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    • 64. 发明授权
    • 2-benzoyl-cyclohexane-1,3-diones
    • US06559100B1
    • 2003-05-06
    • US09485223
    • 2000-02-07
    • Stefan EngelJoachim RheinheimerErnst BaumannWolfgang von DeynRegina Luise HillGuido MayerUlf MisslitzOliver WagnerMatthias WitschelMartina OttenHelmut WalterKarl-Otto Westphalen
    • Stefan EngelJoachim RheinheimerErnst BaumannWolfgang von DeynRegina Luise HillGuido MayerUlf MisslitzOliver WagnerMatthias WitschelMartina OttenHelmut WalterKarl-Otto Westphalen
    • C07D2604
    • C07D307/58A01N43/80C07D261/04
    • Substituted 2-benzoylcyclohexane-1,3-diones of the formula I where: R1 and R2 are each hydrogen, mercapto, nitro, halogen, cyano, thiocyanato, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C2-C6-alkenyl, C2-C6-alkynyl, —OR3, —OCOR3, —OSO2R3, —S(O)nR3, —SO2OR3, —SO2N(R3)2, —NR3SO2R3 or —NR3COR3; R3 is hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, phenyl or phenyl-C1-C6-alkyl; where the abovementioned alkyl radicals may be partially or fully halogenated and/or may carry one to three of the following groups: hydroxyl, mercapto, amino, cyano, R3, —OR3, —SR3, —N(R3)2, ═NOR3, —OCOR3, —SCOR3, —NR3COR3, —CO2R3, —COSR3, —CON(R3)2, C1-C4-alkyliminooxy, C1-C4-alkoxyamino, C1-C4-alkylcarbonyl, C1-C4-alkoxy-C2-C6-alkoxycarbonyl, C1-C4-alkylsulfonyl, heterocyclyl, heterocyclyloxy, phenyl, benzyl, hetaryl, phenoxy, benzyloxy and hetaryloxy, where the eight last mentioned radicals may in turn be substituted; n is 0, 1 or 2; Q is a cyclohexane-1,3-dione ring with or without substitution which is attached in position 2; X1 is a straight-chain or branched C1-C6-alkylene, a C2-C6-alkenylene or a C2-C6-alkynylene chain, where the abovementioned alkylene, alkenylene or alkynylene radicals may be partially halogenated and/or may carry one to three of the following groups: —OR4, —OCOR4, —OCONHR4 or —OSO2R4; except for those of the abovementioned alkenylene radicals where the double bond is &agr;,&bgr; to the phenyl ring and where Het is linked to the double bond via the &bgr; position; R4 is hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, phenyl, phenyl-C1-C6-alkyl, where the abovementioned alkyl, alkenyl or alkynyl radicals may be partially or fully halogenated and/or may be substituted by one or more of the following radicals: hydroxyl, mercapto, amino, cyano, nitro, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy; Het is a three- to six-membered partially or fully saturated heterocyclic group or a three- to six-membered heteroaromatic group having up to three hetero atoms selected from the group consisting of: nitrogen, oxygen or sulfur, where the abovementioned heterocyclic or heteroaromatic group may be partially or fully halogenated and/or may be substituted by R5; R5 is hydrogen, hydroxyl, mercapto, amino, cyano, nitro, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy, where the alkyl radicals may in each case be substituted by in each case one or more of the following radicals: cyano, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy; and agriculturally useful salts thereof, processes and intermediates for preparing compounds of the formula I, compositions comprising them, and the use of the compounds of the formula I and compositions comprising them for controlling harmful plants are described.
    • 66. 发明授权
    • Benzylidenepyrazolones, their preparation and use
    • 亚苄基吡唑啉酮,其制备和用途
    • US06500950B1
    • 2002-12-31
    • US09765626
    • 2001-01-22
    • Joachim RheinheimerMatthias WitschelStefan EngelErnst BaumannWolfgang von DeynRegina Luise HillGuido MayerUlf MisslitzOliver WagnerMartina OttenKarl-Otto WestphalenHelmut Walter
    • Joachim RheinheimerMatthias WitschelStefan EngelErnst BaumannWolfgang von DeynRegina Luise HillGuido MayerUlf MisslitzOliver WagnerMartina OttenKarl-Otto WestphalenHelmut Walter
    • C07D41310
    • C07D413/06A01N43/56A01N43/78A01N43/80C07D231/16C07D231/20
    • Benzylidenepyrazolones of the formula I, where the substituents and the index n have the following meanings: R1 is unsubstituted or substituted C1-C6-alkyl; R2 is unsubstituted or substituted C1-C6-alkyl, unsubstituted or substituted C1-C6-alkoxy, halogen, nitro, cyano; R3 is hydrogen, halogen, nitro, cyano, a group NR5R6, OCOR5, NR5COR6, CO2R5, —COSR5, —CONR5R6, C1-C4-alkoxyiminoalkyl, C1-C6-alkylcarbonyl, unsubstituted or substituted C1-C6-alkyl, unsubstituted or substituted C1-C6-alkoxy, unsubstituted or substituted C1-C6-alkylthio, unsubstituted or substituted C2-C6-alkenyl, unsubstituted or substituted C2-C6-alkynyl, unsubstituted or substituted phenyl, unsubstituted or substituted phenoxy, an unsubstituted or substituted 5- or 6-membered saturated or unsaturated heterocycle which may contain up to 4 nitrogen atoms and/or up to 2 oxygen or sulfur atoms as ring members; R4 is C1-C6-alkyl, C1-C4-haloalkyl; R3 and R4 form an optionally substituted saturated or unsaturated 2- or 3-membered bridge which may contain a sulfur atom which may be oxidized to the sulfoxide or sulfone; R5 is hydrogen or unsubstituted or substituted C1-C6-alkyl; R6 is unsubstituted or substituted C1-C6-alkyl; R7 is hydrogen, C1-C6-alkyl or C1-C4-haloalkyl; n is 0,1 or 2, X is hydrogen, chlorine or bromine; where the compounds claimed may be present both in the trans and in the cis form or as a mixture of these isomers, are described.
    • 式I的亚苄基吡唑酮,其中取代基和指数n具有以下含义:R 1是未取代的或取代的C 1 -C 6 - 烷基; R 2是未取代的或取代的C 1 -C 6 - 烷基,未取代或取代的C 1 -C 6 - 烷氧基,卤素 硝基,氰基; R 3是氢,卤素,硝基,氰基,NR 5 R 6,OCOR 5,NR 5 COR 6,CO 2 R 5,-COSR 5,-CONR 5 R 6,C 1 -C 4烷氧基亚氨基烷基,C 1 -C 6烷基羰基,未取代或取代的C 1 -C 6 - 未取代或取代的C 1 -C 6 - 烷硫基,未取代或取代的C 2 -C 6 - 烯基,未取代或取代的C 2 -C 6 - 炔基,未取代或取代的苯基,未取代或取代的苯氧基,未取代的 或可以含有至多4个氮原子和/或至多2个氧或硫原子作为环成员的取代的5或6元饱和或不饱和杂环; R 4是C 1 -C 6烷基,C 1 -C 4卤代烷基; R 3和 R4形成任选取代的饱和或不饱和的2-或3-元 桥可以含有可被氧化成亚砜或砜的硫原子; R5是氢或未取代或取代的C1-C6-烷基; R6是未取代的或取代的C1-C6-烷基; R7是氢,C1-C6-烷基 或C 1 -C 4卤代烷基; n为0,1或2,X为氢,氯或溴;其中要求保护的化合物可以以反式和顺式形式存在,或以这些异构体的混合物存在。
    • 68. 发明授权
    • Substituted 2-benz(o)ylpyridines, their preparation and their use as herbicides
    • 取代的2-苯并(o)吡啶,其制备及其作为除草剂的用途
    • US06337305B1
    • 2002-01-08
    • US09381033
    • 1999-09-15
    • Peter SchäferGerhard HamprechtMarkus MengesOlaf MenkeMichael RackCyrill ZagarKarl-Otto WestphalenUlf MisslitzHelmut Walter
    • Peter SchäferGerhard HamprechtMarkus MengesOlaf MenkeMichael RackCyrill ZagarKarl-Otto WestphalenUlf MisslitzHelmut Walter
    • C07D21330
    • C07D213/61A01N43/40
    • Substituted 2-benz(o)ylpyridines I and salts thereof where n=0, 1; X=CO, CH2, CH(C1-C4-alkyl), CH—OH, CH—CN, CH-halogen, C(halogen)2, CH—CONH2, CH—CO—O(C1-C4-alkyl), CH—O(C1-C4-alkyl), C(CN)(C1-C4-alkyl); R1=halogen, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl; R2=H, halogen; R3=H, NO2, OH, halogen, C1-C4-alkoxy; R4=H, NO2, OH, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy; R5=H, NO2, CN, halogen, C1-C8-alkyl, C3-C8-alkenyl, C3-C8-alkynyl, C3-C8-cycloalkyl, C1-C8-haloalkyl, C2-C8-haloalkenyl, C2-C8-haloalkinyl, C1-C4-alkoxy-C1-C4-alkyl, C2-C4-alkenyloxy-C1-C4-alkyl, C2-C4-alkynyloxy-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkylsulfinyl-C1-C4-alkyl, C1-C4-alkylsulfonyl-C1-C4-alkyl, cyano-C1-C8-alkyl, cyano-C2-C8-alkenyl, cyano-C3-C8-alkynyl, unsubstituted or substituted OH, SH, SO—H, —SO2—H, COOH or NH—COOH, —SO2Cl, —N(R9,R10), —NH—SO2—(C1-C8-alkyl), —N[—SO2—(C1-C8-alkyl)]2, —N(C1-C8-alkyl)[—SO2—(C1-C8-alkyl)], —SO2—N(R9,R10), —O—CO—NH—R9, unsubstituted or substituted CHO, —O—CHO or —NH—CHO, —NH—CO—NH—R9, —O—CS—NH2, —O—CS—N(C1-C8-alkyl)2, —CO—N(R9,R10), —CS—N(R9,R10), —CO—NH—SO2—(C1-C4-alkyl).
    • 取代的2-苯并(o)吡啶I和其中n = 0,1; X = CO,CH 2,CH(C 1 -C 4 - 烷基),CH-OH,CH-CN,CH-卤素,C(卤素) CH-CONH 2,CH-CO-O(C 1 -C 4 - 烷基),CH-O(C 1 -C 4 - 烷基),C(CN)(C 1 -C 4 - 烷基); R 1 =卤素,C 1 -C 4卤代烷基, C 1 -C 4烷硫基,C 1 -C 4烷基亚磺酰基,C 1 -C 4烷基磺酰基; R 2 = H,卤素; R 3 = H,NO 2,OH,卤素,C 1 -C 4 - 烷氧基; R 4 = H,NO 2,OH,卤素, C 1 -C 4 - 烷基,C 1 -C 4 - 卤代烷基,C 1 -C 4 - 烷氧基; R 5 = H,NO 2,CN,卤素,C 1 -C 8烷基,C 3 -C 8 - 烯基,C 3 -C 8炔基,C 3 -C 8 - 环烷基,C 1 -C 8 - 卤代烷基,C 2 -C 8 - 卤代烯基,C 2 -C 8 - 卤代炔基,C 1 -C 4 - 烷氧基-C 1 -C 4烷基,C 2 -C 4 - 烯氧基-C 1 -C 4烷基,C 2 -C 4 - C 1 -C 4烷基,C 1 -C 4烷硫基-C 1 -C 4烷基,C 1 -C 4烷基亚磺酰基-C 1 -C 4烷基,C 1 -C 4烷基磺酰基-C 1 -C 4 - 烷基,氰基-C 1 -C 8烷基, 氰基-C 2 -C 8 - 烯基,氰基-C 3 -C 8 - 炔基,未取代或取代的OH,SH,SO-H,-SO 2 -H,COOH或NH-COOH,-SO 2 Cl,-N(R 9,R 10) NH-SO 2 - (C 1 -C 8 - 烷基),-N [-SO 2 - (C 1 -C 8 - 烷基)] 2,-N(C 1 -C 8 - 烷基) -SO 2 -N(R 9,R 10),-O-CO-NH-R 9,未取代的 取代的CHO,-O-CHO或-NH-CHO,-NH-CO-NH-R9,-O-CS-NH2,-O-CS-N(C1-