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    • 62. 发明授权
    • Corrosion barrier coating composition
    • 防腐涂料组合物
    • US06323264B1
    • 2001-11-27
    • US09434192
    • 1999-11-04
    • Nikolay NazaryanStanley S. OrkinGlen Greenberg
    • Nikolay NazaryanStanley S. OrkinGlen Greenberg
    • C08K310
    • C08K3/24C08G59/38C08K3/40C09D163/00C08L63/00C08L2666/04
    • The present invention is directed to a corrosion barrier coating composition, comprising an admixture of: (1) about 60 to about 95 wt % of a one-component epoxy resin composition comprising (a) about 10-30% by weight of 4-glycidyloxy, n,n-diglycidyl aniline; (b) about 30-60% by weight of an epoxy resin, wherein the epoxy resin is epichlorohydrin ether of bisphenol A; and (c) about 3-7% by weight of strontium chromate; (2) about 1 to about 30 wt % of polytetrafluoroethylene; and (3) about 1 to about 20 wt % of glass powder, all weight percents being based on the total weight of the composition. The present invention is also directed to a substrate coated with the above corrosion barrier coating composition, and a method of coating a substrate with the above composition.
    • 本发明涉及一种防腐涂料组合物,其包含以下混合物:(1)约60至约95重量%的单组分环氧树脂组合物,其包含(a)约10-30重量%的4-缩水甘油氧基 ,n,n-二缩水甘油基苯胺; (b)约30-60重量%的环氧树脂,其中环氧树脂是双酚A的表氯醇醚; 和(c)约3-7重量%的铬酸锶; (2)约1至约30重量%的聚四氟乙烯; 和(3)约1至约20重量%的玻璃粉末,所有重量百分比均基于组合物的总重量。 本发明还涉及涂覆有上述防腐涂料组合物的基材以及用上述组合物涂布基材的方法。
    • 63. 发明申请
    • Curable two-component mortar composition and its use
    • 可固化的双组分砂浆组成及其用途
    • US20010035111A1
    • 2001-11-01
    • US09765143
    • 2001-01-18
    • Roland GienauSascha DierkerMechthild Krauter
    • C04B007/32C04B007/02C04B024/00
    • C04B40/065C04B26/14C08G59/38C08G59/50C08L63/00C04B7/00
    • A curable, two-component mortar composition is described, which is based on a curable epoxide resin, at least one reactive diluent for the epoxide resin, an amine curing agent and one or more inorganic fillers, as well as, optionally, curing catalysts, rheological aids, thixotropizing agents, stabilizers, dispersants, agents to control the reaction rate and wetting agents, the amine curing agent of the curable epoxide resin and the reactive diluent being kept separate from one another to inhibit any reaction, wherein the mortar composition contains a cross-linking reactive diluent, which has functional epoxy groups with an epoxy functionality of at least 2. The mortar composition is used to fasten anchoring means in boreholes.
    • 描述了可固化的双组分砂浆组合物,其基于可固化的环氧树脂,至少一种用于环氧树脂的反应性稀释剂,胺固化剂和一种或多种无机填料,以及任选的固化催化剂, 流变助剂,触变剂,稳定剂,分散剂,控制反应速率和润湿剂的试剂,可固化环氧树脂的胺固化剂和反应性稀释剂彼此分离以抑制任何反应,其中砂浆组合物含有 交联反应性稀释剂,其具有至少为2的环氧官能团的官能环氧基团。砂浆组合物用于将锚固装置固定在钻孔中。
    • 65. 发明授权
    • Composition for photoimaging
    • 光成像用组合物
    • US06210862B1
    • 2001-04-03
    • US09150824
    • 1998-09-10
    • Richard Allen DayDavid John RussellDonald Herman Glatzel
    • Richard Allen DayDavid John RussellDonald Herman Glatzel
    • G03F7004
    • C08G59/38C08G59/687G03F7/038G03F7/0385H05K3/287Y10S428/901
    • According to the present invention, an improved photoimagable cationically polymerizable epoxy based solder mask is provided that contains a non-brominated epoxy resin system and from about 0.1 to about 15 parts, by weight per 100 parts of resin system, of a cationic photoinitiator. The non-brominated epoxy-resin system has solids that are comprised of from about 10% to about 80% by weight, of a polyol resin having epoxy functionality; from about 0% to about 90% by weight of a polyepoxy resin; and from about 25% to about 85% by weight of an difunctional epoxy resin. Since the photosensitive cationically polymerizable epoxy based solder mask does not contain bromine, it is particularly advantageous halogens in waste processing chemicals or in incinerated scrap circuit boards are regulated by environmental concerns. The photosensitive cationically polymerizable non-brominated epoxy based solder mask has a glass transition temperature greater than about 100° C., preferably greater than about 110° C. The solder mask dries to a tack-free film; thus, artwork used in the photoimaging process will not stick to the dried soldermask film. The polyol resin which is a condensation product of epichlorohydrin and bisphenol A, has a weight average molecular weight of between about 40,000 and 130,000. The polyepoxy resin is an epoxidized multi-functional bisphenol A formaldehyde novolak resin having a weight average molecular weight of 4,000 to 10,000. The epoxidized diglycidyl ether of bisphenol A has two epoxide groups per molecule, a melting point of between about 80° C. and about 110° C. and a weight average molecular weight of between about 600 and 2,500. The invention also relates to a cationically polymerized solder mask.
    • 根据本发明,提供了一种改进的可光成像的可阳离子聚合的环氧基焊接掩模,其包含非溴化环氧树脂体系和每100份树脂体系约0.1至约15重量份的阳离子光引发剂。 非溴化环氧树脂体系具有由约10重量%至约80重量%的具有环氧官能团的多元醇树脂组成的固体; 约0重量%至约90重量%的聚环氧树脂; 和约25重量%至约85重量%的双官能环氧树脂。 由于光敏阳离子聚合型环氧基焊接掩模不含溴,所以特别有利的是废物处理化学品中的卤素或焚烧废料电路板中的卤素受到环境问题的限制。 光敏阳离子聚合的非溴化环氧基焊料掩模具有大于约100℃,优选大于约110℃的玻璃化转变温度。焊料掩模干燥成无粘性膜; 因此,在光成像过程中使用的艺术品不会粘附在干燥的焊接膜上。 作为表氯醇和双酚A的缩合物的多元醇树脂的重均分子量为约40,000〜130,000。 聚环氧树脂是重均分子量为4000〜10000的环氧化多官能双酚A甲醛酚醛清漆树脂。 双酚A的环氧化二缩水甘油醚每分子具有两个环氧基团,熔点在约80℃至约110℃之间,重均分子量约为600-2,500。 本发明还涉及阳离子聚合的焊接掩模。
    • 66. 发明授权
    • Curable composition comprising epoxidized natural oils
    • 包含环氧化天然油的可固化组合物
    • US06194490B1
    • 2001-02-27
    • US09253162
    • 1999-02-19
    • Martin RothQian TangRoger MalherbeCatherine Schoenenberger
    • Martin RothQian TangRoger MalherbeCatherine Schoenenberger
    • C08K336
    • C08L63/00C08G59/38C08G59/42C08G59/686
    • A composition, which comprises (a) a compound containing at least one epoxy group in inner position per molecule, obtained by epoxidation of a natural unsaturated oil or of its derivative; (b) an epoxy compound selected from the group consisting of glycidyl ethers, glycidyl esters and cycloaliphatic epoxides; (c) a polycarboxylic acid anhydride; (d) a compound of formula I, I, III or IV or an acid adduct of a compound of formula I, II, III or IV  wherein R1 to R4 are each independently of one another hydrogen; C1-C18alkyl which is unsubstituted or substituted by one or more than one hydroxyl group amino group, halogen atom, cyano group, C1-C6alkoxy group or C1-C6cyanalkoxy group; C5-C14aryl, C6-C24aralkyl, C3-C14heteroaryl or C4-C14heteroaralkyl which are unsubstituted or substituted by one or more than one C1-C6alkyl group, C1-C6alkoxy group or halogen atom,  n is an integer from 1 to 3, and  R5 and R6 are each independently of the other C1-C6alkyl or, together with the nitrogen atom, form a five- or six-membered ring, and (e) 20-90% by weight, based on the entire composition, of a filler, the average diameter of the filler particles being from 0.1 &mgr;m to 5.0 mm, can be cured to products having a high Tg and are suitable in particular as encapsulating material for electrical and electronic components.
    • 一种组合物,其包含(a)通过天然不饱和油或其衍生物的环氧化获得的每分子含有至少一个内部位置的环氧基的化合物;(b)选自缩水甘油醚, 缩水甘油酯和环脂族环氧化物;(c)多元羧酸酐;(d)式I,I,III或IV的化合物或式I,II,III或IV化合物的酸加合物,其中R 1至R 4各自 独立于氢; 未被取代或被一个或多于一个羟基氨基,卤素原子,氰基,C 1 -C 6烷氧基或C 1 -C 6氰基烷氧基取代的C 1 -C 18烷基; 未被取代或被一个或多于一个C 1 -C 6烷基,C 1 -C 6烷氧基或卤素原子取代的C 5 -C 14芳基,C 6 -C 24芳烷基,C 3 -C 14杂芳基或C 4 -C 14杂芳烷基,n为1至3的整数,R 5 和R 6各自独立地为其它C 1 -C 6烷基,或者与氮原子一起形成五元或六元环,和(e)基于整个组合物的20-90重量%的填料, 填料颗粒的平均直径为0.1μm至5.0mm,可以固化成具有高Tg的产品,并且特别适合用作电气和电子部件的包封材料。