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    • 62. 发明授权
    • Polysiloxane graft copolymer latex for strengthening textile structures
    • 用于加强纺织结构的聚硅氧烷接枝共聚物胶乳
    • US5278228A
    • 1994-01-11
    • US539762
    • 1990-06-18
    • Martin MatnerRaoul ReszHeinrich AlbertsVolker Damrath
    • Martin MatnerRaoul ReszHeinrich AlbertsVolker Damrath
    • C08F283/12C09J151/00C09J151/08D06M13/02D06M13/07D06M13/224D06M13/322D06M13/345D06M13/348D06M15/643D06M15/647C08L51/08
    • C08F283/122D06M15/643
    • A binder for textile structures which are graft copolymer latices in which the following are incroporated in the graft copolymer:(1) as graft substrate, from 40 to 70% by weight, of a polyorganosiloxane end blocked with hydroxyl groups as indicated in the following general formula ##STR1## wherein R.sup.1 denotes alkyl groups having 1 to 24 carbon atoms or aryl groups having 6 to 10 carbon atoms,R.sup.2 denotes divalent alkylene groups having 1 to 8 carbon atoms,R.sup.3 denotes alkyl groups having 1 to 24 carbon atoms, aryl groups, alkoxy groups having 1 to 6 carbon atoms or a hydroxyl group,R.sup.2 and R.sup.3 together with the silicon atom may form a 5 membered or 6 membered ring containing a trivalent unbranched or branched alkyl group having to 8 carbon atoms, anda stands for 80 to 99 mol %,b stands for 1 to 20 mol %, anda+b=100 mol %and the viscosity of the polymer determined at 25.degree. C. is from 100 to 100,000 mPa.s,(2) as grafted vinyl polymer, from 30 to 60% by weight, of styrene and/or .alpha.-methyl styrene, (meth)acrylic acid ester, (meth)-acrylonitrile or mixtures of these monomers and optionally one or more vinyl monomers of the general formula ##STR2## wherein R' denotes a hydrogen atom or a methyl group,R" denotes a alkyl group having 1 to 18 carbon atoms,Y denotes a hydrogen atom or the group OH or OR andZ denotes OH or ##STR3##
    • 用于织物结构的粘合剂是接枝共聚物胶乳,其中以下在接枝共聚物中被覆盖:(1)作为接枝基材,40至70重量%的用羟基封端的聚有机硅氧烷末端,如以下通式所示 式(*化学结构*)其中R1表示具有1至24个碳原子的烷基或具有6至10个碳原子的芳基,R 2表示具有1至8个碳原子的二价亚烷基,R 3表示具有1至24个碳原子的烷基 芳基,碳原子数为1〜6的烷氧基或羟基,R2和R3与硅原子一起形成含有8个碳原子的三价未支链或支链烷基的5元或6元环, 表示80〜99摩尔%,b表示1〜20摩尔%,a + b = 100摩尔%,在25℃下测定的聚合物的粘度为100〜100,000mPa.s,(2)为 接枝乙烯基聚合物,重量比为30至60% 芘和/或(α) - 甲基苯乙烯,(甲基)丙烯酸酯,(甲基)丙烯腈或这些单体的混合物和任选的一种或多种通式(* CHEMICAL STRUCTURE *)的乙烯基单体,其中R'表示 氢原子或甲基,R“表示碳原子数1〜18的烷基,Y表示氢原子或基团OH或OR,Z表示OH或(*化学结构*)
    • 63. 发明授权
    • Electrophotographic light-sensitive material
    • US5229241A
    • 1993-07-20
    • US704560
    • 1991-05-23
    • Eiichi KatoSeishi KasaiKazuo Ishii
    • Eiichi KatoSeishi KasaiKazuo Ishii
    • C08L33/04C08L33/06C08L51/00C08L101/00C09J151/00G03G5/05G03G5/087G03G5/09G03G13/28
    • G03G5/0589G03G5/0592
    • An electrophotographic light-sensitive material comprising a support having provided thereon a photoconductive layer containing at least an inorganic photoconductive substance, a spectral sensitizer and a binder resin, wherein the binder resin contains (1) at least one resin (Resin (A)) having a weight average molecular weight of from 1.times.10.sup.3 to 1.times.10.sup.4 which contains at least 30% by weight of a polymer component represented by the general formula (I) described below and from 0.1 to 10% by weight of a polymer component containing at least one acidic group selected from --PO.sub.3 H.sub.2, --SO.sub.3 H, --COOH, ##STR1## (wherein R represents a hydrocarbon group or --OR' (wherein R' represents a hydrocarbon group), and a cyclic acid anhydride-containing group, and which has at least one acidic group selected from the above-described acidic groups at one terminal of the main chain of the copolymer; ##STR2## wherein a.sub.1 and a.sub.2 each represents a hydrogen atom, a halogen atom, a cyano group or a hydrocarbon group; and R.sub.1 represents a hydrocarbon group; and (2) at least one copolymer (Resin (B)) formed from at least a monofunctional macromonomer (MB) having a weight average molecular weight of not more than 2.times.10.sup.4 and a monomer represented by the general formula (V) described below, the macromonomer (MB) comprising at least a polymer component corresponding to a repeating unit represented by the general formula (IVa) or (IVb) described below, and the macromonomer (MB) having a polymerizable double bond group represented by the general formula (III) described below bonded to only one terminal of the main chain thereof. ##STR3## wherein V.sub.0 represents --COO--, --OCO--, --CH.sub.2 OCO--, --CH.sub.2 COO--, --O--, --SO.sub.2 --, --CO--, --CONHCOO--, --CONHCONH--, --CONHSO.sub.2 --, ##STR4## (wherein P.sub.0 represents a hydrogen atom or a hydrocarbon group); and c.sub.1 and c.sub.2, which may be the same or different, each represents a hydrogen atom, a halogen atom, a cyano group, a hydrocarbon group, --COO--Z.sub.1 or --COO--Z.sub.1 bonded via a hydrocarbon group (wherein Z.sub.1 represents a hydrocarbon group which may be substituted); ##STR5## wherein V.sub.1 has the same meaning as V.sub.0 in the general formula (III); Q.sub.1 represents an aliphatic group having from 1 to 18 carbon atoms or an aromatic group having from 6 to 12 carbon atoms; d.sub.1 and d.sub.2, which may be the same or different, each has the same meaning as c.sub.1 or c.sub.2 in the general formula (III); and Q.sub.0 represents --CN, --CONH.sub.2, or ##STR6## (wherein T represents a hydrogen atom, a halogen atom, a hydrocarbon an alkoxy group, group or --COOZ.sub.2 (wherein Z.sub.2 represents an alkyl group, an aralkyl group, or an aryl group)); wherein V.sub.2 has the same meaning as V.sub.1 in the general formula (IVa); Q.sub.2 has the same meaning as Q.sub.1 in the general formula (IVa); and e.sub.1 and e.sub.2, which may be the same or different, each has the same meaning as c.sub.1 or c.sub.2 in the general formula (III).
    • 64. 发明授权
    • Electrophotographic light-sensitive material
    • US5206105A
    • 1993-04-27
    • US702575
    • 1991-05-20
    • Eiichi Kato
    • Eiichi Kato
    • C08L51/00C08L53/00C09J151/00C09J153/00G03G5/05G03G5/08G03G5/087G03G13/28
    • G03G5/0592G03G5/0589
    • An electrophotographic light-sensitive material comprising a support having provided thereon a photoconductive layer containing at least an inorganic photoconductive substance and a binder resin, wherein the binder resin comprises (A) at least one AB block copolymer (Resin (A)) having a weight average molecular weight of from 1.times.10.sup.3 to 2.times.10.sup.4 and composed of an A block comprising at least one polymer component containing at least one acidic group selected from --PO.sub.3 H.sub.2, --COOH, --SO.sub.3 H, a phenolic hydroxy group, ##STR1## (wherein R represents a hydrocarbon group or --OR' (wherein R' represents a hydrocarbon group)) and a cyclic acid anhydride-containing group, and a B block containing at least a polymer component represented by the following general formula (I): ##STR2## wherein R.sub.1 represents a hydrocarbon group; and (B) at least one graft type copolymer (Resin (B)) having a weight average molecular weight of from 3.times.10.sup.4 to 1.times.10.sup.6 and containing, as a copolymerizable component, at least one monofunctional macromonomer (M) having a weight average molecular weight of from 1.times.10.sup.3 to 2.times.10.sup.4 and comprising an MAB block copolymer composed of an MA block comprising at least one polymer component containing at least one acidic group selected from --PO.sub.3 H.sub.2, --COOH, --SO.sub.3 H, a phenolic hydroxyl group, ##STR3## (wherein R.sub.0 represents a hydrocarbon group or --OR.sub.0 ' (wherein R.sub.0 ' represents a hydrocarbon group)) and a cyclic acid anhydride-containing group, and an MB block containing at least one polymerizable component represented by the general formula (III) described below and having a polymer double bond group bonded to the terminal of the main chain of the MB block polymer: ##STR4## wherein d.sub.1 and d.sub.2 each represents a hydrogen atom, a halogen atom, a cyano group, a hydrocarbon group, --COOR.sub.24 or --COOR.sub.24 bonded via a hydrocarbon group (wherein R.sub.24 represents a hydrocarbon group); X.sub.1 represents --COO--, --OCO--, --CH.sub.2).sub.l1 OCO--, --CH.sub.2).sub.l2 COO--(wherein l.sub.1 and l.sub.2 each represents an integer of from 1 to 3), --O--, --SO.sub.2 --, CO--, ##STR5## (wherein R.sub.23 represents a hydrogen atom or a hydrocarbon group), --CONHCOO--, --CONHCONH--, or ##STR6## and R.sub.21 represents a hydrocarbon group, provided that, when X.sub.1 represents ##STR7## R.sub.21 represents a hydrogen atom or a hydrocarbon group.
    • 67. 发明授权
    • Removable adhesive comprising acrylic microballs, acrylic copolymer and
cross-linker
    • 包含丙烯酸微球,丙烯酸共聚物和交联剂的可移除粘合剂
    • US5128412A
    • 1992-07-07
    • US522509
    • 1990-05-14
    • Hiroyasu MiyasakaYasuaki KitazakiTetsuaki MatsudaJunichi Kobayashi
    • Hiroyasu MiyasakaYasuaki KitazakiTetsuaki MatsudaJunichi Kobayashi
    • C09J151/06C08F8/14C08F8/30C08L33/06C09J133/04C09J133/06C09J151/00
    • C08F8/30C08F8/14C09J133/062C08F2810/20C08L2205/02C08L2205/18C08L33/06C09J2201/606
    • A removable adhesive composition comprising (i) 100 parts by weight of a copolymer (A) which is tacky at ordinary temperature, synthesized of 90 to 99.9% by weight of a nonfunctional vinyl type monomer (a) mainly composed of an acrylate or methacrylate ester having an alkyl group having 2 to 12 carbon atoms and 0.1 to 10% by weight of a functional vinyl type monomer (b) having one or more of a carboxyl group, a hydroxyl group, an amino group or an epoxy group in its molecule; (ii) 20 to 1,000 parts by weight of a copolymer (B) whose glass transition point is 10.degree. C. or less and also having a mean particle diameter of 0.5 to 300 .mu.m, synthesized of 90 to 99.9% by weight of a nonfunctional vinyl type monomer (a) mainly composed of acrylate or methacrylate ester having an alkyl group having 2 to 12 carbon atoms and 0.1 to 10% by weight of an .alpha.-monoolefinic carboxylic acid (c); and (iii) 0.01 to 5 parts by weight of a polyfunctional cross-linking agent (C) which is capable of reacting with the functional groups of said components (b) and (c), and the surfaces of said copolymer (B) being entirely covered with the copolymer (A).The removable adhesive composition of this invention has excellent primary tack, adhesiveness and removability, and which, in particular, can be readily removed from an adherend without leaving any remanent adhesive composition on the adherend and also has excellent adhesiveness.
    • 一种可去除的粘合剂组合物,其包含(i)100重量份在常温下发粘的共聚物(A),合成90至99.9重量%的主要由丙烯酸酯或甲基丙烯酸酯酯组成的非官能的乙烯基型单体(a) 具有2〜12个碳原子的烷基和0.1〜10重量%的分子中具有羧基,羟基,氨基或环氧基中的一个或多个的官能乙烯基类单体(b) (ii)将20〜1000重量份的玻璃化转变点为10℃以下,平均粒径为0.5〜300μm的共聚物(B)合成为90〜99.9重量% 主要由具有2-12个碳原子的烷基的丙烯酸酯或甲基丙烯酸酯和0.1-10重量%的α-单烯烃羧酸(c)组成的非官能的乙烯基型单体(a); 和(iii)0.01至5重量份能够与所述组分(b)和(c)的官能团反应的多官能交联剂(C),所述共聚物(B)的表面为 完全被共聚物(A)覆盖。 本发明的可除去粘合剂组合物具有优异的初粘性,粘合性和可除去性,特别是可以容易地从被粘物除去而不会在被粘物上留下残留的粘合剂组合物,并且还具有优异的粘附性。