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61. 发明授权

US06784135B2 Thermal regulating catalyst composition 有权
标题翻译：热调节催化剂组成
公开(公告)号：US06784135B2
公开(公告)日：2004-08-31
申请号：US10348460
申请日：2003-01-21
申请人： Anton Scholten , Peter F. M. T. Van Nisselrooy , Walter R. De Jongh , Jan Stokman
发明人： Anton Scholten , Peter F. M. T. Van Nisselrooy , Walter R. De Jongh , Jan Stokman
IPC分类号： B01J2108
CPC分类号： H01M8/0631 , B01J8/043 , B01J8/0453 , B01J8/0492 , B01J8/0496 , B01J12/007 , B01J23/80 , B01J29/06 , B01J29/082 , B01J35/0006 , B01J2208/00212 , B01J2208/00495 , B01J2208/0053 , B01J2219/185 , C01B3/16 , C01B3/386 , C01B3/48 , C01B3/58 , C01B3/583 , C01B2203/0261 , C01B2203/0294 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0838 , C01B2203/0844 , C01B2203/085 , C01B2203/0866 , C01B2203/0883 , C01B2203/0894 , C01B2203/1011 , C01B2203/1023 , C01B2203/1041 , C01B2203/1047 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1094 , C01B2203/1241 , C01B2203/1258 , C01B2203/1288 , C01B2203/1294 , C01B2203/1623 , C01B2203/1647 , C01B2203/169 , C01B2203/80 , C01B2203/82 , Y02P20/52
摘要： A composition is provided that can be used, for example, in a fuel processor for a fuel cell system. The composition includes a first material such as a catalyst, and a second material such as a desiccant. The second material is capable of sorbing and desorbing a heat transfer material such as water, and is present in an amount sufficient to sorb an amount of the heat transfer material sufficient to remove a portion of the heat generated when the first material undergoes an exothermic reaction.
摘要翻译：提供了可用于例如用于燃料电池系统的燃料处理器中的组合物。该组合物包括第一种材料如催化剂和第二种材料如干燥剂。第二种材料能够吸附和解吸诸如水的传热材料，并且以足以吸附一定量的传热材料的量存在，足以去除第一种材料发生放热反应产生的一部分热量。

62. 发明授权

US06783741B2 Fuel processing system 有权
标题翻译：燃油加工系统
公开(公告)号：US06783741B2
公开(公告)日：2004-08-31
申请号：US09839997
申请日：2001-04-20
申请人： David J. Edlund , William A. Pledger
发明人： David J. Edlund , William A. Pledger
IPC分类号： B01J1000
CPC分类号： B01J8/0465 , B01J8/009 , B01J8/0469 , B01J8/0496 , B01J8/062 , B01J8/067 , B01J2208/00061 , B01J2208/00106 , B01J2208/00309 , B01J2208/00415 , B01J2208/00495 , B01J2208/0053 , B01J2208/00539 , B01J2208/00548 , C01B3/323 , C01B3/382 , C01B3/503 , C01B3/586 , C01B2203/0233 , C01B2203/041 , C01B2203/0445 , C01B2203/047 , C01B2203/0475 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/085 , C01B2203/0866 , C01B2203/1011 , C01B2203/1058 , C01B2203/1076 , C01B2203/1217 , C01B2203/1223 , C01B2203/1247 , C01B2203/1288 , C01B2203/142 , C01B2203/146 , C01B2203/1628 , C01B2203/1633 , C01B2203/82 , Y02P20/128
摘要： A fuel processing system is disclosed. The system includes a steam reformer adapted to produce hydrogen from a feedstock consisting of water and at least one of an alcohol and a hydrocarbon feedstock. The feedstock is exposed to one or more reformation regions including a reformation catalyst and to a membrane region including at least one hydrogen-selective membrane.
摘要翻译：公开了一种燃料处理系统。该系统包括适于从由水和至少一种醇和烃原料组成的原料产生氢的蒸汽重整器。原料暴露于一个或多个重整区，包括重整催化剂和包含至少一个氢选择性膜的膜区。

63. 发明申请

US20040161381A1 Process and reactor for carrying out non-adiabatic catalytic reactions 审中-公开
标题翻译：用于进行非绝热催化反应的工艺和反应器
公开(公告)号：US20040161381A1
公开(公告)日：2004-08-19
申请号：US10779747
申请日：2004-02-18
发明人： Soren Gyde Thomsen
IPC分类号： C01B003/26
CPC分类号： B01J8/0257 , B01J8/0285 , B01J8/067 , B01J2208/00168 , B01J2208/00212 , B01J2208/021 , B01J2219/00247 , C01B3/382 , C01B3/384 , C01B2203/0233 , C01B2203/0261 , C01B2203/0811 , C01B2203/0844 , C01B2203/0866 , C01B2203/141
摘要： Process for carrying out non-adiabatic reactions comprising the steps of: introducing in parallel a first stream of reactants into a first reaction space and a second stream of reactants into a second reaction space; at reaction conditions contacting the first reactant stream with a catalyst in the first reaction space in indirect heat exchange with a heat exchanging medium and contacting the second reactant stream with a catalyst in the second reaction space in indirect heat exchange with a heat exchanging medium, and withdrawing a first and second steam reformed product gas; and the catalyst in the first reaction space being arranged within a tubular reactor in indirect heat exchanging relationship with the heat exchanging medium by introducing the medium into tubular heat exchange space concentrically surrounding the tubular reactor with the first reaction space, the catalyst in the second reaction space being arranged on shell side of a heat exchange space in indirect heat exchanging relationship with the heat exchanging medium.
摘要翻译：用于进行非绝热反应的方法，包括以下步骤：将第一反应物流并入第一反应空间，将第二反应物流引入第二反应空间; 在反应条件下使第一反应物流与第一反应空间中的催化剂接触，与热交换介质进行间接热交换，并将第二反应物流与第二反应空间中的催化剂与热交换介质间接热交换接触，取出第一和第二蒸汽重整产品气体; 并且第一反应空间中的催化剂被布置在与热交换介质间接热交换关系的管式反应器内，通过将介质引入与第一反应空间同时围绕管式反应器的管式热交换空间中，第二反应中的催化剂空间布置在与热交换介质间接热交换关系的热交换空间的壳侧。

64. 发明申请

US20040154222A1 Fuel processor primary reactor and combustor startup via electrically-heated catalyst 有权
标题翻译：燃料处理器主反应器和通过电加热催化剂的燃烧器启动
公开(公告)号：US20040154222A1
公开(公告)日：2004-08-12
申请号：US10360996
申请日：2003-02-07
发明人： Steven D. Burch , William H. Pettit , Steven G. Goebel
IPC分类号： B01J008/00 , B01J008/04 , C01B003/32
CPC分类号： F23C13/02 , B01J19/2485 , B01J23/40 , B01J35/0033 , B01J2208/00716 , B01J2219/00063 , B01J2219/00135 , B01J2219/002 , B01J2219/00213 , B01J2219/00238 , B01J2219/00265 , C01B3/382 , C01B2203/00 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0844 , C01B2203/085 , C01B2203/0866 , C01B2203/0883 , C01B2203/1023 , C01B2203/107 , C01B2203/1205 , C01B2203/1276 , C01B2203/1288 , C01B2203/142 , C01B2203/1604 , C01B2203/1619 , C01B2203/169 , C01B2203/82 , Y02P20/52
摘要： A primary reactor for a fuel processor system that employs steam and air to convert a liquid hydrocarbon fuel into a hydrogen-rich gas stream. The liquid fuel and an air-steam mixture are mixed in a mixing region within the reactor. The fuel mixture is then directed through an electrically heated catalyst region that heats the mixture to the operation temperature of a light-off catalyst at system start-up. The heated fuel mixture is then directed through a light-off catalyst monolith where the hydrocarbon fuel is dissociated. Once the fuel mixture is heated to the operating temperature of the light-off catalyst, the electrically heated catalyst region is turned off because the exothermic reaction in the light-off catalyst monolith generates the heat necessary to sustain the catalytic reaction.
摘要翻译：用于燃料处理器系统的主反应器，其使用蒸汽和空气将液体烃燃料转化为富氢气流。液体燃料和空气 - 蒸汽混合物在反应器内的混合区域中混合。然后将燃料混合物引导通过电加热的催化剂区域，其在系统启动时将混合物加热至点火催化剂的操作温度。然后将加热的燃料混合物引导通过烃燃料解离的点火催化剂整料。一旦燃料混合物被加热到点火催化剂的操作温度，则电加热的催化剂区域被关闭，因为在关闭催化剂整体中的放热反应产生维持催化反应所需的热量。

65. 发明申请

US20040134127A1 Apparatus and method for hydrocarbon reforming process 失效
标题翻译：烃重整过程的装置和方法
公开(公告)号：US20040134127A1
公开(公告)日：2004-07-15
申请号：US10746577
申请日：2003-12-24
发明人： Hoanh Nang Pham , David Hon Sing Ying , Shoou-l Wang , Scott David Madara , Joel Charles MacMurray
IPC分类号： C10J001/00 , B01J008/04
CPC分类号： B01J8/062 , B01J2208/00495 , B01J2208/00504 , B01J2219/0002 , B01J2219/00038 , B01J2219/1923 , C01B3/384 , C01B2203/0811 , C01B2203/0816 , C01B2203/0866
摘要： The present invention is an apparatus arranged to maximize heat utilization for a hydrocarbon steam reforming process to produce synthesis gas. The apparatus comprises a refractory lined vessel with partition walls that divide the inside of the vessel into (1) a combustion chamber(s) containing one or more burners, and (2) convection chambers used as a means to remove combustion products from the combustion chamber through one or more openings at the opposite end of the burner end. The combustion chamber contains one or more reformer tubes in which a mixed-feed of hydrocarbon and steam flow co-current with combustion products and receive direct radiant heat from the combustion flame through the tube wall. The convection chambers contain a tube-in-tube device filled with catalyst in the annuli. The mixed-feed in the annuli flows counter-current with combustion products and the hot product synthesis gas, and thereby substantially lowers the temperature of the combustion and product gases before the gases exit the furnace. High emissivity materials or walls are used inside the convection chambers to enhance the heat transfer from the flue gas to the reformer tubes.
摘要翻译：本发明是一种设备，用于使烃蒸汽重整过程的热利用率最大化以产生合成气。该装置包括具有分隔壁的耐火衬里容器，其将容器的内部分成（1）包含一个或多个燃烧器的燃烧室，和（2）用作从燃烧中除去燃烧产物的装置的对流室通过在燃烧器端的相对端的一个或多个开口。燃烧室包含一个或多个重整器管，其中烃和蒸汽的混合进料与燃烧产物流动并且从燃烧火焰通过管壁接收直接辐射热。对流室包含一个在管内装有催化剂的管内装置。在空气中的混合进料与燃烧产物和热产物合成气逆流流动，从而在气体离开炉子之前大大降低燃烧和产物气体的温度。在对流室内使用高辐射率材料或壁，以增强从烟道气到重整器管的热传递。

66. 发明申请

US20040083890A1 Hydrogen purification membranes, components and fuel processing systems containing the same 失效
公开(公告)号：US20040083890A1
公开(公告)日：2004-05-06
申请号：US10728473
申请日：2003-12-05
发明人： David J. Edlund , William A. Pledger , R. Todd Studebaker
IPC分类号： B01D053/22
CPC分类号： B01D53/22 , B01D53/228 , B01D63/06 , B01D63/08 , B01D2257/108 , B01D2313/18 , B01D2313/22 , B01D2313/42 , B01J8/006 , B01J8/009 , B01J8/0257 , B01J8/0285 , B01J8/04 , B01J8/0465 , B01J8/0469 , B01J8/0496 , B01J8/062 , B01J8/067 , B01J19/2475 , B01J2208/00053 , B01J2208/00061 , B01J2208/00088 , B01J2208/00106 , B01J2208/00132 , B01J2208/00141 , B01J2208/00256 , B01J2208/00309 , B01J2208/00371 , B01J2208/00415 , B01J2208/00495 , B01J2208/00504 , B01J2208/0053 , B01J2208/00539 , B01J2208/00548 , C01B3/323 , C01B3/38 , C01B3/382 , C01B3/501 , C01B3/503 , C01B3/505 , C01B3/586 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/041 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/0475 , C01B2203/066 , C01B2203/0811 , C01B2203/0816 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/085 , C01B2203/0866 , C01B2203/0877 , C01B2203/0883 , C01B2203/1011 , C01B2203/1041 , C01B2203/1058 , C01B2203/1076 , C01B2203/1217 , C01B2203/1223 , C01B2203/1235 , C01B2203/1241 , C01B2203/1247 , C01B2203/1258 , C01B2203/1276 , C01B2203/1282 , C01B2203/1288 , C01B2203/1294 , C01B2203/142 , C01B2203/146 , C01B2203/1604 , C01B2203/1628 , C01B2203/1633 , C01B2203/1657 , C01B2203/1676 , C01B2203/169 , C01B2203/1695 , C01B2203/82 , C12F5/00 , H01M8/0612 , H01M8/0631 , Y02P20/128 , Y10S48/05
摘要： Hydrogen purification membranes, hydrogen purification devices, and fuel processing and fuel cell systems that include hydrogen purification devices. The hydrogen purification membranes include a metal membrane, which is at least substantially comprised of palladium or a palladium alloy. In some embodiments, the membrane contains trace amounts of carbon, silicon, and/or oxygen. In some embodiments, the membranes form part of a hydrogen purification device that includes an enclosure containing a separation assembly, which is adapted to receive a mixed gas stream containing hydrogen gas and to produce a stream that contains pure or at least substantially pure hydrogen gas therefrom. In some embodiments, the membrane(s) and/or purification device forms a portion of a fuel processor, and in some embodiments, the membrane(s) and/or purification device forms a portion of a fuel processing or fuel cell system.

67. 发明申请

US20040068933A1 Reforming apparatus and operation method thereof 有权
标题翻译：改造设备及其操作方法
公开(公告)号：US20040068933A1
公开(公告)日：2004-04-15
申请号：US10387570
申请日：2003-03-14
申请人： MATSUSHITA ELECTRIC WORKS, LTD.
发明人： Toru Nakamura , Susumu Kobayashi , Hitoshi Kudo , Mikio Sei , Yuichiro Yasuda , Zhongmin Fei
IPC分类号： B01J008/00 , C01B003/24
CPC分类号： B01J8/0465 , B01B1/005 , B01J8/0496 , B01J2208/00203 , B01J2208/00309 , B01J2208/00504 , B01J2208/00513 , B01J2208/0053 , B01J2219/1925 , C01B3/384 , C01B3/48 , C01B2203/0227 , C01B2203/0233 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/0816 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/0866 , C01B2203/0883 , C01B2203/0894 , C01B2203/82 , Y02P20/128 , Y02P20/129
摘要： There is provided a reforming apparatus which shows high efficiency and excellent operation-starting performance, in spite of its compact body and simple structure. The present invention relates to a reforming apparatus which having a gas-producing passage (1) which includes a reforming catalyst section (2), a shift catalyst section (3) and a CO-selective oxidizing catalyst section (4) arranged in this order along a gas flowing direction; and a combustion gas passage (5) for heating the reforming catalyst section (2), the shift catalyst section (3) and the CO-selective oxidizing catalyst section (4). The reformed gas-producing passage (1) is formed of a first passage (1a) including the reforming catalyst section (2) and a second heat-recovering section (6) which recovers heat from the gas having passed through the shift catalyst section (3) and the gas having passed through the CO-selective oxidizing catalyst section (4) and supplies the heat to a fuel gas and steam fed to the reforming catalyst section (2); and a second passage (1b) including the shift catalyst section (3), the CO-selective oxidizing catalyst section (4), and a first heat-recovering section (7) which recovers heat from the gas having passed through the reforming catalyst section (2) and supplies the heat to the reforming catalyst section (2). The first passage (1a) is located adjacent to the combustion gas passage (5), and the second passage (1b) is located adjacent to the first passage (1a).
摘要翻译：提供了尽管体积小且结构简单的高效率和优异的起动性能的重整装置。本发明涉及一种具有气体产生通道（1）的重整装置，该气体生成通道（1）包括重整催化剂部分（2），换挡催化剂部分（3）和选择性氧化催化剂部分（4）沿气体流动方向; 以及用于加热重整催化剂部分（2），变换催化剂部分（3）和CO选择氧化催化剂部分（4）的燃烧气体通道（5）。重整气体产生通道（1）由包括重整催化剂部分（2）的第一通道（1a）和从已经通过变换催化剂部分的气体中回收热量的第二热回收部分（6）形成 3），并且已经通过CO选择氧化催化剂部分（4）的气体并将热量供给到供给到重整催化剂部分（2）的燃料气体和蒸汽; 以及包括所述变换催化剂部分（3），所述CO选择氧化催化剂部分（4）和从已经通过所述重整催化剂部分的气体中回收热量的第一热回收部分（7）的第二通道（1b）（2），并将热量供给到重整催化剂部（2）。第一通道（1a）位于燃烧气体通道（5）附近，第二通道（1b）位于第一通道（1a）附近。

68. 发明申请

US20030213364A1 Hydrogen purification membranes, components and fuel processing systems containing the same 有权
公开(公告)号：US20030213364A1
公开(公告)日：2003-11-20
申请号：US10430110
申请日：2003-05-05
发明人： David J. Edlund , William A. Pledger , R. Todd Studebaker
IPC分类号： B01D053/22
CPC分类号： B01D53/22 , B01D53/228 , B01D63/06 , B01D63/08 , B01D2257/108 , B01D2313/18 , B01D2313/22 , B01D2313/42 , B01J8/006 , B01J8/009 , B01J8/0257 , B01J8/0285 , B01J8/04 , B01J8/0465 , B01J8/0469 , B01J8/0496 , B01J8/062 , B01J8/067 , B01J19/2475 , B01J2208/00053 , B01J2208/00061 , B01J2208/00088 , B01J2208/00106 , B01J2208/00132 , B01J2208/00141 , B01J2208/00256 , B01J2208/00309 , B01J2208/00371 , B01J2208/00415 , B01J2208/00495 , B01J2208/00504 , B01J2208/0053 , B01J2208/00539 , B01J2208/00548 , C01B3/323 , C01B3/38 , C01B3/382 , C01B3/501 , C01B3/503 , C01B3/505 , C01B3/586 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/041 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/0475 , C01B2203/066 , C01B2203/0811 , C01B2203/0816 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/085 , C01B2203/0866 , C01B2203/0877 , C01B2203/0883 , C01B2203/1011 , C01B2203/1041 , C01B2203/1058 , C01B2203/1076 , C01B2203/1217 , C01B2203/1223 , C01B2203/1235 , C01B2203/1241 , C01B2203/1247 , C01B2203/1258 , C01B2203/1276 , C01B2203/1282 , C01B2203/1288 , C01B2203/1294 , C01B2203/142 , C01B2203/146 , C01B2203/1604 , C01B2203/1628 , C01B2203/1633 , C01B2203/1657 , C01B2203/1676 , C01B2203/169 , C01B2203/1695 , C01B2203/82 , C12F5/00 , H01M8/0612 , H01M8/0631 , Y02P20/128 , Y10S48/05
摘要： Hydrogen purification membranes, hydrogen purification devices, and fuel processing and fuel cell systems that include hydrogen purification devices. The hydrogen purification membranes include a metal membrane, which is at least substantially comprised of palladium or a palladium alloy. In some embodiments, the membrane contains trace amounts of carbon, silicon, and/or oxygen. In some embodiments, the membranes form part of a hydrogen purification device that includes an enclosure containing a separation assembly, which is adapted to receive a mixed gas stream containing hydrogen gas and to produce a stream that contains pure or at least substantially pure hydrogen gas therefrom. In some embodiments, the membrane(s) and/or purification device forms a portion of a fuel processor, and in some embodiments, the membrane(s) and/or purification device forms a portion of a fuel processing or fuel cell system.

69. 发明授权

US06632409B1 Reformer for fuel cell system 失效
标题翻译：燃料电池系统改造者
公开(公告)号：US06632409B1
公开(公告)日：2003-10-14
申请号：US09468782
申请日：1999-12-21
申请人： Koichi Kuwaba
发明人： Koichi Kuwaba
IPC分类号： B01J802
CPC分类号： H01M8/0631 , C01B3/323 , C01B3/38 , C01B3/48 , C01B3/58 , C01B2203/0244 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0833 , C01B2203/0838 , C01B2203/0844 , C01B2203/0866 , C01B2203/0872 , C01B2203/0883 , C01B2203/1223 , C01B2203/1288 , C01B2203/142 , C01B2203/146 , C01B2203/1604 , C01B2203/1614 , C01B2203/169 , C01B2203/82
摘要： A reformer includes an evaporation portion for evaporating a raw material, a reforming portion for producing a reformed gas whose principal element is hydrogen from the raw materials, a CO reduction portion for reducing CO involved in the reformed gas, a circulating conduit portion having a storage tank for storing the raw material, a feeding device for feeding the raw material under pressure, a cooling device for cooling the CO reduction portion and a supply device for supplying the raw material to the evaporation portion. The supply device includes a conduit branched from the circulating conduit portion connected to the evaporation portion and a flow control device provided in the conduit.
摘要翻译：重整器包括用于蒸发原料的蒸发部分，用于从原料生成主要元素为氢的重整气体的重整部分，用于还原CO中涉及重整气体的CO还原部分，具有储存器的循环管道部分用于储存原料的罐，用于在压力下供给原料的进料装置，用于冷却CO还原部分的冷却装置和用于将原料供应到蒸发部分的供应装置。供应装置包括从连接到蒸发部分的循环管道部分分支的导管和设置在导管中的流量控制装置。

70. 发明授权

US06630260B2 Water vapor transfer device for a fuel cell power plant 失效
标题翻译：用于燃料电池发电厂的水蒸气传输装置
公开(公告)号：US06630260B2
公开(公告)日：2003-10-07
申请号：US09910331
申请日：2001-07-20
申请人： Jameson R. Forte , Steven Burch , Mark A. Brundage
发明人： Jameson R. Forte , Steven Burch , Mark A. Brundage
IPC分类号： H01M804
CPC分类号： C01B3/34 , C01B3/48 , C01B2203/00 , C01B2203/0244 , C01B2203/0283 , C01B2203/0405 , C01B2203/044 , C01B2203/047 , C01B2203/0495 , C01B2203/066 , C01B2203/0838 , C01B2203/0844 , C01B2203/0866 , C01B2203/142 , C01B2203/146 , C01B2203/148 , C01B2203/82 , H01M8/04119 , H01M8/0612
摘要： A fuel cell system that extracts water from the effluent of a fuel cell for supply to other components of the fuel cell system that require water. A preferred embodiment is a fuel cell system, for the production of electricity from hydrogen gas and an oxidant, comprising: (a) a fuel cell comprising an anode input for a hydrogen-containing anode supply stream, a cathode input for an oxidant-containing cathode supply stream, and a cathode output for cathode effluent comprising water produced by said fuel cell; and (b) a water transfer device, connected to said fuel cell, that transfers water from said cathode effluent to said anode supply stream.
摘要翻译：一种燃料电池系统，其从燃料电池的流出物中提取水以供应到需要水的燃料电池系统的其它部件。优选的实施方案是用于从氢气和氧化剂产生电力的燃料电池系统，包括：（a）燃料电池，其包括用于含氢阳极供应流的阳极输入端，用于含氧化剂的阴极输入端阴极供应流和用于阴极流出物的阴极输出，其包含由所述燃料电池产生的水; 和（b）连接到所述燃料电池的水输送装置，其将水从所述阴极流出物转移到所述阳极供应流。

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