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    • 61. 发明授权
    • Polymer scale deposition preventive agent
    • 聚合物垢沉积预防剂
    • US5548039A
    • 1996-08-20
    • US364498
    • 1994-12-27
    • Toshihide ShimizuMikio Watanabe
    • Toshihide ShimizuMikio Watanabe
    • C08F2/00C08F116/12C08F118/04C08F120/06C08F120/10C08F120/44C08F122/06C08F136/04C08F114/106
    • C08F2/004
    • A polymer scale deposition preventive agent for use in polymerization of a monomer having an ethylenically unsaturated double bond, comprising an alkaline solution containing a condensation product of (A) an anthraquinone compound having at least two amino groups and (B) at least one compound selected from the group consisting of benzoquinone compounds and naphthoquinone compounds. When the monomer is polymerized in a polymerization vessel having a coating formed by applying the aforementioned preventive agent to inner wall surfaces followed by drying, polymer scale can be effectively prevented from being deposited not only on the areas located in the liquid-phase region but also on the areas around the interface between the gas and liquid phases in the polymerization vessel. When an obtained polymer is formed into a sheet or the like, it is possible to obtain a formed product having few fish eyes and low initial coloration.
    • 一种用于聚合具有烯键式不饱和双键的单体的聚合物垢沉积防止剂,其包含含有(A)具有至少两个氨基的蒽醌化合物和(B)至少一种选自下列化合物的缩合产物的碱性溶液: 由苯醌化合物和萘醌化合物组成。 当单体在具有通过将上述预防剂施加到内壁表面并随后干燥而形成的涂层的聚合容器中聚合时,可以有效地防止聚合物垢不仅沉积在位于液相区域的区域,而且还沉积在 在聚合容器中的气相和液相之间的界面周围的区域。 当获得的聚合物形成片材等时,可以获得鱼眼少且初始着色低的成形物。
    • 62. 发明授权
    • Superabsorbent acrylic powders prepared via improved suspension
polymerization
    • 通过改进的悬浮聚合制备超吸收性丙烯酸粉末
    • US5408006A
    • 1995-04-18
    • US104756
    • 1993-08-12
    • Shu R. RebreChristian ColletteThierry Guerin
    • Shu R. RebreChristian ColletteThierry Guerin
    • A61L15/60C08F2/18C08F2/32C08F120/00C08F120/06G08F265/02
    • C08F2/32A61L15/60
    • Particulates of a superabsorbent polymer, e.g., an acrylic polymer such as polyacrylic acid, well suited for a variety of hygienic applications, are prepared by (i) suspending an aqueous solution of a water-soluble monomer charge I in a hydrocarbon medium by means of a polymerizable surfactant having the general formula:R.sub.1 --O--(CH.sub.2 --CH.sub.2 --O).sub.n --R.sub.2wherein R.sub.1 is a hydrocarbon having at least 9 carbon atoms, R.sub.2 is an acryloyl, methacryloyl or maleoyl radical, and the degree of condensation n in respect of the ethylene oxide ranges from 30 to 70, (ii) polymerizing the suspension thus formed, producing a suspension of polymer gel particles and converting the surfactant to effectively remove same from the medium of polymerization, (iii) next absorbing a second monomer charge II into such gel particles, and (iv) polymerizing in the gel particles the second monomer charge II.
    • 通过(i)通过(i)将水溶性单体电荷I的水溶液悬浮在烃介质中,通过以下方法制备超吸收聚合物,例如丙烯酸聚合物如聚丙烯酸,例如聚丙烯酸,其适用于各种卫生应用, 具有以下通式的可聚合表面活性剂:R1-O-(CH2-CH2-O)n-R2其中R1是具有至少9个碳原子的烃,R2是丙烯酰基,甲基丙烯酰基或马来酰基,缩合度n 对于环氧乙烷的范围为30至70,(ii)使由此形成的悬浮液聚合,产生聚合物凝胶颗粒的悬浮液并转化表面活性剂以有效地从聚合介质中除去,(iii)接下来吸收第二单体 将电荷II转化成这样的凝胶颗粒,和(iv)在凝胶颗粒中聚合第二单体电荷II。