/1023 , B01J35/1042 , B01J35/1061 , B01J37/033 , B01J37/036 , B01J2229/42
摘要： Process for the preparation of a micro-mesoporous gel consisting of a silica matrix in which one or more metal oxides are possibly dispersed comprising: (a) subjecting to hydrolysis and gelification a tetra-alkylorthosilicate with an alkyl-trimethylammonium hydroxide having the formula R(CH3)3N—OH, wherein R is selected from n-butyl, n-pentyl, n-hexyl and n-heptyl, possibly in the presence of one or more metal compounds, the molar ratios in this mixture being: R—OH/SiO2=0-10; R(CH3)3N—OH/SiO2=0.05-0.4; H2O/SiO2=5-40; metal oxides/SiO2=0-0.02; whereas the ratio H2O/R(CH3)3N—OH varies according to the number of carbon atoms in the alkylic chain R as follows: R=n-butyl, H2O/R(CH3-)3N—OH
摘要翻译：用于制备由二氧化硅基质组成的微孔介质凝胶的方法，其中一种或多种金属氧化物可能被分散，包括：（a）使原硅酸四烷基酯与具有式R的烷基 - 三甲基氢氧化铵进行水解和凝胶化 CH3）3N-OH，其中R选自正丁基，正戊基，正己基和正庚基，可能在一种或多种金属化合物存在下，该混合物中的摩尔比为：R-OH / SiO2 = 0-10; R（CH3）3N-OH / SiO2 = 0.05-0.4; H2O / SiO2 = 5-40; 金属氧化物/ SiO2 = 0-0.02; 而H 2 O / R（CH 3）3 N-OH的比例根据烷基链R中的碳原子数按如下方式变化：R =正丁基，H 2 O / R（CH 3）3 N-OH 35; R =正戊基，H 2 O / R（CH 3）3 N-OH <70; R =正己基，H 2 O / R（CH 3）3 N-OH <102; R =正庚基，H 2 O / R（CH 3）3 N-OH <136; （b）使步骤（a）中获得的凝胶或固体进行干燥和煅烧。

75. 发明授权

US5965474A FCC metal traps based on ultra large pore crystalline material 失效
标题翻译：基于超大孔结晶材料的FCC金属捕集阱
公开(公告)号：US5965474A
公开(公告)日：1999-10-12
申请号：US847400
申请日：1997-04-29
申请人： Jeffrey William Balko , Arthur W. Chester , Augusto Rodolfo Quinones
发明人： Jeffrey William Balko , Arthur W. Chester , Augusto Rodolfo Quinones
IPC分类号： B01J29/06 , B01J29/00 , B01J29/03 , B01J29/04 , C01G11/02 , C10G11/05 , B01J26/08
CPC分类号： B01J29/005 , B01J29/0308 , B01J29/041 , B01J2229/42 , B01J29/084
摘要： A composition for passivating metal contaminants in catalytic cracking of hydrocarbons includes a non-layered, ultra-large pore crystalline material with at least one peak at a position greater than about 18 Angstrom Units d-spacing with a relative intensity of 100, and a benzene adsorption capacity of greater than about 15 grams benzene per 100 grams anhydrous crystal at 50 torr and 25.degree. C., and a metal passivator incorporated within the crystalline material. A method for passivating contaminating metals uses the composition during catalytic cracking as an additive or as a component of the catalyst.
摘要翻译：用于钝化金属污染物在烃的催化裂化中的组合物包括非层状的超大孔结晶材料，在大于约18埃的位置处具有至少一个峰，相对强度为100的d-间距，以及苯在50托和25℃下每100克无水晶体的吸附能力大于约15克苯，并且结晶材料中的金属钝化剂。用于钝化污染金属的方法在催化裂化过程中使用组合物作为添加剂或作为催化剂的组分。

76. 发明授权

US5800800A Crystalline inorganic oxide compositions prepared by neutral templating route 失效
标题翻译：通过中性模板法制备的结晶无机氧化物组合物
公开(公告)号：US5800800A
公开(公告)日：1998-09-01
申请号：US706552
申请日：1996-09-05
申请人： Thomas J. Pinnavaia , Peter T. Tanev
发明人： Thomas J. Pinnavaia , Peter T. Tanev
IPC分类号： B01J29/03 , B01J29/04 , B01J29/89 , B01J37/03 , C01B33/20 , C01B37/00 , C01B37/02 , C01B39/04 , C07C46/06
CPC分类号： B01J21/04 , B01J21/066 , B01J23/14 , B01J29/0308 , B01J29/041 , B01J29/89 , B01J35/1061 , B01J37/036 , C01B37/00 , C01B37/005 , C01B37/02 , C07C46/06 , Y10S502/509
摘要： This invention relates to new crystalline organic compositions having unique combinations of framework-confined uniform mesopores and textural mesopores and to a method for their preparation. The compositions typically possess a framework wall thickness of at least about 17 .ANG., small elementary particle size of less than about 400 .ANG., and ratio of textural to framework-confined mesoporosity of greater than about 0.2. The formation of the mesoporous structure is accomplished by a novel self-assembly mechanism involving hydrogen bonding between neutral amine surfactant (S.degree.) and neutral inorganic oxide precursor (I.degree.). This S.degree.I.degree. templating approach allows for facile and environmentally benign recycling of the cost-intensive template by simple solvent extraction methods.
摘要翻译：本发明涉及具有框架限制的均匀介孔和质构介孔的独特组合的新型结晶有机组合物及其制备方法。所述组合物通常具有至少约17安培的小的基本粒子尺寸，小于约400安培的小的基本粒度，以及大于约0.2的结构与框架约束的中孔隙比。中孔结构的形成是通过一种新型的自组装机理实现的，该机制涉及中性胺表面活性剂（S DEG）和中性无机氧化物前体（I DEG）之间的氢键合。这种S DEG I DEG模板方法允许通过简单的溶剂萃取方法轻松和环境友好地回收成本密集型模板。

77. 发明授权

US5785946A Crystalline inorganic oxide compositions prepared by neutral templating route 失效
公开(公告)号：US5785946A
公开(公告)日：1998-07-28
申请号：US808190
申请日：1997-02-28
申请人： Thomas J. Pinnavaia , Peter T. Tanev
发明人： Thomas J. Pinnavaia , Peter T. Tanev
IPC分类号： B01J29/03 , B01J29/89 , B01J37/03 , C01B37/00 , C01B37/02 , C01B39/04 , C07C46/06
CPC分类号： C07C46/06 , B01J21/04 , B01J21/066 , B01J23/14 , B01J29/0308 , B01J29/89 , B01J35/1061 , B01J37/036 , C01B37/00 , C01B37/005 , C01B37/02 , Y10S502/509
摘要： This invention relates to new crystalline organic compositions having unique combinations of framework-confined uniform mesopores and textural mesopores and to a method for their preparation. The compositions typically possess a framework wall thickness of at least about 17.ANG., small elementary particle size of less than about 400.ANG., and ratio of textural to framework-confined mesoporosity of greater than about 0.2. The formation of the mesoporous structure is accomplished by a novel self-assembly mechanism involving hydrogen bonding between neutral amine surfactant (S.degree.) and neutral inorganic oxide precursor (I.degree.). This S.degree.I.degree. templating approach allows for facile and environmentally benign recycling of the cost-intensive template by simple solvent extraction methods.

78. 发明授权

US5347060A Phase-transfer catalysis with onium-containing synthetic mesoporous crystalline material 失效
标题翻译：用含鎓合成介孔结晶材料进行相转移催化
公开(公告)号：US5347060A
公开(公告)日：1994-09-13
申请号：US75010
申请日：1993-06-11
申请人： Stuart D. Hellring , Jeffrey S. Beck
发明人： Stuart D. Hellring , Jeffrey S. Beck
IPC分类号： B01J31/18 , B01J29/03 , B01J29/04 , B01J31/02 , B01J31/26 , C07B61/00 , C07C4/14 , C07C4/18 , C07C15/02 , C07C17/20 , C07C19/07
CPC分类号： B01J29/0308 , B01J29/041 , C01B37/02 , C01B37/06 , C01B39/48 , C07C17/208
摘要： This invention relates to phase transfer catalysis (PTC) using a composition of synthetic ultra-large pore crystalline material which contains a cation of an onium compound, e.g. cetyltrimethylammonium, within the pores of said material. The crystalline material has, after calcination, an X-ray diffraction pattern with at least one peak at a d-spacing greater than 18 Angstrom Units and a benzene adsorption capacity of greater than 15 grams benzene per 100 grams of said material at 6.7 kPa (50 torr) and 25.degree. C.
摘要翻译：本发明涉及使用含有鎓化合物阳离子的合成超大孔结晶材料的组合物的相转移催化（PTC）。十六烷基三甲基铵，在所述材料的孔内。结晶材料在煅烧后具有在d-间距大于18埃单位的至少一个峰的X射线衍射图，并且在6.7kPa下每100克所述材料的苯吸附能力大于15克苯（ 50托）和25℃

79. 发明授权

US5304363A Porous materials 失效
标题翻译：多孔材料
公开(公告)号：US5304363A
公开(公告)日：1994-04-19
申请号：US907941
申请日：1992-07-02
申请人： Jeffrey S. Beck , Charles T. Kresge , Sharon B. McCullen , Wieslaw J. Roth , James C. Vartuli
发明人： Jeffrey S. Beck , Charles T. Kresge , Sharon B. McCullen , Wieslaw J. Roth , James C. Vartuli
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , C01B33/26
CPC分类号： C10G47/16 , B01D53/8628 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/3078 , B01J29/0308 , B01J29/041 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42
摘要： There is provided a porous material. A process for preparing this material involves adding an amphiphilic compound to the reaction mixture for preparing a crystalline oxide. The amphiphilic compound may be a quaternary ammonium cationic surfactant. These surfactants may be in the form of lamellar liquid crystals, and may function as templates for the formation of the present mesoporous oxide materials.
摘要翻译：提供多孔材料。制备该材料的方法包括向反应混合物中加入两亲性化合物以制备结晶氧化物。两亲性化合物可以是季铵阳离子表面活性剂。这些表面活性剂可以是层状液晶的形式，并且可以用作形成本中介氧化物材料的模板。

80. 发明授权

US5250282A Use of amphiphilic compounds to produce novel classes of crystalline oxide materials 失效
标题翻译：使用两亲性化合物来生产新型的结晶氧化物材料
公开(公告)号：US5250282A
公开(公告)日：1993-10-05
申请号：US967962
申请日：1992-10-27
申请人： Charles T. Kresge , Michael E. Leonowicz , Wieslaw J. Roth , James C. Vartuli
发明人： Charles T. Kresge , Michael E. Leonowicz , Wieslaw J. Roth , James C. Vartuli
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , C01B33/34
CPC分类号： C10G47/16 , B01D53/8628 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/18 , B01J20/3078 , B01J29/0308 , B01J29/041 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42
摘要： There is provided a process for using amphiphilic compounds in preparing new classes of crystalline oxide materials. These oxide materials may have uniformly large pores, e.g., having a size of about 40 Angstoms in diameter. This process involves combining sources of oxides with micellar solutions of organic amphiphilic compounds, such as quaternary ammonium cationic surfactants. Aggregates of these micelles in the form of liquid crystals are believed to function as templates for the formation of the present highly porous, crystalline materials.
摘要翻译：提供了一种在制备新类型的结晶氧化物材料中使用两亲性化合物的方法。这些氧化物材料可以具有均匀的大孔，例如具有直径约40埃的尺寸。该方法包括将氧化物源与有机两亲性化合物的胶束溶液结合，例如季铵阳离子表面活性剂。认为这些胶体形式的胶束的聚集体用作形成本发明高度多孔的结晶材料的模板。

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