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    • 63. 发明授权
    • Method for preparation of anisotropic materials
    • 各向异性材料的制备方法
    • US07910181B2
    • 2011-03-22
    • US12214578
    • 2008-06-19
    • Patricia A. BeckSean Zhang
    • Patricia A. BeckSean Zhang
    • C09K19/00
    • G11B7/244C08G61/02C08G61/10C08G61/123C08G73/18C08G73/22C08J3/24G02F1/15G11B7/245G11B7/246G11B7/249G11B7/25Y10T428/1005Y10T428/1009Y10T428/1041Y10T428/1082Y10T428/1157Y10T428/2809
    • Various embodiments of the present invention are directed to methods for manufacturing complex, anisotropic materials with desirable properties for information storage, processing, and display. Certain of these methods involve employing a magnetic field during manufacture to induce desired orientations of precursors, subunits, and/or molecular subassemblies. The applied magnetic field steers the precursors, subunits, and/or molecular subassemblies into desirable orientations while the precursors, subunits, and/or molecular subassemblies are assembled or self-assemble into a complex, anisotropic material. One embodiment of the present invention is a class of new, complex, well-ordered, network-like materials that include a ferromagnetic-material-based framework in which organic and/or organometallic compounds are organized. The ferromagnetic-molecule-based framework provides a scaffold for assembling the stable, precisely separated layers of organic and/or organometallic compounds and maintaining the layers of organic and/or organometallic compounds in well-ordered, anisotropic arrangements. Additional embodiments of the present invention are directed to methods for manufacturing the new ferromagnetic-molecule-based, network-like materials.
    • 本发明的各种实施方案涉及用于制造具有用于信息存储,处理和显示的所需特性的复杂的各向异性材料的方法。 这些方法中的某些涉及在制造过程中采用磁场来诱导前体,亚基和/或分子子组件的所需取向。 施加的磁场将前体,亚基和/或分子子组件转向所需的取向,同时将前体,亚基和/或分子子组件组装或自组装成复杂的各向异性材料。 本发明的一个实施方案是一类新的,复杂的,有序的网状材料,其包括其中组织有机和/或有机金属化合物的基于铁磁材料的框架。 基于铁磁分子的框架提供了用于组装稳定且精确分离的有机和/或有机金属化合物层的支架,并且将有机和/或有机金属化合物层保持在有秩序的各向异性布置中。 本发明的另外的实施方案涉及用于制造新的基于铁磁分子的网络状材料的方法。
    • 70. 发明授权
    • Aromatic polymer and producing method thereof
    • 芳香族聚合物及其制造方法
    • US07718757B2
    • 2010-05-18
    • US11920168
    • 2006-05-08
    • Shigeki HabaueSoichiro MurakamiHideyuki Higashimura
    • Shigeki HabaueSoichiro MurakamiHideyuki Higashimura
    • C08G65/38C08G63/00
    • C08G61/10
    • An aromatic polymer, containing a repeating unit represented by Formula (I), and having properties (A1) and (B1): (A1) the number average degree of polymerization of an acetylated product obtained by acetylation of the hydroxyl groups of the polymer is 3 or more, and (B1) at a wavelength where an absolute value of molar ellipticity (degree·cm−2·dmol−1) per mole of the repeating unit of the acetylated product in a circular dichroism spectrum of the acetylated product reaches maximum in a wavelength range of from 200 to 350 nm, the absolute value is 50,000 or more: wherein R represents a hydrocarbon, hydrocarbon-oxy, hydrocarbon-mercapto or hydrocarbon-amino group that may be substituted; the two R's may bind to each other to form a ring; and the repeating unit represented by Formula (I) has no symmetrical plane that has two binding sites and that is perpendicular for the benzene ring.
    • 含有由式(I)表示的重复单元,具有(A1)和(B1)性质的芳族聚合物:(A1)通过聚合物的羟基乙酰化得到的乙酰化产物的数均聚合度为 3以上,并且在乙酰化产物的圆二色谱中每摩尔乙酰化产物的重复单元的绝对摩尔数椭圆率(度·cm-2·dmol-1)的波长的(B1)达到最大 在200〜350nm的波长范围内,绝对值为50,000以上:其中R表示可被取代的烃,烃 - 氧,烃 - 巯基或烃 - 氨基; 两个R可以彼此结合形成环; 并且由式(I)表示的重复单元没有对称平面,其具有两个结合位点,并且与苯环垂直。