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71. 发明授权

US5072050A Ketone-terminated polyoxyalkylene compounds 失效
标题翻译：酮封端的聚氧化烯化合物
公开(公告)号：US5072050A
公开(公告)日：1991-12-10
申请号：US594464
申请日：1990-10-09
申请人： John R. Sanderson , Edward T. Marquis , John M. Larkin
发明人： John R. Sanderson , Edward T. Marquis , John M. Larkin
IPC分类号： C07C45/30 , C07C49/175
CPC分类号： C07C49/175 , C07C45/30
摘要： Mono-, di- and tri-ketones of polyoxyalkylene compounds prepared by a method whereby the terminal hydroxyl groups of polyoxyalkylene compounds are oxidized to ketone groups with an alkali metal or an alkaline earth metal hypochlorite oxidant in the presence of acetic acid are disclosed. These compounds are useful for preparing surface active agents or they may be reacted with amines to provide fuel additives.
摘要翻译：公开了通过使聚氧化烯化合物的末端羟基在乙酸存在下用碱金属或碱土金属次氯酸盐氧化剂氧化成酮基的方法制备的聚氧化烯化合物的单 - ，二 - 和三 - 酮。这些化合物可用于制备表面活性剂，或者它们可与胺反应以提供燃料添加剂。

72. 发明授权

US5053569A Process for oligomerizing olefins to prepare base stocks for synthetic lubricants 失效
标题翻译：低聚烯烃以制备合成润滑剂的基础油的方法
公开(公告)号：US5053569A
公开(公告)日：1991-10-01
申请号：US500631
申请日：1990-03-28
申请人： Edward T. Marquis , John R. Sanderson , John F. Knifton
发明人： Edward T. Marquis , John R. Sanderson , John F. Knifton
IPC分类号： B01J21/16 , C07C2/08 , C07C2/14 , C07C2/22 , C07C9/22 , C10G50/02 , C10M107/10 , C10M107/12
CPC分类号： C10M107/12 , B01J21/16 , C07C2/08 , C07C2/14 , C07C2/22 , C07C9/22 , C10G50/02 , C10M107/10 , C07C2521/16 , C07C2527/128 , C07C2527/138 , C07C2527/25 , C10M2205/003 , C10M2205/0285 , C10M2205/043
摘要： A process is disclosed for preparing synthetic lubricant base stocks. Synthetic lubricant base stocks may be prepared in good yield by oligomerizing linear olefins using certain acidic calcium montmorillonite clay catalysts. When the oligomers are hydrogenated, they provide a synthetic lubricant base stock having excellent properties.
摘要翻译：公开了制备合成润滑剂基础油料的方法。可以通过使用某些酸性钙蒙脱石粘土催化剂使线性烯烃低聚来制备合成润滑剂基础油料。当低聚物被氢化时，它们提供具有优异性能的合成润滑剂基础油料。

73. 发明授权

US5025112A Purification of cumene recycle streams 失效
标题翻译：异丙苯循环物流的净化
公开(公告)号：US5025112A
公开(公告)日：1991-06-18
申请号：US580035
申请日：1990-09-10
申请人： John R. Sanderson , Edward T. Marquis , John F. Knifton
发明人： John R. Sanderson , Edward T. Marquis , John F. Knifton
IPC分类号： B01J21/16 , B01J27/182 , C07B61/00 , C07C7/148 , C07C15/085
CPC分类号： C07C7/148 , Y02P20/52
摘要： A method for purifying a cumene recycle stream by removing 2-phenyl-2-propanol and cumene hydroperoxide before the cumene is distilled and recycled to the peroxidation reactor which comprises reacting the recycle cumene in the presence of an acid treated montmorillonite clay of the formula:M.sub.x/n.sup.n+.sub..y H.sub.2 O(Al.sub.4-x Mg.sub.x) (Si.sub.8)O.sub.20 (OH).sub.4or in the presence of a catalyst comprising phosphoric acid on silica.
摘要翻译：一种在异丙基苯蒸馏并再循环至过氧化反应器之前通过除去2-苯基-2-丙醇和异丙基氢过氧化氢来净化枯烯循环物流的方法，该方法包括在下列通式的酸处理蒙脱石粘土存在下使回收枯烯反应： Mx / nn + .yH2O（Al4-xMgx）（Si8）O20（OH）4或在二氧化硅上含有磷酸的催化剂存在下进行。

74. 发明授权

US4992566A Recovery of tertiary butyl hydroperoxide and tertiary butyl alcohol 失效
标题翻译：叔丁基氢过氧化物和叔丁醇的回收
公开(公告)号：US4992566A
公开(公告)日：1991-02-12
申请号：US401381
申请日：1989-08-31
申请人： Edward T. Marquis , Kenneth P. Keating , John R. Sanderson , Robert A. Meyer
发明人： Edward T. Marquis , Kenneth P. Keating , John R. Sanderson , Robert A. Meyer
IPC分类号： C07D301/14 , B01J23/28 , B01J23/92 , B01J31/22 , B01J38/00 , C07B61/00 , C07C27/28 , C07C29/03 , C07C29/80 , C07C31/12 , C07C407/00 , C07D301/19 , C07D303/04
CPC分类号： C07D301/19 , C07C29/80 , C07C407/003
摘要： Tertiary butyl hydroperoxide and tertiary butyl alcohol are recovered from the reaction product formed by reacting excess propylene with tertiary butyl hydroperoxide in solution in tertiary butyl alcohol in the presence of a soluble molybdenum catalyst, by fractionating the reaction produce to provide distillate propylene, propylene oxide, and tertiary butyl alcohol fractions and a heavy distillation fraction comprising tertiary butyl hydroperoxide, tertiary butyl alcohol and impurities, including dissolved molybdenum catalyst, the tertiary butyl hydroperoxide and tertiary butyl alcohol being recovered from the heavy distillation fraction by vacuum evaporation under evaporation conditions including a temperature of about 25.degree. to about 160.degree. C. and a pressure of about 2 to about 200 mm Hg. in order to provide a lighter condensate fraction comprising about 60 to about 95 wt. % of the heavy distillation fraction and containing from about 70 to about 95 wt. % of tertiary butyl alcohol, about 1 to about 20 wt. % of the tertiary butyl hydroperoxide and from about 15 to about 3 wt. % of impurities and also into a clear liquid heavier residue fraction comprising tertiary butyl alcohol, tertiary butyl hydroperoxide and substantially all of the soluble molybdenum catalyst originally contained in the heavy liquid fraction.

75. 发明授权

US4970346A Dicyano bis-(1,10-phenanthrolene)iron(II) catalyst useful for detergent range alcohols and ketones 失效
标题翻译：可用于洗涤剂范围的醇和酮的二氰基双 - （1,10-菲咯啉）铁（II）催化剂
公开(公告)号：US4970346A
公开(公告)日：1990-11-13
申请号：US428701
申请日：1989-10-30
申请人： John R. Sanderson , Edward T. Marquis
发明人： John R. Sanderson , Edward T. Marquis
IPC分类号： C07C29/48 , C07C45/28 , C07C409/10
CPC分类号： C07C45/28 , C07C29/48
摘要： A process for the production of detergent range alcohols and ketones by reacting an alkane with a hydroperoxide in the presence of dicyano bis-(1,10-phenanthrolene)iron(II) is described. Preferred hydroperoxides include cumene hydroperoxide and tertiary butyl hydroperoxide.
摘要翻译：描述了在二氰基双 - （1,10-菲咯啉）铁（II）存在下通过使烷烃与氢过氧化物反应来生产洗涤剂范围的醇和酮的方法。优选的氢过氧化物包括氢过氧化枯烯和叔丁基过氧化氢。

76. 发明授权

US4960948A Manufacture of ketone derivatives of polyoxypropylene glycols 失效
标题翻译：聚氧丙烯二醇的酮衍生物的制造
公开(公告)号：US4960948A
公开(公告)日：1990-10-02
申请号：US456891
申请日：1989-12-26
申请人： John R. Sanderson , Edward T. Marquis
发明人： John R. Sanderson , Edward T. Marquis
IPC分类号： C08G65/32 , C07C45/30 , C07C49/175 , C08F8/06 , C08G65/324
CPC分类号： C08G65/324 , C07C45/30 , C07C49/175
摘要： Polyoxypropylene diketones are prepared by initially adding predetermined amounts of glacial acetic acid, a polyoxypropylene glycol and, optionally, water, to a reaction zone and thereafter adding an aqueous solution of an alkali metal or an alkaline earth metal hypochlorite oxidant to the reaction zone with agitation under reaction conditions including a temperature of about 10.degree. to about 50.degree. C., a pressure of about 0 to 1,000 psig. and a total reaction time of about 0.5 to 20 hours, whereby said polyoxypropylene glycol will be substantially selectively converted to the said corresponding diketone, and recovering said diketone.
摘要翻译：通过首先向反应区中加入预定量的冰醋酸，聚氧丙烯二醇和任选的水，然后在搅拌下向反应区中加入碱金属或碱土金属次氯酸盐氧化剂的水溶液来制备聚氧丙烯二酮在包括约10℃至约50℃的温度，约0-1000psig压力的反应条件下进行。并且总反应时间为约0.5至20小时，由此所述聚氧丙烯二醇将基本上选择性地转化为所述相应的二酮，并回收所述二酮。

77. 发明授权

US4912266A Catalytic decomposition of tertiary butyl hydroperoxide 失效
标题翻译：叔丁基过氧化氢的催化分解
公开(公告)号：US4912266A
公开(公告)日：1990-03-27
申请号：US94174
申请日：1987-09-08
申请人： John R. Sanderson , John F. Knifton , Edward T. Marquis , Mark A. Mueller
发明人： John R. Sanderson , John F. Knifton , Edward T. Marquis , Mark A. Mueller
IPC分类号： C07C29/132
CPC分类号： C07C29/132
摘要： In order to prepare a feedstock, isobutane is reacted with oxygen in an oxidation zone to provide an oxidation product comprising a solution of tertiary butyl hydroperoxide in unreacted isobutane. A catalyst may be present to catalyze the reaction of the oxygen with the isobutane if desired.The feedstock is charged to a catalytic decomposition zone wherein the tertiary butyl hydroperoxide is decomposed in the presence of an imidazole-promoted metal phthalocyanine catalyst to provide a decomposition reaction product characterized by a compartively high conversion rate and a compartively high selectively of tertiary butyl hydroperoxide to tertiary butyl alcohol.
摘要翻译：为了制备原料，异丁烷在氧化区与氧反应以提供包含叔丁基过氧化氢在未反应的异丁烷中的溶液的氧化产物。如果需要，可以存在催化剂来催化氧与异丁烷的反应。将原料装入催化分解区，其中叔丁基过氧化氢在咪唑促进金属酞菁催化剂存在下分解，得到特征在于高转化率和高选择性的叔丁基过氧化氢的分解反应产物，叔丁醇。

78. 发明授权

US4661272A Thioether diester lubricating oil composition 失效
标题翻译：硫醚二酯润滑油组成
公开(公告)号：US4661272A
公开(公告)日：1987-04-28
申请号：US506733
申请日：1983-06-22
申请人： Edward T. Marquis , Lewis W. Watts, Jr. , Ernest L. Yeakey
发明人： Edward T. Marquis , Lewis W. Watts, Jr. , Ernest L. Yeakey
IPC分类号： C10M105/72 , C10M135/24 , C10M157/06
CPC分类号： C10M135/24 , C07C323/00 , C10M105/72 , C10M2219/084 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/105 , C10N2240/106 , C10N2240/14
摘要： Provided is a novel thioether diester synthetic lubricating oil composition represented by the formula: ##STR1## in which R and R.sub.1 each represent alkyl radicals having from 1 to 6 carbon atoms, with the total number of carbon atoms in R, R, R.sub.1, and R.sub.1 ranging from about 6 to 20, and n is an integer from 2 to 5.
摘要翻译：提供了一种由下式表示的新型硫醚二酯合成润滑油组合物：其中R和R 1各自表示具有1至6个碳原子的烷基，R，R，R 1和R 3中的碳原子总数 R1为约6至20，n为2至5的整数。

79. 发明授权

US4654427A Synthesis of molybdenum oxide/alkanol complexes 失效
标题翻译：氧化钼/烷醇络合物的合成
公开(公告)号：US4654427A
公开(公告)日：1987-03-31
申请号：US804132
申请日：1985-12-06
申请人： Edward T. Marquis , John R. Sanderson , Kenneth P. Keating , William A. Smith
发明人： Edward T. Marquis , John R. Sanderson , Kenneth P. Keating , William A. Smith
IPC分类号： B01J31/22 , C07D301/19 , C07F11/00
CPC分类号： C07D301/19 , B01J31/2208 , B01J31/2226 , B01J2231/72 , B01J2531/64
摘要： Storage stable solutions of molybdenum/alkanol complexes in the alkanol are prepared by reacting a molybdenum oxide and ammonium hydroxide and an amount of a straight chain or branched chain C.sub.6 -C.sub.13 alkanol, within the range of about 10 to about 55 moles of alkanol per gram atom of molybdenum sufficient to form a storage stable molybdenum/alkanol complex. The complex-forming reaction is initiated in the presence of about 1 to about 4 moles of water per gram atom of molybdenum and about 0.5 to about 10 moles of ammonia per gram atom of molybdenum, the water and ammonia preferably being added in the form of concentrated ammonium hydroxide. The reaction is conducted at a temperature of about 120.degree. to about 190.degree. C. for a period of time, normally about 3 to about 8 hours, sufficient to substantially completely remove ammonia and water to provide a liquid reaction product comprising said solution of molybdenum/alkanol complex dissolved in unreacted alkanol and containing about 0.001 to about 0.1 wt. % of water. The reaction product is filtered to provide a clarified storage stable solution of the molybdenum/alkanol complex having a dissolved molybdenum content of about 3 to about 10.5 wt. %.
摘要翻译：钼/烷醇配合物在烷醇中的储存稳定溶液是通过使氧化钼和氢氧化铵与一定量的直链或支链C 6 -C 13烷醇在约10-约55摩尔的链烷醇/克足以形成储存稳定的钼/烷醇络合物的钼原子。在约1至约4摩尔水/克原子钼和约0.5至约10摩尔氨/克原子钼的存在下引发络合物形成反应，优选以水和氨的形式加入水和氨浓氢氧化铵。反应在约120℃至约190℃的温度下进行一段时间，通常约3至约8小时，足以基本上完全除去氨和水，以提供包含所述钼溶液的液体反应产物 /链烷醇络合物溶解在未反应的链烷醇中并含有约0.001至约0.1wt。％的水。将反应产物过滤以提供溶解的钼含量为约3至约10.5重量％的钼/烷醇络合物的澄清储存稳定溶液。％。

80. 发明授权

US4434308A Manufacture of synthetic lubricant additives from internal olefins using boron trifluoride catalysis 失效
标题翻译：使用三氟化硼催化从内部烯烃制造合成润滑剂添加剂
公开(公告)号：US4434308A
公开(公告)日：1984-02-28
申请号：US372492
申请日：1982-04-28
申请人： John M. Larkin , Lewis W. Watts, Jr. , Edward T. Marquis
发明人： John M. Larkin , Lewis W. Watts, Jr. , Edward T. Marquis
IPC分类号： C07C2/20 , C10G50/02 , C07C1/16 , C07C5/00
CPC分类号： C07C2/20 , C10G50/02 , C07C2527/1213 , C07C2531/02
摘要： An improved process for the manufacture of synthetic lubricant additives from internal olefins is described. The process utilizes boron trifluoride catalysis with a promoter to produce oligomer mixtures that have surprisingly low viscosities at low temperatures and surprisingly high viscosity indexes as compared with the oligomers found in other methods. It is important that internal olefins be used almost exclusively in the method of this invention.
摘要翻译：描述了从内烯烃制造合成润滑剂添加剂的改进方法。该方法利用三氟化硼催化促进剂产生低聚物混合物，其在低温下具有惊人的低粘度，并且与其它方法中发现的低聚物相比，具有令人惊奇的高粘度指数。重要的是内部烯烃几乎完全用于本发明的方法中。

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