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61. 发明授权

US06852210B2 Plating method and plating bath precursor used therefor 失效
标题翻译：电镀方法及镀浴前驱体
公开(公告)号：US06852210B2
公开(公告)日：2005-02-08
申请号：US10036506
申请日：2002-01-07
申请人： Keigo Obata , Dong-Hyun Kim , Takao Takeuchi , Seiichiro Nakao , Shinji Inazawa , Ayao Kariya , Masatoshi Majima , Shigeyoshi Nakayama
发明人： Keigo Obata , Dong-Hyun Kim , Takao Takeuchi , Seiichiro Nakao , Shinji Inazawa , Ayao Kariya , Masatoshi Majima , Shigeyoshi Nakayama
IPC分类号： C23C18/31 , C23C18/16 , C23C18/34 , C25D3/56
CPC分类号： C23C18/1617 , C23C18/34 , Y10S428/935 , Y10T428/12681 , Y10T428/12701 , Y10T428/12708 , Y10T428/12792 , Y10T428/12819 , Y10T428/12826 , Y10T428/12847 , Y10T428/12861 , Y10T428/12875 , Y10T428/12889 , Y10T428/12896 , Y10T428/12903 , Y10T428/12944 , Y10T428/12951
摘要： To provide a plating method, which enables wide industrial use of the redox system electroless plating method having excellent characteristics, and a plating bath precursor which is preferable for the plating method. The plating method comprises a process oxidizing first metal ions of a redox system of a plating bath from a lower oxidation state to a high oxidation state, and second metal ions of said redox system are reduced and deposited onto the surface of an object to be plated, wherein a process is provided in which by supplying the electrical current to the plating bath, the first metal ions are reduced from said lower oxidation state to thereby activate the plating bath. The plating bath precursor is formed stabilizing the plating bath so that reduction and deposition of the second metal ions substantially do not occur in order to improve its storing performance.
摘要翻译：为了提供能够广泛地使用具有优异特性的氧化还原体系无电镀方法的镀覆方法，以及优选用于电镀方法的镀浴前体。电镀方法包括将电镀浴的氧化还原体系的第一金属离子氧化为较低氧化态的工艺，并且所述氧化还原体系的第二金属离子被还原并沉积到被镀物体的表面上其中提供了一种通过向电镀槽供应电流的方法，使第一金属离子从所述较低氧化态还原，从而激活镀浴。形成电镀槽前体稳定电镀液，从而基本上不会发生第二金属离子的还原和沉积，以改善其存储性能。

62. 发明授权

US06338787B1 Redox system electroless plating method 有权
标题翻译：氧化还原体系化学镀方法
公开(公告)号：US06338787B1
公开(公告)日：2002-01-15
申请号：US09543356
申请日：2000-04-05
申请人： Keigo Obata , Dong-Hyun Kim , Takao Takeuchi , Seiichiro Nakao , Shinji Inazawa , Ayao Kariya , Masatoshi Majima , Shigeyoshi Nakayama
发明人： Keigo Obata , Dong-Hyun Kim , Takao Takeuchi , Seiichiro Nakao , Shinji Inazawa , Ayao Kariya , Masatoshi Majima , Shigeyoshi Nakayama
IPC分类号： C25C100
CPC分类号： C23C18/1617 , C23C18/34 , Y10S428/935 , Y10T428/12681 , Y10T428/12701 , Y10T428/12708 , Y10T428/12792 , Y10T428/12819 , Y10T428/12826 , Y10T428/12847 , Y10T428/12861 , Y10T428/12875 , Y10T428/12889 , Y10T428/12896 , Y10T428/12903 , Y10T428/12944 , Y10T428/12951
摘要： To provide a plating method, which enables wide industrial use of the redox system electroless plating method having excellent characteristics, and a plating bath precursor which is preferable for the plating method. The plating method comprises a process oxidizing first metal ions of a redox system of a plating bath from a lower oxidation state to a high oxidation state, and second metal ions of said redox system are reduced and deposited onto the surface of an object to be plated, wherein a process is provided in which by supplying the electrical current to the plating bath, the first metal ions are reduced from said lower oxidation state to thereby activate the plating bath. The plating bath precursor is formed stabilizing the plating bath so that reduction and deposition of the second metal ions substantially do not occur in order to improve its storing performance.
摘要翻译：为了提供能够广泛地使用具有优异特性的氧化还原体系无电镀方法的镀覆方法，以及优选用于电镀方法的镀浴前体。电镀方法包括将电镀浴的氧化还原体系的第一金属离子氧化为较低氧化态的工艺，并且所述氧化还原体系的第二金属离子被还原并沉积到被镀物体的表面上其中提供了一种通过向电镀槽供应电流的方法，使第一金属离子从所述较低氧化态还原，从而激活镀浴。形成电镀槽前体稳定电镀液，从而基本上不会发生第二金属离子的还原和沉积，以改善其存储性能。

63. 发明申请

US20110177407A1 ELECTROCHEMICAL REACTOR, METHOD FOR MANUFACTURING THE ELECTROCHEMICAL REACTOR, GAS DECOMPOSING ELEMENT, AMMONIA DECOMPOSING ELEMENT, AND POWER GENERATOR 审中-公开
标题翻译：电化学反应器，制造电化学反应器的方法，气体分解元件，氨分解元素和发电机
公开(公告)号：US20110177407A1
公开(公告)日：2011-07-21
申请号：US13120606
申请日：2009-09-17
申请人： Masatoshi Majima , Atsushi Fukunaga , Shinji Inazawa , Toshio Ueda , Motomi Nakata , Hiroki Mori , Masahiro Yamakawa
发明人： Masatoshi Majima , Atsushi Fukunaga , Shinji Inazawa , Toshio Ueda , Motomi Nakata , Hiroki Mori , Masahiro Yamakawa
IPC分类号： H01M8/06 , H01M8/00 , C25B9/00 , C25B9/06 , C25B9/08
CPC分类号： B01D53/326 , B01D53/56 , B01D53/58 , B01D53/72 , B01D2251/102 , B01D2257/7027 , B01D2257/708 , H01M4/8652 , H01M4/8657 , H01M4/9066 , H01M8/008 , H01M8/2404 , H01M8/243 , H01M8/2432 , H01M2008/1293 , Y02P70/56 , Y02W30/86
摘要： [Object] To provide an electrochemical reactor that is small in size but high in throughput capacity, does not generate NOx or carbon dioxide, can be operated at a low running cost, is easy to handle during assembling, and has a simple structure and high durability, a method for manufacturing the reactor, a gas decomposing element, an ammonia decomposing element, and a power generator.[Solution] An electrochemical reactor 10 includes a porous anode 2, a porous cathode 5 that is paired with the anode, and an ion conductive material 1 having an ion conductivity and being interposed between the anode and the cathode. The anode 2 includes surface-oxidized metal particle chains 21.
摘要翻译：本发明提供一种尺寸小但吞吐能力高的电化学反应器，不产生NOx或二氧化碳，可以低运行成本运行，组装时易于处理，结构简单高耐久性，制造反应器的方法，气体分解元件，氨分解元件和发电机。电解质反应器10包括多孔阳极2，与阳极配对的多孔阴极5和具有离子传导性且介于阳极和阴极之间的离子传导材料1。阳极2包括表面氧化金属粒子链21。

64. 发明授权

US06573007B2 Modified graphite particles and battery using the same 失效
标题翻译：改性石墨颗粒和电池使用相同
公开(公告)号：US06573007B2
公开(公告)日：2003-06-03
申请号：US09897118
申请日：2001-07-03
申请人： Masatoshi Majima , Shinji Inazawa , Satoshi Ujiie , Eriko Yagasaki , Kazuharu Danjo , Shinichi Homma
发明人： Masatoshi Majima , Shinji Inazawa , Satoshi Ujiie , Eriko Yagasaki , Kazuharu Danjo , Shinichi Homma
IPC分类号： H01M402
CPC分类号： H01M4/587 , C01B32/20 , C01P2004/22 , C01P2004/54 , C01P2004/61 , C01P2006/12 , H01M4/133 , H01M2004/021
摘要： Modified graphite particles are described, which have an almost circular and tabular shape, an average particle size Ap of 12 to 18 &mgr;m, a BET specific surface area Ss of 4 to 6 m2/g, and a BET specific surface area to average particle size ratio, Ss/Ap, of 0.35 or less, and which are obtained by treating tabular particles of lumpy or flaky graphite to break or slightly fold the periphery of the tabular particles to increase the degree of circularity. A battery having the modified graphite particles as an anode active material is also described.
摘要翻译：描述了具有几乎圆形和平板状的改性石墨颗粒，平均粒径Ap为12至18μm，BET比表面积Ss为4至6m 2 / g，BET比表面积与平均粒径比例Ss / Ap为0.35以下，通过处理片状或片状石墨的片状颗粒而得到，以破碎或略微折叠片状颗粒的周边以增加圆形度。还描述了具有改性石墨颗粒作为负极活性材料的电池。

65. 发明授权

US06465133B1 Metallic porous body and method of manufacturing the same and battery current collector having the same 有权
标题翻译：金属多孔体及其制造方法以及具有该金属多孔体的电池集电体
公开(公告)号：US06465133B1
公开(公告)日：2002-10-15
申请号：US09567014
申请日：2000-05-09
申请人： Ayao Kariya , Noriki Hayashi , Shinji Inazawa , Masatoshi Majima
发明人： Ayao Kariya , Noriki Hayashi , Shinji Inazawa , Masatoshi Majima
IPC分类号： H01M480
CPC分类号： H01M4/80 , C25D5/56 , H01M4/808 , H01M2300/0014 , Y10T428/12042 , Y10T428/12111
摘要： A metallic porous body comprises a metallic framework having a three-dimensional network with a continuous-pore structure formed by linking sub-stantially polyhedral cells. The substantially polyhedral cells have an average cell diameter of about 200 to about 300 &mgr;m and an average window diameter of about 100 to about 200 &mgr;m. The metallic porous body can be obtained by the following method, for instance: First, a plastic porous body is provided that has an average cell diameter of about 200 to about 300 &mgr;m and an average window diameter of about 100 to about 200 &mgr;m. Second, a conductive layer is formed on a surface of the framework of the plastic porous body to produce a conductive porous body having a resistivity of about 1 k&OHgr;·cm or less. Finally, a continuous metal-plated layer is formed on a surface of the conductive layer by electroplating, with the conductive porous body serving as the cathode. The above-mentioned current collector is provided by filling an active material into the pores of the metallic porous body.
摘要翻译：金属多孔体包括具有三维网状物的金属框架，该三维网状结构具有通过连接亚稳定多面体单元形成的连续孔结构。基本上多边形的单元具有约200至约300μm的平均泡孔直径和约100至约200μm的平均窗口直径。金属多孔体可以通过以下方法获得，例如：首先，提供具有约200至约300μm的平均泡孔直径和约100至约200μm的平均窗口直径的塑料多孔体。其次，在塑料多孔体的框架的表面上形成导电层，以制造电阻率为约1kOMEGA·cm以下的导电性多孔体。最后，通过电镀在导电层的表面上形成连续的金属镀层，导电多孔体用作阴极。通过将活性物质填充到金属多孔体的孔中来提供上述集电体。

66. 发明授权

US08916033B2 Gas decomposition apparatus 有权
标题翻译：气体分解装置
公开(公告)号：US08916033B2
公开(公告)日：2014-12-23
申请号：US13510846
申请日：2010-11-04
申请人： Chihiro Hiraiwa , Masatoshi Majima , Koji Nitta , Atsushi Fukunaga , Shigeki Egashira
发明人： Chihiro Hiraiwa , Masatoshi Majima , Koji Nitta , Atsushi Fukunaga , Shigeki Egashira
IPC分类号： B01D53/32 , C25B9/08 , F01N3/01 , F01N3/08
CPC分类号： F01N3/08 , B01D53/326 , B01D53/925 , B01D2257/404 , B01D2258/012 , F01N3/01 , Y02T10/20
摘要： A gas decomposition apparatus having any one of the following structures: 1) a structure wherein an anode and a cathode on a solid electrolyte layer each have extended regions; the extended regions of the anode and those of the cathode are alternately extended to have a gap between the anode and the cathode; the cathode is higher in electric resistance than the anode; and a cathode electroconductive region connected electroconductively to a power source and made of an electroconductive material is extended in a direction crossing the direction in which the extended regions of the cathode are extended, thereby connecting the extended regions of the cathode electroconductively to each other; and (2) a structure which has an electroconductor layer through which the negative electrode of a power source is electroconductively connected to a cathode; and which is a structure wherein the cathode is laminated on the electroconductor layer to contact the layer, laminates each composed of a solid electrolyte layer and an anode are positioned on the cathode to have a gap between any adjacent two of the laminates, and the anodes are electroconductively connected to the positive electrode of the power source.
摘要翻译：一种具有以下结构之一的气体分解装置：1）固体电解质层上的阳极和阴极各自具有延伸区域的结构; 阳极的延伸区域和阴极的延伸区域交替地延伸以在阳极和阴极之间具有间隙; 阴极电阻比阳极高; 并且电导率连接到电源并由导电材料制成的阴极导电区域沿与阴极的延伸区域延伸的方向交叉的方向延伸，从而将阴极的延伸区域彼此连接; 和（2）具有电导体层的结构，电源的负极通过该导电层与阴极电导连接; 并且其中阴极层叠在电导体层上以接触该层的结构，每个由固体电解质层和阳极构成的层压体位于阴极上，以在任何相邻的两个层压体之间具有间隙，阳极电连接到电源的正极。

67. 发明申请

US20120228126A1 GAS DECOMPOSITION APPARATUS 有权
标题翻译：气体分解装置
公开(公告)号：US20120228126A1
公开(公告)日：2012-09-13
申请号：US13510846
申请日：2010-11-04
申请人： Chihiro Hiraiwa , Masatoshi Majima , Koji Nitta , Atsushi Fukunaga , Shigeki Egashira
发明人： Chihiro Hiraiwa , Masatoshi Majima , Koji Nitta , Atsushi Fukunaga , Shigeki Egashira
IPC分类号： C25B11/04 , C25B11/02 , C25B15/00 , C25B9/06 , C25B9/18
CPC分类号： F01N3/08 , B01D53/326 , B01D53/925 , B01D2257/404 , B01D2258/012 , F01N3/01 , Y02T10/20
摘要： A gas decomposition apparatus having any one of the following structures: 1) a structure wherein an anode and a cathode on a solid electrolyte layer each have extended regions; the extended regions of the anode and those of the cathode are alternately extended to have a gap between the anode and the cathode; the cathode is higher in electric resistance than the anode; and a cathode electroconductive region connected electroconductively to a power source and made of an electroconductive material is extended in a direction crossing the direction in which the extended regions of the cathode are extended, thereby connecting the extended regions of the cathode electroconductively to each other; and (2) a structure which has an electroconductor layer through which the negative electrode of a power source is electroconductively connected to a cathode; and which is a structure wherein the cathode is laminated on the electroconductor layer to contact the layer, laminates each composed of a solid electrolyte layer and an anode are positioned on the cathode to have a gap between any adjacent two of the laminates, and the anodes are electroconductively connected to the positive electrode of the power source.
摘要翻译：一种具有以下结构之一的气体分解装置：1）固体电解质层上的阳极和阴极各自具有延伸区域的结构; 阳极的延伸区域和阴极的延伸区域交替地延伸以在阳极和阴极之间具有间隙; 阴极电阻比阳极高; 并且电导率连接到电源并由导电材料制成的阴极导电区域沿与阴极的延伸区域延伸的方向交叉的方向延伸，从而将阴极的延伸区域彼此连接; 和（2）具有电导体层的结构，电源的负极通过该导电层与阴极电导连接; 并且其中阴极层叠在电导体层上以接触该层的结构，每个由固体电解质层和阳极构成的层压体位于阴极上，以在任何相邻的两个层压体之间具有间隙，阳极电连接到电源的正极。

68. 发明授权

US07915190B2 Metal catalyst and method for production thereof 有权
标题翻译：金属催化剂及其制造方法
公开(公告)号：US07915190B2
公开(公告)日：2011-03-29
申请号：US12686265
申请日：2010-01-12
申请人： Masatoshi Majima , Kohei Shimoda , Kouji Yamaguchi
发明人： Masatoshi Majima , Kohei Shimoda , Kouji Yamaguchi
IPC分类号： B01J37/34 , B01J23/00 , B01J21/00 , B01J20/00
CPC分类号： H01M4/90 , B01J23/42 , B01J35/0013 , B01J35/006 , B01J37/16 , H01M4/9083 , H01M4/92 , H01M4/926
摘要： The present invention relates to a metal catalyst containing fine metal particles, characterized in that the fine metal particles have a particle diameter of 3 nm or less and also have a proportion of metallic bond state of 40% or more, which is ascribed by subjecting to waveform separation of a binding energy peak peculiar to the metal as measured by using an X-ray photoelectron spectrometer. The fine metal particles are preferably fine platinum particles. The fine metal particles are preferably supported on the surface of carrier particles by reducing ions of metal to be deposited through the action of a reducing agent in a reaction system of a liquid phase containing the carrier particles dispersed therein, thereby to deposit the metal on the surface of carrier particles in the form of fine particles. The proportion of metallic bond state of the fine metal particles is adjusted within the above range by reducing after deposition thereby to decrease the oxidation state.
摘要翻译：本发明涉及含有金属微粒的金属催化剂，其特征在于，金属微粒的粒径为3nm以下，金属结合状态的比例为40％以上，这是通过使通过使用X射线光电子能谱仪测量的金属特有的结合能峰的波形分离。细金属颗粒优选为铂颗粒。金属颗粒优选通过在含有分散在其中的载体颗粒的液相的反应体系中通过还原剂的作用还原待沉积的金属离子而负载在载体颗粒的表面上，从而将金属沉积在载体颗粒表面呈细颗粒状。通过在沉积后减少，将金属微粒的金属结合状态的比例调节在上述范围内，从而降低氧化态。

69. 发明授权

US07390442B2 Anisotropic conductive film and method for producing the same 有权
标题翻译：各向异性导电膜及其制造方法
公开(公告)号：US07390442B2
公开(公告)日：2008-06-24
申请号：US10506425
申请日：2003-03-03
申请人： Hideki Kashihara , Masamichi Yamamoto , Jun Yorita , Hideaki Toshioka , Misako Osoegawa , Keiji Koyama , Masatoshi Majima , Yoshie Tani
发明人： Hideki Kashihara , Masamichi Yamamoto , Jun Yorita , Hideaki Toshioka , Misako Osoegawa , Keiji Koyama , Masatoshi Majima , Yoshie Tani
IPC分类号： H01B1/02 , H01B1/22
CPC分类号： H01R4/04 , G01R1/06755 , G01R1/073 , G01R3/00 , H01R43/007 , Y10T428/25 , Y10T428/258 , Y10T428/31678
摘要： An anisotropic conductive film, and its production method, especially suitable for mounting a semiconductor package and sufficiently satisfying the requirements of higher density mounting because short circuit does not occur in the plane direction of the film even if the pitch of electrodes is small, or suitable for mounting a contact probe because conductive connection not fused with a high current can be ensured with a lower pressure and even a high frequency signal can be dealt with. The anisotropic conductive film contains metal powder having such a shape that many fine metal particles are linked as a conductive component, wherein the length of the chain of metal powder is set not longer than the distance between adjacent electrodes being bonded conductively when a semiconductor package is mounted, and the diameter of the chain is set in the range of 1 μm-20 μm when a contact probe is mounted. At least a part of the film is formed while orienting a chain formed of a paramagnetic metal with a magnetic field.
摘要翻译：各向异性导电膜及其制造方法，特别适用于安装半导体封装，并且充分满足更高密度安装的要求，因为即使电极的间距小或适当，也不会在膜的平面方向上发生短路为了安装接触式探头，因为能够以更低的压力确保导电连接不会与高电流并联，甚至可以处理高频信号。各向异性导电膜含有金属粉末，其具有许多细金属颗粒作为导电组分连接的形状，其中金属粉末链的长度设定为不超过当半导体封装为半导体封装时导电地接合的相邻电极之间的距离当安装接触探针时，链条的直径设定在1mum-20mum的范围内。在由具有磁场的顺磁金属形成的链定向的同时形成膜的至少一部分。

70. 发明申请

US20050106382A1 Anisotropic conductive film and method for producing the same 有权
标题翻译：各向异性导电膜及其制造方法
公开(公告)号：US20050106382A1
公开(公告)日：2005-05-19
申请号：US10506425
申请日：2003-03-03
申请人： Hideaki Kashihara , Masamichi Yamamoto , Jun Yorita , Hideaki Toshioka , Misako Osoegawa , Keiji Koyama , Masatoshi Majima , Yoshie Tani
发明人： Hideaki Kashihara , Masamichi Yamamoto , Jun Yorita , Hideaki Toshioka , Misako Osoegawa , Keiji Koyama , Masatoshi Majima , Yoshie Tani
IPC分类号： G01R1/067 , G01R1/073 , G01R3/00 , H01R4/04 , H01R43/00 , H05K3/32 , B32B15/04
CPC分类号： H01R4/04 , G01R1/06755 , G01R1/073 , G01R3/00 , H01R43/007 , Y10T428/25 , Y10T428/258 , Y10T428/31678
摘要： An anisotropic conductive film, and its production method, especially suitable for mounting a semiconductor package and sufficiently satisfying the requirements of higher density mounting because short circuit does not occur in the plane direction of the film even if the pitch of electrodes is small, or suitable for mounting a contact probe because conductive connection not fused with a high current can be ensured with a lower pressure and even a high frequency signal can be dealt with. The anisotropic conductive film contains metal powder having such a shape that many fine metal particles are linked as a conductive component, wherein the length of the chain of metal powder is set not longer than the distance between adjacent electrodes being bonded conductively when a semiconductor package is mounted, and the diameter of the chain is set in the range of 1 μm-20 μm when a contact probe is mounted. At least a part of the film is formed while orienting a chain formed of a paramagnetic metal with a magnetic field.
摘要翻译：各向异性导电膜及其制造方法，特别适用于安装半导体封装，并且充分满足更高密度安装的要求，因为即使电极的间距小或适当，也不会在膜的平面方向上发生短路为了安装接触式探头，因为能够以更低的压力确保导电连接不会与高电流并联，甚至可以处理高频信号。各向异性导电膜含有金属粉末，其具有许多细金属颗粒作为导电组分连接的形状，其中金属粉末链的长度设定为不超过当半导体封装为半导体封装时导电地接合的相邻电极之间的距离当安装接触探针时，链条的直径设定在1mum-20mum的范围内。在由具有磁场的顺磁金属形成的链定向的同时形成膜的至少一部分。

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