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    • 73. 发明授权
    • Method for manufacturing SOI substrate
    • 制造SOI衬底的方法
    • US07615456B2
    • 2009-11-10
    • US12076923
    • 2008-03-25
    • Shoji AkiyamaYoshihiro KubotaAtsuo ItoMakoto KawaiYuuji TobisakaKoichi Tanaka
    • Shoji AkiyamaYoshihiro KubotaAtsuo ItoMakoto KawaiYuuji TobisakaKoichi Tanaka
    • H01L21/331H01L21/8222
    • H01L21/76256H01L27/12
    • A method for manufacturing an SOI substrate superior in film thickness uniformity and resistivity uniformity in a substrate surface of a silicon layer having a film thickness reduced by an etch-back method is provided. After B ions is implanted into a front surface of a single-crystal Si substrate 10 to form a high-concentration boron added p layer 11 having a depth L in the outermost front surface, the single-crystal Si substrate 10 is appressed against a quartz substrate 20 to be bonded at a room temperature. Chemical etching is performed with respect to the single-crystal Si substrate 10 from a back surface thereof to set its thickness to L or below. A heat treatment is carried out with respect to an SOI substrate in a hydrogen containing atmosphere to outwardly diffuse B from the high-concentration boron added p layer 11, thereby acquiring a boron added p layer 12 having a desired resistance value. During this heat treatment, B in an Si crystal is diffused to the outside of the crystal in a state where it is coupled with hydrogen in the atmosphere, and a B concentration in the high-concentration boron added p layer 11 is reduced. In regard to a heat treatment temperature at this time, in view of a softening point of the insulative substrate, an upper limit of the heat treatment temperature is set to 1250° C., and 700° C. is selected as a lower limit of the temperature at which B can be diffused.
    • 提供一种制造SOI衬底的方法,该SOI衬底具有通过蚀刻方法减小的膜厚度的硅层的衬底表面中的膜厚均匀性和电阻率均匀性优异的SOI衬底。 在将B离子注入到单晶Si衬底10的前表面中以形成在最外表面具有深度L的高浓度硼添加p层11之后,将单晶Si衬底10贴在石英 基板20在室温下结合。 从其背面对单晶硅基板10进行化学蚀刻,将其厚度设定为L以下。 对含氢气氛中的SOI衬底进行热处理,从高浓度硼添加p层11向外扩散B,从而获得具有所需电阻值的添加硼的p层12。 在该热处理中,Si结晶中的B在与大气中的氢相结合的状态下扩散到晶体外部,并且在高浓度硼添加p层11中的B浓度降低。 就此时的热处理温度而言,考虑到绝缘基板的软化点,将热处理温度的上限设定为1250℃,选择700℃为下限值 B可以扩散的温度。
    • 74. 发明申请
    • Method for producing semiconductor substrate
    • 半导体衬底的制造方法
    • US20090111242A1
    • 2009-04-30
    • US12230984
    • 2008-09-09
    • Shoji AkiyamaYoshihiro KubotaAtsuo ItoMakoto KawaiYuuji TobisakaKoichi Tanaka
    • Shoji AkiyamaYoshihiro KubotaAtsuo ItoMakoto KawaiYuuji TobisakaKoichi Tanaka
    • H01L21/762
    • H01L21/76254
    • An object of the present invention is to provide a method by which bonding at a low temperature is possible and an amount of metal contaminants in an SOI film is decreased. An embodiment of the present invention is realized in the following manner. A single crystal silicon substrate 10 surface-activated by a plasma-treatment and a quartz substrate 20 are bonded together at a low temperature, to which an external impact is given to mechanically delaminate silicon film from a single crystal silicon bulk thereby obtaining a semiconductor substrate (SOI substrate) having a silicon film (SOI film) 12. Next, the SOI substrate is subjected to a heat-treatment at a temperature of 600° C. to 1250° C. so that metal impurities accidentally mixed into an interface of the SOI film and the quartz substrate and into the SOI film in such a step as a plasma-treatment are gettered to a surface region of the silicon film 12. Then, in the end, a surface layer (gettering layer) of the silicon film 12 of the SOI substrate after the heat-treatment is removed to finally prepare an SOI film 13 and a semiconductor substrate (SOI substrate) is obtained.
    • 本发明的目的是提供一种可以在低温下进行接合并降低SOI膜中的金属污染物的量的方法。 以下述方式实现本发明的实施例。 通过等离子体处理表面激活的单晶硅衬底10和石英衬底20在低温下被接合在一起,对其进行外部冲击以将硅膜从单晶硅体层剥离,从而获得半导体衬底 (SOI衬底)12。接下来,将SOI衬底在600℃至1250℃的温度下进行热处理,使得金属杂质意外地混入到 SOI膜和石英衬底以及诸如等离子体处理的步骤中的SOI膜被吸收到硅膜12的表面区域。然后,最后,将硅膜12的表面层(吸气层) 的SOI基板,最终制作SOI膜13,得到半导体基板(SOI基板)。
    • 76. 发明申请
    • Method for manufacturing pyrolytic boron nitride composite substrate
    • 制造热解氮化硼复合基板的方法
    • US20080251192A1
    • 2008-10-16
    • US12078276
    • 2008-03-28
    • Makoto KawaiYoshihiro KubotaAtsuo ItoKoichi TanakaYuuji TobisakaShoji Akiyama
    • Makoto KawaiYoshihiro KubotaAtsuo ItoKoichi TanakaYuuji TobisakaShoji Akiyama
    • B32B38/10
    • H01L21/76254C23C14/48
    • Wettability of a PBN material surface with respect to a metal is improved to expand use applications. Hydrogen ions are implanted into a surface of a silicon substrate 10 to form an ion implanted region 11 at a predetermined depth near a surface of the silicon substrate 10, and a plasma treatment or an ozone treatment is performed with respect to a main surface of the silicon substrate 10 for the purpose of surface cleaning or surface activation. The main surfaces of the silicon substrate 10 and a PBN substrate 20 subjected to the surface treatment are appressed against each other to be bonded at a room temperature, and an external impact shock is given to the bonded substrate to mechanically delaminate a silicon film 12 from a bulk 13 of the silicon substrate to be transferred. An obtained PBN composite substrate 30 is diced to form a chip having a desired size, and a refractory metal is metallized on the silicon film 12 side to be connected with a wiring material.
    • PBN材料表面相对于金属的润湿性得到改善以扩大使用应用。 将氢离子注入到硅衬底10的表面中以在硅衬底10的表面附近的预定深度处形成离子注入区11,并且相对于硅衬底10的主表面进行等离子体处理或臭氧处理 硅基板10,用于表面清洁或表面活化。 经过表面处理的硅衬底10和PBN衬底20的主表面在室温下相互粘合,并且对键合衬底施加外部冲击冲击,从而将硅膜12从 待转移的硅衬底的体积13。 将获得的PBN复合基板30切割成具有所需尺寸的芯片,并且将难熔金属在硅膜12侧金属化以与布线材料连接。
    • 79. 发明授权
    • Silicon on insulator (SOI) wafer and process for producing same
    • 绝缘体上硅(SOI)晶片及其制造方法
    • US08703580B2
    • 2014-04-22
    • US12163764
    • 2008-06-27
    • Atsuo ItoYoshihiro KubotaKiyoshi Mitani
    • Atsuo ItoYoshihiro KubotaKiyoshi Mitani
    • H01L21/30H01L21/46
    • H01L21/84H01L21/76254H01L27/1203H01L29/78603
    • In a manufacturing method for manufacturing a silicon on insulator (SOI) wafer, an ion injection layer is formed within the wafer, by injecting a hydrogen ion or a rare gas ion from a surface of the single crystal silicon wafer, the ion injection surface of the single crystal silicon wafer and/or a surface of the transparent insulation substrate is processed using plasma and/or ozone, the ion injection surface of the single crystal silicon wafer is bonded to the surface of the transparent insulation substrate, by bringing them into close contact with each other at room temperature, with the processed surface(s) as bonding surface(s), and an SOI layer is formed on the transparent insulation substrate, by mechanically peeling the single crystal silicon wafer by giving an impact to the ion injection layer.
    • 在制造绝缘体上硅(SOI)晶片的制造方法中,通过从单晶硅晶片的表面注入氢离子或稀有气体离子,在晶片内形成离子注入层,离子注入层 使用等离子体和/或臭氧处理单晶硅晶片和/或透明绝缘基板的表面,通过使单晶硅晶片的离子注入表面接近透明绝缘基板的表面, 在室温下彼此接触,将处理后的表面作为接合表面,并且通过对单晶硅晶片进行机械剥离而对透明绝缘基板形成冲击,形成SOI层 层。