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    • 61. 发明申请
    • EXHAUST GAS PURIFYING APPARATUS FOR INTERNAL COMBUSTION ENGINE
    • 用于内燃机的排气净化装置
    • US20100132340A1
    • 2010-06-03
    • US12530237
    • 2008-03-10
    • Keisuke SanoTakaaki ItouMimikazu YodaKazuhiro Wakao
    • Keisuke SanoTakaaki ItouMimikazu YodaKazuhiro Wakao
    • F01N3/00F01N3/10
    • B01D53/9495B01D2251/208B01D2257/404B01D2258/012F01N3/0814F01N3/34F01N13/009F01N2410/00
    • An object of the present invention is to provide an exhaust gas purifying apparatus for an internal combustion engine which can properly purge at least NOx of unpurified components contained in exhaust gas while considering characteristics of NOx desorbed from an adsorbent. A bypass passage 18 bypassing a main exhaust passage 12 of the internal combustion engine 10 is provided. A HC/NOx adsorbent 22 having a function of adsorbing HC and NOx is provided in the bypass passage 18. A second underfloor catalyst 30 is provided downstream of the adsorbent 22. A purge passage 26 branching off from the bypass passage 18 while connecting to an intake passage is provided. An exhaust switching valve 20 and a purge control valve 28 are provided as a flow path switching means that is capable of switching a flow target into which the exhaust gas flows between the main exhaust passage 12 and the bypass passage 18. If the purging operations are executed, the intake purging operation is first executed. After that, the intake purging operation is switched to the exhaust purging operation at a timing existing after the purge of NOx is completed and at the time point at which the temperature of the adsorbent becomes stable.
    • 本发明的目的是提供一种用于内燃机的废气净化装置,其能够考虑到从吸附剂脱附的NOx的特性,能够适当地净化废气中所含的未纯化成分的NOx。 设置有绕过内燃机10的主排气通路12的旁路通道18。 具有吸附HC和NOx的功能的HC / NOx吸附剂22设置在旁通通道18中。第二底板催化剂30设置在吸附剂22的下游。一个从旁路通道18分支的清洗通道26,同时连接到 提供进气通道。 设置排气切换阀20和排气控制阀28作为流路切换装置,其能够切换排气在主排气通路12和旁通通路18之间流动的流动目标。如果清洗操作是 首先执行进气清洗操作。 之后,在完成NOx的净化之后的时刻和吸附剂的温度稳定的时刻,进行排气操作切换到排气净化操作。
    • 63. 发明授权
    • Exhaust gas purification device for an internal combustion engine
    • 内燃机用废气净化装置
    • US06499294B1
    • 2002-12-31
    • US09399287
    • 1999-09-17
    • Kenji KatohTakaaki ItouHiroshi TanakaShuichi KuboYoshiyuki MandokoroMasahiro Taki
    • Kenji KatohTakaaki ItouHiroshi TanakaShuichi KuboYoshiyuki MandokoroMasahiro Taki
    • F01N310
    • F01N3/0864B01D53/9431B01D53/9495F01N3/0814F01N3/0842F01N3/0871F01N13/009F01N13/0097F01N13/011F01N2250/12F01N2510/00F01N2510/06F01N2570/16F02D41/0275Y02T10/22Y02T10/24
    • A converter containing a NOx absorbing and reducing catalyst is disposed in the exhaust passage of an internal combustion engine. The upstream half portion (portion of the inlet side) of the substrate of the NOx absorbing and reducing catalyst in the converter carries the oxygen storage component that absorbs oxygen in the exhaust gas when the air-fuel ratio of the exhaust gas is lean and releases the absorbed oxygen when the air-fuel ratio of the exhaust gas flowing in is rich in addition to carrying the NOx absorbing and reducing catalyst. After NOx is absorbed by the NOx absorbing and reducing catalyst as a result of operating the engine at a lean air-fuel ratio, the engine is operated at a rich air-fuel ratio, so that NOx is released from the NOx absorbing and reducing catalyst and is purified by reduction. Here, oxygen is released from the oxygen storage component carried by the upstream half portion of the substrate and is reacted with the H2 and CO components in the exhaust gas, so that the temperature of the NOx absorbing and reducing catalyst is raised within short periods of time due to the heat of reaction. Therefore, the catalyst exhibits increased activity and the NOx absorbing and reducing catalyst exhibits improved NOx purification capability.
    • 含有NOx吸收和还原催化剂的转化器设置在内燃机的排气通道中。 转换器中的NOx吸收还原催化剂的基板的上游半部(入口侧的部分)在废气的空燃比稀的时候携带吸收废气中的氧的储氧成分,释放 除了携带NOx吸收还原催化剂之外,当排出的废气的空燃比富含时,吸收的氧也富含。 由于作为发动机以稀薄的空燃比运转,NO x吸收还原催化剂吸收了NOx之后,发动机的空燃比浓度较高,使NO x从NOx吸收还原催化剂 并通过还原进行纯化。 这里,从由基板的上游半部分承载的储氧成分中释放出氧,并与废气中的H 2和CO成分反应,使NOx吸收还原催化剂的温度在短时间内升高 时间由于反应的热量。 因此,催化剂表现出增加的活性,NOx吸收和还原催化剂表现出提高的NOx净化能力。
    • 65. 发明授权
    • Exhaust gas purification device for an internal combustion engine
    • 内燃机用废气净化装置
    • US6109024A
    • 2000-08-29
    • US75358
    • 1998-05-08
    • Yukio KinugasaTakaaki ItouKoichi Takeuchi
    • Yukio KinugasaTakaaki ItouKoichi Takeuchi
    • F01N3/08B01D53/86B01D53/94F01N3/24F01N3/28F01N13/02F01N13/04F02B75/12F02D41/02F02D41/40F01N3/00
    • F01N3/0842F01N13/009F01N13/011F01N3/101F02D41/0275F02D41/405F01N2900/0418F02B2075/125F02D2041/389Y02T10/123Y02T10/22Y02T10/44
    • In an exhaust gas purification device, a three-way catalyst, an NO.sub.x absorbing-reducing catalyst and an NH.sub.3 adsorbing-denitrating catalyst are disposed in an exhaust gas passage of the internal combustion engine. The engine is provided with direct cylinder injection valves which inject fuel directly into the respective cylinders. A control circuit controls the amount of fuel injected from the injection valve so that the air-fuel ratio of the combustion in the cylinders becomes a lean air-fuel ratio during the normal operation of the engine. Therefore, a lean air-fuel ratio exhaust gas is discharged from the cylinders during the normal operation and NO.sub.x, in the exhaust gas is absorbed by the NO.sub.x absorbing-reducing catalyst. When the amount of NO.sub.x absorbed in the NO.sub.x absorbing-reducing catalyst increases to a predetermined level, the control circuit performs an additional fuel injection during the expansion stroke or exhaust stroke of cylinders in order to adjust the air-fuel ratio of the exhaust gas leaving the cylinders to a rich air-fuel ratio. The rich air-fuel ratio exhaust gas leaving the cylinders flows into the three-way catalyst and NO.sub.x in the exhaust gas is converted into NH.sub.3 at the three-way catalyst. When the rich air-fuel ratio exhaust gas flows through the NO.sub.x absorbing-reducing catalyst, NO.sub.x is released from the NO.sub.x absorbing-reducing catalyst and is reduced to N.sub.2 by NH.sub.3 in the exhaust gas.
    • 在排气净化装置中,在内燃机的废气通道中设置三元催化剂,NOx吸收还原催化剂和NH 3吸附脱硝催化剂。 发动机配有直接气缸喷射阀,其将燃料直接喷射到相应的气缸中。 控制电路控制从喷射阀喷射的燃料量,使得在发动机的正常运行期间气缸中的燃烧空燃比变为稀空燃比。 因此,在正常操作期间,从空气中排出贫空燃比废气,并且排气中的NOx被NOx吸收还原催化剂吸收。 当NOx吸收还原催化剂吸收的NOx的量增加到预定水平时,控制电路在气缸的膨胀冲程或排气冲程期间执行额外的燃料喷射,以便调节离开废气的空燃比 气缸以较高的空燃比。 离开气缸的富空燃比废气流入三元催化剂,废气中的NOx在三元催化剂下转化为NH3。 当富空燃比废气流过NOx吸收还原催化剂时,NOx从NOx吸收还原催化剂释放,并通过排气中的NH 3还原为N2。