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    • 72. 发明授权
    • Method for producing ceramic products
    • 陶瓷制品的制造方法
    • US5459114A
    • 1995-10-17
    • US256807
    • 1994-07-25
    • Hiroshi KayaKiyoshi SatoHiroki MorozumiAtushi TezukaTomoko AokiHirohiko NakaharaTadashi SuzukiTakeshi Isoda
    • Hiroshi KayaKiyoshi SatoHiroki MorozumiAtushi TezukaTomoko AokiHirohiko NakaharaTadashi SuzukiTakeshi Isoda
    • C04B35/589C04B35/80C04B41/45C04B41/50C04B41/52C04B41/81C04B41/87C04B41/89C04B35/58
    • C04B41/009C04B35/589C04B35/80C04B35/806C04B41/4554C04B41/5053C04B41/52C04B41/81C04B41/87C04B41/89
    • Repetition of a process of impregnating a metal fiber or ceramic fiber preform or porous ceramic with (3) a mixture of polysilazane-type polymers with a number average molecular weight of 200-3000 and a viscosity adjusted to 100 Pa.s or lower at the impregnation temperature, prepared by mixing (1) one or more types of polysilazane-type polymers with a number average molecular weight of 200-3000 and a viscosity of less than 1 Pa.s at the impregnation temperature with (2) one or more types of polysilazane-type polymers with a number average molecular weight of 200-100,000 and having a viscosity of 1 Pa.s or higher or solid at the impregnation temperature, which are selected from polysilazanes whose main repeating unit is --[(SiH.sub.2).sub.n (NH).sub.r ]-- (where n and r are 1, 2 or 3), and copolymers, modified polymers and crosslinked polymers based thereon, and performing crosslinking curing and then firing, is performed for its conversion into a ceramic. The above polysilazane may be, for example, an inorganic polysilazane, an inorganic polysiloxazane, a polyorgano(hydro)silazane, a modified polysilazane or a polymetallosilazane. By performing the CVD coating before or after said process of impregnation, curing and firing, delamination of the fibers may be minimized.
    • PCT No.PCT / JP93 / 01730 Sec。 371日期:1994年7月25日 102(e)日期1994年7月25日PCT提交1993年11月26日PCT公布。 公开号WO94 / 12448 日期:1994年6月9日。重复使用(3)数均分子量为200-3000的聚硅氮烷型聚合物和粘度调节至100的混合物浸渍金属纤维或陶瓷纤维预制体或多孔陶瓷的方法 通过在浸渍温度下混合(1)数均分子量为200-3000和粘度小于1Pa.s的一种或多种聚硅氮烷型聚合物制备的浸渍温度下的Pa.s或更低, (2)一种或多种数均分子量为200-100,000,粘度为1Pa·s或更高的聚硅氮烷型聚合物或浸渍温度下的固体,其选自聚硅氮烷,其主要重复单元为 - [(SiH2)n(NH)r] - (其中n和r为1,2或3),并且基于其进行交联固化,然后进行烧结的共聚物,改性聚合物和交联聚合物进行转化为 陶瓷。 上述聚硅氮烷可以是例如无机聚硅氮烷,无机聚硅氮烷,聚有机(氢)硅氮烷,改性聚硅氮烷或聚金属硅氮烷。 通过在所述浸渍,固化和焙烧过程之前或之后进行CVD涂层,可以使纤维的分层最小化。