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    • 2. 发明授权
    • Method of reducing sulfur in hydrocarbon feedstock using a membrane separation zone
    • 使用膜分离区减少烃原料中的硫的方法
    • US07267761B2
    • 2007-09-11
    • US10671807
    • 2003-09-26
    • Jeffrey William Balko
    • Jeffrey William Balko
    • C10G17/00C10G45/00
    • C10G53/16C10G25/003C10G53/08C10G69/02C10G69/14
    • A membrane is used in combination with fractionation and hydrodesulfurization to reduce the sulfur content of hydrocarbon feeds, preferably sulfur-containing naphtha feeds. A membrane separation zone is employed to treat a fraction of effluent from a fractionation zone containing sulfur-containing non-aromatic hydrocarbons to produce a sulfur rich permeate and sulfur deficient retentate. The sulfur rich permeate and a second fraction of the fractionation zone, which contains sulfur-containing aromatic hydrocarbons, are further treated in a hydrodesulfurization zone. The stream from the hydrodesulfurization zone and the sulfur deficient retentate from the membrane separation zone are then processed as low sulfur hydrocarbon streams, especially those streams being processed in the manufacture of gasoline when the initial hydrocarbon stream is naphtha from a fluidized catalytic cracking unit.
    • 将膜与分馏和加氢脱硫结合使用以降低烃进料,优选含硫石脑油进料的硫含量。 使用膜分离区来处理含有含硫非芳香烃的分馏区的一部分流出物,以产生富含硫的渗透物和硫缺乏的滞留物。 含硫的渗透物和含有含硫芳烃的分馏区的第二馏分在加氢脱硫区进一步处理。 来自加氢脱硫区的流和来自膜分离区的缺硫滞留物随后作为低硫烃流处理,特别是当初始烃流为流化催化裂化装置的石脑油时,在制造汽油时加工的那些物流。