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71. 发明授权

US4174322A Thiobis(oxazolines) 失效
标题翻译：硫堇（恶唑啉）
公开(公告)号：US4174322A
公开(公告)日：1979-11-13
申请号：US817217
申请日：1977-07-20
申请人： Stanley J. Brois , Antonio Gutierrez
发明人： Stanley J. Brois , Antonio Gutierrez
IPC分类号： C07D307/32 , C07D307/33 , C07D307/60 , C07D309/30 , C10L1/233 , C10L1/24 , C10M133/48 , C10M133/58 , C10M135/32 , F02B3/06 , C07D263/08
CPC分类号： C07D307/33 , C07D307/32 , C07D307/60 , C07D309/30 , C10L1/233 , C10L1/2493 , C10M133/48 , C10M133/58 , C10M135/32 , C10M2205/00 , C10M2205/022 , C10M2205/026 , C10M2205/14 , C10M2207/024 , C10M2209/084 , C10M2209/086 , C10M2209/112 , C10M2215/065 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/30 , C10M2219/085 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2219/09 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106 , C10M2223/041 , C10M2223/045 , C10M2223/047 , C10M2229/02 , C10M2229/05 , C10N2210/03 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2270/02 , F02B3/06
摘要： Lactone oxazoline reaction products of hydrocarbon substituted lactone carboxylic acids, for example, polybutyl lactone carboxylic acid, with 2,2-disubstituted-2-amino-1-alkanols, such as tris-(hydroxymethyl)aminomethane (THAM), and their derivatives are useful additives in oleaginous compositions, such as sludge dispersants for lubricating oil, or anti-rust agents for gasoline.
摘要翻译：烃取代的内酯羧酸（例如聚丁内酯羧酸）与2,2-二取代-2-氨基-1-链烷醇如三 - （羟甲基）氨基甲烷（THAM）及其衍生物的内酯恶唑啉反应产物是含油组合物中有用的添加剂，如润滑油污泥分散剂，或汽油防锈剂。

72. 发明授权

US4100187A Olefin-thionophosphine sulfide reaction products, their derivatives and use thereof as oil and fuel additives 失效
标题翻译：烯烃 - 硫代磷化氢反应产物，其衍生物和作为油和燃料添加剂的用途
公开(公告)号：US4100187A
公开(公告)日：1978-07-11
申请号：US622073
申请日：1975-10-14
申请人： Stanley J. Brois
发明人： Stanley J. Brois
IPC分类号： C07F9/32 , C07F9/38 , C07F9/40 , C07F9/6578 , C08F8/34 , C08F8/40 , C10L1/26 , C10M137/14 , C10M159/12 , C10M169/00 , C07F9/04
CPC分类号： C10M159/123 , C07F9/6578 , C08F8/40 , C10L1/2691 , C10M1/08 , C10M137/14 , C10M2203/10 , C10M2203/102 , C10M2203/104 , C10M2203/106 , C10M2203/108 , C10M2205/026 , C10M2207/282 , C10M2207/32 , C10M2207/34 , C10M2209/084 , C10M2209/086 , C10M2209/103 , C10M2209/104 , C10M2209/109 , C10M2209/111 , C10M2211/02 , C10M2215/065 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10M2223/045 , C10M2223/047 , C10M2223/06 , C10M2223/061 , C10M2223/063 , C10M2223/065 , C10M2223/12 , C10M2225/00 , C10M2225/02 , C10M2225/04 , C10M2225/041 , C10M2229/02 , C10M2229/05 , C10N2210/02 , C10N2270/02
摘要： Adducts are formed in a process which involves the reaction of an olefin, including olefin polymers, with a dimeric thionophosphine sulfide. Further derivatives may be formed by reacting the resulting olefin-thionophosphine sulfide adduct products with amines, e.g., alkylene polyamines, aziridines, phosphines or metal salts, e.g., zinc salts. Or, alkylene polyamine- or aziridine- treated olefin-thionophosphine sulfide reaction products may be further reacted with metal salts, e.g., zinc acetate. A representative material can be prepared by reacting polyisobutylene with an arylthionophosphine sulfide, and then further reacting the resulting cyclic bis(phosphinodithioic acid) anhydride product with an alkylene polyamine or aziridine, which in turn, may be further modified by reaction with zinc acetate.The oil soluble olefin-thionophosphine sulfide products, as well as its oil soluble derivatives outlined above, may be used as additives for lubricating oil, and petroleum fuels, e.g., gasoline or fuel oil.
摘要翻译：在包括烯烃聚合物的烯烃与二聚硫代膦硫化物反应的方法中形成加合物。另外的衍生物可以通过使所得到的烯烃 - 硫代膦硫化物加合产物与胺例如亚烷基多胺，氮丙啶，膦或金属盐例如锌盐反应形成。或者，亚烷基多胺或氮丙啶处理的烯烃 - 硫代膦化物反应产物可以与金属盐例如乙酸锌进一步反应。代表性材料可以通过使聚异丁烯与芳基硫羰基硫化膦反应制备，然后使所得的环状双（膦酸二硫酸）酸酐产物与亚烷基多胺或氮丙啶进一步反应，其又可以通过与乙酸锌反应进一步改性。

73. 发明授权

US4069023A Carboxylate esters of 1-aza-3,7-dioxabicyclo[3.3.0] oct-5-yl methyl alcohols, their preparation and use as additives for oleaginous compositions 失效
标题翻译： 1-氮杂-3,7-二氧杂双环{8 3.3.0 {9 {0辛-5-基甲醇，其制备和用作油性组合物的添加剂的羧酸酯
公开(公告)号：US4069023A
公开(公告)日：1978-01-17
申请号：US752873
申请日：1976-12-20
申请人： Stanley J. Brois , Jack Ryer , Esther Winans
发明人： Stanley J. Brois , Jack Ryer , Esther Winans
IPC分类号： C10M133/48 , C07D491/22 , C07D498/04 , C08F8/00 , C10L1/22 , C10L10/08 , C10M133/00 , C10N30/04 , C10N30/06 , C10N30/12 , C10N40/25
CPC分类号： C07D491/22 , C07D498/04 , C08F8/30 , C10L1/221 , C10L10/04 , C10L10/08 , C10M2205/00 , C10M2205/022 , C10M2205/026 , C10M2205/14 , C10M2207/024 , C10M2207/282 , C10M2207/32 , C10M2207/34 , C10M2209/084 , C10M2209/086 , C10M2209/103 , C10M2209/112 , C10M2211/02 , C10M2215/065 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/30 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2223/04 , C10M2223/042 , C10M2223/045 , C10M2223/12 , C10M2225/04 , C10M2229/02 , C10M2229/05 , C10N2210/02 , C10N2240/08 , C10N2270/02
摘要： Ester derivatives of 1-aza-3,7-dioxabicyclo [3.3.0] oct-5-yl methyl alcohols which are the reaction products of organic acid materials, preferably long chain dicarboxylic anhydrides such as octadecenyl and polyisobutenylsuccinic anhydrides and aldehyde/tris [hydroxy-methyl] aminomethane (THAM) adducts or mixtures are oleaginous compositions which feature activity in gasoline as rust inhibitors and carburetor detergents; in automatic transmission fluids as friction modifiers and rust inhibitors; and, in automotive, industrial and lubricating oils as sludge dispersants, rust-inhibitors, friction modifiers and copper alloy corrosion inhibitors, the particular use depending on the molecular weight of the ester.
摘要翻译：作为有机酸材料的反应产物的1-氮杂-3,7-二氧杂二环[3.3.0]辛-5-基甲醇的酯衍生物，优选长链二羧酸酐如十八碳烯基和聚异丁烯基琥珀酸酐和醛/三[ 羟基甲基]氨基甲烷（THAM）加合物或混合物是含油组合物，其特征在于作为防锈剂和化油器洗涤剂的汽油中的活性; 在自动变速器油中作为摩擦改进剂和防锈剂; 并且在作为污泥分散剂，防锈剂，摩擦改进剂和铜合金腐蚀抑制剂的汽车，工业和润滑油中，具体用途取决于酯的分子量。

74. 发明授权

US4017406A Carboxylate half esters of 1-aza-3,7-dioxabicyclo[3.3.0] oct-5-yl methyl alcohols, their preparation and use as additives for oleaginous compositions 失效
标题翻译： 1-氮杂-3,7-二氧杂双环{8 3.3.0 {9 {0辛-5-基甲醇，其制备和用作油性组合物的添加剂的羧酸酯半酯
公开(公告)号：US4017406A
公开(公告)日：1977-04-12
申请号：US573545
申请日：1975-05-01
申请人： Stanley J. Brois , Jack Ryer , Esther Winans
发明人： Stanley J. Brois , Jack Ryer , Esther Winans
IPC分类号： C10M133/48 , C07D491/22 , C07D498/04 , C08F8/00 , C10L1/22 , C10L10/08 , C10M133/00 , C10N30/04 , C10N30/06 , C10N30/12 , C10N40/25 , C10M1/32
CPC分类号： C07D491/22 , C07D498/04 , C08F8/30 , C10L1/221 , C10L10/04 , C10L10/08 , C10M2205/00 , C10M2205/022 , C10M2205/026 , C10M2205/14 , C10M2207/024 , C10M2207/282 , C10M2207/32 , C10M2207/34 , C10M2209/084 , C10M2209/086 , C10M2209/103 , C10M2209/112 , C10M2211/02 , C10M2215/065 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/30 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2223/04 , C10M2223/042 , C10M2223/045 , C10M2223/12 , C10M2225/04 , C10M2229/02 , C10M2229/05 , C10N2210/02 , C10N2240/08 , C10N2270/02
摘要： Ester derivatives of 1-aza-3,7-dioxabicyclo [3.3.0] oct-5-yl methyl alcohols which are the reaction products of organic acid materials, preferably long chain dicarboxylic anhydrides such as octadecenyl and polyisobutenylsuccinic anhydrides and aldehyde/tris [hydroxy-methyl] aminomethane (THAM) adducts or mixtures are oleaginous compositions which feature activity in gasoline as rust inhibitors and carburetor detergents; in automatic transmission fluids as friction modifiers and rust inhibitors; and, in automotive, industrial and lubricating oils as sludge dispersants, rust-inhibitors, friction modifiers and copper alloy corrosion inhibitors, the particular use depending on the molecular weight of the ester.
摘要翻译：作为有机酸材料的反应产物的1-氮杂-3,7-二氧杂二环[3.3.0]辛-5-基甲醇的酯衍生物，优选长链二羧酸酐如十八碳烯基和聚异丁烯基琥珀酸酐和醛/三[ 羟基甲基]氨基甲烷（THAM）加合物或混合物是含油组合物，其特征在于作为防锈剂和化油器洗涤剂的汽油中的活性; 在自动变速器油中作为摩擦改进剂和防锈剂; 并且在作为污泥分散剂，防锈剂，摩擦改进剂和铜合金腐蚀抑制剂的汽车，工业和润滑油中，具体用途取决于酯的分子量。

75. 发明授权

US06730747B1 Carbonyl containing compounds 失效
标题翻译：含羰基化合物
公开(公告)号：US06730747B1
公开(公告)日：2004-05-04
申请号：US09476924
申请日：2000-01-04
申请人： Stanley J. Brois
发明人： Stanley J. Brois
IPC分类号： C08F800
CPC分类号： C08F8/28 , C08F8/00 , C08F10/00
摘要： In accordance with the present invention, there is provided a novel composition of matter having the formula: wherein Ra, Rb, Rc, Rd and Re are independently selected from the group consisting of H, alkyl groups and substituted alkyl groups having about 1 to 106 carbon atoms, alkenyl groups and substituted alkenyl groups having about 3 to 106 carbon atoms, wherein the substituents on the alkyl and/or alkenyl groups are selected from the group consisting of alkoxy, halogen, CN, OH, HO(CH2CH2O)x (X=1-10), acyl, acyloxy and aryl substituents.
摘要翻译：根据本发明，提供了具有下式的物质的新组合物：其中Ra，Rb，Rc，Rd和Re独立地选自H，烷基和具有约1-10个碳原子的取代的烷基具有约3至10 6个碳原子的烯基和取代的烯基，其中烷基和/或烯基上的取代基选自烷氧基，卤素，CN，OH，HO （CH 2 CH 2 O）x（X = 1-10），酰基，酰氧基和芳基取代基。

76. 发明授权

US06569820B2 Manufacture of lubricant additives 有权
标题翻译：制造润滑油添加剂
公开(公告)号：US06569820B2
公开(公告)日：2003-05-27
申请号：US09816053
申请日：2001-03-23
申请人： Jonathan M. McConnachie , Ian A. W. Bell , Edward I. Stiefel , Stanley J. Brois , Ernestine W. Hill , Alisdair J. Brown
发明人： Jonathan M. McConnachie , Ian A. W. Bell , Edward I. Stiefel , Stanley J. Brois , Ernestine W. Hill , Alisdair J. Brown
IPC分类号： C10M13900
CPC分类号： C10M159/18 , C07F11/005 , C10M135/18 , C10M2219/068 , C10M2227/09 , C10N2210/06 , C10N2240/08 , C10N2270/02
摘要： Oil-soluble or oil-dispersible trinuclear molybdenum-sulfur compounds are made by reacting, in a polar medium, a reactant molybdenum compound containing an anion that possesses a trinuclear molybdenum core, and a dithiocarbamate that is produced in situ.
摘要翻译：通过在极性介质中使含有具有三核钼核的阴离子的反应物钼化合物和原位产生的二硫代氨基甲酸酯反应制备油溶性或油分散性三核钼硫化合物。

77. 发明授权

US5849193A Surface active metal chelated nutrients for bioremediation of hydrocarbon contaminated soils and water 失效
公开(公告)号：US5849193A
公开(公告)日：1998-12-15
申请号：US678841
申请日：1996-07-12
申请人： Ramesh Varadaraj , Stanley J. Brois , Jan Bock , Cornelius Hendrick Brons
发明人： Ramesh Varadaraj , Stanley J. Brois , Jan Bock , Cornelius Hendrick Brons
IPC分类号： B09C1/10 , C02F1/68 , C11D3/32 , C12N1/38 , C02F3/00
CPC分类号： C02F1/682 , B09C1/10 , C11D3/32 , C12N1/38 , Y10S210/925 , Y10S516/02 , Y10S516/07
摘要： The present invention provides for enhanced bioremediation of hydrocarbon contaminated soils and waters by treating soil or water with a composition comprising of a metal chelated macrocyclic amido amines or mixtures thereof represented by the structural formula: ##STR1## where R is selected from linear or branched alkanes with 8 to 22 carbons, linear or branched alkenes with 4 to 22 carbon atoms; T.sub.1, T.sub.2 and T.sub.3 are independently selected from ethylene, trimethylene, CH.sub.2 CH.sub.2 (NHCH.sub.2 CH.sub.2).sub.x where x is an integer from 1 to 10; MaQb is a metal compound wherein M is a cation selected from cations of Fe, Co, Ni, Cu, Zn, and Mn; and, Q is an anion selected from nitrate, phosphate anions; and a and b are integers from 1 to 3 necessary to satisfy the valence requirements of M and Q. a phosphorous source, and a diluent.

78. 发明授权

US5646098A Carbonyl containing compounds and their derivatives as multi-functional fuel and lube additives 失效
标题翻译：含羰基化合物及其衍生物作为多功能燃料和润滑添加剂
公开(公告)号：US5646098A
公开(公告)日：1997-07-08
申请号：US242750
申请日：1994-05-13
申请人： Stanley J. Brois
发明人： Stanley J. Brois
IPC分类号： C07D239/02 , C07C45/71 , C07C49/707 , C07C49/713 , C07C49/727 , C07C49/747 , C07C59/90 , C07C69/716 , C07C69/732 , C07C235/28 , C07D239/62 , C08C19/00 , C08F8/00 , C08F8/28 , C10L1/14 , C10L1/18 , C10L1/185 , C10L1/19 , C10L1/192 , C10L1/195 , C10L1/198 , C10L1/22 , C10L1/224 , C10L1/228 , C10L1/234 , C10L1/238 , C10L1/24 , C10L1/26 , C10L1/30 , C10L10/00 , C10L10/08 , C10M129/24 , C10M129/86 , C10M133/52 , C10M145/00 , C10M149/00 , C10M159/12 , C10N30/02 , C10N30/04 , C10N40/25 , C10M139/00
CPC分类号： C10M133/52 , C07C235/28 , C07C45/71 , C07C49/747 , C07C59/90 , C07C69/732 , C07D239/62 , C08C19/00 , C08F8/02 , C08F8/28 , C08F8/42 , C08F8/44 , C10L1/143 , C10L1/1814 , C10L1/1857 , C10L1/19 , C10L1/198 , C10L1/224 , C10L1/2283 , C10L1/238 , C10L1/303 , C10L10/04 , C10M129/86 , C08F2800/20 , C08F2810/30 , C10L1/1817 , C10L1/188 , C10L1/1881 , C10L1/1883 , C10L1/1905 , C10L1/191 , C10L1/221 , C10L1/2222 , C10L1/2225 , C10L1/2227 , C10L1/223 , C10L1/2235 , C10L1/226 , C10L1/2286 , C10L1/23 , C10L1/232 , C10L1/233 , C10L1/2335 , C10L1/2406 , C10L1/2418 , C10L1/2425 , C10L1/2431 , C10L1/2443 , C10L1/245 , C10L1/2456 , C10L1/2475 , C10L1/2493 , C10L1/26 , C10L1/2608 , C10L1/2616 , C10L1/2641 , C10L1/265 , C10L1/2658 , C10L1/2683 , C10L1/2691 , C10L1/30 , C10L1/301 , C10L1/305 , C10M2207/28 , C10M2207/282 , C10M2207/34 , C10M2215/04 , C10M2215/08 , C10M2215/082 , C10M2215/26 , C10M2215/28 , C10M2217/046 , C10M2217/06 , C10N2240/00 , C10N2240/02 , C10N2240/06 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/105 , C10N2240/106 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C10N2270/02
摘要： The invention relates to novel compositions comprising ene and free radical adducts of unsaturated and saturated hydrocarbons, and acyclic and cyclic vicinal polycarbonyl compounds such as diethyl ketomalonate and indantrione. The adducts are reacted with nucleophiles such as amines, electrophiles such as anhydrides and esters, and metal ions. Post-products are obtained via reaction of said products with capping reagents such as boric acid. Compositions containing said adducts, products and post-products include oleaginous substances such as fuels and lube oils.
摘要翻译：本发明涉及包含不饱和和饱和烃的烯和自由基加成物的新型组合物，以及无环和环状连位多羰基化合物，例如酮咯酸二乙酯和茚满酮。加合物与亲核试剂例如胺，亲电试剂如酸酐和酯以及金属离子反应。后产物通过所述产物与封端试剂例如硼酸的反应获得。含有所述加合物，产品和后期产品的组合物包括含油物质如燃料和润滑油。

79. 发明授权

US5514588A Surfactant-nutrients for bioremediation of hydrocarbon contaminated soils and water 失效
标题翻译：表面活性剂 - 用于碳氢化合物污染土壤和水的生物修复的营养物质
公开(公告)号：US5514588A
公开(公告)日：1996-05-07
申请号：US354985
申请日：1994-12-13
申请人： Ramesh Varadaraj , Cornelius H. Brons , Jan Bock , Stanley J. Brois
发明人： Ramesh Varadaraj , Cornelius H. Brons , Jan Bock , Stanley J. Brois
IPC分类号： B09C1/10 , C02F3/34 , C12N1/38 , B09B3/00 , A61L11/00
CPC分类号： B09C1/10 , C02F3/34 , C12N1/38
摘要： The present invention provides for enhanced bioremediation of hydrocarbon contaminated soils and waters by treating soil or water with a composition comprising a phosphorous source, a diluent and a compound or mixtures thereof represented by the structural formula: ##STR1## wherein R is a linear or branched alkane having about 8 to about 22 carbons, a linear or branched alkene having about 4 to about 22 carbon atoms; T.sub.1, T.sub.2, T.sub.3 are independently ethylene, trimethylene, or CH.sub.2 CH.sub.2 (NHCH.sub.2 CH.sub.2).sub.x, where x is an integer from 1 to 10; Q is HNO.sub.3 or H.sub.3 PO.sub.4 ; and, n is an integer from 0 to 10.
摘要翻译：本发明通过用包含磷源，稀释剂和化合物或其混合物的组合物处理土壤或水来提供烃污染的土壤和水的增强的生物修复，其结构式如下：其中R是直链或支链具有约8至约22个碳原子的烷烃，具有约4至约22个碳原子的直链或支链烯烃; T1，T2，T3独立地为亚乙基，三亚甲基或CH 2 CH 2（NHCH 2 CH 2）x，其中x为1至10的整数; Q是HNO3或H3PO4; n为0〜10的整数。

80. 再颁专利

USRE35004E Cyclic carbonyl containing polymers 失效
标题翻译：含羰基的聚合物
公开(公告)号：USRE35004E
公开(公告)日：1995-07-25
申请号：US92150
申请日：1993-07-15
申请人： Stanley J. Brois
发明人： Stanley J. Brois
IPC分类号： C07C45/71 , C07C49/747 , C07C59/90 , C07C69/732 , C07C235/28 , C07D239/62 , C08C19/00 , C08F8/00 , C08F8/28 , C08L23/26 , C10L1/14 , C10L1/18 , C10L1/185 , C10L1/19 , C10L1/198 , C10L1/224 , C10L1/228 , C10L1/238 , C10L1/30 , C10L10/00 , C10M129/86 , C10M133/52 , C08K5/15 , C07D251/04
CPC分类号： C10M133/52 , C07C235/28 , C07C45/71 , C07C49/747 , C07C59/90 , C07C69/732 , C07D239/62 , C08C19/00 , C08F8/00 , C08F8/28 , C08L23/26 , C10L1/143 , C10L1/1814 , C10L1/1857 , C10L1/19 , C10L1/198 , C10L1/224 , C10L1/2283 , C10L1/238 , C10L1/303 , C10L10/00 , C10M129/86
摘要： The present invention relates to novel polymers which are adducts of an unsaturated hydrocarbon, wherein the novel polymers are produced by contacting cyclic carbonyl monomers with an unsaturated hydrocarbon to form novel cyclic carbonyl polymers having an Mn of about 500 to about 10.sup.7.

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