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    • 76. 发明授权
    • Fully dry post-via-etch cleaning method for a damascene process
    • 用于镶嵌工艺的完全干燥的经过蚀刻的清洁方法
    • US06323121B1
    • 2001-11-27
    • US09570018
    • 2000-05-12
    • Jen-Cheng LiuChao-Cheng ChenLi-Chih ChaoChia-Shiung TsaiMing-Huei Lui
    • Jen-Cheng LiuChao-Cheng ChenLi-Chih ChaoChia-Shiung TsaiMing-Huei Lui
    • H01L214763
    • H01L21/02063H01L21/31116H01L21/31138H01L21/31144H01L21/76807
    • A method is described for cleaning freshly etched dual damascene via openings and preparing them for copper fill without damage or contamination of exposed organic or other porous low-k insulative layers. The method is entirely dry and does not expose the porous materials to contamination from moisture or solvents. The method is effective for removing all traces of residual polymer deposits from an in-process substrate wafers after via or damascene trench etching. The method employs an in-situ three-step treatment comprising a first step of exposing the electrically biased substrate wafer to a O2/N2 ashing plasma to remove photoresist and polymers, a second step immediately following the first step of remove silicon nitride etch stop layers, and a final step of treating the wafer with H2/N2 to remove copper polymer deposits formed during nitride removal. The H2/N2 plasma is capable of removing the difficult polymer residues which are otherwise only removable by wet stripping procedures. The H2/N2 plasma is not harmful to exposed porous low-k dielectric layers as well as copper metallurgy.
    • 描述了一种用于通过开口清洁新鲜蚀刻的双镶嵌件的方法,并且它们用于铜填充而不损坏或污染暴露的有机或其它多孔低k绝缘层。 该方法是完全干燥的,并且不会使多孔材料暴露于水分或溶剂的污染物中。 该方法对于在通孔或镶嵌沟槽蚀刻之后从工艺衬底晶片去除残余聚合物沉积物的所有迹线是有效的。 该方法采用原位三步处理,其包括将电偏置的衬底晶片暴露于O 2 / N 2灰分等离子体以去除光致抗蚀剂和聚合物的第一步骤,紧接着在去除氮化硅蚀刻停止层的第一步骤之后的第二步骤 ,以及用H2 / N2处理晶片以除去在氮化物除去期间形成的铜聚合物沉积物的最后步骤。 H 2 / N 2等离子体能够去除困难的聚合物残余物,否则其仅可通过湿式剥离方法除去。 H2 / N2等离子体对暴露的多孔低k电介质层以及铜冶金无害。
    • 77. 发明授权
    • Method to increase the etch rate selectivity between metal and
photoresist via use of a plasma treatment
    • 通过使用等离子体处理来增加金属和光致抗蚀剂之间的蚀刻速率选择性的方法
    • US6133145A
    • 2000-10-17
    • US169434
    • 1998-10-09
    • Chao-Cheng Chen
    • Chao-Cheng Chen
    • H01L21/027H01L21/3213H01L21/768H01L21/4763
    • H01L21/32139H01L21/0273H01L21/76838
    • A process for fabricating an aluminum based interconnect structure, using a plasma treated photoresist shape as an etch mask, has been developed. The process features treating a photoresist shape, to be used as an etch mask during RIE patterning procedures, in a nitrogen containing plasma. The plasma nitrogen treated photoresist shape is eroded at a decreased rate, when compared to counterpart non-treated photoresist shapes, during the RIE procedure used to fabricate the aluminum based interconnect structure. The increased etch rate ratio, between layers used for the interconnect structure, and the plasma treated photoresist shape, allows thinner photoresist shapes to be used, and therefore allows narrower lines and spaces to be achieved.
    • 已经开发了使用等离子体处理的光致抗蚀剂形状作为蚀刻掩模来制造铝基互连结构的方法。 该方法的特征是在含氮等离子体中处理光刻胶形状,以在RIE图案化步骤期间用作蚀刻掩模。 在用于制造铝基互连结构的RIE程序期间,与对照未处理的光致抗蚀剂形状相比,等离子体氮处理的光致抗蚀剂形状以降低的速率被侵蚀。 用于互连结构的层之间的增加的蚀刻速率比和等离子体处理的光致抗蚀剂形状允许使用更薄的光致抗蚀剂形状,因此允许实现更窄的线和空间。
    • 78. 发明授权
    • Etch recipe for embedded DRAM passivation with etch stopping layer scheme
    • 用蚀刻停止层方案的嵌入式DRAM钝化蚀刻配方
    • US5989784A
    • 1999-11-23
    • US55463
    • 1998-04-06
    • Yu-Hua LeeCheng-Ming WuChao-Cheng Chen
    • Yu-Hua LeeCheng-Ming WuChao-Cheng Chen
    • H01L21/768H01L23/525G03F7/40B44C1/22C03C15/00C25F3/00
    • H01L23/5258H01L21/76802H01L2924/0002
    • A method of forming an etch stop layer 40 above a fuse 16 in a fuse opening (or window) 92 using a specialized 2 stage etch process. The invention has two important features: First, the etch stop layer 40 is formed from a polysilicon layer (P2 or P4) that is used to fabricate semiconductor devices on a substrate. The etch stop layer 40 is preferably formed of polysilicon layer to is used to from a contact to the substrate 10 (P2) or to form part of a capacitor (P4). Second, a specialized two stage etch process is used where the second stage etches the etch stop layer 40 while simultaneously forming a passivation layer 114 over a metal pad 85. The method comprises: forming fuses 16 over said isolation regions 10 over the fuse area 15; forming a first dielectric layer 30 overlying the fuses 16; forming an etch stop layer 40 over the first dielectric layer 30; forming an insulating layer 43 over the etch stop layer; forming a fuse opening 92 in the insulating layer 43 by etching, in a first etch stage, thorough fuse photoresist openings 90A and stopping the first etch stage on the etch stop layer 40; and etching though the etch stop layer 40 in the fuse opening 92 in a second etch stage.
    • 使用专门的2级蚀刻工艺在保险丝开口(或窗口)92中的熔丝16上方形成蚀刻停止层40的方法。 本发明具有两个重要特征:首先,蚀刻停止层40由用于在基板上制造半导体器件的多晶硅层(P2或P4)形成。 蚀刻停止层40优选由多晶硅层形成,用于从接触到衬底10(P2)或形成电容器(P4)的一部分。 第二,使用专门的两级蚀刻工艺,其中第二阶段蚀刻蚀刻停止层40,同时在金属焊盘85上形成钝化层114.该方法包括:在保险丝区域15上方的所述隔离区域10上形成保险丝16 ; 形成覆盖保险丝16的第一电介质层30; 在第一介电层30上形成蚀刻停止层40; 在所述蚀刻停止层上形成绝缘层43; 在绝缘层43中通过在第一蚀刻阶段中蚀刻完整的熔融光致抗蚀剂开口90A并停止蚀刻停止层40上的第一蚀刻阶段来在绝缘层43中形成熔丝开口92; 并且在第二蚀刻阶段通过熔丝开口92中的蚀刻停止层40进行蚀刻。
    • 79. 发明授权
    • Fluorocarbon polymer layer deposition predominant pre-etch plasma etch
method for forming patterned silicon containing dielectric layer
    • 用于形成图案化含硅介电层的氟碳聚合物层沉积主要预蚀刻等离子体蚀刻方法
    • US5942446A
    • 1999-08-24
    • US928235
    • 1997-09-12
    • Chao-Cheng ChenChen-Hua Yu
    • Chao-Cheng ChenChen-Hua Yu
    • H01L21/311H01L21/768H01L21/00
    • H01L21/31144H01L21/31116H01L21/76802
    • A method for forming a patterned silicon containing dielectric layer within a microelectronics fabrication. There is first provided a substrate employed within a microelectronics fabrication. There is then formed over the substrate a silicon containing dielectric layer. There is then formed upon the silicon containing dielectric layer a hard mask layer, where the hard mask layer leaves exposed a portion of the silicon containing dielectric layer. There is then etched partially through a first plasma etch method the silicon containing dielectric layer to form a partially etched silicon containing dielectric layer. The first plasma etch method employs a first etchant gas composition comprising a first fluorocarbon etchant gas which predominantly forms a fluoropolymer layer upon at least the hard mask layer. Finally, there is then etched through a second plasma etch method the partially etched silicon containing dielectric layer to form a patterned silicon containing dielectric layer. The second plasma etch method employs a second etchant gas composition comprising a second fluoro etchant gas which predominantly etches the partially etched silicon containing dielectric layer in forming the patterned silicon containing dielectric layer.
    • 一种用于在微电子制造中形成图案化含硅介电层的方法。 首先提供了在微电子制造中使用的衬底。 然后在衬底上形成含硅介电层。 然后在含硅电介质层上形成硬掩模层,其中硬掩模层离开暴露一部分含硅电介质层。 然后通过第一等离子体蚀刻方法将含硅介电层部分地蚀刻以形成部分蚀刻的含硅介电层。 第一等离子体蚀刻方法采用第一蚀刻剂气体组合物,其包括在至少硬掩模层上主要形成含氟聚合物层的第一碳氟化合物蚀刻剂气体。 最后,然后通过第二等离子体蚀刻方法蚀刻部分蚀刻的含硅介电层,以形成图案化的含硅介电层。 第二等离子体蚀刻方法采用包含第二氟蚀刻剂气体的第二蚀刻剂气体组合物,其主要在形成图案化的含硅介电层时蚀刻部分蚀刻的含硅介电层。