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    • 62. 发明申请
    • METHOD FOR PRODUCING POLYMER ELECTROLYTE MEMBRANE AND POLYMER ELECTROLYTE MEMBRANE
    • 聚合物电解质膜和聚合物电解质膜的制备方法
    • US20100035113A1
    • 2010-02-11
    • US12516329
    • 2007-11-26
    • Mitsunori Nodono
    • Mitsunori Nodono
    • H01M8/10H01M8/00
    • H01B1/122C08G65/40C08G75/23C08J5/2256C08J2365/02C08J2381/02C08J2387/00C08L65/02C08L81/06C08L2205/05H01M8/1025H01M8/1027H01M8/1032H01M8/1081H01M8/1086Y02P70/56C08L2666/22
    • A method for continuously producing a polymer electrolyte membrane including: (i) a preparation step for preparing a polymer electrolyte solution by dissolving a polymer electrolyte containing an ion conductive polymer having an ion-exchange group in an organic solvent capable of dissolving the polymer electrolyte, (ii) a coating step for continuously obtaining a laminate film 1 wherein a supporting substrate and a layer containing an ion conductive polymer are laminated, by casting the polymer electrolyte solution obtained in the step (i) onto the continuously fed supporting substrate, and (iii) a drying step for continuously obtaining a laminate film 2 wherein the supporting substrate and a polymer electrolyte membrane intermediate are laminated, by removing the organic solvent remaining in the layer containing an ion conductive polymer with passing the laminate film 1 obtained in the step (ii) in a drying furnace; wherein the residence time of the laminate film 1 in the drying furnace in the step (iii) is 50 minutes or shorter and the remaining organic solvent concentration in the polymer electrolyte membrane intermediate in the laminate film 2 immediately after the laminate film 2 passes through the drying furnace is 40% by weight or lower.
    • 一种连续制造聚合物电解质膜的方法,包括:(i)通过将含有离子交换基团的离子导电聚合物的聚合物电解质溶解在能够溶解聚合物电解质的有机溶剂中来制备聚合物电解质溶液的制备步骤, (ii)通过将步骤(i)中得到的高分子电解质溶液浇铸到连续供给的支撑基板上,连续地获得层叠膜1的层叠膜1,其中支撑基板和含有离子导电聚合物的层被层压,并且( iii)干燥步骤,通过将通过步骤获得的层压膜1除去残留在含有离子导电聚合物的层中的有机溶剂,从而连续获得其中支撑基材和聚合物电解质膜中间体的叠层膜2 ii)在干燥炉中; 其中,步骤(iii)中的层压膜1在干燥炉中的停留时间为50分钟以下,层叠膜2之后立即层叠膜2中的高分子电解质膜中间的剩余有机溶剂浓度通过 干燥炉为40重量%以下。
    • 66. 发明申请
    • Process for producing polymer electrolyte emulsion
    • 生产聚合物电解质乳液的方法
    • US20090208810A1
    • 2009-08-20
    • US12309000
    • 2007-06-29
    • Ryuma KurodaShin SaitoHiroyuki KuritaKentaro Masui
    • Ryuma KurodaShin SaitoHiroyuki KuritaKentaro Masui
    • H01M8/10
    • C08J3/07H01M8/0289H01M8/1027H01M8/1032H01M8/1039H01M8/1081Y02P70/56
    • A process for producing a polymer electrolyte emulsion having the following steps (1) and (2) is provided. Step (1): a step of dissolving a polymer electrolyte in a solvent comprising a good solvent for the polymer electrolyte to prepare a polymer electrolyte solution having a polymer electrolyte concentration of 0.1 to 10% by weight. Step (2): a step of mixing the polymer electrolyte solution obtained in the step (1), and a poor solvent for the polymer electrolyte at a ratio of 4 to 99 parts by weight of the poor solvent based on 1 part by weight of the polymer electrolyte solution. In addition, a process for producing a polymer electrolyte emulsion comprising separating a polymer electrolyte dispersion in which a polymer electrolyte particle is dispersed in a dispersing medium, with a membrane is provided.
    • 提供了具有以下步骤(1)和(2)的制备高分子电解质乳液的方法。 工序(1):将聚合物电解质溶解在包含高分子电解质的良溶剂的溶剂中,制备聚合物电解质浓度为0.1〜10重量%的高分子电解质溶液的工序。 步骤(2):将步骤(1)中获得的聚合物电解质溶液与用于聚合物电解质的不良溶剂以4至99重量份的不良溶剂的比例混合,基于1重量份的 聚合物电解质溶液。 此外,提供了一种制备聚合物电解质乳液的方法,其包括用聚合物电解质分散体分散其中聚合物电解质颗粒分散在分散介质中的膜。