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61. 发明授权

US5804656A Compositions of the ABS type for processing by extrusion and deep drawing 失效
标题翻译：用于挤出和深冲加工的ABS类型的组合物
公开(公告)号：US5804656A
公开(公告)日：1998-09-08
申请号：US778845
申请日：1997-01-06
申请人： Herbert Eichenauer , Peter Kruger , Harry Staratschek , Edgar Leitz , Dieter Wittman , Karl-Erwin Piejko , Jurgen Ramthun
发明人： Herbert Eichenauer , Peter Kruger , Harry Staratschek , Edgar Leitz , Dieter Wittman , Karl-Erwin Piejko , Jurgen Ramthun
IPC分类号： B29C47/00 , B29C55/02 , B29L7/00 , C08F297/04 , C08L25/12 , C08L53/02 , C08L55/02 , C08L9/00
CPC分类号： C08L25/12 , C08L55/02
摘要： Compositions of the ABS type containing A) one or more graft rubbers of A.1) from 10 to 60 parts by weight of one or more monomers on A.2) from 40 to 90 parts by weight of one or more rubber backbones having glass transition temperatures
摘要翻译：含A）的组合物，A）一种或多种A.1的接枝橡胶）10至60重量份的A.2上的一种或多种单体）40至90份重量的一种或多种具有玻璃的橡胶主链转变温度<0℃，B）至少一种通过树脂形成单体的自由基聚合获得的无橡胶的热塑性树脂，其中橡胶主链A.2）的平均粒径（d50值）为0.20-0.35μm m和接枝橡胶A）通过使用包含有机氢过氧化物和有机还原剂的引发剂体系通过自由基乳液接枝聚合制备，以及其用于通过深冲制备模制品的用途。

62. 发明授权

US5274031A Polymer alloys of high ageing resistance 失效
标题翻译：耐老化的聚合物合金
公开(公告)号：US5274031A
公开(公告)日：1993-12-28
申请号：US435057
申请日：1989-11-13
申请人： Herbert Eichenauer , Alfred Pischtschan , Christian Lindner
发明人： Herbert Eichenauer , Alfred Pischtschan , Christian Lindner
IPC分类号： C08L51/00 , C08L51/04 , C08L51/06 , C08L51/08
CPC分类号： C08L51/04 , C08L51/085
摘要： Molding compounds ofA) 5 to 95 parts by weight of a graft product of resin-forming monomers on a particulate silicone rubber having a total rubber content of from 30 to 90% by weight andB) 95 to 5 parts by weight of resin-forming monomers on a particulate EPDM rubber having a total rubber content of 10 to 50% by weight andC) 10 to 200 parts by weight (based on 100 parts by weight A+B) of a graft product of resin-forming monomers on a particulate acrylate rubber having a total rubber content of from 30 to 80% by weight.
摘要翻译： A）成型化合物A）5至95重量份的树脂形成单体的接枝产物在总橡胶含量为30至90重量％的颗粒状硅橡胶上，B）95至5重量份树脂 - 在总橡胶含量为10至50重量％的颗粒状EPDM橡胶上形成单体，C）10至200重量份（基于100重量份A + B）的树脂形成单体的接枝产物总橡胶含量为30至80重量％的颗粒状丙烯酸酯橡胶。

63. 发明授权

US4859731A Polymeric dihydroxy compounds and their use as stabilizers for polymers 失效
标题翻译：聚合二羟基化合物及其作为聚合物稳定剂的用途
公开(公告)号：US4859731A
公开(公告)日：1989-08-22
申请号：US223541
申请日：1988-07-25
申请人： Herbert Eichenauer , Hartwig Hocker , Thomas Heitz
发明人： Herbert Eichenauer , Hartwig Hocker , Thomas Heitz
IPC分类号： C08F8/00
CPC分类号： C08F8/00
摘要： Polymer dihydroxy compounds corresponding to the following formula ##STR1## in whichR.sup.1, R.sup.2, R.sup.3 =H or C.sub.1 -C.sub.4 alkyl,R.sup.4 =H or C.sub.1 -C.sub.4 alkyl,R.sup.5 =--C.sub.6 H.sub.5, --C.sub.6 H.sub.4 CH.sub.3, --CH.dbd.CH.sub.2, or --CO.sub.2 R.sup.7,R.sup.6 =C.sub.1 -C.sub.4 alkyl, aryl, or H,R.sup.7 =C.sub.1 -C.sub.4 alkyl,m=0 or 1,n=5 to 100,q=0 or 1,a process for their production and their use in thermoplastic molding compositions.
摘要翻译：对应于下式的化合物二羟基化合物，其中R1，R2，R3 = H或C1-C4烷基，R4 = H或C1-C4烷基，R5 = -C6H5，-C6H4CH3，-CH = CH2或 - CO 2 R 7，R 6 = C 1 -C 4烷基，芳基或H，R 7 = C 1 -C 4烷基，m = 0或1，n = 5〜100，q = 0或1，其制备方法及其在热塑性成型组合物。

64. 发明授权

US07358290B2 Polycarbonate molding compositions with improved hydrolysis resistance 有权
标题翻译：具有改善耐水解性的聚碳酸酯模塑组合物
公开(公告)号：US07358290B2
公开(公告)日：2008-04-15
申请号：US11342739
申请日：2006-01-30
申请人： Eckhard Wenz , Thomas Eckel , Olaf Meincke , Holger Warth , Herbert Eichenauer
发明人： Eckhard Wenz , Thomas Eckel , Olaf Meincke , Holger Warth , Herbert Eichenauer
IPC分类号： C08K3/26 , C08L69/00
CPC分类号： C08L69/005 , C08F279/02 , C08F279/04 , C08K3/26 , C08K3/32 , C08K5/0008 , C08L27/18 , C08L51/04 , C08L55/02 , C08L69/00 , C08L2666/14 , C08L2666/02 , C08L2666/24
摘要： A thermoplastic molding composition is disclosed. The composition that contains at least one member selected from the group consisting of aromatic polycarbonate and polyester carbonate, a rubber-modified vinyl (co)polymer, and calcium carbonate having average particle diameter of less than 100 nm is particularly suitable for making articles resistant to hydrolysis.
摘要翻译：公开了一种热塑性模塑组合物。含有选自芳族聚碳酸酯和聚酯碳酸酯，橡胶改性的乙烯基（共）聚合物，平均粒径小于100nm的碳酸钙中的至少一种的组合物特别适用于制造耐受水解。

65. 发明申请

US20070135549A1 ABS moulding materials containing special metal compounds 审中-公开
标题翻译： ABS成型材料含有特殊的金属化合物
公开(公告)号：US20070135549A1
公开(公告)日：2007-06-14
申请号：US11633798
申请日：2006-12-05
申请人： Herbert Eichenauer
发明人： Herbert Eichenauer
IPC分类号： C08K3/10
CPC分类号： C08L51/04 , C08K3/22 , C08L55/02 , C08L67/02 , C08L69/00 , G01N2021/6439 , C08L2666/14 , C08L2666/24 , C08L2666/02
摘要： ABS moulding materials containing an addition of at least one compound of the lanthanides, process for the preparation of the moulding materials and a method for identifying ABS moulding materials.
摘要翻译：含有至少一种镧系化合物的ABS成型材料，用于制备成型材料的方法以及用于识别ABS成型材料的方法。

66. 发明授权

US06753366B1 Flame resistant ABS polycarbonate mouldable materials 有权
标题翻译：耐火ABS聚碳酸酯可塑材料
公开(公告)号：US06753366B1
公开(公告)日：2004-06-22
申请号：US09485288
申请日：2000-02-07
申请人： Thomas Eckel , Dieter Wittmann , Herbert Eichenauer , Heinrich Alberts
发明人： Thomas Eckel , Dieter Wittmann , Herbert Eichenauer , Heinrich Alberts
IPC分类号： C08K5523
CPC分类号： C08L51/04 , C08K5/523 , C08L25/12 , C08L27/18 , C08L69/00 , C08L69/005 , C08L2666/02 , C08L2666/14 , C08L2666/04
摘要： A thermoplastic, flame-retardant moulding composition having improved mechanical properties is disclosed. The composition contains 40 to 99 parts by weight of a thermoplastic polycarbonate or polyester carbonate, 0.5 to 60 parts by weight of a graft polymer, 0 to 45 parts by weight of a thermoplastic vinyl copolymer, 0.5 to 20 parts by weight of a mixture of at least one mono- and at least one oligo-phosphorus conforming to the general formula and 0.05 to 5 parts by weight of a fluorinated polyolefine.
摘要翻译：公开了具有改进的机械性能的热塑性阻燃模塑组合物。该组合物包含40至99重量份的热塑性聚碳酸酯或聚碳酸酯，0.5至60重量份的接枝聚合物，0至45重量份的热塑性乙烯基共聚物，0.5至20重量份的至少一种单和至少一种符合通式的低聚磷和0.05-5重量份氟化聚烯烃。

67. 发明授权

US06639000B2 ABS molding compositions having improved processability 失效
标题翻译： ABS成型组合物具有改善的加工性能
公开(公告)号：US06639000B2
公开(公告)日：2003-10-28
申请号：US09955890
申请日：2001-09-18
申请人： Wolfgang Siebourg , Edgar Leitz , Herbert Eichenauer
发明人： Wolfgang Siebourg , Edgar Leitz , Herbert Eichenauer
IPC分类号： C08K520
CPC分类号： C08L25/02 , C08F285/00 , C08K5/103 , C08K5/20 , C08L51/04 , C08L55/02 , C08L2666/24 , C08L2666/14 , C08L2666/04
摘要： An additive mixture containing a dibenzoate and either or both of a compound containing at least one structural unit and a compound containing at least one structural unit is disclosed. The additive combination enhances the processability of a thermoplastic molding composition that contains a (co)polymer of styrene, methyl methacrylate, acrylonitrile, methacrylonitrile, maleic anhydride and N-substituted maleimide and a graft copolymer.
摘要翻译：公开了含有二苯甲酸酯和含有至少一个结构单元的化合物和包含至少一种结构单元的化合物中的一种或两种的添加剂混合物。添加剂组合增强了含有苯乙烯，甲基丙烯酸甲酯，丙烯腈，甲基丙烯腈，马来酸酐和N-取代的马来酰亚胺的共聚合物和接枝共聚物的热塑性模塑组合物的加工性能。

68. 发明授权

US06569951B2 Elastic-thermoplastic graft polymers prepared by multi-stage free radical polymerization 有权
公开(公告)号：US06569951B2
公开(公告)日：2003-05-27
申请号：US09967311
申请日：2001-09-28
申请人： Herbert Eichenauer , Hans-Erich Gasche , Ulrich Jansen
发明人： Herbert Eichenauer , Hans-Erich Gasche , Ulrich Jansen
IPC分类号： C08F27904
CPC分类号： C08L55/02 , C08F279/02 , C08F279/04 , C08L51/04 , C08L2666/14 , C08L2666/02
摘要： An elastic-thermoplastic graft polymer prepared by a multi-stage free radical polymerization is described. The elastic-thermoplastic graft polymer is prepared by polymerizing (i) one or more monomers containing vinyl groups, and (ii) at least one molecular weight regulating compound, in the presence of (iii) at least one rubber in latex form. The ratio of monomers (M) to the molecular weight regulating compound (MWR) is altered throughout the various stages of the polymerization method. The M:MWR ratio is: from 50:1 to 400:1 in the first stage; from 100:1 to 800:1 in the second stage; and from 200:1 to 2000:1 in the third stage of the polymerization. In at least one further reaction stage of the polymerization, the monomers, in the absence of the molecular weight regulating compound, are polymerized in the presence of the rubber. This further reaction stage occurs before the first stage and/or after the third stage of the polymerization. The multi-stage polymerization is conducted such that: M:MWR (first stage)≦M:MWR (second stage)

69. 发明授权

US5719232A ABS type thermoplastic moulding compounds 失效
标题翻译： ABS型热塑性成型料
公开(公告)号：US5719232A
公开(公告)日：1998-02-17
申请号：US424656
申请日：1995-04-19
申请人： Adolf Schmidt , Herbert Eichenauer , Ulrich Jansen
发明人： Adolf Schmidt , Herbert Eichenauer , Ulrich Jansen
IPC分类号： C08F2/22 , C08L55/02
CPC分类号： C08L55/02 , Y10S525/902
摘要： ABS type thermoplastic moulding compounds obtainable by A) producing a rubber latex with an average particle diameter d.sub.50 of 30 to 160 nm and a gel content of 75 to 100 wt. % B) emulsion polymerization of an amount of butadiene and optionally up to 50 wt. % (with reference to the total amount of monomer in stage B) of a comonomer in the presence of the rubber obtained in stage A, such that a rubber latex (B) with an average particle diameter d.sub.50 =220 to 330 nm and a gel content of 25 to 70 wt. % is produced, C) emulsion polymerization of 40 to 95 parts by wt. of a mixture of styrene and acrylonitrile, which optionally contains up to 50 wt. % (with reference to the total amount of monomers used in stage C) of one or more comonomers, in the presence of 5 to 60 parts by wt. (with reference to the solids) of the rubber obtained in stage B by introducing the monomer in such a way that 55 to 90 wt. % of the monomers are added within the first half of the total monomer introduction time, and D) mixing the polymer obtained in stage C, preferably after first converting it into a powder, with at least one thermoplastic vinyl resin.
摘要翻译： ABS型热塑性成型化合物，其可通过以下方法得到：A）制备平均粒径d50为30〜160nm，凝胶含量为75〜100重量％的橡胶胶乳。 B）一定量的丁二烯的乳液聚合和任选的至多50wt。在阶段A中获得的橡胶存在下，共聚单体的％（相对于阶段B中的单体的总量），使得平均粒径d 50 = 220〜330nm的橡胶胶乳（B）和凝胶含量为25〜70wt。产生％，C）乳液聚合40〜95重量份。的苯乙烯和丙烯腈的混合物，其任选地含有至多50重量％在5至60重量份存在下，一种或多种共聚单体的％（相对于阶段C中使用的单体的总量）。（相对于固体），通过以55〜90重量％的比例引入单体，得到阶段B中得到的橡胶。在全部单体引入时间的前半部分内加入％的单体，和D）将在阶段C中获得的聚合物，优选在首先将其转化为粉末之后，与至少一种热塑性乙烯基树脂混合。

70. 发明授权

US5708079A Thermoplastic ABS moulding compositions 失效
标题翻译：热塑性ABS模塑组合物
公开(公告)号：US5708079A
公开(公告)日：1998-01-13
申请号：US642913
申请日：1996-05-06
申请人： Herbert Eichenauer , Edgar Leitz , Karl-Erwin Piejko , Peter Kruger
发明人： Herbert Eichenauer , Edgar Leitz , Karl-Erwin Piejko , Peter Kruger
IPC分类号： C08L51/04 , C08F2/26 , C08F279/00 , C08F279/04 , C08L55/00 , C08L55/02 , C08L101/00
CPC分类号： C08L55/02
摘要： Thermoplastic moulding compositions containing A) 5 to 95 parts by wt of at least one particle-shaped graft rubber polymer of the ABS type manufactured by emulsion polymerization, in which the graft rubber particles have such a structure detectable by transmission electron microscope photographs, in which the individual particles contain irregular cell-shaped inclusions of resin-forming polymer and the surface of the particles shows such an irregular toothed structure, that for every particle imaged 5 to 30 of such teeth are present, which are distinguished from an idealized round particle (with a diameter d) by a diameter d+d/x with x=3 to 15, B) 95 to 5 parts by wt of at least one particle-shaped graft rubber polymer of the ABS type manufactured by emulsion polymerization, in which the graft rubber particles have such a structure detectable by transmission electron microscope photographs, in which the individual particles do not have a pronounced inner structure as in A) and possess a round particle shape with completely tooth-free surface and optionally C) 0 to 300 parts by wt of at least one thermoplastic rubber-free resin.
摘要翻译：含有A）5〜95重量份的通过乳液聚合制造的ABS型的至少一种颗粒状接枝橡胶聚合物，其中接枝橡胶颗粒具有通过透射电子显微镜照片可检测的结构，其中单个颗粒含有不规则的形成树脂的聚合物的细胞形夹杂物，并且颗粒的表面显示出这种不规则的齿状结构，对于存在这种齿的5至30个的每个颗粒，其与理想化的圆形颗粒直径d）直径d + d / x，x = 3〜15，B）95〜5重量份的通过乳液聚合制造的ABS型的至少一种颗粒状接枝橡胶聚合物，其中接枝橡胶颗粒具有通过透射电子显微镜照片可检测的结构，其中单个颗粒不具有如A）中明显的内部结构，并具有具有完全无牙表面的圆形颗粒形状和任选的C）0至300重量份的至少一种不含热塑性橡胶的树脂。

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