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61. 发明申请

US20030060302A1 Highly durable and abrasion resistant composite diamond-like carbon decorative coatings with controllable color for metal substrates 审中-公开
标题翻译：高耐用耐磨复合金刚石碳装饰涂层，金属基材可控制颜色
公开(公告)号：US20030060302A1
公开(公告)日：2003-03-27
申请号：US10151222
申请日：2002-05-20
发明人： Joseph J. Rogers , Rudolph Hugo Petrmichl , Fred Michael Kimock , Victor Michael Zeeman JR. , Joseph David Sydlo
IPC分类号： A63B053/00
CPC分类号： C23C16/006 , A63B53/00 , A63B53/04 , A63B53/0487 , A63B53/12 , A63B60/00 , A63B2053/0416 , A63B2060/004 , A63B2209/02 , C23C16/30 , C23C16/458 , C23C16/509
摘要： Detailed are highly durable and abrasion-resistant composite diamond-like carbon (DLC) coatings with controllable color ideally, but not exclusively, suitable as decorative coatings for metal substrates, for example. The composite DLC coatings typically include at least a layer of Si-DLC which comprises the elements C, H, and Si, and color choices include light yellow, bronze, copper-gold, burgundy, bluish-black, and black.
摘要翻译：详细描述了具有可控颜色的高耐久性和耐磨复合金刚石碳（DLC）涂层，理想地但不排他地适用于例如金属基底的装饰涂层。复合DLC涂层通常包括至少一层包含元素C，H和Si的Si-DLC层，并且颜色选择包括浅黄，青铜，铜 - 金，勃艮第，蓝黑和黑色。

62. 发明申请

US20030054099A1 Condensation coating process 有权
标题翻译：冷凝涂层工艺
公开(公告)号：US20030054099A1
公开(公告)日：2003-03-20
申请号：US10215858
申请日：2002-08-09
发明人： Holger Jurgensen , Johannes Kaeppeler , Gerd Strauch , Dietmar Schmitz
IPC分类号： C23C016/00
CPC分类号： C23C16/45574 , C23C14/0015 , C23C14/12 , C23C14/22 , C23C14/228 , C23C16/006 , C23C16/4481 , C23C16/45565 , C23C16/4557 , C23C16/45572
摘要： A method and device for the production of coated substrates, such as OLEDs is disclosed, whereby at least one layer is deposited on the at least one substrate, by means of a condensation method and a solid and/or fluid precursor and, in particular, at least one sublimate source is used for at least one part of the reaction gases. The invention is characterized in that, by means of a temperature control of the reaction gases between precursor source(s) and substrate, a condensation of the reaction gases before the substrate(s) is avoided.
摘要翻译：公开了用于生产涂覆的基底（例如OLED）的方法和装置，其中至少一层通过缩合方法和固体和/或流体前体沉积在至少一个基底上，特别地，至少一个升华源用于至少一部分反应气体。本发明的特征在于，通过对前体源和基底之间的反应气体的温度控制，避免了反应气体在基底之前的冷凝。

63. 发明授权

US06379798B1 Laminated coated-material for cutting tool 有权
标题翻译：用于切割工具的层压涂层材料
公开(公告)号：US06379798B1
公开(公告)日：2002-04-30
申请号：US09420504
申请日：1999-10-19
申请人： Itsuo Yazaki
发明人： Itsuo Yazaki
IPC分类号： B32B900
CPC分类号： C23C16/006 , C23C14/0015 , C23C16/01 , C23C16/26 , C23C16/308 , C23C16/34 , C23C16/403 , C23C30/005 , Y10T428/30
摘要： There is disclosed a laminated coated-material for cutting tool which comprises a laminated coated-sintered alloy in which on the surface of a substrate comprising a hard alloy or a cermet at least two layers containing an inner layer comprising aluminum oxide and positioned at the substrate side, and an outermost layer having a decorative color and positioned at the far most side of the substrate, and the outermost layer is so coated that it is peeled off by mechanical stress.
摘要翻译：公开了一种用于切割工具的层压涂层材料，其包括层压涂覆烧结合金，其中在包含硬质合金或金属陶瓷的基材的表面上至少包含含有氧化铝的内层并位于基材侧面和具有装饰性颜色并位于基板最远侧的最外层，并且最外层被涂覆以使其被机械应力剥离。

64. 发明申请

US20020032073A1 HIGHLY DURABLE AND ABRASION RESISTANT COMPOSITE DIAMOND-LIKE CARBON DECORATIVE COATINGS WITH CONTROLLABLE COLOR FOR METAL SUBSTRATES 无效
公开(公告)号：US20020032073A1
公开(公告)日：2002-03-14
申请号：US09246976
申请日：1999-02-09
发明人： JOSEPH J. ROGERS , RUDOLPH HUGO PETRMICHL , FRED MICHAEL KIMOCK , VICTOR MICHAEL ZEEMAN JR. , JOSEPH DAVID SYDLO
IPC分类号： A63B053/04
CPC分类号： C23C16/006 , A63B53/00 , A63B53/04 , A63B53/0487 , A63B53/12 , A63B60/00 , A63B2053/0416 , A63B2060/004 , A63B2209/02 , C23C16/30 , C23C16/458 , C23C16/509
摘要： The invention provides a highly durable and abrasion-resistant composite diamond-like carbon coating with controllable color which is ideally suitable as a decorative coating on electrically conductive, e.g. metal, substrates, including architectural hardware and fixtures made of brass and other metals, jewelry, medical and dental instruments, writing instruments such as pens and pencils, musical instruments, eyeglass frames, cigar and cigarette lighters, automobile hood ornaments and other components, sporting equipment and other products for leisure activities such as golf club shafts, golf club heads, cycling equipment, and fishing and hunting equipment, and other similar electrically conductive substrates. The invention also provides the process for depositing a highly adherent, highly abrasion resistant composite diamond-like carbon coating to metal substrates. The invention also provides the process for depositing a highly adherent, highly abrasion resistant composite diamond-like carbon coating to electrically conductive substrates. The composite diamond-like carbon coating structure consists of at least a first layer of Si-DLC which comprises the elements C, H, Si and possibly O and N. An additional coating containing layers of Si-DLC and DLC may be applied over top of the first Si-DLC layer. The optional additional layers of Si-DLC are also containing the elements C, H, Si and possibly O and N. The optional additional layers of DLC contain the elements C, H and possibly N. The decorative and abrasion-resistant composite diamond-like carbon coating is deposited by ion-assisted plasma deposition from carbon-containing and silicon-containing precursor gases consisting of hydrocarbon, silane, organosilane, organosilazane and organo-oxysilicon compounds, or mixtures thereof, and has the properties of Nanoindentation hardness in the range of approximately 5 to 35 GPa, modulus in the range of approximately 50 GPa to 300 GPa, thickness in the range of approximately 1 to 25 micrometers, and colors which can be varied continuously along the spectrum of: light yellow to bronze to copper-gold to burgundy to bluish-black to black, exhibiting reflected light chromaticity coordinate values (Y, x, y) values for Y of approximately 5 to 50, x of approximately 0.25 to 0.50, and for y of approximately 0.25 to 0.45. The elemental composition, refractive index and thickness of the composite diamond-like carbon coating are chosen to produce the desired reflected optical color. The deposition process parameters such as precursor gas composition, plasma power, pressure, and substrate bias voltage are adjusted to produce coatings with different elemental composition and refractive indexes, which change the reflected optical color, and hardness and elastic modulus, which effect the abrasion resistance and durability of the coating.

65. 发明授权

US5427843A Ceramic-coated metal sheet 失效
标题翻译：陶瓷涂层金属板
公开(公告)号：US5427843A
公开(公告)日：1995-06-27
申请号：US270789
申请日：1994-07-05
申请人： Shumpei Miyajima , Wataru Ito , Misao Hashimoto , Isao Ito
发明人： Shumpei Miyajima , Wataru Ito , Misao Hashimoto , Isao Ito
IPC分类号： C23C14/06 , C23C14/08 , C23C14/34 , C23C16/30 , C23C16/32 , C23C16/34 , C23C16/36 , C23C16/40 , C23C28/04 , C23C30/00
CPC分类号： C23C16/006 , C23C14/0015 , C23C14/0635 , C23C14/0641 , C23C14/0664 , C23C14/083 , C23C16/32 , C23C16/34 , C23C16/36 , C23C16/405 , Y10T428/24975 , Y10T428/31678
摘要： A ceramic single layer-coated metal sheet having an excellent decorative property and a high weatherability, which comprises a metal substrate and a transparent ceramic layer formed on the metal substrate by a dry process such as physical vapor deposition or chemical vapor deposition, said transparent ceramic layer having a thickness of 0.05 to 5 .mu.m and a refractive index in the visible region of at least 2.0. A ceramic multiple layer-coated metal sheet having an excellent decorative property and a high weatherability is also disclosed, which further comprises a colored ceramic layer between the substrate and the transparent ceramic layer, the first layer being formed of at least one member selected from the group consisting of nitrides, carbides and carbonitrides of at least one element selected from the group consisting of Ti, Zr, Hf, Cr, Nb and Al and having a thickness of 0.1 to 1 .mu.m.
摘要翻译：一种陶瓷单层涂覆金属片，其具有优异的装饰性和高耐候性，其包括通过诸如物理气相沉积或化学气相沉积的干法在金属基底上形成的金属基底和透明陶瓷层，所述透明陶瓷层的厚度为0.05〜5μm，可见光区域的折射率为2.0以上。还公开了具有优异的装饰性和高耐候性的陶瓷多层涂覆金属片，其还包括在基底和透明陶瓷层之间的着色陶瓷层，第一层由选自以下的至少一种构成：由选自Ti，Zr，Hf，Cr，Nb和Al中的至少一种元素的氮化物，碳化物和碳氮化物组成的组，其厚度为0.1至1μm。

66. 发明授权

US5190807A Abrasion wear resistant polymeric substrate product 失效
标题翻译：耐磨聚合物基材
公开(公告)号：US5190807A
公开(公告)日：1993-03-02
申请号：US600210
申请日：1990-10-18
申请人： Fred M. Kimock , Bradley J. Knapp , Steven J. Finke
发明人： Fred M. Kimock , Bradley J. Knapp , Steven J. Finke
IPC分类号： B32B7/02 , B32B9/00 , C23C16/02 , C23C16/26 , C23C16/27 , G02B1/04 , G02B1/10 , G02C7/02
CPC分类号： C23C16/006 , C23C16/0272 , C23C16/26 , G02B1/105 , Y10S428/913 , Y10T428/24975 , Y10T428/265 , Y10T428/30 , Y10T428/31663 , Y10T428/31678
摘要： A substantially optically transparent coated substrate product with a highly adherent, abrasion-resistant diamond-like hard carbon coating is disclosed. The substrate product is comprised of a polymeric substrate, an adhesion-mediating polysiloxane polymer layer, one or more intermediate layers and an outer layer of diamond-like hard carbon. In another embodiment of the invention a thin metallic interlayer is disposed between a first interlayer layer and subsequent interlayers and/or diamond-like hard carbon. The invention also allows for the production of adherent thin film interference layer coatings (i.e. quarter wavelength stacks and anti-reflection coatings) using diamond-like hard carbon as the high refractive index layer and the interlayer(s) as the low refractive index layer or, alternatively, using diamond-like hard carbon as the low refractive index layer and the interlayer(s) as the high refractive index layer. The invention further discloses a method for fabricating the coated substrate product. The substrate product, exhibiting excellent resistance to abrasion and chemical attack, is particularly useful for commercial plastic articles such as optical lenses and sunglass lenses made of polycarbonate, CR-39.RTM., or acrylic plastics.
摘要翻译：公开了具有高粘附性，耐磨损的类金刚石硬质碳涂层的基本上光学透明的涂覆基材产品。基底产品由聚合物基底，粘附介导性聚硅氧烷聚合物层，一个或多个中间层和金刚石状硬碳外层组成。在本发明的另一个实施方案中，薄金属中间层设置在第一中间层和随后的夹层和/或类金刚石硬碳之间。本发明还允许使用金刚石状硬碳作为高折射率层和作为低折射率层的中间层来制造粘附薄膜干涉层涂层（即四分之一波长叠层和抗反射涂层），或，或者，使用类金刚石硬碳作为低折射率层和中间层作为高折射率层。本发明还公开了一种用于制造涂覆的基底产品的方法。表现出优异的抗磨损和化学侵蚀性的基材产品对于诸如由聚碳酸酯，CR-39 TM或丙烯酸塑料制成的光学透镜和太阳眼镜片的商业塑料制品特别有用。

67. 发明申请

US20180235328A1 MULTI-COATED METALLIC PRODUCTS AND METHODS OF MAKING THE SAME 审中-公开
公开(公告)号：US20180235328A1
公开(公告)日：2018-08-23
申请号：US15960116
申请日：2018-04-23
申请人： Frederick Goldman, Inc.
发明人： Andrew Derrig
IPC分类号： A44C27/00 , A44B15/00
CPC分类号： A44C27/002 , A44B15/00 , A44B15/005 , A44C5/00 , A44C7/00 , A44C9/00 , A44C15/0035 , A44C15/005 , A44C15/0065 , A44C15/009 , A44C25/001 , A44C25/007 , A44C27/006 , A45C1/06 , A45C2001/062 , C23C14/0015 , C23C14/14 , C23C14/22 , C23C16/006 , C23C16/06 , C23C16/44 , Y10T24/1379 , Y10T24/202 , Y10T29/49588 , Y10T428/12493 , Y10T428/12576 , Y10T428/12708 , Y10T428/12736 , Y10T428/12743 , Y10T428/1275 , Y10T428/12757 , Y10T428/12778 , Y10T428/12792 , Y10T428/12806 , Y10T428/12819 , Y10T428/12826 , Y10T428/1284 , Y10T428/12861 , Y10T428/12875 , Y10T428/12889 , Y10T428/12896 , Y10T428/12944 , Y10T428/12951 , Y10T428/12979 , Y10T428/265 , Y10T428/31678 , Y10T442/2098
摘要： The present invention relates generally to a coated jewelry article or a coated component of a jewelry article, comprising a jewelry article or a component of a jewelry article, a first metallic coating, and a second metallic coating.

68. 发明授权

US09949538B2 Multi-coated metallic products and methods of making the same 有权
公开(公告)号：US09949538B2
公开(公告)日：2018-04-24
申请号：US14589924
申请日：2015-01-05
申请人： Frederick Goldman, Inc.
发明人： Andrew Derrig
IPC分类号： A44C15/00 , A44C27/00 , C23C14/00 , C23C16/00 , A44B15/00 , A44C5/00 , A44C7/00 , A44C9/00 , A44C25/00 , A45C1/06 , C23C14/14 , C23C14/22 , C23C16/06 , C23C16/44
CPC分类号： A44C27/002 , A44B15/00 , A44B15/005 , A44C5/00 , A44C7/00 , A44C9/00 , A44C15/0035 , A44C15/005 , A44C15/0065 , A44C15/009 , A44C25/001 , A44C25/007 , A44C27/006 , A45C1/06 , A45C2001/062 , C23C14/0015 , C23C14/14 , C23C14/22 , C23C16/006 , C23C16/06 , C23C16/44 , Y10T24/1379 , Y10T24/202 , Y10T29/49588 , Y10T428/12493 , Y10T428/12576 , Y10T428/12708 , Y10T428/12736 , Y10T428/12743 , Y10T428/1275 , Y10T428/12757 , Y10T428/12778 , Y10T428/12792 , Y10T428/12806 , Y10T428/12819 , Y10T428/12826 , Y10T428/1284 , Y10T428/12861 , Y10T428/12875 , Y10T428/12889 , Y10T428/12896 , Y10T428/12944 , Y10T428/12951 , Y10T428/12979 , Y10T428/265 , Y10T428/31678 , Y10T442/2098
摘要： The present invention relates generally to a coated jewelry article or a coated component of a jewelry article, comprising a jewelry article or a component of a jewelry article, a first metallic coating, and a second metallic coating.

69. 发明授权

US09790592B2 Decorative article having black hard coating film 有权
公开(公告)号：US09790592B2
公开(公告)日：2017-10-17
申请号：US14779375
申请日：2014-03-19
申请人： CITIZEN HOLDINGS CO., LTD. , CITIZEN WATCH CO., LTD.
发明人： Osamu Tanaka
IPC分类号： C23C16/27 , C23C16/26 , C23C16/00 , C23C16/513 , C23C16/52
CPC分类号： C23C16/26 , C23C16/006 , C23C16/513 , C23C16/52
摘要： Provided is a decorative article including a black hard coating film which is excellently inhibited from suffering a deterioration of appearance quality such as a scratch due to use thereof, and which has excellent decorativeness. The decorative article according to the present invention is a decorative article including: a base; and a black hard coating film which is formed on the base, and which includes diamond-like carbon, wherein the hydrogen content of a surface, reverse to a surface closer to the base, of the black hard coating film is more than the hydrogen content of the surface, closer to the base, of the black hard coating film; and the hydrogen content of the surface, reverse to the surface closer to the base, of the black hard coating film is 30.0 to 75.0 atm %.

70. 发明授权

US09534291B2 DLC coating with run-in layer 有权
标题翻译： DLC涂层带有渗入层
公开(公告)号：US09534291B2
公开(公告)日：2017-01-03
申请号：US14769452
申请日：2014-02-10
申请人： OERLIKON TRADING AG, TRÜBBACH
发明人： Sebastien Guimond , Manfred Wurzer , Franz Widowitz
IPC分类号： C23C16/02 , C23C16/26 , C23C16/00 , C23C16/455 , C09D1/00 , C23C16/50
CPC分类号： C23C16/26 , C09D1/00 , C23C16/006 , C23C16/0272 , C23C16/45523 , C23C16/50
摘要： A coating that resists wear; first, at least one DLC layer with a high degree of hardness is applied to a component and then a gradient layer, whose density decreases in the direction toward the surface, is applied to this DLC layer. By means of the hardness progression that this produces in the gradient layer, the gradient layer functions as a run-in layer in applications with sliding surfaces.
摘要翻译：耐磨损的涂层; 首先，将具有高硬度的至少一个DLC层施加到部件上，然后将其密度沿着朝向表面的方向减小的梯度层施加到该DLC层。通过在梯度层中产生的硬度进程，梯度层在具有滑动表面的应用中用作渗入层。

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