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    • 61. 发明授权
    • Outer layer material having entanglement of hydrophobic polymer hostblended with a maleated hydrophobic polymer co-host, and hydrophilic polymer guest
    • 外层材料具有与马来酸化疏水性聚合物共主体共混的疏水性聚合物和亲水性聚合物客体的缠结
    • US08524884B2
    • 2013-09-03
    • US12148598
    • 2008-04-21
    • Susan P. JamesMin ZhangGuy BeauregardRachael Kurkowski Oldinski
    • Susan P. JamesMin ZhangGuy BeauregardRachael Kurkowski Oldinski
    • C07H5/04C07H1/00
    • C08J3/246A61L31/048C08B37/00C08B37/0072C08J9/42C08J2323/06C08J2405/08C08L5/08Y10T428/249953C08L2666/02C08L101/00C08L2666/26
    • An outer layer material having an entanglement comprising an intermingling of cloaked hydrophilic guest and a hydrophobic polymer host, wherein molecules of the guest have been crosslinked with each other. Under certain circumstances, using complexes of the guest may be desirable or even necessary. Prior to intermingling with the guest, a host blend may be produced to include a physical blend of a hydrophobic polymer host and a maleated hydrophobic co-host (preferably, an anhydride functionalized hydrophobic polymer, whereby the polymer so functionalized, is the same as that selected for the host). The intermingling of the guest and host, or host-co-host blend, includes a physical tangling, whether it also comprises crosslinking by primary bonding (e.g., chemical/covalent bonding) there-between. Also a method of producing an outer layer material having such an entanglement, including the steps of: temporarily cloaking at least a portion of the hydrophilic groups of the guest; intermingling at least a portion of the cloaked groups with a porous polymeric structure by diffusing the guest with cloaked groups into at least a portion of the structure's pores; within the pores, crosslinking at least a portion of the molecules of the guest with the guest; and removing the cloaking. Cloaking may be performed by silylation or acylation. Intermingling may be performed by producing a mixture of guest and host, or host blend, (whether in solution, powdered, granular, etc., form); next, a crosslinking of the guest with itself is performed; then, the mixture is molded into the outer layer with or without additional crosslinking of the host to the host.
    • 具有缠结的外层材料,其包含掩蔽的亲水性客体和疏水性聚合物主体的混合物,其中客体的分子彼此交联。 在某些情况下,使用客人的复合物可能是理想的或甚至是必需的。 在与客体混合之前,可以制备主体共混物以包括疏水性聚合物主体和马来酸化疏水性共主体的物理共混物(优选为酸酐官能化的疏水性聚合物,由此使官能化的聚合物与之相同) 为主机选择)。 客体和宿主或宿主 - 共同宿主混合物的混合包括物理缠结,不管其是否还包括通过其间的初次键合(例如,化学/共价键合)的交联。 还有一种制造具有这种缠结的外层材料的方法,包括以下步骤:暂时掩蔽客体的至少一部分亲水基团; 通过将具有掩蔽基团的客体扩散到结构的孔的至少一部分中来将具有多孔聚合物结构的至少一部分掩蔽组混合; 在孔内,与客体交联客体的至少一部分分子; 并去除隐形。 掩蔽可以通过甲硅烷基化或酰化进行。 混合可以通过生产客体和主体或主体混合物的混合物(无论是溶液,粉末状,颗粒状等)形式进行; 接下来,进行客人与其自身的交联; 然后,将该混合物模塑到外层中,该主体与主体有或没有额外的交联。
    • 67. 发明申请
    • THERMOPLASTIC ELASTOMER COMPOSITION
    • 热塑性弹性体组合物
    • US20130059978A1
    • 2013-03-07
    • US13597931
    • 2012-08-29
    • Ryosuke KUROKAWANobuhiro NATSUYAMA
    • Ryosuke KUROKAWANobuhiro NATSUYAMA
    • C08L19/00C08L37/00C08L33/02C08L23/14C08L23/12
    • C08L23/0815C08J3/246C08J2323/08C08J2323/12C08L23/10C08L51/06C08L67/08C08L2205/035C08L2312/00
    • Disclosed is a thermoplastic elastomer composition that will provide little load on the environment and has superior mechanical characteristics, the composition being obtained by melt-kneading 10 to 90 parts of ethylene-α-olefin based copolymer rubber (A), 1 to 50 parts of non-petroleum source-derived thermoplastic resin (B), 1 to 50 parts of modified propylene-based copolymer (C), 1 to 50 parts of propylene-based polymer (D), 0.001 to 5 parts of crosslinking agent (E), and 0 to 50 parts of mineral oil-based softening agent (F), wherein the amounts of components (A), (B), (C), (D), and (F) are amounts in weight calculated where the combined amount of components (A), (B), (C), (D) and (F) is considered to be 100 parts by weight, and the amount of component (E) is an amount in weight calculated where the combined amount of components (A), (B), (C), (D), and (F) is considered to be 100 parts by weight.
    • 公开了一种热塑性弹性体组合物,其对环境的负荷很小,并且具有优异的机械特性,该组合物通过将10至90份乙烯-α-烯烃基共聚物橡胶(A)熔融捏合而获得,1至50份 非石油源系热塑性树脂(B),1〜50份改性丙烯类共聚物(C),1〜50份丙烯类聚合物(D),0.001〜5份交联剂(E), 和0〜50份矿物油性软化剂(F),其中组分(A),(B),(C),(D)和(F)的量是计算的重量, 的组分(A),(B),(C),(D)和(F)被认为是100重量份,并且组分(E)的量是当组分 (A),(B),(C),(D)和(F))为100重量份。
    • 68. 发明申请
    • THERMOPLASTIC ELASTOMER COMPOSITION
    • 热塑性弹性体组合物
    • US20130059977A1
    • 2013-03-07
    • US13597886
    • 2012-08-29
    • Ryosuke KUROKAWANobuhiro NATSUYAMA
    • Ryosuke KUROKAWANobuhiro NATSUYAMA
    • C08L23/08C08L23/12C08L37/00C08L67/04
    • C08L23/0815C08J3/246C08J2323/08C08J2323/12C08L23/02C08L23/10C08L51/06C08L2205/035
    • Disclosed is a thermoplastic elastomer composition that will provide little load on the environment and has superior mechanical characteristics, the composition being obtained by melt-kneading 10 to 90 parts of ethylene-α-olefin based copolymer rubber (A), 1 to 50 parts of non-petroleum source-derived thermoplastic resin (B), 0.01 to 20 parts of modified ethylene-based copolymer (C), 1 to 50 parts of propylene-based polymer (D), 0.001 to 5 parts of crosslinking agent (E), and 0 to 50 parts of a mineral oil-based softening agent (F), wherein the amounts of components (A), (B), (D) and (F) are amounts in weight calculated where the total amount of components (A), (B), (D) and (F) is considered to be 100 parts, and the amounts of components (C) and (E) are amounts in weight calculated where the total amount of components (A), (B), (D) and (F) is considered to be 100 parts.
    • 公开了一种热塑性弹性体组合物,其对环境的负荷很小,并且具有优异的机械特性,该组合物通过将10至90份乙烯-α-烯烃基共聚物橡胶(A)熔融捏合而获得,1至50份 非石油源系热塑性树脂(B),0.01〜20份改性乙烯类共聚物(C),1〜50份丙烯类聚合物(D),0.001〜5份交联剂(E), 和0〜50份矿物油性软化剂(F),其中组分(A),(B),(D)和(F)的量是以组分(A ),(B),(D)和(F)被认为是100份,组分(C)和(E)的量是按组分(A),(B) ,(D)和(F)被认为是100份。